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电子顺磁共振法测定煤、沥青、石油和沉积岩分散有机质中自由基含量及其在地质上的意义 被引量:1

ESR DETERMINATION OF RADICAL CONTENT IN DISPERSED ORGANIC MATERIAL FROM COAL, ASPHALT, PETROLEUM AND SEDIMENTARY ROCKS AND ITS IMPLICATIONS IN GEOLOGY
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摘要 Method for determining the radical content in dispersed organic matter from coal, asphalt, petroleum and sedimentary rocks by means of ESR is discussed. Factors affecting the results are also considered. The possibility of using radical content as an indicator is suggested for the degree of metamorphism of the dispersed organic matter and for other geologic problems pertaining to sedimentary rocks and deposits.From the variation of relative concentrations of radical in flame coal samples determined after experiments at elevated temperatures and pressures, the maxium temperature to which the flane coal may have been subjected during its evolution and the temperature-pressure limit for the flame coal-fat coal inversion have been predicted. Method for determining the radical content in dispersed organic matter fromcoal, asphalt, petroleum and sedimentary rocks by means of ESR is discussed. Fac-tors affecting the results are also considered. The possibility of using radical contentas an indicator is suggested for the degree of metamorphism of the dispersed organicmatter and for other geologic problems pertaining to sedimentary rocks and deposits.From the variation of relative concentrations of radical in flame coal samples deter-mined after experiments at elevated temperatures and pressures, the maxium tempera-ture to which the flame coal may have been subjected during its evolution and thetemperature-pressure limit for the flame coal-fat coal inversion have been predicted.
出处 《地球化学》 CAS 1975年第1期75-82,共8页 Geochimica
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