摘要
用电化学循环伏安法和计时电位法研究了葡萄糖在碳纳米管 /纳米TiO2 膜载Pt (CNT/nano TiO2 /Pt)复合电极上的电催化氧化 .结果表明 ,在碱性介质中CNT/nano TiO2 /Pt复合电极对葡萄糖的电氧化具有高催化活性 ,葡萄糖氧化峰电流密度高达 13mA/cm2 ,比铂电极上的增大一倍 ;复合电极性能稳定 ,抗中毒能力强 ,不易发生氧化振荡 ,是葡萄糖燃料电池和葡萄糖传感器的高活性催化电极 .
Electrocatalytic oxidation of glucose on carbon nanotube/nanocrystalline TiO2 film loaded Pt (CNT/nanoTiO(2)/Pt) complex electrode was investigated by cyclic voltammetry and chronopotentiometry. The results indicated that CNT/nano-TiO2/Pt complex electrode has high catalytic activity to the electrochemical oxidation of glucose in alkaline media, and the peak current density of oxidation of glucose is up to 13 mA/cm(2), which is one time higher than that on a platinum electrode. The complex electrode performance is stable, and it is strong resistant to poisoning and difficult to oxidize oscillatory. It is a highly catalytic electrode for using in glucose fuel cell and glucose sensor.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
2004年第24期2403-2406,共4页
Acta Chimica Sinica
基金
安徽省自然科学基金 (No.0 0 0 4 531 7)
安徽省高校科研基金(Nos.2 0 0 3kj1 4 1
2 0 0 4kj1 64zd)资助项目
