摘要
The manganese(Ⅲ) complex [Mn (acacen) {N (CN)2}]n [H2acacen =bis (acetylacetone)ethylenediimine] has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridge ligandμ1,5-[N(CN)2]- linking [Mn(acacen)] moiety. The magnetic property of the compound (75～300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain. CCDC: 244940.
The manganese(III) complex [Mn(acacen){N(CN)(2)}](n) [H(2)acacen=bis(acetylacetone)ethylenediimine] has been synthesized and the structure has been determined. The complex forms a one-dimensional chain structure via the bidentate bridge ligand mu(1,5)-[N(CN)(2)](-) linking [Mn(acacen)] moiety. The magnetic property of the compound (75similar to300 K) shows the existence of an antiferromagnetic exchange interaction among paramagnetic centers along the chain.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2004年第12期1463-1466,共4页
Chinese Journal of Inorganic Chemistry
基金
江苏省高校自然科学基金(No.03KJB150118)
江苏省有机合成重点实验室开放基金资助项目
