期刊文献+

茜素紫光度法检测超声波辐照水体系产生的羟自由基 被引量:6

Assay of Hydroxy Producted from Ultrasonic Using Alizarin Violet Spectphotometry
在线阅读 下载PDF
导出
摘要 为了了解超声作用与羟自由基产量的关系,利用茜素紫能被羟自由基及过氧化氢(H2O2)所氧化而改变颜色的性质,用紫外 可见分光光度计测定超声作用后茜素紫溶液在515nm波长处吸光度的变化,从而间接地检测羟自由基的产量。研究结果表明,羟自由基的产量随单位体积超声输出功率增加而增加。在输出体积功率约为12W/cm3时羟自由基的产量基本达到饱和,同时,在该输出功率下超声波作用产生的羟自由基与超声作用时间呈良好的线性关系。 In order to grasp the relationships between the cavitations and the amount of radicals produced with the effects of ultrasonic cavitations, a method of detecting hydroxy radicals by chromogenic reaction of oxidation of alizarin violet was introduced in this paper. The amount of hydroxy produced by ultrasonic cavitations can be calculated indirectly by the value of absorbency of alizarin violet solutions in UV absorption spectrum. The results indicate that with the increase of the ultrasonic output power, the amount of hydroxy increases accordingly. When the ultrasonic output power reaches the value of 12 W/cm^3, the produces of hydroxy are almost saturated and there is a linear relationship existing between the time of ultrasonic treatment and the produces.
出处 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2004年第5期793-796,共4页 Journal of Central South University:Science and Technology
基金 国家重大基础研究发展规划项目(G1999064892 2)
关键词 超声波 空化作用 羟自由基 茜素紫 ultrasonic cavitation hydroxy alizarin violet
  • 相关文献

参考文献14

  • 1CASTELLANOS M M, REYMAN D, SIEIRO C, et al. ESR-spin Trapping Study on the Sonochemistry of Liquids in the Presence of Oxygen: Evidence for the Superoxide Radical Anion Formation[J]. Ultrasonic Sonochemistry, 2001,8(1):17-22.
  • 2VERCET A, LOPEZ P, BURGOS J, et al. Free Radical Production by Manothermosonication[J]. Ultrasonics, 1998,36(2):615-618.
  • 3KUIJPERS M W, KEMMERE M F, KEURENTJES J T, et al. Calorimetric Study of the Energy Efficiency for Ultrasound-induced Radical Formation[J]. Ultrasonics, 2002, 40 (5):675-678.
  • 4P(E)TRIER C, FRANCONY A. Ultrasonic Waste-water Treatment: Incidence of Ultrasonic Frequency on the Rate of Phenol and Carbon Tetrachloride Degradation[J]. Ultrasonics Sonochemistry, 1997,4(4):295-300.
  • 5AMIT J, CHATTERJEE K. Estimation of Hydroxyl Free Radicals Produced by Ultrasound in Fricke Solution Used as a Chemical Dosimeter[J]. Ultrasonics Sonochemistry, 1995,12(3):87-91.
  • 6赵逸云,冯若,杨晓云,鲍慈光,李铷.频率对声致羟自由基形成的影响[J].声学技术,1998,17(1):12-14. 被引量:18
  • 7陈兆华,朱昌平,赵逸云,王惠,冯若.用碘释放法研究低频超声的声化学产额[J].声学技术,1997,16(4):192-193. 被引量:23
  • 8ZHU Ben-zhan, ZHAO Hong-tao, BALARAMAN K, et al. Metal-independent Production of Hydroxyl Radicals by Halogenated Quinines and Hydrogen Peroxide[J]. Free Radical Biology & Medicine,2001,32(5):465-473.
  • 9任凤莲,吴南,吴心传.茜素紫光度法检测H_(2)O_(2)/Co^(2+)产生的羟自由基[J].中南工业大学学报,2000,31(6):514-516. 被引量:8
  • 10吴南,任凤莲,吴心传.茜素紫显色剂检测Fenton反应产生的·OH[J].化学试剂,2001,23(1):42-43. 被引量:9

二级参考文献17

共引文献61

同被引文献116

引证文献6

二级引证文献23

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部