摘要
Ullmann coupling is a powerful and versatile C-C bond formation re-action widely used in the synthesis of various organic intermediates[1].Aryl chlorides are considered ideal substrates due to their low cost and easy availability.However,the activation of aryl chlorides requires higher temperatures,as the dissociation energy of C-Cl bonds is high[2].
基金
supported by the National Key Research and Deve lopment Program of China(2020YFA0211004)
the National Natural Science Foundation of China(22376143,22176128,22236005)
Innovation Program of ShanghaiMunicipal Education Commission(2023ZKZD50)
Program of Shanghai Academic Research Leader(21XD1422800)
Shanghai Government(22dz1205400,23520711100),Chinese Education Ministry Key Laboratory and International Joint Laboratory on Resource Chemistry,and Shanghai Eastern Scholar Program
the'111 Innovation and Talent Recruitment Base on Photochemical and Energy Materials'(No.D18020)
Shanghai Engineering Research Center of Green Energy Chemical Engineering(18DZ2254200)and Shanghai Frontiers Science Center of Biomimetic Catalysis.
