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Fe-Mn-Al-Cr系反铁磁精密电阻合金的探索 被引量:5

An Exploration of Antiferromagnetic Fe-Mn-Al-Cr Precision Resistance Alloys
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摘要 根据作者对Fe-Mn基合金系相变与反铁磁转变的研究结果,提出一种反铁磁性r-Fe-Mn-Al-Cr新精密电阻合金的设计方法。研究了Al与Cr对r-Fe-Mn合金残余电阻率、反铁磁转变及伴随的电阻反常变化的影响,Al增加残余电阻率的作用为0.087/μΩ·m/at%,Cr为0.012μΩ·m/at%。当反铁磁有序散射电阻率的增加适能补偿声子散射电阻率的减少时,合金呈现很小的电阻温度系数。据此,在Fe-Mn基合金中由Mn、Al与Cr的优化组合,研制出具有较好综合性能的两种Fe-Mn-Al-Cr精密电阻合金,它们的工作温度范围、电阻率及温度系数大约分別为180~350K、1.00μΩ·m及-20~+20×10^(-6)K^(-1)。Fe-Mn-Al-Cr精密电阻合金的性能虽低于Karma合金,但前者的显著优点是其性能稳定,对热处理工艺不敏感。 Presents a process of designing antiferromagnetic γ-Fe-Mn-Al-Cr precision resistance alloys on the basic of an investigation on the antiferromagnetic transition and austenite region in Fe-Mn host alloys. Studies the effect of Al or Cr content on the residual resistance, Ne'el transition and anomalous changes of resistance in γ-Fe-Mn alloys. In the case of Fe-Mn-Al-Cr alloys, resiclual resistivity increases by approximately 8.7μΩ·cm and 1.2μΩ·cm for adding l at% Al and l at% Cr, respectively. The temperature coefficient (l/ρ) (dρ/dT) of alloys becomes a minimal value when the decrease in phonon scattering resistivity is compensated by the increase in antiferromagnetic ordered scattering resistivity. By the appropriate combination of Mn. Al and Cr content in γ-Fe-31%Mn host, two of antiferromagnetic γ-Fe-Mn-Al-Cr precision resistance alloys with desirable combination properties have been found. Their temperature range, resistivity and mean temperature cocfficient are about 180K to 350K, 1.0μΩ·m and -20K to+20×10^(-6)K^(-1), respectively. The resistive properties which are insensitive to heat treatment is a excellent character of γ-Fe-Mn-Al-Cr alloy although the resistive properties of γ-Fe-Mn-Al-Cr alloys are somewhat lower than that of karma alloy. Finally, the origin of antiferromagnetic ordered scattering resistance has been discussed in brief.
作者 张彦生
出处 《大连铁道学院学报》 1993年第4期77-83,共7页 Journal of Dalian Railway Institute
基金 国家自然科学基金:59171021
关键词 电阻合金 反铁磁转变 低电阻合金 precision resistance alloys paramagnetic-antiferromagnetic transition Fe-Mn-Al-Cr alloys
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参考文献1

  • 1张彦生,师昌绪.铁-锰、铝系奥氏体钢——耐热钢、无磁钢和低温钢[J]金属学报,1964(03).

同被引文献45

  • 1朱雪梅,王新建,刘明,张彦生.Fe-30Mn-9Al奥氏体钢高温循环氧化特征[J].腐蚀科学与防护技术,2005,17(1):31-33. 被引量:11
  • 2杨亲民.铜镍锰钴应变电阻合金的研究[J].功能材料,1994,25(4):376-384. 被引量:4
  • 3朱雪梅,钟曙晖,张彦生.Fe—Mn─Al合金的腐蚀性能与钝化膜的研究[J].中国腐蚀与防护学报,1996,16(4):275-280. 被引量:4
  • 4张彦生 师昌绪.铁-锰-铝系奥氏体钢--耐热钢、无磁钢和低温钢[J].金属学报,1964,(7):285-285.
  • 5张彦生 Fe Mn.Cr-A1系反铁磁定膨胀合金的研究.科技通报,1993,9(1):6-11.
  • 6ZHANG YAN SHENG, LU XING. Compositional dependence of the Neel transition, structural stability, magnetic properties and electrical resistivity in Fe-Mn-A1-Cr-Si alloys[ J]. Mater. Sci. Eng. ,2002,334(A1 ) : 19-27.
  • 7ZHANG Y S,ZHU X M. Electrochemical polarization and passive film of a cryogenic and non-magnetic steel in aqueous solution [ J ]. Steel Res. , 1993,64 ( 11 ) :564- 569.
  • 8ZHU X M ,ZHANG Y S. Investigation of the electrochemical corrosion behaviour and passive film for Fe-Mn, Fe-Mn-A1, and Fe-Mn-A1-Cr alloys in aqueous solution [ J ]. Corrosion, 1998,54( 1 ) :3-12.
  • 9ZHU X M, ZHANG Y S. An XPS study of passive film formation on Fe-30Mn-9Alalloy in sodium sulphate solution [ J ]. Applied Surface Science, 1998,125 : 11-16.
  • 10ZHU X M ,ZHANG Y S. Electrochemical polarization and passive film of austenitic Fe-Mn-A1-Cr alloy in aqueous solutions [ J ]. British Corrosion Journal, 1997,32: 127- 131.

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