α,β-环氧酮化合物中环氧化部分的转化及应用
Transformation and Application of Epoxide in α,β-Epoxy Ketone Compound
摘要
本文讲述了有机合成中光学活性的α,β-环氧酮化合物中环氧化部分在不同试剂下的转化,并列举了一些相关的合成应用。
This article discusses the transformation of epoxide in optically activeα,β-epoxy ketones under different reagents and enumerates some synthetic applications of this kind of transformation.
出处
《阴山学刊(自然科学版)》
2008年第4期25-29,共5页
Yinshan Academic Journal(Natural Science Edition)
基金
包头师范学院自然科学基金(Nos.BS2006012027)
关键词
环氧酮
环氧化合物
转化
Epoxy ketone
Epoxide
Transformation
参考文献11
-
1Molander G A,,Hahn G.Lanthanides in Organic Synthesis.4. Reduction ofα,β-epoxy Ketones with Samarium Diiodide.A Route to Chiral,Nonracemic Aldols. Journal of Organic Chemistry . 1986
-
2Miyashita M,Suzuki T,Yoshikoshi A.Synthesis of Dehydroisoerivanin, Isoerivanin,Ludovicin C,and 1α,3α-Dihydroxyarbusculin B Utilizing the Organoselenium-mediated Reduction of Epoxy Ketone. Chemistry Letters . 1987
-
3Miyashita M,Suzuki T,Hoshino M,Yoshikoshi A.The Organoselenium -mediated Reduction ofα,β-epoxy Ketones,α,β-epoxy Esters,and Their Congeners toβ-hydroxy Carbonyl Compounds: Novel Methodologies for the Synthesis of Aldols and Their Analogues. Tetrahedron . 1997
-
4Mukaiyama T,Arai H.A New Method for the Synthesis of Unsymmetrical Bis-Aldols by the Samarium(Ⅱ)Iodide-Mediated Aldol Reaction of Aldehydes with Aryl or Alkyl Oxiranyl Ketones. Chemistry Letters . 2000
-
5McElroy A.B,,Warren S.Stereocontrolled(E,Z and erythro, threo)Synthesis ofβ-hydroxyallylic Sulphides. Tetrahedron Letters . 1985
-
6Domalaga J M,Bach R D.Lewis Acid Catalyzed Acyl Migration with Optically Active(Z)-and(E)-1,3-Diphenyl-2-buten -1-one Oxide.Evidence of a concerted pathway. Journal of the American Ceramic Society . 1978
-
7Tsankova E,Enev V,Simova S.Intramolecular Cyclisation ofα,β-epoxy-artemisia ketone. Tetrahedron . 1984
-
8Ito S,Sato M.A Simple Synthetic Method of Trans-5-Aryl and 5-Cyclopropyl Derivatives of 2-Isoxazolin-4-ol via Intramolecular Ring Opening ofα,β-Epoxy Ketone Oximes. Bull.Chem.Soc.Jpn . 1990
-
9Donnely J,A,,Farrell D F.The Chemistry of 2‘-amino analogs of 2‘-hydroxychalcone and its Derivatives. Journal of Organic Chemistry . 1990
-
10Chen W P,Egar A L,Hursthouse M B,Roberts S M.Synthesis of Optically Active 2,3-substituted-1,2,3,4-tetrahydro-4 -quinolones Using Polyleucine. Tetrahedron Letters . 1998
-
1雍胜利,宫慧丽.环氧酮化合物中酮羰基的转化及应用[J].阴山学刊(自然科学版),2007,21(4):53-57.
-
2范荣玉,郑细鸣.无皂乳液聚合法制备单分散大粒径聚苯乙烯微球研究[J].广西轻工业,2007,23(2):34-36. 被引量:1
-
3唐系封.关于炔烃亲电加成与亲核加成本质的探讨[J].高等函授学报(自然科学版),2001,14(1):26-29.
-
4郎春燕,林龙飞,魏建军,徐进勇,张路,夏祥,吴晓蓉,周莉.化学试剂络合对改性活性炭吸附痕量铂、钯的影响[J].化学试剂,2014,36(3):248-250.
-
5宁静恒,许晓武.Mitsunobu反应不同试剂和条件应用研究[J].中国科技成果,2008,9(12):32-34.
-
6吴芳英,嵇志琴,黄坚锋.一类与铍、硼形成杂多核配合物试剂的荧光性能研究[J].化学试剂,1999,21(2):71-72.
-
7杨明艳,张莉,王道全,王明安.反式-3-苯基-12-取代环十二酮的合成及晶体结构[J].高等学校化学学报,2017,38(3):403-412.
-
8王新一,谢亚娟.试剂对亲核取代反应历程的影响[J].天津化工,1999,13(5):27-28.
-
9马稳,甘雄.火焰原子吸收法测定夏桑菊中的10种微量元素[J].分析科学学报,2004,20(4):442-443. 被引量:4
-
10屠兰英,付华,赵启文.不同试剂对硝酸钾结晶习性和结块性的影响[J].青海大学学报(自然科学版),2010,28(6):31-33. 被引量:2