摘要
本试验在无水乙醇介质中用六水合氯化钐与缩二脲反应制得了一种新的配合物,经分析测试得知,该配合物可能的结构式为:〔Sm(BuH_2)_4〕Cl_3,并证实了缩二脲是通过羰基氧原子与S_m^3+配位,且Cl^-未参与配位作用.
In this study, We have obtained a new kind of coordination complex by the reaction of SmCl_3·6H_2O with biruet in anhydrous alcohol.We knew by the determination.The possible constitutional formula of the coordination complex is [SmBuH_2]_4]Cl_3,and the biruet cooperated with Sm^(3+)by the Oxygen of Carbonyl, and the Cl did't cooperated with Sm^(3+).
出处
《河北师范大学学报（自然科学版）》
CAS
1993年第3期43-47,共5页
Journal of Hebei Normal University：Natural Science
关键词
氯化钐
缩二脲
配合物
合成
钐
SmCl_3·6H_2O biruet coordination complex
