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Local Strain Engineering of Two-Dimensional Transition Metal Dichalcogenides Towards Quantum Emitters
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作者 Ruoqi Ai Ximin Cui +1 位作者 Yang Li Xiaolu Zhuo 《Nano-Micro Letters》 2025年第5期78-116,共39页
Two-dimensional transition metal dichalcogenides(2D TMDCs)have received considerable attention in local strain engineering due to their extraordinary mechanical flexibility,electonic structure,and optical properties.T... Two-dimensional transition metal dichalcogenides(2D TMDCs)have received considerable attention in local strain engineering due to their extraordinary mechanical flexibility,electonic structure,and optical properties.The strain-induced out-of-plane deformations in 2D TMDCs lead to diverse excitonic behaviors and versatile modulations in optical properties,paving the way for the development of advanced quantum technologies,flexible optoelectronic materials,and straintronic devices.Research on local strain engineering on 2D TMDCs has been delved into fabrication techniques,electronic state variations,and quantum optical applications.This review begins by summarizing the state-of-the-art methods for introducing local strain into 2D TMDCs,followed by an exploration of the impact of local strain engineering on optical properties.The intriguing phenomena resulting from local strain,such as exciton funnelling and anti-funnelling,are also discussed.We then shift the focus to the application of locally strained 2D TMDCs as quantum emitters,with various strategies outlined for modulating the properties of TMDC-based quantum emitters.Finally,we discuss the remaining questions in this field and provide an outlook on the future of local strain engineering on 2D TMDCs. 展开更多
关键词 Two-dimensional transition metal dichalcogenides Local strain Excitonic behaviors Quantum emitters
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Role of root morphological and architectural traits:Insights into root-inspired anchorage and updates foundation systems
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作者 Wengang Zhang Ruije Huang +5 位作者 Jiaying Xiang Ningning Zhang Matteo Oryem Ciantia Leilei Liu Jian Yin Changbing Qin 《Biogeotechnics》 2025年第1期72-74,共3页
Plant root systems,a crucial component of biogeotechnics,have been recognized as a promising and sustainable strategy to address novel challenges in geotechnical engineering,i.e.,climate change(Ng et al.,2022).Root-so... Plant root systems,a crucial component of biogeotechnics,have been recognized as a promising and sustainable strategy to address novel challenges in geotechnical engineering,i.e.,climate change(Ng et al.,2022).Root-soil composite and root-reinforced slopes have re-ceived widespread attention in recent decades,due to the ability of root to regulate soil properties through mechanical reinforcement and hy-draulic transpiration(Li&Duan,2023;Ni et al.,2024).Fig.1 provides a co-occurrence network plot of plant root-based soil reinforcement strategies published over the last decade,where three clusters are identified with different colors.On the left of the network map,clusters in red and blue are primarily driven by geotechnical investigations of vegetated slopes(i.e.,plant root reinforced slopes)and root-soil com-posite/root-permeated soils,as denoted by the terms like"model","test","slope","strength"and"vegetation",while the green cluster on the right side demonstrates botany-related domains,for instance,"plant growth",Indeed,the reinforcement of vegetated soil strength is com-plex and varies significantly with an abundance of factors,both me-chanically and hydraulically.Particularly,the impact of root mor-phology and architecture cannot be negligible,including keywords"root area ratio"root distribution""root morphology"root diame-ter"root density"in Fig.1 with the root size and root depth ranking foremost. 展开更多
关键词 root architecture regulate soil properties root morphology plant root systemsa root soil composite plant root geotechnical engineeringieclimate change ng mechanical reinforcement
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Trending and emerging prospects of physics-based and ML-based wildfire spread models:a comprehensive review
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作者 Harikesh Singh Li‑Minn Ang +4 位作者 Tom Lewis Dipak Paudyal Mauricio Acuna Prashant Kumar Srivastava Sanjeev Kumar Srivastava 《Journal of Forestry Research》 2025年第1期27-59,共33页
The significant threat of wildfires to forest ecology and biodiversity,particularly in tropical and subtropical regions,underscores the necessity for advanced predictive models amidst shifting climate patterns.There i... The significant threat of wildfires to forest ecology and biodiversity,particularly in tropical and subtropical regions,underscores the necessity for advanced predictive models amidst shifting climate patterns.There is a need to evaluate and enhance wildfire prediction methods,focusing on their application during extended periods of intense heat and drought.This study reviews various wildfire modelling approaches,including traditional physical,semi-empirical,numerical,and emerging machine learning(ML)-based models.We critically assess these models’capabilities in predicting fire susceptibility and post-ignition spread,highlighting their strengths and limitations.Our findings indicate that while traditional models provide foundational insights,they often fall short in dynamically estimating parameters and predicting ignition events.Cellular automata models,despite their potential,face challenges in data integration and computational demands.Conversely,ML models demonstrate superior efficiency and accuracy by leveraging diverse datasets,though they encounter interpretability issues.This review recommends hybrid modelling approaches that integrate multiple methods to harness their combined strengths.By incorporating data assimilation techniques with dynamic forecasting models,the predictive capabilities of ML-based predictions can be significantly enhanced.This review underscores the necessity for continued refinement of these models to ensure their reliability in real-world applications,ultimately contributing to more effective wildfire mitigation and management strategies.Future research should focus on improving hybrid models and exploring new data integration methods to advance predictive capabilities. 展开更多
关键词 Wildfire spread Fire prediction models Cellular automata model WRF-Fire/SFire FIRETEC CAWFE WFDS
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High-Precision and Ultraspeed Monitoring of Melt-Pool Morphology in Laser-Directed Energy Deposition Using Deep Learning
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作者 Jiayu Yang Guan Liu +4 位作者 Wei Zhu Yingjie Zhang Wenbin Zhou Defu Liu Yongcheng Lin 《Additive Manufacturing Frontiers》 2025年第2期81-89,共9页
Laser-directed energy deposition(L-DED)is an advanced additive manufacturing technology primarily adopted in metal three-dimensional printing systems.The L-DED process is characterized by various defects,thus necessit... Laser-directed energy deposition(L-DED)is an advanced additive manufacturing technology primarily adopted in metal three-dimensional printing systems.The L-DED process is characterized by various defects,thus necessitating the extensive use of in-situ monitoring to enable real-time adjustments of process parameters by detecting molten-pool features.To address the challenge of accurately extracting the molten-pool morphology from an undetached spatter,an innovative monitoring method based on the U-Net(U-shaped network)is proposed herein.A lightweight architecture accelerates the processing speed,whereas an enhanced loss function incorporating weight maps augments the segmentation precision.The model performance is evaluated by comparing its segmentation accuracy and processing speed with those of the conventional U-Net,using the mean intersection over union(MIoU)as the segmentation metric.The improved model demonstrates superior segmentation accuracy at the interface between the molten pool and spatter,with a peak MIoU of 0.9798 achieved on the test set.Furthermore,this model processes each image in an extremely short time of 17.9 ms.Using this segmentation algorithm,the error in extracting the molten-pool width from single-track experiments is within 0.1 mm.The proposed method for monitoring the molten-pool morphology is suitable for deployment in online monitoring systems,thus providing a foundation for subsequent process-parameter regulation. 展开更多
关键词 Laser-directed energy deposition Molten-pool morphology Semantic segmentation Mean intersection over union(MIoU)
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Mouse model of anti-RANKL discontinuation reveals reduced bone mass and quality through disruption of bone remodeling
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作者 Koji Ishikawa Soji Tani +8 位作者 Nobuhiro Sakai Yoshifumi Kudo Hideyo Horiuchi Hiromi Kimura-Suda Masamichi Takami Mayumi Tsuji Katsunori Inagaki Yuji Kiuchi Takako Negishi-Koga 《Bone Research》 2025年第4期1001-1014,共14页
The discontinuation of denosumab[antibody targeting receptor activator of nuclear factor kappa B ligand(RANKL)]therapy may increase the risk of multiple vertebral fractures;however,the underlying pathophysiology is la... The discontinuation of denosumab[antibody targeting receptor activator of nuclear factor kappa B ligand(RANKL)]therapy may increase the risk of multiple vertebral fractures;however,the underlying pathophysiology is largely unknown.In patients who underwent discontinuation after multiple injections of denosumab,the levels of tartrate-resistant acid phosphatase 5b increased compared to pretreatment levels,indicating a phenomenon known as“overshoot.”The rate of decrease in bone mineral density during the withdrawal period was higher than the rate of decrease associated with aging,suggesting that the physiological bone metabolism had broken down.Overshoot and significant bone loss were also observed in mice receiving continuous administration of anti-RANKL antibody after treatment was interrupted,resembling the original pathology.In mice long out of overshoot,bone resorption recovered,but osteoblast numbers and bone formation remained markedly reduced.The bone marrow exhibited a significant reduction in stem cell(SC)antigen 1-and platelet-derived growth factor receptor alpha-expressing osteoblast progenitors(PαS cells)and alkaline phosphatase-positive early osteoblasts.Just before the overshoot phase,the osteoclast precursor cell population expands and RANKL-bearing extracellular vesicles(EVs)became abundant in the serum,leading to robust osteoclastogenesis after cessation of anti-RANKL treatment.Thus,accelerated bone resorption due to the accumulation of RANKLbearing EVs and long-term suppression of bone formation uncoupled from bone resorption leads to the severe bone loss characteristic of denosumab discontinuation. 展开更多
关键词 vertebral fractureshoweverthe decrease bone mineral density bone mass tartrate resistant acid phosphatase b mouse model anti RANKL discontinuation bone remodeling bone quality
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Integration of Bio-Enzyme-Treated Super-Wood and AIE-Based Nonwoven Fabric for Efficient Evaporating the Wastewater with High Concentration of Ammonia Nitrogen
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作者 Qian Ding Bingqi Jin +5 位作者 Yinxia Zheng Huiru Zhao Jun Wang Haoxuan Li Dong Wang Ben Zhong Tang 《Nano-Micro Letters》 2025年第8期1-16,共16页
The treatment of ammonia nitrogen wastewater(ANW)has garnered significant attention due to the ecology,and even biology is under increasing threat from over discharge ANW.Conventional ANW treatment methods often encou... The treatment of ammonia nitrogen wastewater(ANW)has garnered significant attention due to the ecology,and even biology is under increasing threat from over discharge ANW.Conventional ANW treatment methods often encounter challenges such as complex processes,high costs and secondary pollution.Considerable progress has been made in employing solar-induced evaporators for wastewater treatment.However,there remain notable barriers to transitioning from fundamental research to practical applications,including insufficient evaporation rates and inadequate resistance to biofouling.Herein,we propose a novel evaporator,which comprises a bio-enzyme-treated wood aerogel that serves as water pumping and storage layer,a cost-effective multi-walled carbon nanotubes coated hydrophobic/hydrophilic fibrous nonwoven mat functioning as photothermal evaporation layer,and aggregation-induced emission(AIE)molecules incorporated as anti-biofouling agent.The resultant bioinspired evaporator demonstrates a high evaporation rate of 12.83 kg m^(−2) h^(−1) when treating simulated ANW containing 30 wt%NH4Cl under 1.0 sun of illumination.AIE-doped evaporator exhibits remarkable photodynamic antibacterial activity against mildew and bacteria,ensuring outstanding resistance to biofouling over extended periods of wastewater treatment.When enhanced by natural wind under 1.0 sun irradiation,the evaporator achieves an impressive evaporation rate exceeding 20 kg m^(−2) h^(−1) .This advancement represents a promising and viable approach for the effective removal of ammonia nitrogen wastewater. 展开更多
关键词 Wood aerogel AIE Anti-biofouling Solar-driven interface evaporation Ammonia nitrogen wastewater treatment
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Evolution and Prospects of Foundation Models: From Large Language Models to Large Multimodal Models 被引量:3
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作者 Zheyi Chen Liuchang Xu +5 位作者 Hongting Zheng Luyao Chen Amr Tolba Liang Zhao Keping Yu Hailin Feng 《Computers, Materials & Continua》 SCIE EI 2024年第8期1753-1808,共56页
Since the 1950s,when the Turing Test was introduced,there has been notable progress in machine language intelligence.Language modeling,crucial for AI development,has evolved from statistical to neural models over the ... Since the 1950s,when the Turing Test was introduced,there has been notable progress in machine language intelligence.Language modeling,crucial for AI development,has evolved from statistical to neural models over the last two decades.Recently,transformer-based Pre-trained Language Models(PLM)have excelled in Natural Language Processing(NLP)tasks by leveraging large-scale training corpora.Increasing the scale of these models enhances performance significantly,introducing abilities like context learning that smaller models lack.The advancement in Large Language Models,exemplified by the development of ChatGPT,has made significant impacts both academically and industrially,capturing widespread societal interest.This survey provides an overview of the development and prospects from Large Language Models(LLM)to Large Multimodal Models(LMM).It first discusses the contributions and technological advancements of LLMs in the field of natural language processing,especially in text generation and language understanding.Then,it turns to the discussion of LMMs,which integrates various data modalities such as text,images,and sound,demonstrating advanced capabilities in understanding and generating cross-modal content,paving new pathways for the adaptability and flexibility of AI systems.Finally,the survey highlights the prospects of LMMs in terms of technological development and application potential,while also pointing out challenges in data integration,cross-modal understanding accuracy,providing a comprehensive perspective on the latest developments in this field. 展开更多
关键词 Artificial intelligence large language models large multimodal models foundation models
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Quantitative analysis of microstructure evolution,stress partitioning and thermodynamics in the dynamic transformation of Fe-14Ni alloy 被引量:2
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作者 Lian Li Goro Miyamoto +5 位作者 Yongjie Zhang Miaoquan Li Satoshi Morooka Katsunari Oikawa Yo Tomota Tadashi Furuhara 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第17期221-234,共14页
Dynamic transformation(DT)of austenite(γ)to ferrite(α)in the hot deformation of various carbon steels was widely investigated.However,the nature of DT remains unclear due to the lack of quantitative analysis of stre... Dynamic transformation(DT)of austenite(γ)to ferrite(α)in the hot deformation of various carbon steels was widely investigated.However,the nature of DT remains unclear due to the lack of quantitative analysis of stress partitioning between two phases and the uncertainty of local distribution of substitu-tional elements at the interface in multi-component carbon steels used in the previous studies.Therefore,in the present study,a binary Fe-Ni alloy withα+γduplex microstructure in equilibrium was prepared and isothermally compressed inα+γtwo-phase region to achieve a quantitative analysis of microstruc-ture evolution,stress partitioning,and thermodynamics during DT.γtoαDT during isothermal compres-sion andαtoγreverse transformation on isothermal annealing under unloaded condition after deforma-tion were accompanied by Ni partitioning.The lattice strains during thermomechanical processing were obtained via in-situ neutron diffraction measurement,based on which the stress partitioning behavior betweenγandαwas discussed by using the generalized Hooke’s law.A thermodynamic framework for the isothermal deformation in solids was established based on the basic laws of thermodynamics,and it was shown that the total Helmholtz free energy change in the deformable material during the isothermal process should be smaller than the work done to the deformable material.Under the present thermody-namic framework,the microstructure evolution in the isothermal compression of Fe-14Ni alloy was well explained by considering the changes in chemical free energy,plastic and elastic energies,and the work done to the material.In addition,the stabilization of the softαphase in Fe-14Ni alloy by deformation was rationalized since theγtoαtransformation decreased the total Helmholtz free energy by decreasing the elastic and dislocation energies. 展开更多
关键词 Iron Nickel Dynamic transformation Isothermal deformation Stress partitioning Neutron diffraction THERMODYNAMICS
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Crystal growth,structure and crystal field splitting and fitting of Yb:GdScO_(3) 被引量:1
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作者 Jia-Hong Li Qing-Li Zhang +4 位作者 Gui-Hua Sun Jin-Yun Gao Ren-Qin Dou Xiao-Fei Wang Shou-Jun Ding 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第11期411-416,共6页
A good quality(5 at.%Yb:GdScO_(3))single crystal of F30 mm37 mm was grown successfully by the Czochralski method.Its structure is studied by the x-ray diffraction(XRD),and its atomic coordinates are obtained by Rietve... A good quality(5 at.%Yb:GdScO_(3))single crystal of F30 mm37 mm was grown successfully by the Czochralski method.Its structure is studied by the x-ray diffraction(XRD),and its atomic coordinates are obtained by Rietveld refinement.The crystal field energy level splitting of Yb^(3+)in GdScO_(3) is determined by employing the absorption and photoluminescence spectra at 8 K.Only ^(2)F_(7/2)(4)is far from the ground state ^(2)F_(7/2)(1)by 710 cm^(-1) among the crystal field energy levels split from ^(2)F_(7/2),so it is more easier to realize the laser operation of ^(2)F_(5/2)(1)^(2)F_(7/2)(4)with wavelength 1060 nm.The spin–orbit coupling parameters and intrinsic crystal field parameters(CFPs).The intrinsic crystal field parameters¯B k(k=2,4,6)of the crystal were fitted by the superposition model.The CFPs evaluated with¯Bk and coordination factor are taken as the initial parameters to fit the crystal field energy levels of the crystal,and the crystal field parameters B_(q)^(k) are obtained finally with the root-mean-square deviation 9 cm-1.It is suggested that the ligand point charge,covalency and overlap interaction are slightly weaker than charge interpenetration and coulomb exchange interaction for Yb^(3+)in GdScO_(3).The obtained Hamiltonian parameters can be used to calculate crystal field energy levels and wave functions of Yb:GdScO_(3) to analyze the mechanism of the luminescence or laser. 展开更多
关键词 rare earth scandate crystal field PHOTOLUMINESCENCE laser crystal
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Liquefaction and post-liquefaction behaviors of sands affected by immersion-induced degradation of crushed mudstone
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作者 Tadao Enomoto 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第5期1799-1812,共14页
A series of undrained triaxial tests was conducted to investigate the effect of crushed mudstone with the immersion-induced degradation on the liquefaction and post-liquefaction properties,and the undrained shearing b... A series of undrained triaxial tests was conducted to investigate the effect of crushed mudstone with the immersion-induced degradation on the liquefaction and post-liquefaction properties,and the undrained shearing behavior without precedent cyclic-loading histories of sands containing crushed mudstone.The tested materials with a main particle diameter of 2-0.85 mm were prepared by mixing sands and crushed mudstone to reach the prescribed mudstone content defined by dry mass ranging from 0% to 50%.The mixtures were subjected to immersion under a certain stress level and were subsequently tested.In addition,one-dimensional compression tests were also supplementally performed to visually observe the immersion-induced degradation of crushed mudstone.The test results mainly showed that: (1) the liquefaction resistance,the post-liquefaction undrained strength,and the undrained strength without a precedent cyclic-loading history decreased significantly with increasing mudstone content,M c ,up to 20%;(2) even a small amount of crushed mudstone affected these strengths;(3) the above-mentioned large reductions in the strengths were attributed to the immersion-induced degradation of crushed mudstone;(4) at M_(c) >20%,the liquefaction resistance increased while the significant increase in the undrained static strengths with and without precedent cyclic-loading histories was not observed;and (5) the increase in the liquefaction resistance at M_(c) >20% may have been attributed to both the gradual increase in the plasticity and the formation of the soil aggregates among deteriorated crushed mudstone,while the increase in the specimen density did not play an important role in such behavior. 展开更多
关键词 LIQUEFACTION Post-liquefaction behavior Triaxial test Sands containing crushed mudstone
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Biomass Control via UV Lamp Application and Nutrient Supply Restriction in the Biofiltration of Gaseous VOCs
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作者 Takashi Higuchi Kokoro Hashizume 《Journal of Environmental Science and Engineering(B)》 CAS 2024年第3期97-104,共8页
Biofiltration may have clogging problems owing to excess biomass growth during the treatment of gaseous pollutants.In this study,we employed an UV(Ultraviolet)lamp and controlled the nutrient supply to conduct a biofi... Biofiltration may have clogging problems owing to excess biomass growth during the treatment of gaseous pollutants.In this study,we employed an UV(Ultraviolet)lamp and controlled the nutrient supply to conduct a biofiltration process for treating 2-butanone(MEK:Methyl Ethyl Ketone)and toluene in a gas stream.Two methods of UV lamp usage(direct and indirect irradiation)and several nutrient supply methods were tested.However,no clear effect was observed with either UV usage.Under the optimal conditions,97%of the MEK and 69%of the toluene gases were removed after 29 s of EBRT(Empty Bed Retention Time).The inlet loads were 18 and 19 mg/(m^(3)·h)for MEK and toluene,respectively.Under these conditions,23 g-N/(m^(3)·day)of nitrate-nitrogen was consumed.Excess biomass growth occurred during simultaneous excess nutrient supply and a persistent irrigation schedule.In this study,we demonstrated the effective use of a dense nitrate solution to deliver an appropriate amount of nutrients and moisture,and the optimal irrigation frequency was four times per week. 展开更多
关键词 BIOFILTRATION gaseous VOCs(Volatile Organic Compounds) nutrient supply UV lamp ozone
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Nanofluid Heat Transfer in Irregular 3D Surfaces under Magnetohydrodynamics andMulti-Slip Effects
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作者 Mumtaz Khan Muhammad Shoaib Anwar +1 位作者 Mudassar Imran Amer Rasheed 《Frontiers in Heat and Mass Transfer》 EI 2024年第5期1399-1419,共21页
This study employs the Buongiorno model to explore nanoparticle migration in a mixed convection second-grade fluid over a slendering(variable thickness)stretching sheet.The convective boundary conditions are applied t... This study employs the Buongiorno model to explore nanoparticle migration in a mixed convection second-grade fluid over a slendering(variable thickness)stretching sheet.The convective boundary conditions are applied to the surface.In addition,the analysis has been carried out in the presence of Joule heating,slips effects,thermal radiation,heat generation and magnetohydrodynamic.This study aimed to understand the complex dynamics of these nanofluids under various external influences.The governing model has been developed using the flow assumptions such as boundary layer approximations in terms of partial differential equations.Governing partial differential equations are first reduced into ordinary differential equations and then numerically solved using the Runge-Kutta-Fehlberg method(RK4)in conjunction with a shooting scheme.Our results indicate significant increases in Nusselt and Sherwood numbers by up to 14.6%and 23.2%,respectively,primarily due to increases in the Brownian motion parameter and thermophoresis parameter.Additionally,increases in the magnetic field parameter led to a decrease in skin friction coefficients by 37.5%.These results provide critical insights into optimizing industrial processes such as chemical production,automotive cooling systems,and energy generation,where efficient heat andmass transfer are crucial.Buongiornomodel;velocity-slip effects;Joule heating;convective boundary conditions;Runge-Kutta-Fehlberg method(RK4). 展开更多
关键词 Buongiorno model velocity-slip effects Joule heating convective boundary conditions Runge-Kutta-Fehlberg method(RK4)
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Determinants of Tobacco Cultivation and the Associated Impacts of Adoption in Hurungwe District, Zimbabwe
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作者 Spencer Sibanda Satoshi Tsuyuki 《Agricultural Sciences》 2024年第4期505-531,共27页
Tobacco is an essential cash crop in Zimbabwe and a strategic livelihood option for hundreds of thousands of rural households. However, the crop is linked to negative environmental, economic, and social impacts. The e... Tobacco is an essential cash crop in Zimbabwe and a strategic livelihood option for hundreds of thousands of rural households. However, the crop is linked to negative environmental, economic, and social impacts. The existing studies on tobacco cultivation in Zimbabwe present contradictory findings on the determinants and impacts of adoption, leaving unanswered questions about the crop’s sustainability impact in the country. This article investigates the determinants of smallholder farmers’ decisions to grow tobacco and the associated impacts of adoption. Random and purposive sampling were used to select 273 household surveys, including tobacco and non-tobacco smallholder farmers, and 56 expert interviews to answer the research questions. We employed regression models alongside expert interviews and document analysis to identify the determinants influencing the decision-making process of smallholder farmers in Zimbabwe regarding tobacco cultivation. Additionally, our investigation aimed to elucidate the perceived impacts associated with the adoption of this agricultural practice. The regression analysis indicated that the farmer’s age, education level, farming experience, family size, household income, and perceived high farm profitability are significant drivers of tobacco adoption. We also discovered divergent and convergent perceptions of the critical impacts of tobacco cultivation. The study highlights the need for proactive multi-stakeholder collaboration and sustainable financial arrangements to address the negative impacts of tobacco production. As the primary stakeholder responsible for regulating and promoting agricultural activities, the Zimbabwean government should provide meaningful financial support, increase access to credit, and ensure better market facilities for alternative crops to reduce the over-dependence on tobacco. 展开更多
关键词 Tobacco Cultivation Determinants of Adoption Sustainability Impacts Economic Livelihood Stakeholder Perceptions
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Solar-driven methane-to-ethanol conversion by “intramolecular junction” with both high activity and selectivity 被引量:1
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作者 Qijun Tang Wenguang Tu Zhigang Zou 《Chinese Journal of Structural Chemistry》 2025年第6期6-7,共2页
Methane(CH4),the predominant component of natural gas and shale gas,is regarded as a promising carbon feedstock for chemical synthesis[1].However,considering the extreme stability of CH4 molecules,it's quite chall... Methane(CH4),the predominant component of natural gas and shale gas,is regarded as a promising carbon feedstock for chemical synthesis[1].However,considering the extreme stability of CH4 molecules,it's quite challenging in simultaneously achieving high activity and selectivity for target products under mild conditions,especially when synthesizing high-value C2t chemicals such as ethanol[2].The conversion of methane to ethanol by photocatalysis is promising for achieving transformation under ambient temperature and pressure conditions.Currently,the apparent quantum efficiency(AQE)of solar-driven methane-to-ethanol conversion is generally below 0.5%[3,4].Furthermore,the stability of photocatalysts remains inadequate,offering substantial potential for further improvement. 展开更多
关键词 natural gas shale gasis target products carbon feedstock chemical synthesis howeverconsidering intramolecular junction solar driven methane ethanol conversion
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Participatory Forest Management and Gender Inclusiveness within the Community Forest Management Groups of Bhutan
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作者 Norbu Zangmo Takuya Hiroshima +1 位作者 Spencer Sibanda Jigme Dorji 《Journal of Geoscience and Environment Protection》 2024年第4期12-30,共19页
Community forest management groups (CFMGs) in Bhutan exhibit participatory forest management practices that recognize the importance of community’s collective participation in the management of natural forest resourc... Community forest management groups (CFMGs) in Bhutan exhibit participatory forest management practices that recognize the importance of community’s collective participation in the management of natural forest resources. This approach involves the community in the stewardship of designated forest areas and resources to ensure sustainable livelihoods and realization of forest conservation objectives. The increase of CFMGs in the country has been successful. However, research on the extent of gender-inclusive participation in CFMGs is either insufficient or missing vis-à-vis the allocation of decision-making power. Therefore, this study analyzes the factors influencing gender participation in CFMGs and their integration into decision-making processes. Primary data were collected from 12 study sites spanning 4 regions, complemented by secondary data from the Forest Department. Regression models were used to identify factors significantly influencing CFMG member participation in decision-making. The empirical results of this study reveal that gender is a significant factor influencing participation in CFMG decision-making. The study concludes that there is insufficient participation of women members in decision-making processes. Therefore, consideration of gender should be included in the development phase of the CFMG policy in addition to promoting awareness of inequity between gender and the promotion of leadership roles for women in CFMGs. 展开更多
关键词 DECISION-MAKING Face-to-Face Interview Regression Analysis WOMEN
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Influence of Heavy Fuel Oil on the Thermo-Physical and Erodibility Properties of Earthen Materials
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作者 Ohindemi G. Yameogo Donzala D. Some +3 位作者 Souleymane Ouedraogo Philbert Nshimiyimana Sié Kam Dieudonné J. Bathiebo 《Journal of Minerals and Materials Characterization and Engineering》 2024年第1期37-48,共12页
This study focuses on the use of heavy fuel oil in construction material in Burkina Faso. Its mixture with silty or clayey soil is used as a coating to reinforce the walls of raw earth constructions which are very sen... This study focuses on the use of heavy fuel oil in construction material in Burkina Faso. Its mixture with silty or clayey soil is used as a coating to reinforce the walls of raw earth constructions which are very sensitive to water. The interest of this study is to determine erodibility, water content, while highlighting the influence of the porosity accessible by water on thermal diffusion in construction material containing heavy fuel oil. The heavy fuel oil was mixed with a silty-clayey soil, in different proportions, and water to make bricks samples on which tests were carried out. At the end of the experimental tests, it appears that the water content increases gradually, but not significantly with the addition of heavy fuel oil, which causes a slight increase in the speed of heat propagation through the material with reduced porosity, particularly those containing higher quantities of heavy fuel oil. Conversely, we note a good performance of heavy fuel oil in terms of water resistance properties such as porosity accessible by water and erodibility. This allows us to conclude that the mixture of heavy fuel oil and silty-clayey soil used as a coating material could greatly reduce water infiltration into the walls of housing constructions with raw earthen materials. 展开更多
关键词 Porosity Accessible by Water ERODIBILITY Water Content Thermal Diffusion
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On Markov and Zariski Embeddings in a Free Group
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作者 Victor Hugo Yanez Dmitri Shakhmatov 《南开大学学报(自然科学版)》 北大核心 2025年第1期18-21,共4页
Let G be a group.The family of all sets which are closed in every Hausdorf group topology of G form the family of closed sets of a T_(1) topology M_(G) on G called the Markov topology.Similarly,the family of all algeb... Let G be a group.The family of all sets which are closed in every Hausdorf group topology of G form the family of closed sets of a T_(1) topology M_(G) on G called the Markov topology.Similarly,the family of all algebraic subsets of G forms a family of closed sets for another T_(1)topology Z_(G) on G called the Zarski topology.A subgroup H of G is said to be Markov(resp.Zarski)embedded if the equality M_(G|H)=M_(H)(resp.Z_(G|H)=Z_(H))holds.I's proved that an abirary subgroup of a free group is both Zariski and Markov embedded in it. 展开更多
关键词 free group Zariski topology Markov embedding centralizer in a free group
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Experimental Investigation on the Mechanical Properties of Silicone Elastomers Filled with Fumed Silica for Seismic Isolation Bearings
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作者 Arthur Ramandalina Ji Dang 《Journal of Building Material Science》 2025年第1期44-61,共18页
Laminated elastomeric bearings used in seismic isolation rely on the mechanical properties of their constituent elastomers to ensure effective performance.However,despite their resistance to temperature fluctuations a... Laminated elastomeric bearings used in seismic isolation rely on the mechanical properties of their constituent elastomers to ensure effective performance.However,despite their resistance to temperature fluctuations and environmental aggressors,silicone elastomers exhibit relatively low stiffness,limiting their direct applicability in seismic isolation.This study investigates the effect of fumed silica as a reinforcing filler to enhance the mechanical properties of laminated silicone elastomeric bearings.Elastomeric samples were fabricated with varying fumed silica proportions and subjected to Shore A hardness,uniaxial tensile,and lap shear tests to assess the influence of filler content.Additionally,quasi-static tests were conducted on reduced-scale bearing prototypes under combined vertical compression and cyclic horizontal shear to evaluate their seismic isolation performance.The results demonstrate that fumed silica reinforcement significantly increases stiffness,as evidenced by higher Shore A hardness values.However,a trade-off was observed in tensile properties,with reductions in tensile strength and elongation at break.Despite this,the equivalent elastic modulus did not show substantial variation up to large deformations,indicating that stiffness is preserved under most working conditions.Lap shear tests showed that fumed silica improves shear resistance,while quasi-static tests revealed inelastic behavior with small increases in equivalent shear coefficients but no substantial loss in damping ratios.These findings suggest that fumed silica reinforcement enhances silicone elastomers’stiffness and shear resistance while maintaining moderate damping properties,making it a promising approach for improving the mechanical performance of elastomeric bearings in seismic isolation applications. 展开更多
关键词 Silicone Elastomer Fumed Silica Elastomeric Bearing Seismic Isolation Experimental Study
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Age-Optimal Cached Distribution in the Satellite-Integrated Internet of Things via Cross-Slot Directed Graph
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作者 Hu Zhouyong Li Yue +1 位作者 Zhang Hanxu Yang Zhihua 《China Communications》 2025年第6期300-318,共19页
In the Satellite-integrated Internet of Things(S-IoT),data freshness in the time-sensitive scenarios could not be guaranteed over the timevarying topology with current distribution strategies aiming to reduce the tran... In the Satellite-integrated Internet of Things(S-IoT),data freshness in the time-sensitive scenarios could not be guaranteed over the timevarying topology with current distribution strategies aiming to reduce the transmission delay.To address this problem,in this paper,we propose an age-optimal caching distribution mechanism for the high-timeliness data collection in S-IoT by adopting a freshness metric,as called age of information(AoI)through the caching-based single-source multidestinations(SSMDs)transmission,namely Multi-AoI,with a well-designed cross-slot directed graph(CSG).With the proposed CSG,we make optimizations on the locations of cache nodes by solving a nonlinear integer programming problem on minimizing Multi-AoI.In particular,we put up forward three specific algorithms respectively for improving the Multi-AoI,i.e.,the minimum queuing delay algorithm(MQDA)based on node deviation from average level,the minimum propagation delay algorithm(MPDA)based on the node propagation delay reduction,and a delay balanced algorithm(DBA)based on node deviation from average level and propagation delay reduction.The simulation results show that the proposed mechanism can effectively improve the freshness of information compared with the random selection algorithm. 展开更多
关键词 age of information cached distribution satellite-integrated internet of things time-varying graph
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