摘要
以工业低压法甲醇合成为背景,对文献上各种理想气体状态的平衡常数 K_f 计算式进行了分析与比较,探讨了造成 K_f 计算值之间误差的原因。
Based on the background of industrial'low—pressure'methanol synthesis,the equilibrium con- stants K_f in methanol synthesis in literature since 1930S were appraised.It was found that the obvious devia- tions of K_f values of different authors would be given because of the different basic thermochemical data and the accumulation of the deviations.
关键词
甲醇
合成
理想气体状态
平衡常数
Methanol synthesis
Ideal gas state
Equilibrium constant
