摘要
本文用流动余辉技术研究了亚稳态原子Ne(~3P_(0,2))与CH_3F、CHF_2Cl、CH_2I_2等分子的传能反应,获得了自由基碎片CH(A,B,C)、CH_2(b^1B_1)和CF_2(A^1B_1)的化学发光光谱,并初步探讨了反应机理。
Energy-- transfer reactions between Ne(~3P_o, 2) and CH_3F, CHF_2C_1, CH_2I_2molecules have been investigated via the Flowing Afterglow technology.The chemical emission spectra of radicals CH(A, B, C), CH_2(b^1B_l)and CF_2(A^1B_1)are obtained and the reaction mechanism discussed.
关键词
亚稳态原子
传能反应
卤代甲烷
metastable atom
energy--transfer reaction
halide methane molecule