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阴极保护下高绝缘性能防护层的电化学阻抗谱特征 被引量:2

EIS CHARACTERISTICS OF PERFECTLY INSULATED COATING SYSTEMS UNDED CATHODIC PROTECTION POTENTIAL
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摘要 利用电化学阻抗谱 (EIS)方法研究高绝缘性能防护层 /碳钢试片体系 ,测定阴极极化电位下 4种常用防护层的EIS谱图 .分析它们在 0 6mol/LNaCl溶液和土壤中的阻抗谱特征 ,研究结果表明 ,Bode图及电化学等效电路解析得到的防护层电容 (Cf)值可用来对防护层质量进行表征 . Four kinds of perfectly insulated coating systems in common use was studied by electrochemical impedance spectroscopy(EIS).Their EIS characteristics under cathodic polarization potential in 0.6 mol/L NaCl and in soil respectively were analyzed.We tried to obtain evaluating method for coating quality.The study result demonstrated that the Bode figure and the C f value obtained according to equivalent circuit for the corrosion behavior of a polymer-coated metal could be used to evaluate coating quality.
出处 《腐蚀科学与防护技术》 CAS CSCD 北大核心 2004年第6期392-394,共3页 Corrosion Science and Protection Technology
基金 国家重点基础研究专项经费资助 (G19990 65 0 )
关键词 防护层 电化学阻抗谱 碳钢 阴极保护 EIS 阴极极化 电位 绝缘性能 等效电路 用电 EIS cathodic polarization potential coating quality
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参考文献4

  • 1Q Le Thu, G P Bierwagen, S Touzain. EIS and ENM measurements for three different organic coatings on aluminum [J].Progress in Organic Coatings, 2001,42:179.
  • 2Darowicki K. The application of impedance measurements for the determination of the probability of the course of corrosion processes[J]. Corrosion Science, 1997, 39(6): 1087.
  • 3Bierwagen G, Tallman D, Li junping. EIS studies of coated metals in accelerated exposure [J]. Progress in organic coatings,2003, 46(2): 149.
  • 4Fedrizzi L, Deforian F et al. Evaluation of the protective properties of organic coatings on copper pipes for refrigerator cooling circuit[J]. Electrochimica Acta, 1999 44 (24) :4251.

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