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Novel Catalytic Hydrodechlorination of CCl_2F_2 over Supported PdCl_2-(n-C_4H_9)_4N^+Cl^- Molten salts

Novel Catalytic Hydrodechlorination of CCl_2F_2 over Supported PdCl_2-(n-C_4H_9)_4N^+Cl^- Molten salts
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摘要 A novel supported liquid phase film catalyst: Supported PdCl2-(n-C4H9),N+Cl- molten salts was found to be an effective catalyst with good stability for selective hydrodechlorination of CCl2F2 (CFC-12) to its alternatives CH2F2 and CHClF2. Addition of CoCl2, GaCl3 and CuCl2 to PdCl2-(n-C4H9),N+Cl- modifies the catalytic performance of supported molten salts. A novel supported liquid phase film catalyst: Supported PdCl2-(n-C4H9),N+Cl- molten salts was found to be an effective catalyst with good stability for selective hydrodechlorination of CCl2F2 (CFC-12) to its alternatives CH2F2 and CHClF2. Addition of CoCl2, GaCl3 and CuCl2 to PdCl2-(n-C4H9),N+Cl- modifies the catalytic performance of supported molten salts.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第6期533-536,共4页 中国化学快报(英文版)
关键词 Liquid film catalyst palladium chloride tetrabutylammonium chloride molten salts CFC-12 hydrodechlorination HFC-32 HCFC-22 Liquid film catalyst palladium chloride tetrabutylammonium chloride molten salts CFC-12 hydrodechlorination HFC-32 HCFC-22
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