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河南小秦岭金矿区黄铁矿的红外光谱研究 被引量:2

STUDY ON PYRITE INFRARED SPECTRA OF GOLD DEPOSIT IN XIAO QINLING DISTRICT OF HENAN PROVINCE
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摘要 本文主要报道了河南小秦岭金矿区的不同矿体位置的黄铁矿(FeS_2)的红外反射光谱,讨论了其声子结构及低频端Plasmon反射边的物理起源,并且用低温实验和有关光谱计算证明了有关结论,还根据所确定的Plasmon效应系数X值,发现与相应的样品中的杂质Pb,Cu,Au等元素在量值上存在一定的正相关性。 The far-infrared reflectance spectra of FeS_2(pyrite) samples collected from different positions of a gold deposit in Xiao Qinling district of Henan province of China are reported in this paper. The physical origins of phonon spectra structures and the sample of FeS_2 plasmon reflectance edge are discussed. Some conclusions are proved by the low-temperature experiments and theoritical calculations. In addition, the different X values of different samples of FeS_2 are determined by the plasmon effects that are caused by assembled oscillations of free carriers of intreband,and we found that the X values have positive correlations with the natural impurities: Au, Pb, Cu. Perhaps this positive correlations are of some ignificance in applications.
出处 《矿物岩石》 CAS CSCD 1993年第3期4-11,共8页 Mineralogy and Petrology
关键词 黄铁矿 红外光谱 相关性 金矿区 pyrite infrared spectra plasmon reflectance edge impurity correlation
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参考文献3

  • 1刘靓娴,肖树建.黄铁矿热电系数用于找金的一个实例[J].地质与勘探,1991,27(6):35-42. 被引量:4
  • 2S. B. Lalvani,A. Weston,J. T. Masden. Characterization of semiconducting properties of naturally occurring polycrystalline FeS2 (pyrite)[J] 1990,Journal of Materials Science(1):107~112
  • 3H. D. Lutz,G. W?schenbach. Infrared reflection spectra, directional dispersion of the phonon modes and dynamical effective charges of FeS2-Marcasite[J] 1985,Physics and Chemistry of Minerals(3):155~160

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