To evaluate the accuracy of rockburst tendency classification in coal-bearing sandstone strata,this study conducted uniaxial compression loading and unloading tests on sandstone samples with four distinct grain sizes....To evaluate the accuracy of rockburst tendency classification in coal-bearing sandstone strata,this study conducted uniaxial compression loading and unloading tests on sandstone samples with four distinct grain sizes.The tests involved loading the samples to 60%,70%,and 80%of their uniaxial compressive strength,followed by unloading and reloading until failure.Key parameters such as the elastic energy index and linear elasticity criteria were derived from these tests.Additionally,rock fragments were collected to calculate their initial ejection kinetic energy,serving as a measure of rockburst tendency.The classification of rockburst tendency was conducted using grading methods based on burst energy index(WET),pre-peak stored elastic energy(PES)and experimental observations.Multi-class classification and regression analyses were applied to machine learning models using experimental data to predict rockburst tendency levels.A comparative analysis of models from two libraries revealed that the Random Forest model achieved the highest accuracy in classification,while the Ada Boost Regressor model excelled in regression predictions.This study highlights that on a laboratory scale,integrating ejection kinetic energy with the unloading ratio,failure load,W_(ET)and PES through machine learning offers a highly accurate and reliable approach for determining rockburst tendency levels.展开更多
Gas storage in abandoned mines is one way to reuse waste space resources.The surrounding rock of gas storage reservoirs in underground roadways undergoes damage and deformation under the cyclic loading of gas charging...Gas storage in abandoned mines is one way to reuse waste space resources.The surrounding rock of gas storage reservoirs in underground roadways undergoes damage and deformation under the cyclic loading of gas charging and discharging,which can pose a risk to the safety of the reservoirs.This study establishes a true triaxial numerical model of rock mass with the discrete element method(DEM)and explores the crack evolution of surrounding rock of underground gas storage during cyclic loading and unloading.Also,a damage evolution model in numerical analysis considering residual deformation is developed to explain the experimental results.As was revealed,cyclic loading and unloading resulted in fatigue damage in the specimen and caused strength deterioration of the specimen.During the loading process,the uniformly distributed force chains of the rock mass redistributed,evolving gradually to mostly transverse force chains.This contributed to the appearance of blank areas in the force chains when through cracks appear.The ratio of tensile cracks to shear cracks gradually decreases and finally stabilizes at 7:1.The damage evolution model considering residual strain can be mutually verified with the numerical simulation results.Based on the DEM model,it was found that there was a certain threshold of confining pressure.When the confining pressure exceeded 30 MPa,the deformation to ductility of sandstone samples began to accelerate,with a greater residual strength.This study provides a theoretical basis for analyzing the long-term mechanical behavior of surrounding rock of gas storage in abandoned mines.展开更多
In this paper,we consider a robust semi-infinite interval-valued optimization problem with inequality constraints having an uncertain parameter.The parametric representation of the aforesaid problem is also considered...In this paper,we consider a robust semi-infinite interval-valued optimization problem with inequality constraints having an uncertain parameter.The parametric representation of the aforesaid problem is also considered in order to derive the necessary and sufficient optimality conditions.Furthermore,we formulate a mixed-type dual problem and derive duality results which associate the robust weak efficient solution of the primal and its dual problems.Several examples are given to illustrate the results in the manuscript.展开更多
This study investigates the performance enhancement of super-sulfated cement(SSC)derived from arsenic-containing bio-oxidation waste(BW)through the incorporation of carbonated recycled concrete fines(CRCF).The finding...This study investigates the performance enhancement of super-sulfated cement(SSC)derived from arsenic-containing bio-oxidation waste(BW)through the incorporation of carbonated recycled concrete fines(CRCF).The findings revealed that the addition of 5wt%CRCF yields optimal performance,with compressive strengths reaching approximately 1.83,12.59,and 42.81 MPa at 1,3,and 28 d,respectively.These values represented significant increases of 408.3%,10.0%,and 14.3%compared to the reference sample.The improvement was attributed to the synergistic effects of ultrafine CRCF particles acting as fillers and nucleation sites,as well as the high reactivity of silica gels,which promoted the formation of additional hydration gels.Microstructural analysis confirmed that CRCF addition refined pore structure,and enhanced the stiffness of C-S-H gels.Furthermore,CRCF served as a net CO_(2) sink,sequestering 0.268 kg CO_(2) per kilogram of CRCF and thereby reducing the carbon footprint of SSC.In addition,the feasibility of applying CRCF-modified SSC in cemented paste backfill(CPB)is highlighted,given the high cement-related carbon footprint of conventional CPB.When 5wt%CRCFmodified SSC was employed in CPB,its 3-d compressive strength attained over 70%of that of ordinary Portland cement(OPC),while the 28-d strength was comparable to that of OPC.The proposed binder thus provides a sustainable pathway for BW valorization,combining waste utilization,carbon sequestration,and improved engineering performance.展开更多
Water inrush hazards from the floor strata of longwall workingface are commonly encountered in North China coalfields,which essentially result from the evolution of permeability in the floor rock under complex mining-...Water inrush hazards from the floor strata of longwall workingface are commonly encountered in North China coalfields,which essentially result from the evolution of permeability in the floor rock under complex mining-induced stress conditions.Current research rarely addresses the evolution of rock permeability under such complex stress paths.Describing this evolution using only one stress parameter,such as effective stress,deviatoric stress,axial stress,or confining stress,is highly challenging.In this study,we developed a laboratory loading scheme that simulates mining-induced stress evolution.Hydro-mechanical experiments were conducted to investigate the evolution of rock permeability under mining stress.The mechanism on the change of stress-permeability relationships in mining-disturbed rock is revealed,supporting to the analysis of management strategies for floor water-inrush disasters.The results show that rock permeability evolves through four stages,including rapid decline,gradual fluctuation,sharp increase,and slow attenuation.1–2 permeability surges occurred during mining-stress loading,closely linked to the emergence and reversal of deviatoric stress in magnitude and direction.With the first permeability surge,the deviatoric stress within the mudstone reached approximately 1.7 MPa,whereas that of the sandstone was about 1 MPa.The second permeability surge in the mudstone corresponded to the secondary rotation of the principal stress direction.CT and ultrasonic tests suggested an increase in microcracks in both rocks during the first permeability surge.However,the deviatoric stress-permeability plot before and after mining indicated that the fracture of mudstone sample changed significantly,while that of the sandstone remained unchanged.The permeability surges observed at different stages are interpreted as resulting from shear-induced reopening of pre-existing fractures and the formation of new shear-failure fractures.A stress-permeability model jointly governed by effective mean stress and deviatoric stress was established.Furthermore,two strategies are proposed for the floor water-inrush disasters prevention,(i)timely backfilling to reduce deviatoric stress,(ii)grouting after the first permeability surge.This work provides insights into stress-seepage behavior in rocks under complex stress evolution and offers new perspectives for identifying potential water inrush pathways in the floor strata of coal seam during longwall mining.展开更多
Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important eval...Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important evaluation parameter.In this study,the concept of whole-process carbon sequestration using coal-based solid waste and CO_(2),including sequential stirring and curing stages,was proposed to evaluate the performance evolution of CS.The results showed that CO_(2) pressure and ambient temperature positively correlated with the CS amount from coal-based SWB.In particular,CO_(2) pressure prevailed in the stirring stage,while the ambient temperature effect was more significant in the curing stage.The CS amounts obtained during the stirring stage alone,the curing stage alone,and two sequential stages ranged from 0.66%–3.10%,3.53%–5.09%,and 5.12%–6.02%,respectively.The functional group and micromorphology analyses revealed that the prevailing mechanism at the CS stirring stage was the stirringdriven gas dissolution-leaching-mineralization reaction,while that at the curing stage was the hydration-driven gas permeation-dissociation-CS reaction.Both were essentially solid-liquid-gas multiphase chemical reactions.The results are instrumental in substantiating the coal-based SWB carbon sequestration evolution patterns and mechanisms and providing data support for waste disposal and carbon emission reduction in the coal industry.展开更多
The diversion effect caused by the linked structure in a metro tunnel with cross-passage complicates the impact of longitudinal fire source location on the smoke backflow layering behavior that has not been clarified,...The diversion effect caused by the linked structure in a metro tunnel with cross-passage complicates the impact of longitudinal fire source location on the smoke backflow layering behavior that has not been clarified,despite the fact that the scenario exists in practice.A series of laboratory-scale experiments were conducted in this study to investigate the smoke back-layering length in a model tunnel with cross-passage.The heat release rate,the velocity of longitudinal air flow,and the location of the fire source were all varied.It was found that the behavior of smoke backflow for the fire source located at the upstream of bifurcation point resembles a single-hole tunnel fire.As the fire source’s position shifts downstream from the bifurcation point,the length of smoke back-layering progressively increases.A competitive interaction exists between airflow diversion and smoke diversion during smoke backflow,significantly affecting the smoke back-layering length in the main tunnel.The dimensionless smoke back-layering length model was formulated in a tunnel featuring a cross-passage,taking into account the positions of longitudinal fire sources.The dimensionless smoke back-layering length exhibits a positive correlation with the 17/18 power of total heat release rate Q and a negative correlation with the 5/2 power of longitudinal ventilation velocity V.展开更多
Coal mine underground reservoirs help address the severe water imbalance in ecologically fragile mining regions of western China,but evaluating their storage capacity remains challenging due to the coupled effects of ...Coal mine underground reservoirs help address the severe water imbalance in ecologically fragile mining regions of western China,but evaluating their storage capacity remains challenging due to the coupled effects of gangue deformation,saturation,and goaf geometry.This study investigates the deformation and void evolution of fragmented gangue with varying lithologies,particle sizes,and water contents through an independent-developed testing system and theoretical model.A planar micro-unit model and a three-dimensional spatial structure model are proposed to quantify the storage coefficient and total reservoir capacity of underground water storage structures.These models incorporate the effects of stratified lithologies,saturation-induced softening,and spatially distributed stress conditions.The methodology is applied to the underground reservoir in Chahasu coal mine,and the results show that under increasing stress,storage coefficients decline exponentially,with pronounced differences between single-and double-lithology structures.The storage coefficient in the spatial model demonstrate greater resilience to stress concentration compared to planar models,and further analysis identifies critical thresholds in roof fracture distances and stress-recovery times affecting long-term storage performance.This research provides a comprehensive framework for evaluating underground reservoir storage potential,offering theoretical support and engineering guidance for the sustainable utilization of mine water.展开更多
Perovskite oxides are highly promising catalysts for the combustion removal of volatile organic compounds(VOCs)due to their excellent stability,structural flexibility,and compositional versatility.This study presents ...Perovskite oxides are highly promising catalysts for the combustion removal of volatile organic compounds(VOCs)due to their excellent stability,structural flexibility,and compositional versatility.This study presents a novel perovskite oxide that exhibits enhanced catalytic activity and superior durability for toluene combustion at reduced temperatures.This improvement is achieved by phosphorus doping at the B-site of LaCoO_(3-δ)(LC)perovskite oxide,followed by post-synthesis acid etching for a proper time.The resulting catalyst demonstrates increased specific surface area,higher total pore volume,and enhanced oxygen vacancy concentration both in the bulk and on the surface.Additionally,the activity of surface lattice oxygen species is significantly improved,leading to enhanced catalytic performance in toluene combustion.Notably,the optimized catalyst shows an exceptionally low activation energy(E_(a))of 49.3 kJ mol^(-1),with a T90 reduction of over 214℃compared to the phosphorus doped LC and 190℃compared to pristine LC.Phosphorus doping plays a main role in significantly improving the long-term durability,particularly in the presence of CO_(2)and H_(2)O,while acid etching boosts the catalytic activity.This work introduces a rational and innovative strategy for optimizing VOC oxidation by improving the structure and surface chemical states of perovskite catalysts.展开更多
In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics...In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics.Given copper's extensive industrial applications,sustainable recovery from low-grade ores is critical.Five key parameters-acid concentration,leaching time,particle size,temperature,and solids percentage-were identified as major influences on copper recovery.The results revealed that leaching time and solids percentage,along with interactions between temperature-time and temperature-solids percentage,had the most significant effects.Optimal conditions for 80% copper recovery while minimizing iron recovery below 3% included an acid concentration of 1.21 mol L^(-1),a leaching time of 108 min,a particle size of 438μm,a temperature of 45℃,and a solids percentage of 18.2%.Leaching kinetics were analyzed using shrinking core models,with the Dickinson model best describing the process,showing an activation energy of 32.63 kJ mol^(-1),indicative of mixed diffusion and chemical reaction control.The final kinetic model effectively predicted the influence of key parameters.These findings highlight the importance of optimizing process variables and selecting suitable kinetic models to enhance extraction efficiency,reduce costs,and improve sustainability in copper recovery.展开更多
This study provides new evidence for a significant Neoproterozoic tectono-thermal event in the southern Dharwar Craton,based on U-Pb dating of rutile and monazite from metamorphic rocks of the Sargur Group.Trace eleme...This study provides new evidence for a significant Neoproterozoic tectono-thermal event in the southern Dharwar Craton,based on U-Pb dating of rutile and monazite from metamorphic rocks of the Sargur Group.Trace element analysis of rutile in garnet-bearing amphibolite,amphibolite,garnet-bearing staurolite-kyanite schist,and grunerite-garnet schist suggests that their protoliths were primarily basaltic rocks,sediments with mafic component,pelitic sediments,and mixed sediments with both mafic and felsic components,respectively.Rutile U-Pb ages of 625±22 Ma(garnet-bearing amphibolite),752±5.1 Ma(amphibolite),836±4 Ma to 663±26 Ma(garnet-bearing staurolite kyanite schist)and 860±13 Ma(grunerite-garnet schist),along with a monazite U-Pb age of 789±4.4 Ma(garnet-bearing staurolite kyanite schist),record a significant Neoproterozoic(860-625 Ma)tectono-thermal event along the southern margin of the western Dharwar Craton.This event is most likely associated with aborted rift-related alkaline magmatism along the northern margin of the Southern Granulite Terrane(SGT)and the southern margin of the Dharwar Craton.Given the lack of direct evidence for the assembly of the Rodinia supercontinent in the Dharwar Craton and SGT,this Neoproterozoic event is unlikely to be related to the breakup of Rodinia.展开更多
The Rukwa Rift section of the East Africa Rift System presents a type setting for radiogenic helium accumulation in a petroleum free basin.As a prerequisite for accumulation,a considerable high heat flow anomaly is re...The Rukwa Rift section of the East Africa Rift System presents a type setting for radiogenic helium accumulation in a petroleum free basin.As a prerequisite for accumulation,a considerable high heat flow anomaly is required from tectonothermal events to drive the release and circulation of radiogenic helium in the continental crust.Here we apply statistical analysis on geochemical data observed in thermal springs and recorded heat flow to account for crustal helium mass balance for each tectonothermal event in the region.Our results demonstrate anomalously high heat flow~64-99 mW/m^(2) with a consistent trend of helium isotopic ratio and fluid chemistry in the Rukwa Rift.Mass balance calculation show that the whole crustal volume underlying the East Africa Helium Pool(EAHP)has a capability of producing radiogenic helium of about 9.9×10^(6) mol/yr(22×10^(-6) mol 4He/m^(2) yr)while the total radiogenic helium flux ranges between~2.39×10^(6) mol/yr and~2.68×10^(9) mol/yr.The Tanzania Craton contributes largely to radiogenic helium releasing up to 50% of the total capacity in the region.The total ^(4)He emission in the Rukwa Rift Basin is about 4.45×10^(5)-5.01×10^(8) mol/yr which is thus equivalent to 19%-21% of the total production capacity in the region.These results imply that the helium accumulation in the EAHP would have started as early as Paleoproterozoic(2.349 Ga).These results provide a qualitative and quantitative insight to assess both helium and geothermal potentiality in the region.展开更多
Cemented rockfill(CRF)combines structural support with sustainable reuse of coal-derived solid waste.This study integrates digital image correlation,acoustic emission monitoring,and finite-discrete element simulations...Cemented rockfill(CRF)combines structural support with sustainable reuse of coal-derived solid waste.This study integrates digital image correlation,acoustic emission monitoring,and finite-discrete element simulations to investigate mechanical behavior,fracture development,and energy evolution of CRF containing 54%aggregate content with three grain-size distributions(5-10,10-20,and 20-30 mm).Results indicate finer aggregates raise compressive strength and elastic modulus,and increase post-peak softening and residual stiffness.Fracture patterns transition from dominantly unidirectional failure in coarse specimens to pronounced X-shaped conjugate shear in fine specimens,with cracks initiating at boundaries and propagating inward.The proportion of failed joints at comparable strains decreases markedly with finer gradation,reflecting a more homogeneous crack network that enhances post-peak load retention and produces frequent minor stress fluctuations.Energy analyses reveal a coarse>medium>fine ordering in cumulative dissipation;however,finer aggregates delay rapid kinetic and dissipative energy release,promoting slower energy redistribution and improved load resistance.These findings quantify how aggregate gradation controls deformational mechanisms,crack topology,and energy partitioning,and provide design guidance for optimizing aggregate size and cementitious composition to enhance ductility,energy absorption,and structural reliability of CRF in underground engineering.展开更多
Traditional mining in open pit mines often uses explosives,leading to environmental hazards,with flyrock being a critical issue.In detail,excess flying rock beyond the designated explosion area was identified as the p...Traditional mining in open pit mines often uses explosives,leading to environmental hazards,with flyrock being a critical issue.In detail,excess flying rock beyond the designated explosion area was identified as the primary cause of fatal and non-fatal blasting hazards in open pit mining.Therefore,the accurate and reliable prediction of flyrock becomes crucial for effectively managing and mitigating associated problems.This study used the Light Gradient Boosting Machine(LightGBM)model to predict flyrock in a lead-zinc mine,with promising results.To improve its accuracy,multi-verse optimizer(MVO)and ant lion optimizer(ALO)metaheuristic algorithms were introduced.Results showed MVO-LightGBM outperformed conventional LightGBM.Additionally,decision tree(DT),support vector machine(SVM),and classification and regression tree(CART)models were trained and compared with MVO-LightGBM.The MVO-LightGBM model excelled over DT,SVM,and CART.This study highlights MVO-LightGBM's effectiveness and potential for broader applications.Furthermore,a multiple parametric sensitivity analysis(MPSA)algorithm was employed to specify the sensitivity of parameters.MPSA results indicated that the highest and lowest sensitivities are relevant to blasted rock per hole and spacing with theγ=1752.12 andγ=49.52,respectively.展开更多
Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"ove...Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"overcoming rigidity by flexibility",the prevention and control method with"rigid-flexible coupling(R-F-C)"was put forward.Through numerical simulation calculation,the impact damage process,acoustic emission(AE)evolution characteristics,and element stress/displacement evolution characteristics of unsupported surrounding rock structure model,rigid supporting surrounding rock structure model,and"R-F-C"supporting surrounding rock structure model under horizontal bidirectional impact loading were compared and analyzed.Based on the theory of stress wave propagation,the dynamic instability catastrophe mechanism of three kinds of supporting structure models induced by horizontal bidirectional impact loading was revealed.Based on the Mohr-Coulomb strength theory,the stress discrimination methods of dynamic catastrophe of surrounding rock induced by horizontal bidirectional impact loading under three kinds of supporting structures were proposed.Combined with the above numerical simulation study,the explosion impact physical and mechanical test of"R-F-C"surrounding rock supporting plate structure was further designed and carried out.Finally,combined with the"conceptual model of ball-cliff potential energy instability",the energy driving theory and energy transformation mechanism of impact-induced rockburst under three kinds of supporting structures were discussed deeply.The research results provided a scientific basis for further promoting the effective application of"R-F-C"supporting structure in the prevention and control of dynamic instability of deep tunnel/roadway surrounding rock.展开更多
During the past decade, coal dust and gas explosions have been the most two serious types of disasters in China, threatening the lives of miners and causing significant losses in terms of national property. In this pa...During the past decade, coal dust and gas explosions have been the most two serious types of disasters in China, threatening the lives of miners and causing significant losses in terms of national property. In this paper, an evaluation model of coal dust and gas explosions was constructed based on a fuzzy fault tree by taking the Xingli Coal Mine as a research site to identify the risk factors of coal dust and gas explosions.Furthermore, the hazards associated with such explosions were evaluated for this particular coal mine.After completing an on-site investigation, the fuzzy probabilities of basic events were obtained through expert scoring, and these expert opinions were then aggregated as trapezoidal fuzzy numbers to calculate the degrees of importance of all basic events. Finally, these degrees of importance were sorted. According to the resulting order, the basic events with higher probabilities were determined to identify key hazards in the daily safety management of this particular coal mine. Moreover, effective measures for preventing gas and coal dust explosions were derived. The fuzzy fault tree analysis method is of high significance in the analysis of accidental coal mine explosions and provides theoretical guidance for improving the efficiency of coal mine safety management in a scientific and feasible manner.展开更多
Abstract： Trivalent europium doped zinc oxide （ZnO：Eu3＋） nanocrystals were synthesized via room temperature chemical co-pre- cipitation and they were systematically characterized by means of X-ray diffraction （...Abstract： Trivalent europium doped zinc oxide （ZnO：Eu3＋） nanocrystals were synthesized via room temperature chemical co-pre- cipitation and they were systematically characterized by means of X-ray diffraction （XRD）, Fourier transform infrared spectroscopy （FTIR） and photoluminescence （PL） spectroscopy. The as-synthesized samples were found to have hexagonal wurtzite coexisted with the intermediate Zn5（OH）sC12·H2O phase, while the single hexagonal phase was facilitated due to the calcinations. The as obtained samples were broadly composed ofnanoflakes while the highly crystalline nanorods were formed due to low temperature annealing of the as-synthesized samples. The crystallite size of the nanoflakes and nanorods （40-90 nm） were extracted from the XRD pattern which was found to be consistent with scanning electron microscopy （SEM） measurements. The photoluminescence （PL） spectra of nanophosphors showed bright red and orange emissions at 618 and 594 nm respectively with efficient broad blue green emis- sion spectrum due to ZnO lattice. Further, a good energy transfer process from ZnO host to Eu3＋ was observed in PL emission and excitation spectra of Eu3＋ doped ZnO ions. In all, the present nanophosphors were found to have great potentiality for bio-appli- cations.展开更多
The increasing use of diesel-powered equipment in confined spaces(underground mines) has the potential to over expose underground miners under the threat of diesel particulate matter(DPM). Miners in underground mines ...The increasing use of diesel-powered equipment in confined spaces(underground mines) has the potential to over expose underground miners under the threat of diesel particulate matter(DPM). Miners in underground mines can be exposed to DPM concentrations far more than works in other industries. A great number of animal and epidemiological studies have shown that both short-term and long-term DPM exposure have adverse health effect. Based on reviews of related studies, especially some recent evidence, this paper investigated the long and short-term health effects based on animal studies and epidemiological studies. The exposure-response relationship studies were also explored and compared to the current DPM regulation or standards in some countries. This paper found that the DPM health effect studies specifically for miners are not sufficient to draw solid conclusions, and a recommendation limit of DPM concentration can be put in place for better protection of miners from DPM health risk. Current animal studies lack the use of species that have similar lung functions as human for understanding the cancer mode of action in human. And finally, the DPM health hazard will continue to be a challenging topic before the mode of action and reliable exposure-response relationship are established.展开更多
Work injuries in mines are complex and generally characterized by several factors starting from personal to technical and technical to social characteristics.In this paper,investigation was made through the applicatio...Work injuries in mines are complex and generally characterized by several factors starting from personal to technical and technical to social characteristics.In this paper,investigation was made through the application of structural equation modeling to study the nature of relationships between the influencing/associating personal factors and work injury and their sequential relationships leading towards work injury occurrences in underground coal mines.Six variables namely,rebelliousness,negative affectivity,job boredom,job dissatisfaction and work injury were considered in this study.Instruments were developed to quantify them through a questionnaire survey.Underground mine workers were randomly selected for the survey.Responses from 300 participants were used for the analysis.The structural model of LISREL was used to estimate the interrelationships amongst the variables.The case study results show that negative affectivity and job boredom induce more job dissatisfaction to the workers whereas risk taking attitude of the individual is positively influenced by job dissatisfaction as well as by rebelliousness characteristics of the individual.Finally,risk taking and job dissatisfaction are having positive significant direct relationship with work injury.The findings of this study clearly reveal that rebelliousness,negative affectivity and job boredom are the three key personal factors influencing work related injuries in mines that need to be addressed properly through effective safety programs.展开更多
Accuracy in predictions leads to better planning with a minimum of opportunity lost. In open pit mining,the complexity of operations, coupled with a highly uncertain and dynamic production environment,limit the accura...Accuracy in predictions leads to better planning with a minimum of opportunity lost. In open pit mining,the complexity of operations, coupled with a highly uncertain and dynamic production environment,limit the accuracy of predictions and force a reactive planning approach to mitigate deviations from original plans. A simulation optimization framework/tool is presented in this paper to account for uncertainties in mining operations for robust short-term production planning and proactive decision making. This framework/tool uses a discrete event simulation model of mine operations, which interacts with a goalprogramming based mine operational optimization tool to develop an uncertainty based short-term schedule. Using scenario analysis, this framework allows the planner to make proactive decisions to achieve the mine's operational and long-term objectives. This paper details the development of simulation and optimization models and presents the implementation of the framework on an iron ore mine case study for verification through scenario analysis.展开更多
基金financial support for this work provided by the National Natural Science Foundation of China (No.52227901)。
文摘To evaluate the accuracy of rockburst tendency classification in coal-bearing sandstone strata,this study conducted uniaxial compression loading and unloading tests on sandstone samples with four distinct grain sizes.The tests involved loading the samples to 60%,70%,and 80%of their uniaxial compressive strength,followed by unloading and reloading until failure.Key parameters such as the elastic energy index and linear elasticity criteria were derived from these tests.Additionally,rock fragments were collected to calculate their initial ejection kinetic energy,serving as a measure of rockburst tendency.The classification of rockburst tendency was conducted using grading methods based on burst energy index(WET),pre-peak stored elastic energy(PES)and experimental observations.Multi-class classification and regression analyses were applied to machine learning models using experimental data to predict rockburst tendency levels.A comparative analysis of models from two libraries revealed that the Random Forest model achieved the highest accuracy in classification,while the Ada Boost Regressor model excelled in regression predictions.This study highlights that on a laboratory scale,integrating ejection kinetic energy with the unloading ratio,failure load,W_(ET)and PES through machine learning offers a highly accurate and reliable approach for determining rockburst tendency levels.
基金National Natural Science Foundation of China,Grant/Award Numbers:U22A20598,52104107National Key Research and Development Program of China,Grant/Award Numbers:2023YFC2907300,2019YFE0118500,2019YFC1904304Natural Science Foundation of Jiangsu Province,Grant/Award Number:BK20200634。
文摘Gas storage in abandoned mines is one way to reuse waste space resources.The surrounding rock of gas storage reservoirs in underground roadways undergoes damage and deformation under the cyclic loading of gas charging and discharging,which can pose a risk to the safety of the reservoirs.This study establishes a true triaxial numerical model of rock mass with the discrete element method(DEM)and explores the crack evolution of surrounding rock of underground gas storage during cyclic loading and unloading.Also,a damage evolution model in numerical analysis considering residual deformation is developed to explain the experimental results.As was revealed,cyclic loading and unloading resulted in fatigue damage in the specimen and caused strength deterioration of the specimen.During the loading process,the uniformly distributed force chains of the rock mass redistributed,evolving gradually to mostly transverse force chains.This contributed to the appearance of blank areas in the force chains when through cracks appear.The ratio of tensile cracks to shear cracks gradually decreases and finally stabilizes at 7:1.The damage evolution model considering residual strain can be mutually verified with the numerical simulation results.Based on the DEM model,it was found that there was a certain threshold of confining pressure.When the confining pressure exceeded 30 MPa,the deformation to ductility of sandstone samples began to accelerate,with a greater residual strength.This study provides a theoretical basis for analyzing the long-term mechanical behavior of surrounding rock of gas storage in abandoned mines.
基金supported by the MATRICES,SERB-DST,New Delhi,India(No.MTR/2021/000002).
文摘In this paper,we consider a robust semi-infinite interval-valued optimization problem with inequality constraints having an uncertain parameter.The parametric representation of the aforesaid problem is also considered in order to derive the necessary and sufficient optimality conditions.Furthermore,we formulate a mixed-type dual problem and derive duality results which associate the robust weak efficient solution of the primal and its dual problems.Several examples are given to illustrate the results in the manuscript.
基金supports from the National Natural Science Foundation of China(No.52304148)the Youth Project of Shanxi Basic Research Program(No.202203021212262).
文摘This study investigates the performance enhancement of super-sulfated cement(SSC)derived from arsenic-containing bio-oxidation waste(BW)through the incorporation of carbonated recycled concrete fines(CRCF).The findings revealed that the addition of 5wt%CRCF yields optimal performance,with compressive strengths reaching approximately 1.83,12.59,and 42.81 MPa at 1,3,and 28 d,respectively.These values represented significant increases of 408.3%,10.0%,and 14.3%compared to the reference sample.The improvement was attributed to the synergistic effects of ultrafine CRCF particles acting as fillers and nucleation sites,as well as the high reactivity of silica gels,which promoted the formation of additional hydration gels.Microstructural analysis confirmed that CRCF addition refined pore structure,and enhanced the stiffness of C-S-H gels.Furthermore,CRCF served as a net CO_(2) sink,sequestering 0.268 kg CO_(2) per kilogram of CRCF and thereby reducing the carbon footprint of SSC.In addition,the feasibility of applying CRCF-modified SSC in cemented paste backfill(CPB)is highlighted,given the high cement-related carbon footprint of conventional CPB.When 5wt%CRCFmodified SSC was employed in CPB,its 3-d compressive strength attained over 70%of that of ordinary Portland cement(OPC),while the 28-d strength was comparable to that of OPC.The proposed binder thus provides a sustainable pathway for BW valorization,combining waste utilization,carbon sequestration,and improved engineering performance.
基金supported by the National Natural Science Foundation of China(Nos.U22A20165 and 52474156)the Key Research and Development Program of Xinjiang Uyghur Autonomous Region(No.2023B01010-1)the China Scholarship Council(No.202406420054).
文摘Water inrush hazards from the floor strata of longwall workingface are commonly encountered in North China coalfields,which essentially result from the evolution of permeability in the floor rock under complex mining-induced stress conditions.Current research rarely addresses the evolution of rock permeability under such complex stress paths.Describing this evolution using only one stress parameter,such as effective stress,deviatoric stress,axial stress,or confining stress,is highly challenging.In this study,we developed a laboratory loading scheme that simulates mining-induced stress evolution.Hydro-mechanical experiments were conducted to investigate the evolution of rock permeability under mining stress.The mechanism on the change of stress-permeability relationships in mining-disturbed rock is revealed,supporting to the analysis of management strategies for floor water-inrush disasters.The results show that rock permeability evolves through four stages,including rapid decline,gradual fluctuation,sharp increase,and slow attenuation.1–2 permeability surges occurred during mining-stress loading,closely linked to the emergence and reversal of deviatoric stress in magnitude and direction.With the first permeability surge,the deviatoric stress within the mudstone reached approximately 1.7 MPa,whereas that of the sandstone was about 1 MPa.The second permeability surge in the mudstone corresponded to the secondary rotation of the principal stress direction.CT and ultrasonic tests suggested an increase in microcracks in both rocks during the first permeability surge.However,the deviatoric stress-permeability plot before and after mining indicated that the fracture of mudstone sample changed significantly,while that of the sandstone remained unchanged.The permeability surges observed at different stages are interpreted as resulting from shear-induced reopening of pre-existing fractures and the formation of new shear-failure fractures.A stress-permeability model jointly governed by effective mean stress and deviatoric stress was established.Furthermore,two strategies are proposed for the floor water-inrush disasters prevention,(i)timely backfilling to reduce deviatoric stress,(ii)grouting after the first permeability surge.This work provides insights into stress-seepage behavior in rocks under complex stress evolution and offers new perspectives for identifying potential water inrush pathways in the floor strata of coal seam during longwall mining.
基金supported by the National Key R&D Program of China(No.2023YFC3904304)the National Natural Science Foundation of China(No.52304158)Jiangsu Key Laboratory for Clean Utilization of Carbon Resources Research Project(No.BM2024007)。
文摘Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important evaluation parameter.In this study,the concept of whole-process carbon sequestration using coal-based solid waste and CO_(2),including sequential stirring and curing stages,was proposed to evaluate the performance evolution of CS.The results showed that CO_(2) pressure and ambient temperature positively correlated with the CS amount from coal-based SWB.In particular,CO_(2) pressure prevailed in the stirring stage,while the ambient temperature effect was more significant in the curing stage.The CS amounts obtained during the stirring stage alone,the curing stage alone,and two sequential stages ranged from 0.66%–3.10%,3.53%–5.09%,and 5.12%–6.02%,respectively.The functional group and micromorphology analyses revealed that the prevailing mechanism at the CS stirring stage was the stirringdriven gas dissolution-leaching-mineralization reaction,while that at the curing stage was the hydration-driven gas permeation-dissociation-CS reaction.Both were essentially solid-liquid-gas multiphase chemical reactions.The results are instrumental in substantiating the coal-based SWB carbon sequestration evolution patterns and mechanisms and providing data support for waste disposal and carbon emission reduction in the coal industry.
基金funded by the National Natural Science Foundation of China(NSFC)under Grant No.52278415the National Key Research and Development Program of China under Grant No.2022YFC3801104+2 种基金Hebei Provincial Department of Education Project under Grant No.QN2025304the Innovation Fund Project of Hebei University of Engineering under Grant No.SJ2401002066the Sichuan Science and Technology Program under Grant No.2023YFS0407。
文摘The diversion effect caused by the linked structure in a metro tunnel with cross-passage complicates the impact of longitudinal fire source location on the smoke backflow layering behavior that has not been clarified,despite the fact that the scenario exists in practice.A series of laboratory-scale experiments were conducted in this study to investigate the smoke back-layering length in a model tunnel with cross-passage.The heat release rate,the velocity of longitudinal air flow,and the location of the fire source were all varied.It was found that the behavior of smoke backflow for the fire source located at the upstream of bifurcation point resembles a single-hole tunnel fire.As the fire source’s position shifts downstream from the bifurcation point,the length of smoke back-layering progressively increases.A competitive interaction exists between airflow diversion and smoke diversion during smoke backflow,significantly affecting the smoke back-layering length in the main tunnel.The dimensionless smoke back-layering length model was formulated in a tunnel featuring a cross-passage,taking into account the positions of longitudinal fire sources.The dimensionless smoke back-layering length exhibits a positive correlation with the 17/18 power of total heat release rate Q and a negative correlation with the 5/2 power of longitudinal ventilation velocity V.
基金supported by the National Natural Science Foundation of China(Nos.52404153,52504157 and 52504156)the Natural Science Foundation of Jiangsu Province(No.BK20241649).
文摘Coal mine underground reservoirs help address the severe water imbalance in ecologically fragile mining regions of western China,but evaluating their storage capacity remains challenging due to the coupled effects of gangue deformation,saturation,and goaf geometry.This study investigates the deformation and void evolution of fragmented gangue with varying lithologies,particle sizes,and water contents through an independent-developed testing system and theoretical model.A planar micro-unit model and a three-dimensional spatial structure model are proposed to quantify the storage coefficient and total reservoir capacity of underground water storage structures.These models incorporate the effects of stratified lithologies,saturation-induced softening,and spatially distributed stress conditions.The methodology is applied to the underground reservoir in Chahasu coal mine,and the results show that under increasing stress,storage coefficients decline exponentially,with pronounced differences between single-and double-lithology structures.The storage coefficient in the spatial model demonstrate greater resilience to stress concentration compared to planar models,and further analysis identifies critical thresholds in roof fracture distances and stress-recovery times affecting long-term storage performance.This research provides a comprehensive framework for evaluating underground reservoir storage potential,offering theoretical support and engineering guidance for the sustainable utilization of mine water.
基金support from the National Key Research and Development Program of China(Project No.2018YFB1502903).
文摘Perovskite oxides are highly promising catalysts for the combustion removal of volatile organic compounds(VOCs)due to their excellent stability,structural flexibility,and compositional versatility.This study presents a novel perovskite oxide that exhibits enhanced catalytic activity and superior durability for toluene combustion at reduced temperatures.This improvement is achieved by phosphorus doping at the B-site of LaCoO_(3-δ)(LC)perovskite oxide,followed by post-synthesis acid etching for a proper time.The resulting catalyst demonstrates increased specific surface area,higher total pore volume,and enhanced oxygen vacancy concentration both in the bulk and on the surface.Additionally,the activity of surface lattice oxygen species is significantly improved,leading to enhanced catalytic performance in toluene combustion.Notably,the optimized catalyst shows an exceptionally low activation energy(E_(a))of 49.3 kJ mol^(-1),with a T90 reduction of over 214℃compared to the phosphorus doped LC and 190℃compared to pristine LC.Phosphorus doping plays a main role in significantly improving the long-term durability,particularly in the presence of CO_(2)and H_(2)O,while acid etching boosts the catalytic activity.This work introduces a rational and innovative strategy for optimizing VOC oxidation by improving the structure and surface chemical states of perovskite catalysts.
基金Open Access funding enabled and organized by Projekt DEAL.
文摘In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics.Given copper's extensive industrial applications,sustainable recovery from low-grade ores is critical.Five key parameters-acid concentration,leaching time,particle size,temperature,and solids percentage-were identified as major influences on copper recovery.The results revealed that leaching time and solids percentage,along with interactions between temperature-time and temperature-solids percentage,had the most significant effects.Optimal conditions for 80% copper recovery while minimizing iron recovery below 3% included an acid concentration of 1.21 mol L^(-1),a leaching time of 108 min,a particle size of 438μm,a temperature of 45℃,and a solids percentage of 18.2%.Leaching kinetics were analyzed using shrinking core models,with the Dickinson model best describing the process,showing an activation energy of 32.63 kJ mol^(-1),indicative of mixed diffusion and chemical reaction control.The final kinetic model effectively predicted the influence of key parameters.These findings highlight the importance of optimizing process variables and selecting suitable kinetic models to enhance extraction efficiency,reduce costs,and improve sustainability in copper recovery.
基金supported by the National Natural Science Foundations of China(Grant Nos:41890831 and 42172214)the MOST Special Fund from the State Key Laboratory of Continental Dynamics,Northwest University.
文摘This study provides new evidence for a significant Neoproterozoic tectono-thermal event in the southern Dharwar Craton,based on U-Pb dating of rutile and monazite from metamorphic rocks of the Sargur Group.Trace element analysis of rutile in garnet-bearing amphibolite,amphibolite,garnet-bearing staurolite-kyanite schist,and grunerite-garnet schist suggests that their protoliths were primarily basaltic rocks,sediments with mafic component,pelitic sediments,and mixed sediments with both mafic and felsic components,respectively.Rutile U-Pb ages of 625±22 Ma(garnet-bearing amphibolite),752±5.1 Ma(amphibolite),836±4 Ma to 663±26 Ma(garnet-bearing staurolite kyanite schist)and 860±13 Ma(grunerite-garnet schist),along with a monazite U-Pb age of 789±4.4 Ma(garnet-bearing staurolite kyanite schist),record a significant Neoproterozoic(860-625 Ma)tectono-thermal event along the southern margin of the western Dharwar Craton.This event is most likely associated with aborted rift-related alkaline magmatism along the northern margin of the Southern Granulite Terrane(SGT)and the southern margin of the Dharwar Craton.Given the lack of direct evidence for the assembly of the Rodinia supercontinent in the Dharwar Craton and SGT,this Neoproterozoic event is unlikely to be related to the breakup of Rodinia.
基金funded by United Kingdom Commonwealth Scholarship Commission。
文摘The Rukwa Rift section of the East Africa Rift System presents a type setting for radiogenic helium accumulation in a petroleum free basin.As a prerequisite for accumulation,a considerable high heat flow anomaly is required from tectonothermal events to drive the release and circulation of radiogenic helium in the continental crust.Here we apply statistical analysis on geochemical data observed in thermal springs and recorded heat flow to account for crustal helium mass balance for each tectonothermal event in the region.Our results demonstrate anomalously high heat flow~64-99 mW/m^(2) with a consistent trend of helium isotopic ratio and fluid chemistry in the Rukwa Rift.Mass balance calculation show that the whole crustal volume underlying the East Africa Helium Pool(EAHP)has a capability of producing radiogenic helium of about 9.9×10^(6) mol/yr(22×10^(-6) mol 4He/m^(2) yr)while the total radiogenic helium flux ranges between~2.39×10^(6) mol/yr and~2.68×10^(9) mol/yr.The Tanzania Craton contributes largely to radiogenic helium releasing up to 50% of the total capacity in the region.The total ^(4)He emission in the Rukwa Rift Basin is about 4.45×10^(5)-5.01×10^(8) mol/yr which is thus equivalent to 19%-21% of the total production capacity in the region.These results imply that the helium accumulation in the EAHP would have started as early as Paleoproterozoic(2.349 Ga).These results provide a qualitative and quantitative insight to assess both helium and geothermal potentiality in the region.
基金funding from the National Natural Science Foundation of China(Nos.52478389 and 52525401).
文摘Cemented rockfill(CRF)combines structural support with sustainable reuse of coal-derived solid waste.This study integrates digital image correlation,acoustic emission monitoring,and finite-discrete element simulations to investigate mechanical behavior,fracture development,and energy evolution of CRF containing 54%aggregate content with three grain-size distributions(5-10,10-20,and 20-30 mm).Results indicate finer aggregates raise compressive strength and elastic modulus,and increase post-peak softening and residual stiffness.Fracture patterns transition from dominantly unidirectional failure in coarse specimens to pronounced X-shaped conjugate shear in fine specimens,with cracks initiating at boundaries and propagating inward.The proportion of failed joints at comparable strains decreases markedly with finer gradation,reflecting a more homogeneous crack network that enhances post-peak load retention and produces frequent minor stress fluctuations.Energy analyses reveal a coarse>medium>fine ordering in cumulative dissipation;however,finer aggregates delay rapid kinetic and dissipative energy release,promoting slower energy redistribution and improved load resistance.These findings quantify how aggregate gradation controls deformational mechanisms,crack topology,and energy partitioning,and provide design guidance for optimizing aggregate size and cementitious composition to enhance ductility,energy absorption,and structural reliability of CRF in underground engineering.
基金funded by the Key Laboratory of Geological Safety of Coastal Urban Underground Space,Ministry of Natural Resources of China(Grant No.BHKF2022Y02)Natural Science Foundation of Guangdong Province,China(Grant No.2024A1515011162)Natural Science Foundation of Shandong Province,China(Grant No.ZR2024QE021).
文摘Traditional mining in open pit mines often uses explosives,leading to environmental hazards,with flyrock being a critical issue.In detail,excess flying rock beyond the designated explosion area was identified as the primary cause of fatal and non-fatal blasting hazards in open pit mining.Therefore,the accurate and reliable prediction of flyrock becomes crucial for effectively managing and mitigating associated problems.This study used the Light Gradient Boosting Machine(LightGBM)model to predict flyrock in a lead-zinc mine,with promising results.To improve its accuracy,multi-verse optimizer(MVO)and ant lion optimizer(ALO)metaheuristic algorithms were introduced.Results showed MVO-LightGBM outperformed conventional LightGBM.Additionally,decision tree(DT),support vector machine(SVM),and classification and regression tree(CART)models were trained and compared with MVO-LightGBM.The MVO-LightGBM model excelled over DT,SVM,and CART.This study highlights MVO-LightGBM's effectiveness and potential for broader applications.Furthermore,a multiple parametric sensitivity analysis(MPSA)algorithm was employed to specify the sensitivity of parameters.MPSA results indicated that the highest and lowest sensitivities are relevant to blasted rock per hole and spacing with theγ=1752.12 andγ=49.52,respectively.
基金Project(2023AH051167)supported by the Natural Science Research Project of Anhui Educational Committee,ChinaProject(AHBP2024B-04)supported by the Foundation of Anhui Engineering Research Center of New Explosive Materials and Blasting Technology,China+1 种基金Project(GXZDSYS2023103)supported by the Open Fund for Anhui Key Laboratory of Mining Construction Engineering,ChinaProjects(52274071,52404155)supported by the National Natural Science Foundation of China。
文摘Aiming at the problem of dynamic instability of hard-brittle jointed rock surrounding in deep tunnel/roadway engineering,combining with the support concepts of"coupling rigidity with flexibility"and"overcoming rigidity by flexibility",the prevention and control method with"rigid-flexible coupling(R-F-C)"was put forward.Through numerical simulation calculation,the impact damage process,acoustic emission(AE)evolution characteristics,and element stress/displacement evolution characteristics of unsupported surrounding rock structure model,rigid supporting surrounding rock structure model,and"R-F-C"supporting surrounding rock structure model under horizontal bidirectional impact loading were compared and analyzed.Based on the theory of stress wave propagation,the dynamic instability catastrophe mechanism of three kinds of supporting structure models induced by horizontal bidirectional impact loading was revealed.Based on the Mohr-Coulomb strength theory,the stress discrimination methods of dynamic catastrophe of surrounding rock induced by horizontal bidirectional impact loading under three kinds of supporting structures were proposed.Combined with the above numerical simulation study,the explosion impact physical and mechanical test of"R-F-C"surrounding rock supporting plate structure was further designed and carried out.Finally,combined with the"conceptual model of ball-cliff potential energy instability",the energy driving theory and energy transformation mechanism of impact-induced rockburst under three kinds of supporting structures were discussed deeply.The research results provided a scientific basis for further promoting the effective application of"R-F-C"supporting structure in the prevention and control of dynamic instability of deep tunnel/roadway surrounding rock.
基金supported by the National Natural Science Foundation of China (Nos.51504008,71371014,and 51774012)the Natural Science Foundation of Anhui Higher Education Institutions of China (No.KJ2015A068)+3 种基金the Anhui Provincial Natural Science Foundation (No.1608085QE115)the China Postdoctoral Science Foundation funded project (Nos.2015M571913 and 2018T110612)the Postdoctoral Fund of Anhui Province (No.2017B212)the Scientific Research Foundation for Introduction of Talent of Anhui University of Science & Technology (No.ZY530)
文摘During the past decade, coal dust and gas explosions have been the most two serious types of disasters in China, threatening the lives of miners and causing significant losses in terms of national property. In this paper, an evaluation model of coal dust and gas explosions was constructed based on a fuzzy fault tree by taking the Xingli Coal Mine as a research site to identify the risk factors of coal dust and gas explosions.Furthermore, the hazards associated with such explosions were evaluated for this particular coal mine.After completing an on-site investigation, the fuzzy probabilities of basic events were obtained through expert scoring, and these expert opinions were then aggregated as trapezoidal fuzzy numbers to calculate the degrees of importance of all basic events. Finally, these degrees of importance were sorted. According to the resulting order, the basic events with higher probabilities were determined to identify key hazards in the daily safety management of this particular coal mine. Moreover, effective measures for preventing gas and coal dust explosions were derived. The fuzzy fault tree analysis method is of high significance in the analysis of accidental coal mine explosions and provides theoretical guidance for improving the efficiency of coal mine safety management in a scientific and feasible manner.
文摘Abstract： Trivalent europium doped zinc oxide （ZnO：Eu3＋） nanocrystals were synthesized via room temperature chemical co-pre- cipitation and they were systematically characterized by means of X-ray diffraction （XRD）, Fourier transform infrared spectroscopy （FTIR） and photoluminescence （PL） spectroscopy. The as-synthesized samples were found to have hexagonal wurtzite coexisted with the intermediate Zn5（OH）sC12·H2O phase, while the single hexagonal phase was facilitated due to the calcinations. The as obtained samples were broadly composed ofnanoflakes while the highly crystalline nanorods were formed due to low temperature annealing of the as-synthesized samples. The crystallite size of the nanoflakes and nanorods （40-90 nm） were extracted from the XRD pattern which was found to be consistent with scanning electron microscopy （SEM） measurements. The photoluminescence （PL） spectra of nanophosphors showed bright red and orange emissions at 618 and 594 nm respectively with efficient broad blue green emis- sion spectrum due to ZnO lattice. Further, a good energy transfer process from ZnO host to Eu3＋ was observed in PL emission and excitation spectra of Eu3＋ doped ZnO ions. In all, the present nanophosphors were found to have great potentiality for bio-appli- cations.
文摘The increasing use of diesel-powered equipment in confined spaces(underground mines) has the potential to over expose underground miners under the threat of diesel particulate matter(DPM). Miners in underground mines can be exposed to DPM concentrations far more than works in other industries. A great number of animal and epidemiological studies have shown that both short-term and long-term DPM exposure have adverse health effect. Based on reviews of related studies, especially some recent evidence, this paper investigated the long and short-term health effects based on animal studies and epidemiological studies. The exposure-response relationship studies were also explored and compared to the current DPM regulation or standards in some countries. This paper found that the DPM health effect studies specifically for miners are not sufficient to draw solid conclusions, and a recommendation limit of DPM concentration can be put in place for better protection of miners from DPM health risk. Current animal studies lack the use of species that have similar lung functions as human for understanding the cancer mode of action in human. And finally, the DPM health hazard will continue to be a challenging topic before the mode of action and reliable exposure-response relationship are established.
文摘Work injuries in mines are complex and generally characterized by several factors starting from personal to technical and technical to social characteristics.In this paper,investigation was made through the application of structural equation modeling to study the nature of relationships between the influencing/associating personal factors and work injury and their sequential relationships leading towards work injury occurrences in underground coal mines.Six variables namely,rebelliousness,negative affectivity,job boredom,job dissatisfaction and work injury were considered in this study.Instruments were developed to quantify them through a questionnaire survey.Underground mine workers were randomly selected for the survey.Responses from 300 participants were used for the analysis.The structural model of LISREL was used to estimate the interrelationships amongst the variables.The case study results show that negative affectivity and job boredom induce more job dissatisfaction to the workers whereas risk taking attitude of the individual is positively influenced by job dissatisfaction as well as by rebelliousness characteristics of the individual.Finally,risk taking and job dissatisfaction are having positive significant direct relationship with work injury.The findings of this study clearly reveal that rebelliousness,negative affectivity and job boredom are the three key personal factors influencing work related injuries in mines that need to be addressed properly through effective safety programs.
基金part of a PhD research, which was supported by Mine Optimization Laboratory, University of Alberta-Canada
文摘Accuracy in predictions leads to better planning with a minimum of opportunity lost. In open pit mining,the complexity of operations, coupled with a highly uncertain and dynamic production environment,limit the accuracy of predictions and force a reactive planning approach to mitigate deviations from original plans. A simulation optimization framework/tool is presented in this paper to account for uncertainties in mining operations for robust short-term production planning and proactive decision making. This framework/tool uses a discrete event simulation model of mine operations, which interacts with a goalprogramming based mine operational optimization tool to develop an uncertainty based short-term schedule. Using scenario analysis, this framework allows the planner to make proactive decisions to achieve the mine's operational and long-term objectives. This paper details the development of simulation and optimization models and presents the implementation of the framework on an iron ore mine case study for verification through scenario analysis.
