New Palladium-Imidazole and Imidazoline Complexes:Structures and Reactivity in Coupling Reaction

New Palladium-Imidazole and Imidazoline Complexes:Structures and Reactivity in Coupling Reaction

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摘要 1 Results We have recently reported the Mizoroki-Heck reaction catalyzed by PdCl2 and imidazole ligands[1]. During the course of our study of palladium imidazole complex,we disclosed the synthesis of trans-Pd(Ln)2Cl2 by the reaction of PdCl2 with Ln (where L1=2-phenylimidazole,L2=2-phenylimidazole) in a 1∶2 molar ratio.The single crystals of trans-Pd(L1)2Cl2·2DMF (1a) and trans-Pd(L2)2Cl2 (2a) were obtained by following slow evaporation of DMF as a solvent. The single crystal of trans-Pd(L2)2Cl2 (2b) w...

作者 Satoshi Haneda Kazuo Eda Masahiko Hayashi

机构地区 Department of Chemistry

出处《复旦学报（自然科学版）》 CAS CSCD 北大核心 2007年第5期768-,共1页 Journal of Fudan University：Natural Science

关键词 palladium complex IMIDAZOLE IMIDAZOLINE X-ray analysis coupling reaction Mizoroki-Heck reaction palladium complex imidazole imidazoline X-ray analysis coupling reaction Mizoroki-Heck reaction

分类号 O626 [理学—有机化学]

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1Haneda S,Okui A,Ueba C,et al. Tetrahedron . 2007
2Haneda S,Ueba C,Eda K,et al. Advanced Synthesis and Catalysis . 2007

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复旦学报（自然科学版）

2007年第5期

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New Palladium-Imidazole and Imidazoline Complexes:Structures and Reactivity in Coupling Reaction

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