摘要
莰烯在硫酸催化下与1.2-丙二醇反应,制得1-冰片氧基-2-丙醇,产率42.6%.1-冰片氧基-2-丙醇用三氧化铬的硫酸溶液氧化后得到冰片氧基丙酮,产率77.6.上述合成的化合物均进行了MS.IR.HNMR分析和评香鉴定.
The reaction of camphene with 1,3-propanediol in the presence the yield is 42. 6%. The oxidation of 1-bornyloxy 2-propanol by chromic acid affords bornyloxy propanone and the yield is 74. 6%. The products are identified by MS, IR, ' HNMR and their aroma are also determined.
出处
《江西师范大学学报（自然科学版）》
CAS
1993年第2期157-159,共3页
Journal of Jiangxi Normal University(Natural Science Edition)
基金
江西省科委资助项目
关键词
莰烯
合成香料
冰片氧基丙酮
camphene
synthesis of perfumes
O-alkylation
oxidation
