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Ag-Al_2O_3催化剂选择性催化还原稀薄燃烧NO_x的研究

STUDY ON Ag-Al_2O_3 CATALYSTS FOR SELECTIVE CATALYTIC REDUCTION OF NO_X IN RAREFIED BURNING
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摘要 本研究主要考察了丙烯为还原剂 ,溶胶 凝胶和共沉淀两种方法制备的Ag Al2 O3催化剂的活性 ,实验结果表明Ag(5 ) Al2 O3(SG)催化剂具有最高的活性。同时详细考察了C3H6 浓度、NO浓度和空速等因素对Ag(5 ) Al2 O3(SG)催化剂活性的影响 ,实验结果表明该催化剂在高空速条件下仍然具有良好的性能。此外 ,还考察了乙烯、丙烷和辛烷为还原剂 ,Ag(5 ) Al2 O3(SG)催化剂的活性 ,实验结果表明以辛烷为还原剂 ,该催化剂还原NOx 的活性 。 Ag-Al_2O_3 catalysts prepared by sol-gel and coprecipitation methods were used for selective catalytic reduction of NO_X by propene in the presence of oxygen.The Ag(5)-Al_2O_3(SG) was found to be the most active catalyst for NO_X selective catalytic reduction.The influences of C_3H_6 concentration,No concentration and space velocity on the activities of the catalyst for the selective catalytic reduction of NO_X with propene in the presence of oxygen were investigated in detail.The result showed that the activity of the catalyst was high even at very high space velocity.In addition,the activities of the catalyst for selective catalytic reduction of NO_X with ethylene,propane and octane as reductants were studied, respectively.It could be concluded that the catalytic activity of the catalyst,especially in low temperature region, was markedly improved using octane as reductant.
出处 《环境工程》 CAS CSCD 北大核心 2004年第6期39-42,共4页 Environmental Engineering
基金 国家高新技术发展计划 (863)计划资助 (2 0 0 1AA6430 0 30 ) 云南省自然科学基金项目 (2 0 0 1EQ0 0 5)
关键词 催化剂活性 AL2O3 还原剂 低温活性 空速 丙烯 丙烷 SG NO浓度 实验结果 Ag-Al_2O_3, sol-gel, co-precipitation, nitrogen oxides and selective catalytic reduction
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  • 1M. Iwamato, Proc. of symposium on catalytic technology for the removal of nitrogen oxides. Catalysis Soc. Janpan 1990.17.
  • 2M. Sheff. Selective catalytic reduction of NOx with N-free reductants,Chemical Review 1995,95:209 - 225.
  • 3M. Iwamoto, H. Yahiro, Novel catalytic decomposition and reduction of NO. Catalysis Today, 1994.22:5 - 18.
  • 4M. Iwamato, Heterogeneous catalysis for removal of NO in excess oxygen process in 1994. Catalysis Today, 1996.29:29 - 35.
  • 5H. Hamada, Selective reduction of NO by hydrocarbom and oxygenated hydrocarbons over metal oxides catalysts. Catalysis Today, 1994.22:21 -40.
  • 6T. Tabata, M. Kokitsu, O. Okada, Study on patent literature of catalysts for a new NOx removal process. Catalysis Today, 1994.22 : 147 - 169.
  • 7R. Burch and P. J. Millington, Selective reduction of nitrogen oxides by hydrocarbons under lean-burn conditions using supported platinum grou pmetal catalysts. Catalysis Today, 1995.26 : 185 - 206.
  • 8T. Miyadera, Alumina-supported silver catalysts for the selective reduction of nitric oxide with propene and oxygen-containing organic compounds.Applied. Catalysis. B : Evironmental, 1993.2 : 199 - 205.
  • 9T. Miyadera, K. Yoshida. Alumina-supported catalysts for the selective reduction of nitric oxide by propenes, Chemistry Letters, 1993:1483 - 1486.
  • 10T. E. Hoost, R. J. Kudla, K. M. Collins, et al. Characterization of Ag/Al2 O3 catalysts and their lean-NOx properties. Applied Catalysis B :Environmental, 1997.13 : 59 - 67.

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