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One-step Synthesis of n-Butanol from Ethanol Condensation over Alumina-supported Metal Catalysts 被引量:4

One-step Synthesis of n-Butanol from Ethanol Condensation over Alumina-supported Metal Catalysts
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摘要 One-step synthesis of n-butanol from bimolecular condensation of ethanol was firstlyachieved over nickel supported gamma alumina catalyst. A mechanism of dehydration path for thegrowth of carbon chain by eliminating a hydroxy group from one ethanol molecule with a α-H ofother ethanol molecule rather than aldol condensation was verified. One-step synthesis of n-butanol from bimolecular condensation of ethanol was firstlyachieved over nickel supported gamma alumina catalyst. A mechanism of dehydration path for thegrowth of carbon chain by eliminating a hydroxy group from one ethanol molecule with a α-H ofother ethanol molecule rather than aldol condensation was verified.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第12期1497-1500,共4页 中国化学快报(英文版)
关键词 Ethanol condensation N-BUTANOL nickel supported on gamma alumina DEHYDRATION Ethanol condensation n-butanol nickel supported on gamma alumina dehydration
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