摘要
用单扫描示波极谱检测技术,求出钯催化孔雀绿(MG)氧化次磷酸钠体系的反应级数和不同温度下的速率常数,计算了表观活化能。并根据实验事实对反应机理进行了探讨。
The rate constants at different temperature as well as reaction orders of Pd(Ⅱ) -H2PO2--MG system are measured, with single-sweep oscillopolarograpy being detection technique and malachite green indicator. The apparent activation energy is calculated and a reasonable mechanism is proposed.
出处
《广西师范大学学报（自然科学版）》
CAS
1993年第2期48-53,共6页
Journal of Guangxi Normal University:Natural Science Edition
基金
国家自然科学基金资助项目
关键词
示波极谱法
孔雀绿
钯
次磷酸钠
single-sweep oscillopolarography
kinetics
malachite green
palladium
