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钽处理对钛基IrO_2电极组织及放氧行为的影响 被引量:7

The Effect of Ta Surface Treatment on the Microstructure and Behavior of Oxygen Evolution of IrO_2-Ti Anode
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摘要 研究了草酸刻蚀和钽处理对钛基IrO_2阳极的显微结构及放氧寿命的影响,重点研究了钽处理的影响。结果表明,经钽处理后的钛基IrO_2电极,涂层与基体结合良好;阳极的电催化活性提高;活性层内形成的Ta_2O_5系阀性金属氧化物,可提高活性层的抗钝化性,放氧寿命延长。 The effect of oxalic acid etching and Ta surface treatment on the microstructure and behavior of oxygen evolution of IrO_2-Ti anode are studied. The results show that after treated by tantalum, a good bond between the coating and the substrate has been achieved. The electro-catalytic activity of the anode has been increased. Passivation resistance of the active layer can be raised by Ta_2O_5 formed in the layer, the life of oxygen evolution has been prolong.
出处 《稀有金属材料与工程》 SCIE EI CAS CSCD 1993年第1期59-67,共9页 Rare Metal Materials and Engineering
关键词 钽处理 电催化活性 钛基阳极 Ta surface treatment Ti anode electro-catalytic activity life of oxygen evolution
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