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Structure and Catalytic Behavior of CuO-ZrO-CeO_2 Mixed Oxides 被引量:1

Structure and Catalytic Behavior of CuO-ZrO-CeO_2 Mixed Oxides
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摘要 The effect of doping CuO on the structure and properties of zirconia ceria mixed oxide was studied. The results show that addition of CuO decreases the reduction temperature of ceria, and stabilizes the cubic structure of mixed oxides, and enhances catalytic activity of CuO ZrO CeO 2 mixed oxides for CO oxidation. Increasing ceria content in the mixed oxides can enhance the catalytic activity, but some impurities such as sulfate make catalytic activity falling. There is little effect of calcination temperature on catalytic activities, implying that these catalysts are effective with good thermal stability. The effect of doping CuO on the structure and properties of zirconia ceria mixed oxide was studied. The results show that addition of CuO decreases the reduction temperature of ceria, and stabilizes the cubic structure of mixed oxides, and enhances catalytic activity of CuO ZrO CeO 2 mixed oxides for CO oxidation. Increasing ceria content in the mixed oxides can enhance the catalytic activity, but some impurities such as sulfate make catalytic activity falling. There is little effect of calcination temperature on catalytic activities, implying that these catalysts are effective with good thermal stability.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2002年第5期533-537,共5页 稀土学报(英文版)
关键词 rare earths mixed oxide CO oxidation copper oxide rare earths mixed oxide CO oxidation copper oxide
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  • 1Meng-Fei Luo,Guang-Lie Lu,Xiao-Ming Zheng,Yi-Jun Zhong,Ting-Hua Wu.Redox Properties of CexZr1?xO2 Mixed Oxides Prepared by the Sol–gel Method[J].Journal of Materials Science Letters.1998(18)

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