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无限稀金属溶液的活度系数与温度的关系及其应用 被引量:1

RELATIONSHIP BETWEEN ACTIVITY COEFFICIENT AND TEMPERATURE IN INFINITE DILUTE METAL SOLUTIONS AND ITS APPLICATION
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摘要 在热力学近似和实验数据验证的基础上,推证出无限稀金属溶液的活度系数与温度的关系为lnу_i~∞=b/T+α通过此式,可将Wilson方程推广到由某温度下无限稀金属溶液的实验数据■和■估算所需温度下二元和三元液态合金的热力学性质。 Based on the thermodynamic approach and the verification of experiment al data, relationship between activity coefficient and temperature in infinite dilute metal solutions was proposed as With the aid of the equation above, the Wilson equation can be extended to calculating the thermodynamic properties of binary and ternary liquid alloys using the experimental data of and at interested temperatures.
作者 陶东平
机构地区 昆明工学院
出处 《有色金属》 CSCD 1993年第3期59-63,共5页 Nonferrous Metals
关键词 活度 无限稀溶液 WILSON方程 activity infinite dilute solution Wilson equation
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参考文献1

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同被引文献38

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