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Studies on irradiation stability of polystyrene by NMR

Studies on irradiation stability of polystyrene by NMR
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摘要 The irradiation stability of polystyrene (PS) was studied by 13C and 1H NMR spectra, Nuclear Overhauser Relaxation (NOE) and 13C NMR spin-lattice relaxation time (T1). The results indicate that 13C and 1H NMR chemical shifts, NOE and T1 were almost invariant with the increase of irradiation dose. This shows that polystyrene is particularly stable within 2.5 kGy doses and the mechanism of its stability is discussed. The irradiation stability of polystyrene (PS) was studied by I3C and 'H NMR spectra, Nuclear Overhauser Relaxation (NOE) and I3C NMR spin-lattice relaxation time (T1). The results indicate that I3C and 1H NMR chemical shifts, NOE and T1 were almost invariant with the increase of irradiation dose. This shows that polystyrene is particularly stable within 2.5 kGy doses and the mechanism of its stability is discussed.
机构地区 XinjiangUniversity
出处 《Nuclear Science and Techniques》 SCIE CAS CSCD 2004年第4期216-218,共3页 核技术(英文)
基金 Supported by the Doctor Foundation of Xinjiang University
关键词 辐射稳定性 聚苯乙烯 碳13核磁共振 氢核磁共振 Polystyrene, I3C NMR, 'H NMR, Irradiation stability
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参考文献4

  • 1[1]Charlesby A, Stevens J H. Int J Radiat Phys Chem, 1976,8:719
  • 2[2]Horil F, Kitamaru R, Suzuk T. J Polym Sci Polym Lett,1977, 15:65
  • 3[3]Komoroski R A. High resolution NMR spectroscopy of synthetic polymer in bulk, VCH Publishers, Deerfield Beach, 1986:36
  • 4[4]Fedotov V D, Schneider H. Structure and dynamics of bulk polymers by NMR methods, Berlin:Springer-Verlag, 1989:48

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