摘要
Solar-driven photocatalytic CO_(2) hydrogenation to high value-added carbon hydrocarbon compounds(C_(2+))is an ideal pathway to solve energy shortages and environmental concerns.Nevertheless,the prepara-tion of specific C2+compounds from CO_(2) is very challenging because of the need to overcome issues such as C=O bond activation,C-C bond coupling and the highly stable structure of CO_(2)[l].In recent years,it has been widely accepted that the identification of active sites for CO_(2) adsorption and activation by catalysts is a prerequisite for the realization of CO_(2) hydrogenation reactions.Therefore,the construction of appro-priate active sites is the key to improve the efficient conversion of CO_(2) and product selectivity[2].
基金
supported by NationalNatural Science Foundation of China(22172086,22105117)
the Major Basic Research Project of Shandong Province(ZR2021ZD06)
Taishan Scholars Program of Shandong Province(No.tsqn202103064)
Natural Science Foundation of Shandong Province(ZR2022MB078).
