Environmentally friendly lead-free relaxor ferroelectric ceramics with outstanding energy storage performance have become a key research direction for advanced pulsed power systems due to their ultrafast discharge spe...Environmentally friendly lead-free relaxor ferroelectric ceramics with outstanding energy storage performance have become a key research direction for advanced pulsed power systems due to their ultrafast discharge speed and high energy density.However,the development of environmentally friendly,leadfree energy storage ceramics faces multiple critical challenges,such as low breakdown strength,low energy storage density,and low efficiency.To address these issues,we developed a novel lead-free TTBs relaxor ferroelectric ceramic,Bi_(0.15)Na_(0.15)Sr_(0.3)Ba_(0.4)Nb_2O_6-1 wt%C_(6)H_(5)O_(7)Na_(3),achieving a W_(rec)of 9.53 J cm^(-3)and an ultra-highηof 92%at 730 kV cm^(-1).This represents a significant breakthrough in the performance of lead-free TTBs energy storage ceramics.By incorporating C_(6)H_(5)O_(7)Na_(3),we effectively suppressed the concentration of oxygen vacancy defects,inhibited abnormal grain growth,and formed dense grain boundaries to prevent defect diffusion under external stimulation.These modifications enhance energy storage performance and excellent stability.This finding not only validate an optimization strategy for TTBs-based dielectric capacitors but also introduce C_(6)H_(5)O_(7)Na_(3) into the lead-free relaxor ferroelectric ceramic system.In summary,this work establishes a new design paradigm integrating'leadfree composition,high performance,and high stability'characteristics,providing crucial technological support for applying lead-free energy storage ceramics in pulse power systems and next-generation energy storage applications.展开更多
Improving the cycling stability of metal sulfide-based anode materials at high rate is of great significance for advanced sodium ion batteries.However,the sluggish reaction kinetics is a big obstacle for the developme...Improving the cycling stability of metal sulfide-based anode materials at high rate is of great significance for advanced sodium ion batteries.However,the sluggish reaction kinetics is a big obstacle for the development of high-performance sodium storage electrodes.Herein,we have rationally engineered the heterointerface by designing the Fe1?xS/MoS2 heterostructure with abundant“ion reservoir”to endow the electrode with excellent cycling stability and rate capability,which is proved by a series of in and ex situ electrochemical investigations.Density functional theory calculations further reveal that the heterointerface greatly decreases sodium ion diffusion barrier and facilitates charge-transfer kinetics.Our present findings not only provide a deep analysis on the correlation between the structure and performance,but also draw inspiration for rational heterointerface engineering toward the next-generation high-performance energy storage devices.展开更多
Photocatalytic decomposition of sugars is a promising way of providing H_(2),CO,and HCOOH as sus-tainable energy vectors.However,the production of C_(1) chemicals requires the cleavage of robust C−C bonds in sugars wi...Photocatalytic decomposition of sugars is a promising way of providing H_(2),CO,and HCOOH as sus-tainable energy vectors.However,the production of C_(1) chemicals requires the cleavage of robust C−C bonds in sugars with concurrent production of H_(2),which remains challenging.Here,the photo-catalytic activity for glucose decomposition to HCOOH,CO(C_(1) chemicals),and H_(2) on Cu/TiO_(2)was enhanced by nitrogen doping.Owing to nitrogen doping,atomically dispersed and stable Cu sites resistant to light irradiation are formed on Cu/TiO_(2).The electronic interaction between Cu and nitrogen ions originates valence band structure and defect levels composed of N 2p orbit,distinct from undoped Cu/TiO_(2).Therefore,the lifetime of charge carriers is prolonged,resulting in the pro-duction of C_(1) chemicals and H_(2) with productivities 1.7 and 2.1 folds that of Cu/TiO_(2).This work pro-vides a strategy to design coordinatively stable Cu ions for photocatalytic biomass conversion.展开更多
This study aimed to investigate the effects of infant feces-derived Bifidobacterium breve CCFM1078 on rheumatoid cachexia(RC).Twenty-four female Wistar rats were assigned to 3 groups:CON group(normal saline by gavage)...This study aimed to investigate the effects of infant feces-derived Bifidobacterium breve CCFM1078 on rheumatoid cachexia(RC).Twenty-four female Wistar rats were assigned to 3 groups:CON group(normal saline by gavage),CIA group(collagen-induced arthritis(CIA),normal saline by gavage),and CCFM1078 group(CIA,3×10^(9)CFU/(rat·day)B.breve CCFM1078 gavage).The results demonstrated that B.breve CCFM1078 not only improved skeletal muscle function in CIA rats,but also modulated the gut microbiota,skeletal muscle metabolism and hormone levels,reduced inflammation in the knee joint and skeletal muscles,decreased activity of the nuclear factor κB(NF-κB)inflammatory signaling pathway,enhanced the insulin receptor substrate 1(IRS1)/phosphatidylinositol 3-kinase/protein kinase(PI3K/Akt)signaling pathway,promoted skeletal muscle differentiation,and maintained skeletal muscle fiber diameter,consequently slowing down the progression of RC.These findings suggested that B.breve CCFM1078 may have a beneficial role as part of a dietary intervention for RC,enhancing overall therapeutic effects.展开更多
Concrete production often relies on natural aggregates,which can lead to resource depletion and environmental harm.In addition,improper disposal of thermoplastic waste exacerbates ecological problems.Although signific...Concrete production often relies on natural aggregates,which can lead to resource depletion and environmental harm.In addition,improper disposal of thermoplastic waste exacerbates ecological problems.Although significant attention has recently been given to recycling various waste materials into concrete,studies specifically addressing thermoplastic recycled aggregates are still trending.This underscores the need to comprehensively review existing literature,identify research trends,and recognize gaps in understanding the mechanical performance of thermoplastic-based recycled aggregate concrete.Accordingly,this review summarizes recent investigations focused on the mechanical properties of thermoplastic-based recycled aggregate concrete,emphasizing aspects such as compressive strength,tensile behavior,modulus of elasticity,and durability characteristics.The primary aim is to consolidate scattered research findings,identify key parameters influencing mechanical behavior,and propose future research directions.Understanding the influence of recycled thermoplastic aggregates on concrete performance significantly supports sustainable construction practices by reducing dependency on virgin aggregates and mitigating environmental impacts associated with waste disposal.In addition,assessing mechanical performance contributes to confidence in the practical application,encouraging the broader adoption of thermoplastic-based recycled aggregate concrete in construction projects.Through this critical synthesis,the review guides researchers and industry practitioners toward informed decisions on the feasibility and reliability of integrating thermoplastic waste into concrete,thereby promoting sustainable infrastructure development.展开更多
We report the results of the experiment on synthesizing ^(287,288)Mc isotopes (Z=115) using the fusionevaporation reaction ^(243)Am(^(48)Ca,4n,3n)^(287,288)Mc at the Spectrometer for Heavy Atoms and Nuclear Structure-...We report the results of the experiment on synthesizing ^(287,288)Mc isotopes (Z=115) using the fusionevaporation reaction ^(243)Am(^(48)Ca,4n,3n)^(287,288)Mc at the Spectrometer for Heavy Atoms and Nuclear Structure-2(SHANS2),a gas-filled recoil separator located at the China Accelerator Facility for Superheavy Elements(CAFE2).In total,20 decay chains are attributed to ^(288)Mc and 1 decay chain is assigned to ^(287)Mc.The measured oa-decay properties of ^(287,288)Mc as well as its descendants are consistent with the known data.No additional decay chains originating from the 2n or 5n reaction channels were detected.The excitation function of the ^(243)Am(^(48)Ca,3n)^(288)Mc reaction was measured at the cross-section level of picobarn,which indicates the promising capability for the study of heavy and superheavy nuclei at the facility.展开更多
As a cornerstone for applications such as autonomous driving,3D urban perception is a burgeoning field of study.Enhancing the performance and robustness of these perception systems is crucial for ensuring the safety o...As a cornerstone for applications such as autonomous driving,3D urban perception is a burgeoning field of study.Enhancing the performance and robustness of these perception systems is crucial for ensuring the safety of next-generation autonomous vehicles.In this work,we introduce a novel neural scene representation called Street Detection Gaussians(SDGs),which redefines urban 3D perception through an integrated architecture unifying reconstruction and detection.At its core lies the dynamic Gaussian representation,where time-conditioned parameterization enables simultaneous modeling of static environments and dynamic objects through physically constrained Gaussian evolution.The framework’s radar-enhanced perception module learns cross-modal correlations between sparse radardata anddense visual features,resulting ina22%reduction inocclusionerrors compared tovisiononly systems.A breakthrough differentiable rendering pipeline back-propagates semantic detection losses throughout the entire 3D reconstruction process,enabling the optimization of both geometric and semantic fidelity.Evaluated on the Waymo Open Dataset and the KITTI Dataset,the system achieves real-time performance(135 Frames Per Second(FPS)),photorealistic quality(Peak Signal-to-Noise Ratio(PSNR)34.9 dB),and state-of-the-art detection accuracy(78.1%Mean Average Precision(mAP)),demonstrating a 3.8×end-to-end improvement over existing hybrid approaches while enabling seamless integration with autonomous driving stacks.展开更多
The rapid growth in available network bandwidth has directly contributed to an exponential increase in mobile data traffic,creating significant challenges for network energy consumption.Also,with the extraordinary gro...The rapid growth in available network bandwidth has directly contributed to an exponential increase in mobile data traffic,creating significant challenges for network energy consumption.Also,with the extraordinary growth of mobile communications,the data traffic has dramatically expanded,which has led to massive grid power consumption and incurred high operating expenditure(OPEX).However,the majority of current network designs struggle to efficientlymanage a massive amount of data using little power,which degrades energy efficiency performance.Thereby,it is necessary to have an efficient mechanism to reduce power consumption when processing large amounts of data in network data centers.Utilizing renewable energy sources to power the Cloud Radio Access Network(C-RAN)greatly reduces the need to purchase energy from the utility grid.In this paper,we propose a bandwidth-aware hybrid energypowered C-RAN that focuses on throughput and energy efficiency(EE)by lowering grid usage,aiming to enhance the EE.This paper examines the energy efficiency,spectral efficiency(SE),and average on-grid energy consumption,dealing with the major challenges of the temporal and spatial nature of traffic and renewable energy generation across various network setups.To assess the effectiveness of the suggested network by changing the transmission bandwidth,a comprehensive simulation has been conducted.The numerical findings support the efficacy of the suggested approach.展开更多
Transition metal-N-C materials have considerably been demonstrated as promising catalysts for cathodic oxygen reduction reaction(ORR)in Zn-air batteries.Current efforts mainly focus on tailoring coordination structure...Transition metal-N-C materials have considerably been demonstrated as promising catalysts for cathodic oxygen reduction reaction(ORR)in Zn-air batteries.Current efforts mainly focus on tailoring coordination structure and identifying active sites of metal-N-C materials for ORR,while the mass transport of metal-N-C employed in catalytic layers of working electrodes is seldom engineered.Herein,a Fe-N-C single-atom catalyst featuring high mesoporosity and abundant electrochemically accessible active sites is developed through post-loading Fe species into defective N-doped carbon support.The Fe-N-C single-atom catalyst serving as the air cathode of Zn-air battery delivers a peak power density of 189.9 mW cm^(−2),significantly larger than 114.2 mW cm^(−2) of commercial Pt/C and 162.9 mW cm^(−2) of the Fe-N-C contrast catalyst with low mesoporosity.More importantly,through adding hydrophobic polytetrafluoroethylene(PTFE)nanoparticles in the catalytic layer of air cathode,the peak power density of Fe-N-C single-atom catalyst is further increased to 212.3 mW cm^(−2).The increased peak power density is attributed to the enhancement of O_(2) mass transport,as evidenced by a substantially decreased diffusion layer thickness that is obtained from electrochemical impedance spectroscopy.展开更多
Inverted perovskite solar cells based on weakly polarized hole-transporting layers suffer from the problem of polarity mismatch with the perovskite precursor solution,resulting in a nonideal wetting surface.In additio...Inverted perovskite solar cells based on weakly polarized hole-transporting layers suffer from the problem of polarity mismatch with the perovskite precursor solution,resulting in a nonideal wetting surface.In addition to the bottom-up growth of the polycrystalline halide perovskite,this will inevitably worse the effects of residual strain and heterogeneity at the buried interface on the interfacial carrier transport and localized compositional deficiency.Here,we propose a multifunctional hybrid pre-embedding strategy to improve substrate wettability and address unfavorable strain and heterogeneities.By exposing the buried interface,it was found that the residual strain of the perovskite films was markedly reduced because of the presence of organic polyelectrolyte and imidazolium salt,which not only realized the halogen compensation and the coordination of Pb^(2+) but also the buried interface morphology and defect recombination that were well regulated.Benefitting from the above advantages,the power conversion efficiency of the targeted inverted devices with a bandgap of 1.62 eV was 21.93%and outstanding intrinsic stability.In addition,this coembedding strategy can be extended to devices with a bandgap of 1.55 eV,and the champion device achieved a power conversion efficiency of 23.74%.In addition,the optimized perovskite solar cells retained 91%of their initial efficiency(960 h)when exposed to an ambient relative humidity of 20%,with a T80 of 680 h under heating aging at 65℃,exhibiting elevated durability.展开更多
Metasurfaces offer exceptional capabilities for controlling electromagnetic waves,enabling the realization of unique electromagnetic properties.As communication technology continues to evolve,metasurfaces present prom...Metasurfaces offer exceptional capabilities for controlling electromagnetic waves,enabling the realization of unique electromagnetic properties.As communication technology continues to evolve,metasurfaces present promising applications in wireless communications.This paper reviews the latest advancements in metasurface research within the communication sector,explores metasurface-based wireless relay technologies,and summarizes various wireless communication methods employing different types of metasurfaces across diverse modulation schemes.This paper provides a detailed discussion on the design of wireless communication systems based on coding metasurfaces to simplify transmitter architecture,as well as the development of intelligent coding metasurfaces in the communication field.It also elaborates on the application of vector vortex light fields in metasurface communication.Finally,it offers a forward-looking perspective on wireless communication systems that incorporate coded metasurfaces.This review aims to furnish researchers with a thorough understanding of the current state and future directions of coded metasurface applications in communications.展开更多
The development of high-performance electrocatalysts with rapid mass and charge transfer for the hydrogen evolution reaction(HER)at high current densities is critical to enabling practical hydrogen production via alka...The development of high-performance electrocatalysts with rapid mass and charge transfer for the hydrogen evolution reaction(HER)at high current densities is critical to enabling practical hydrogen production via alkaline water electrolysis(AWE).Currently,important research advancements have been made in the rational design of ruthenium(Ru)-based electrocatalysts,aiming to satisfy the performance requirements of large-scale electrochemical hydrogen production.A timely summary of recent advances is pivotal for designing next-generation Ru-based electrocatalysts.Herein,we systematically examine key strategies for optimizing their electronic effect and water/bubble behaviors,alongside detailed discussions on recent breakthroughs in integrated Ru-based AWE systems.Furthermore,we outline the remaining bottlenecks and future directions for deploying Ru-based electrocatalysts in commercial applications.展开更多
There was limited knowledge about the flow fluctuations and cycling processes of saline springs in the Nangqen Basin in the Sanjiang tectonic zone.In this work,the flow variations of the saline springs during the wet ...There was limited knowledge about the flow fluctuations and cycling processes of saline springs in the Nangqen Basin in the Sanjiang tectonic zone.In this work,the flow variations of the saline springs during the wet and dry seasons were monitored using volumetric and cross-sectional methods,and the cycling process of the saline springs was quantitatively identified using the integrated hydrochemical and isotopic methods.The results show that most saline springs in the Nangqen Basin had significantly different flow rates,ion concentrations,and TDS concentrations.The ions mainly come from carbonate and sulfate minerals.There is no internal hydraulic connection between these saline springs,and the impact of seasonal changes on the flow is relatively small,indicating that the saline springs originate mainly from deep circulation.The recharge elevation of the saline springs ranges 3661-4990 m a.s.l.,with an average of 4100 m a.s.l.The circulation depth of the saline springs ranges of 240-570 m,with an average of 431 m.The recycle time ranges of 1.15-30.86 years,with an average of 15.66 years.These results could provide a scientific basis for the development and utilization of saline spring resources in the Nangqen Basin.展开更多
Copper is a versatile material,commonly utilized in power transmission and electronic devices,but its relative high reactivity necessitates a long-lasting protective technique.Here,we report a method that combines pla...Copper is a versatile material,commonly utilized in power transmission and electronic devices,but its relative high reactivity necessitates a long-lasting protective technique.Here,we report a method that combines plasma-enhanced non-equilibrium magnetron sputtering physical vapor deposition(PEUMS-PVD)and anodization to construct a self-healing three-dimensional Ti/Al-doped TiO_(2)nanotubes/Ti_(3)AlC_(2)coating on the surface of Cu substrates.This novel strategy enhances the corrosion resistance of copper substrates in marine environments,with corrosion current densities of up to 4.5643×10^(−8)A/cm^(2).Among them,the doping of nano-aluminum particles makes the coating self-healing.The mechanistic analysis of the corrosion behaviors during early immersion experiments was conducted using electrochemical noise,and revealed that during the initial stages of coating immersion,uniform corrosion predominates,with a minor occurrence of localized corrosion.展开更多
Membrane fouling is a persistent challenge in membrane-based technologies,significantly impacting efficiency,operational costs,and system lifespan in applications like water treatment,desalination,and industrial proce...Membrane fouling is a persistent challenge in membrane-based technologies,significantly impacting efficiency,operational costs,and system lifespan in applications like water treatment,desalination,and industrial processing.Foul-ing,caused by the accumulation of particulates,organic compounds,and microorganisms,leads to reduced permeability,increased energy demands,and frequent maintenance.Traditional fouling control approaches,relying on empirical models and reactive strategies,often fail to address these issues efficiently.In this context,artificial intelligence(AI)and machine learning(ML)have emerged as innovative tools offering predictive and proactive solutions for fouling man-agement.By utilizing historical and real-time data,AI/ML techniques such as artificial neural networks,support vector machines,and ensemble models enable accurate prediction of fouling onset,identification of fouling mechanisms,and optimization of control measures.This review provides a detailed examination of the integration of AI/ML in membrane fouling prediction and mitigation,discussing advanced algorithms,the role of sensor-based monitoring,and the importance of robust datasets in enhancing predictive accuracy.Case studies highlighting successful AI/ML applications across various membrane processes are presented,demonstrating their transformative potential in improving system performance.Emerging trends,such as hybrid modeling and IoT-enabled smart systems,are explored,alongside a criti-cal analysis of research gaps and opportunities.This review emphasizes AI/ML as a cornerstone for sustainable,cost-effective membrane operations.展开更多
Piezoceramic is ubiquitously used in high-performance sensors and actuators.Three-dimensional(3D)printing of lead zirconate titanate(PZT)is attractive and highly desired for such device applications,but most of the ex...Piezoceramic is ubiquitously used in high-performance sensors and actuators.Three-dimensional(3D)printing of lead zirconate titanate(PZT)is attractive and highly desired for such device applications,but most of the existing methods are inherently limited to micron resolution,which makes them untenable for fabricating complex 3D architectures with high-definition features.Here,an electrohydrodynamic jet(E-Jet)nanoprinting strategy has been proposed to fabricate PZT 3D structures with the characteristics of flexibility and scalability.Different kinds of 3D PZT true nanostructures(resolution∼40 nm,aspect ratio∼400)were directly fabricated using a 100μm-sized nozzle.And the PZT nanostructures exhibited well-developed perovskite crystal morphology,large elastic strain(elongation≈13%),and high piezoelectric property(d_(31)≈(236.5×10^(−12))C·N^(-1)).A bionic PZT air-flow sensor was printed to monitor air-flow detection,demonstrating well sensitivity with ultra-slow air-flow of 0.02 m·s^(-1).The discovery reveals an efficient pathway to 3D-printing PZT nanostructures for next-generation high-performance piezoelectric devices.展开更多
Microneedles(MNs)have attracted increasing attention as a transdermal delivery system(TDDS)[1].However,traditional volatile Chinese medicines cannot be dissolved in conventional soluble MN materials,such as hyaluronic...Microneedles(MNs)have attracted increasing attention as a transdermal delivery system(TDDS)[1].However,traditional volatile Chinese medicines cannot be dissolved in conventional soluble MN materials,such as hyaluronic acid and chitosan,making it difficult for many traditional Chinese medicine ingredients to be applied to MN.Elemene(ELE)was successfully isolated from Curcuma longa,and has numerous antitumor and curative effects[2].展开更多
Spinal fusion is a commonly used technique to treat acute and chronic spinal diseases by fusion of the adjacent vertebrae, aiming at achieving stability and eliminating the mobility of the objective segment. While bon...Spinal fusion is a commonly used technique to treat acute and chronic spinal diseases by fusion of the adjacent vertebrae, aiming at achieving stability and eliminating the mobility of the objective segment. While bone autografts and allografts have been conventionally used for spinal fusion, limitations persist in achieving optimization of both good osteoinductive capacity and mechanical stability. In this study, additively manufactured Zn-Li scaffolds were developed and evaluated for their potential in spinal fusion. First, three scaffold structures (BCC, Diamond, and Gyroid) were designed and verified in vitro. Due to the smooth transition surfaces and uniform degradation behavior, the Gyroid Zn-Li scaffold demonstrated mechanical integrity during degradation and enhanced cellular proliferation compared to the other two scaffolds. Subsequently, Zn-Li scaffolds (Gyroid) were selected for posterolateral lumbar fusion (L4/L5) in rabbits. Following 12 weeks of implantation, the Zn-Li scaffolds demonstrated a moderate biodegradation rate and satisfactory biocompatibility. Compared to bone allografts, the Zn-Li scaffolds significantly improved osseointegration adjacent to the transverse processes, which led to enhanced segmental stability of the fused vertebrae post posterolateral lumbar fusion. Overall, the results show that the biodegradable Zn-Li scaffold holds substantial potential as the next-generation graft for spinal fusion.展开更多
Metallic scaffolds with lightweight,low elastic modulus,and high energy-absorbing capacity are widely utilized in industrial applications but usually require post-heat treatment to enhance their comprehen-sive mechani...Metallic scaffolds with lightweight,low elastic modulus,and high energy-absorbing capacity are widely utilized in industrial applications but usually require post-heat treatment to enhance their comprehen-sive mechanical properties.However,it is unclear how to utilize the impact ofβ-Nb on the surrounding matrix for NiTiNb ternary alloys to achieve strength-ductility-superelasticity enhancement.Here,we pre-pared rhomboidal dodecahedral NiTiNb porous scaffolds with a porosity of 85.9%by additive manufac-turing.Subsequently,annealing treatment was employed to drastically reduce the phase transformation temperatures and expand the thermal hysteresis.Interestingly,the 850℃ annealed scaffold exhibited exceeding double compressive strength of the as-built sample,with a remarkable improvement in ductil-ity and superelasticity.From the microstructure perspective,high-temperature annealing caused a further eutectic reaction of the unmelted Nb particles with the NiTi matrix and the transformation of mesh-likeβ-Nb into dispersedly distributed sphericalβ-Nb particles.The microstructure evolution after defor-mation indicated that stress-induced martensitic transformation occurred in the matrix away from the NiTi-Nb eutectic region whereas almost no martensite formed nearbyβ-Nb particles.Atom probe tomog-raphy characterization revealed an element diffusion zone in several nanometers surrounding theβ-Nb particle,where the substitution of Nb with Ti led to a higher Ni:Ti atomic ratio,lowering transforma-tion temperatures.Molecular dynamics simulations illustrated thatβ-Nb particles can not only entangle dislocations internally,acting as reinforcements but also hinder the twin growth,contributing to strain hardening.This work elucidates the influence ofβ-Nb particles on the deformation mechanism of the NiTi-Nb eutectic region through in-depth atomic-scale investigation,which can provide inspiration for the improvement of comprehensive mechanical properties of NiTiNb alloys.展开更多
Smart windows(SWs)garner significant potential in green buildings owing to their capability of on-demand tuning the solar gains.Apart from solar regulation,people always desire a type of slippery SW which can repel th...Smart windows(SWs)garner significant potential in green buildings owing to their capability of on-demand tuning the solar gains.Apart from solar regulation,people always desire a type of slippery SW which can repel the surface hydrous contaminants for anti-fouling application.Unfortunately,the up-to-date slippery SWs that respond to electrical/thermal stimuli have drawbacks of inferior durability and high energy-consumption,which greatly constrain their practical usability.This article presents our current work on an ultra-robust and energy-efficient near-infrared-responsive smart window(NIR-SW)which can regulate the optical transmittance and droplet’s adhesion in synergy.Significantly,laser-printing strategy enables us to seed the shape-memory photothermal microwalls on a transparent substrate,which can promote daylighting while maintaining privacy by near-infrared(NIR)switching between being transparent and opaque.As a light manipulator,it turns transparent with NIR-activated erect microwalls like an open louver;however,it turns opaque with the pressure-fixed bent microwalls akin to a closed louver.Simultaneously,the droplets can easily slip on the surface of erect microwalls similar to a classical lotus effect;by contrast,the droplets will tightly pin on the surface of bent microwalls analogous to the prevalent rose effect.Owing to shape-memory effect,this optical/wettability regulation is thus reversible and reconfigurable in response to the alternate NIR/pressure trigger.Moreover,NIR-SW unfolds a superior longevity despite suffering from the raindrop’s impacting more than 10000 cycles.Remarkably,such a new-type SW is competent for thermal management,anti-icing system,peep-proof screen,and programmable optics.This work renders impetus for the researchers striving for self-cleaning intelligent windows,energy-efficient greenhouse,and so forth.展开更多
基金supported by the National Natural Science Foundation of China(U23A20605 and 52201173)the S&T Program of Hebei(22567627H)+3 种基金the Henan key Laboratory of Aeronautical Materials and Application Technology Open fund(ZHKF-230113)the Opening Project of State Key Laboratory of Metastable Materials Science and Technology(202513)the Hebei Key Laboratory of Dielectric and Electrolyte Functional Material,Northeastern University at Qinhuangdao(HKDEFM2021301)the Fundamental Research Funds for the Central Universities(2024GFYD002)。
文摘Environmentally friendly lead-free relaxor ferroelectric ceramics with outstanding energy storage performance have become a key research direction for advanced pulsed power systems due to their ultrafast discharge speed and high energy density.However,the development of environmentally friendly,leadfree energy storage ceramics faces multiple critical challenges,such as low breakdown strength,low energy storage density,and low efficiency.To address these issues,we developed a novel lead-free TTBs relaxor ferroelectric ceramic,Bi_(0.15)Na_(0.15)Sr_(0.3)Ba_(0.4)Nb_2O_6-1 wt%C_(6)H_(5)O_(7)Na_(3),achieving a W_(rec)of 9.53 J cm^(-3)and an ultra-highηof 92%at 730 kV cm^(-1).This represents a significant breakthrough in the performance of lead-free TTBs energy storage ceramics.By incorporating C_(6)H_(5)O_(7)Na_(3),we effectively suppressed the concentration of oxygen vacancy defects,inhibited abnormal grain growth,and formed dense grain boundaries to prevent defect diffusion under external stimulation.These modifications enhance energy storage performance and excellent stability.This finding not only validate an optimization strategy for TTBs-based dielectric capacitors but also introduce C_(6)H_(5)O_(7)Na_(3) into the lead-free relaxor ferroelectric ceramic system.In summary,this work establishes a new design paradigm integrating'leadfree composition,high performance,and high stability'characteristics,providing crucial technological support for applying lead-free energy storage ceramics in pulse power systems and next-generation energy storage applications.
基金the support from the Thousand Young Talents Program of Chinathe National Natural Science Foundation of China(Nos.51602200,61874074,21603192)+3 种基金Science and Technology Project of Shenzhen(JCYJ20170817101100705,JCYJ20170817100111548,ZDSYS201707271014468)the(Key)Project of Department of Education of Guangdong Province(No.2016KZDXM008)supported by Shenzhen Peacock Plan(No.KQTD2016053112042971)Singapore Ministry of Education Academic Research Fund Tier 2(MOE2018-T2-2-178).
文摘Improving the cycling stability of metal sulfide-based anode materials at high rate is of great significance for advanced sodium ion batteries.However,the sluggish reaction kinetics is a big obstacle for the development of high-performance sodium storage electrodes.Herein,we have rationally engineered the heterointerface by designing the Fe1?xS/MoS2 heterostructure with abundant“ion reservoir”to endow the electrode with excellent cycling stability and rate capability,which is proved by a series of in and ex situ electrochemical investigations.Density functional theory calculations further reveal that the heterointerface greatly decreases sodium ion diffusion barrier and facilitates charge-transfer kinetics.Our present findings not only provide a deep analysis on the correlation between the structure and performance,but also draw inspiration for rational heterointerface engineering toward the next-generation high-performance energy storage devices.
文摘Photocatalytic decomposition of sugars is a promising way of providing H_(2),CO,and HCOOH as sus-tainable energy vectors.However,the production of C_(1) chemicals requires the cleavage of robust C−C bonds in sugars with concurrent production of H_(2),which remains challenging.Here,the photo-catalytic activity for glucose decomposition to HCOOH,CO(C_(1) chemicals),and H_(2) on Cu/TiO_(2)was enhanced by nitrogen doping.Owing to nitrogen doping,atomically dispersed and stable Cu sites resistant to light irradiation are formed on Cu/TiO_(2).The electronic interaction between Cu and nitrogen ions originates valence band structure and defect levels composed of N 2p orbit,distinct from undoped Cu/TiO_(2).Therefore,the lifetime of charge carriers is prolonged,resulting in the pro-duction of C_(1) chemicals and H_(2) with productivities 1.7 and 2.1 folds that of Cu/TiO_(2).This work pro-vides a strategy to design coordinatively stable Cu ions for photocatalytic biomass conversion.
基金supported by the National Natural Science Foundation of China(32021005)111 project(BP0719028)the Collaborative Innovation Center of Food Safety and Quality Control in Jiangsu Province.
文摘This study aimed to investigate the effects of infant feces-derived Bifidobacterium breve CCFM1078 on rheumatoid cachexia(RC).Twenty-four female Wistar rats were assigned to 3 groups:CON group(normal saline by gavage),CIA group(collagen-induced arthritis(CIA),normal saline by gavage),and CCFM1078 group(CIA,3×10^(9)CFU/(rat·day)B.breve CCFM1078 gavage).The results demonstrated that B.breve CCFM1078 not only improved skeletal muscle function in CIA rats,but also modulated the gut microbiota,skeletal muscle metabolism and hormone levels,reduced inflammation in the knee joint and skeletal muscles,decreased activity of the nuclear factor κB(NF-κB)inflammatory signaling pathway,enhanced the insulin receptor substrate 1(IRS1)/phosphatidylinositol 3-kinase/protein kinase(PI3K/Akt)signaling pathway,promoted skeletal muscle differentiation,and maintained skeletal muscle fiber diameter,consequently slowing down the progression of RC.These findings suggested that B.breve CCFM1078 may have a beneficial role as part of a dietary intervention for RC,enhancing overall therapeutic effects.
文摘Concrete production often relies on natural aggregates,which can lead to resource depletion and environmental harm.In addition,improper disposal of thermoplastic waste exacerbates ecological problems.Although significant attention has recently been given to recycling various waste materials into concrete,studies specifically addressing thermoplastic recycled aggregates are still trending.This underscores the need to comprehensively review existing literature,identify research trends,and recognize gaps in understanding the mechanical performance of thermoplastic-based recycled aggregate concrete.Accordingly,this review summarizes recent investigations focused on the mechanical properties of thermoplastic-based recycled aggregate concrete,emphasizing aspects such as compressive strength,tensile behavior,modulus of elasticity,and durability characteristics.The primary aim is to consolidate scattered research findings,identify key parameters influencing mechanical behavior,and propose future research directions.Understanding the influence of recycled thermoplastic aggregates on concrete performance significantly supports sustainable construction practices by reducing dependency on virgin aggregates and mitigating environmental impacts associated with waste disposal.In addition,assessing mechanical performance contributes to confidence in the practical application,encouraging the broader adoption of thermoplastic-based recycled aggregate concrete in construction projects.Through this critical synthesis,the review guides researchers and industry practitioners toward informed decisions on the feasibility and reliability of integrating thermoplastic waste into concrete,thereby promoting sustainable infrastructure development.
基金supported in part by the National Key R&D Program of China (Contract Nos.2023YFA1606500,2024YFE0109800,and 2024YFE0110400)Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB34010000)+5 种基金the Gansu Key Project of Science and Technology (Grant No.23ZDGA014)the Guangdong Major Project of Basic and Applied Basic Research (Grant No.2021B0301030006)the National Natural Science Foundation of China (Grant Nos.12105328,W2412040,12475126,12422507,12035011,12375118,12435008,and W2412043)the Chinese Academy of Sciences Project for Young Scientists in Basic Research(Grant No.YSBR-002)the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant Nos.2020409 and 2023439)the Russian Science Foundation (Grant No.25-42-00003)。
文摘We report the results of the experiment on synthesizing ^(287,288)Mc isotopes (Z=115) using the fusionevaporation reaction ^(243)Am(^(48)Ca,4n,3n)^(287,288)Mc at the Spectrometer for Heavy Atoms and Nuclear Structure-2(SHANS2),a gas-filled recoil separator located at the China Accelerator Facility for Superheavy Elements(CAFE2).In total,20 decay chains are attributed to ^(288)Mc and 1 decay chain is assigned to ^(287)Mc.The measured oa-decay properties of ^(287,288)Mc as well as its descendants are consistent with the known data.No additional decay chains originating from the 2n or 5n reaction channels were detected.The excitation function of the ^(243)Am(^(48)Ca,3n)^(288)Mc reaction was measured at the cross-section level of picobarn,which indicates the promising capability for the study of heavy and superheavy nuclei at the facility.
文摘As a cornerstone for applications such as autonomous driving,3D urban perception is a burgeoning field of study.Enhancing the performance and robustness of these perception systems is crucial for ensuring the safety of next-generation autonomous vehicles.In this work,we introduce a novel neural scene representation called Street Detection Gaussians(SDGs),which redefines urban 3D perception through an integrated architecture unifying reconstruction and detection.At its core lies the dynamic Gaussian representation,where time-conditioned parameterization enables simultaneous modeling of static environments and dynamic objects through physically constrained Gaussian evolution.The framework’s radar-enhanced perception module learns cross-modal correlations between sparse radardata anddense visual features,resulting ina22%reduction inocclusionerrors compared tovisiononly systems.A breakthrough differentiable rendering pipeline back-propagates semantic detection losses throughout the entire 3D reconstruction process,enabling the optimization of both geometric and semantic fidelity.Evaluated on the Waymo Open Dataset and the KITTI Dataset,the system achieves real-time performance(135 Frames Per Second(FPS)),photorealistic quality(Peak Signal-to-Noise Ratio(PSNR)34.9 dB),and state-of-the-art detection accuracy(78.1%Mean Average Precision(mAP)),demonstrating a 3.8×end-to-end improvement over existing hybrid approaches while enabling seamless integration with autonomous driving stacks.
文摘The rapid growth in available network bandwidth has directly contributed to an exponential increase in mobile data traffic,creating significant challenges for network energy consumption.Also,with the extraordinary growth of mobile communications,the data traffic has dramatically expanded,which has led to massive grid power consumption and incurred high operating expenditure(OPEX).However,the majority of current network designs struggle to efficientlymanage a massive amount of data using little power,which degrades energy efficiency performance.Thereby,it is necessary to have an efficient mechanism to reduce power consumption when processing large amounts of data in network data centers.Utilizing renewable energy sources to power the Cloud Radio Access Network(C-RAN)greatly reduces the need to purchase energy from the utility grid.In this paper,we propose a bandwidth-aware hybrid energypowered C-RAN that focuses on throughput and energy efficiency(EE)by lowering grid usage,aiming to enhance the EE.This paper examines the energy efficiency,spectral efficiency(SE),and average on-grid energy consumption,dealing with the major challenges of the temporal and spatial nature of traffic and renewable energy generation across various network setups.To assess the effectiveness of the suggested network by changing the transmission bandwidth,a comprehensive simulation has been conducted.The numerical findings support the efficacy of the suggested approach.
基金supported by the National Natural Science Foundation of China(21838003,91834301,21978278,21978087)the Shanghai Scientific and Technological Innovation Project(18JC1410500,19JC1410400)the Fundamental Research Funds for the Central Universities(222201718002)。
文摘Transition metal-N-C materials have considerably been demonstrated as promising catalysts for cathodic oxygen reduction reaction(ORR)in Zn-air batteries.Current efforts mainly focus on tailoring coordination structure and identifying active sites of metal-N-C materials for ORR,while the mass transport of metal-N-C employed in catalytic layers of working electrodes is seldom engineered.Herein,a Fe-N-C single-atom catalyst featuring high mesoporosity and abundant electrochemically accessible active sites is developed through post-loading Fe species into defective N-doped carbon support.The Fe-N-C single-atom catalyst serving as the air cathode of Zn-air battery delivers a peak power density of 189.9 mW cm^(−2),significantly larger than 114.2 mW cm^(−2) of commercial Pt/C and 162.9 mW cm^(−2) of the Fe-N-C contrast catalyst with low mesoporosity.More importantly,through adding hydrophobic polytetrafluoroethylene(PTFE)nanoparticles in the catalytic layer of air cathode,the peak power density of Fe-N-C single-atom catalyst is further increased to 212.3 mW cm^(−2).The increased peak power density is attributed to the enhancement of O_(2) mass transport,as evidenced by a substantially decreased diffusion layer thickness that is obtained from electrochemical impedance spectroscopy.
基金funded by the National Natural Science Foundation of China(62004165)the Fundamental Research Funds for the Central Universities.
文摘Inverted perovskite solar cells based on weakly polarized hole-transporting layers suffer from the problem of polarity mismatch with the perovskite precursor solution,resulting in a nonideal wetting surface.In addition to the bottom-up growth of the polycrystalline halide perovskite,this will inevitably worse the effects of residual strain and heterogeneity at the buried interface on the interfacial carrier transport and localized compositional deficiency.Here,we propose a multifunctional hybrid pre-embedding strategy to improve substrate wettability and address unfavorable strain and heterogeneities.By exposing the buried interface,it was found that the residual strain of the perovskite films was markedly reduced because of the presence of organic polyelectrolyte and imidazolium salt,which not only realized the halogen compensation and the coordination of Pb^(2+) but also the buried interface morphology and defect recombination that were well regulated.Benefitting from the above advantages,the power conversion efficiency of the targeted inverted devices with a bandgap of 1.62 eV was 21.93%and outstanding intrinsic stability.In addition,this coembedding strategy can be extended to devices with a bandgap of 1.55 eV,and the champion device achieved a power conversion efficiency of 23.74%.In addition,the optimized perovskite solar cells retained 91%of their initial efficiency(960 h)when exposed to an ambient relative humidity of 20%,with a T80 of 680 h under heating aging at 65℃,exhibiting elevated durability.
基金supported in part by National Natural Science Foundation of China(U24A20307 and 62175224)in part by the science and technology innovation leading talent project of special support plan for high-level talents in Zhejiang Province(2021R52032)+2 种基金in part by the China Jiliang University Basic Research ExpensesZhejiang University Students Science and Technology Innovation Activity Plan-New Talent Plan(2024R409C054)in part by the Natural Science Foundation of Zhejiang Province under Grant(ZCLZ25F0502).
文摘Metasurfaces offer exceptional capabilities for controlling electromagnetic waves,enabling the realization of unique electromagnetic properties.As communication technology continues to evolve,metasurfaces present promising applications in wireless communications.This paper reviews the latest advancements in metasurface research within the communication sector,explores metasurface-based wireless relay technologies,and summarizes various wireless communication methods employing different types of metasurfaces across diverse modulation schemes.This paper provides a detailed discussion on the design of wireless communication systems based on coding metasurfaces to simplify transmitter architecture,as well as the development of intelligent coding metasurfaces in the communication field.It also elaborates on the application of vector vortex light fields in metasurface communication.Finally,it offers a forward-looking perspective on wireless communication systems that incorporate coded metasurfaces.This review aims to furnish researchers with a thorough understanding of the current state and future directions of coded metasurface applications in communications.
基金National Natural Science Foundation of China(22472049)Natural Science Foundation of Wuhan(2024040801020308)+3 种基金Postdoctor Project of Hubei Province(2024HBBHCXB001)China Postdoctoral Science Foundation(2024M750846)Provincial Natural Science Foundation of Hunan(2025JJ20013)Changsha Natural Science Foundation(kq2402051)。
文摘The development of high-performance electrocatalysts with rapid mass and charge transfer for the hydrogen evolution reaction(HER)at high current densities is critical to enabling practical hydrogen production via alkaline water electrolysis(AWE).Currently,important research advancements have been made in the rational design of ruthenium(Ru)-based electrocatalysts,aiming to satisfy the performance requirements of large-scale electrochemical hydrogen production.A timely summary of recent advances is pivotal for designing next-generation Ru-based electrocatalysts.Herein,we systematically examine key strategies for optimizing their electronic effect and water/bubble behaviors,alongside detailed discussions on recent breakthroughs in integrated Ru-based AWE systems.Furthermore,we outline the remaining bottlenecks and future directions for deploying Ru-based electrocatalysts in commercial applications.
基金supported by the National Natural Science Foundation of China(Nos.42007169,U20A2088)the Natural Science Foundation of Qinghai Province(No.2020-ZJ-932Q)the Second Tibetan Plateau Scientific Expedition and Research Program(STEP)(No.2019QZKK0805-02)。
文摘There was limited knowledge about the flow fluctuations and cycling processes of saline springs in the Nangqen Basin in the Sanjiang tectonic zone.In this work,the flow variations of the saline springs during the wet and dry seasons were monitored using volumetric and cross-sectional methods,and the cycling process of the saline springs was quantitatively identified using the integrated hydrochemical and isotopic methods.The results show that most saline springs in the Nangqen Basin had significantly different flow rates,ion concentrations,and TDS concentrations.The ions mainly come from carbonate and sulfate minerals.There is no internal hydraulic connection between these saline springs,and the impact of seasonal changes on the flow is relatively small,indicating that the saline springs originate mainly from deep circulation.The recharge elevation of the saline springs ranges 3661-4990 m a.s.l.,with an average of 4100 m a.s.l.The circulation depth of the saline springs ranges of 240-570 m,with an average of 431 m.The recycle time ranges of 1.15-30.86 years,with an average of 15.66 years.These results could provide a scientific basis for the development and utilization of saline spring resources in the Nangqen Basin.
基金Projects(42106051,42006046,U2106206) supported by the National Natural Science Foundation of ChinaProject(22373501D) supported by Hebei Provincial Key R&D Program,China。
文摘Copper is a versatile material,commonly utilized in power transmission and electronic devices,but its relative high reactivity necessitates a long-lasting protective technique.Here,we report a method that combines plasma-enhanced non-equilibrium magnetron sputtering physical vapor deposition(PEUMS-PVD)and anodization to construct a self-healing three-dimensional Ti/Al-doped TiO_(2)nanotubes/Ti_(3)AlC_(2)coating on the surface of Cu substrates.This novel strategy enhances the corrosion resistance of copper substrates in marine environments,with corrosion current densities of up to 4.5643×10^(−8)A/cm^(2).Among them,the doping of nano-aluminum particles makes the coating self-healing.The mechanistic analysis of the corrosion behaviors during early immersion experiments was conducted using electrochemical noise,and revealed that during the initial stages of coating immersion,uniform corrosion predominates,with a minor occurrence of localized corrosion.
文摘Membrane fouling is a persistent challenge in membrane-based technologies,significantly impacting efficiency,operational costs,and system lifespan in applications like water treatment,desalination,and industrial processing.Foul-ing,caused by the accumulation of particulates,organic compounds,and microorganisms,leads to reduced permeability,increased energy demands,and frequent maintenance.Traditional fouling control approaches,relying on empirical models and reactive strategies,often fail to address these issues efficiently.In this context,artificial intelligence(AI)and machine learning(ML)have emerged as innovative tools offering predictive and proactive solutions for fouling man-agement.By utilizing historical and real-time data,AI/ML techniques such as artificial neural networks,support vector machines,and ensemble models enable accurate prediction of fouling onset,identification of fouling mechanisms,and optimization of control measures.This review provides a detailed examination of the integration of AI/ML in membrane fouling prediction and mitigation,discussing advanced algorithms,the role of sensor-based monitoring,and the importance of robust datasets in enhancing predictive accuracy.Case studies highlighting successful AI/ML applications across various membrane processes are presented,demonstrating their transformative potential in improving system performance.Emerging trends,such as hybrid modeling and IoT-enabled smart systems,are explored,alongside a criti-cal analysis of research gaps and opportunities.This review emphasizes AI/ML as a cornerstone for sustainable,cost-effective membrane operations.
基金supported by National Natural Science Foundation of China(Grant No.52105577)Natural Science Foundation of Zhejiang Province(Grant No.LQ22E050001)+3 种基金Natural Science Foundation of Ningbo(Grant Nos.2024J427 and 2023J376)China Postdoctoral Science Foundation(Grant No.2024M753510)Ningbo Yongjiang Talent Introduction Programme(Grant No.2021A-137-G)Research Grants Council of the Hong Kong Special Administrative Region,China(Grant Nos.11200623 and RFS2021-1S05).
文摘Piezoceramic is ubiquitously used in high-performance sensors and actuators.Three-dimensional(3D)printing of lead zirconate titanate(PZT)is attractive and highly desired for such device applications,but most of the existing methods are inherently limited to micron resolution,which makes them untenable for fabricating complex 3D architectures with high-definition features.Here,an electrohydrodynamic jet(E-Jet)nanoprinting strategy has been proposed to fabricate PZT 3D structures with the characteristics of flexibility and scalability.Different kinds of 3D PZT true nanostructures(resolution∼40 nm,aspect ratio∼400)were directly fabricated using a 100μm-sized nozzle.And the PZT nanostructures exhibited well-developed perovskite crystal morphology,large elastic strain(elongation≈13%),and high piezoelectric property(d_(31)≈(236.5×10^(−12))C·N^(-1)).A bionic PZT air-flow sensor was printed to monitor air-flow detection,demonstrating well sensitivity with ultra-slow air-flow of 0.02 m·s^(-1).The discovery reveals an efficient pathway to 3D-printing PZT nanostructures for next-generation high-performance piezoelectric devices.
基金supported by Shandong Provincial Natural Science Foundation Innovation and Development Joint Project,China(Grant No.:ZR2021LZY039)Zhejiang Provincial Traditional Chinese Medicine Science and Technology Plan,China(Grant No.:2021ZB184)。
文摘Microneedles(MNs)have attracted increasing attention as a transdermal delivery system(TDDS)[1].However,traditional volatile Chinese medicines cannot be dissolved in conventional soluble MN materials,such as hyaluronic acid and chitosan,making it difficult for many traditional Chinese medicine ingredients to be applied to MN.Elemene(ELE)was successfully isolated from Curcuma longa,and has numerous antitumor and curative effects[2].
基金supported by the National Natural Science Foundation of China(grant Nos.52301302,U22A20121,52175274,52111530042,and 5210010632)the China Postdoctoral Science Foundation(grant No.2023M732339)+1 种基金the Guangdong Basic and Applied Basic Research Foundation(Nos.2021A1515220086,2023A1515220095,and 2024A1515012042)the Beijing Natural Science Foundation(Grant No.L212014).
文摘Spinal fusion is a commonly used technique to treat acute and chronic spinal diseases by fusion of the adjacent vertebrae, aiming at achieving stability and eliminating the mobility of the objective segment. While bone autografts and allografts have been conventionally used for spinal fusion, limitations persist in achieving optimization of both good osteoinductive capacity and mechanical stability. In this study, additively manufactured Zn-Li scaffolds were developed and evaluated for their potential in spinal fusion. First, three scaffold structures (BCC, Diamond, and Gyroid) were designed and verified in vitro. Due to the smooth transition surfaces and uniform degradation behavior, the Gyroid Zn-Li scaffold demonstrated mechanical integrity during degradation and enhanced cellular proliferation compared to the other two scaffolds. Subsequently, Zn-Li scaffolds (Gyroid) were selected for posterolateral lumbar fusion (L4/L5) in rabbits. Following 12 weeks of implantation, the Zn-Li scaffolds demonstrated a moderate biodegradation rate and satisfactory biocompatibility. Compared to bone allografts, the Zn-Li scaffolds significantly improved osseointegration adjacent to the transverse processes, which led to enhanced segmental stability of the fused vertebrae post posterolateral lumbar fusion. Overall, the results show that the biodegradable Zn-Li scaffold holds substantial potential as the next-generation graft for spinal fusion.
基金financial supports of National Natural Science Foundation of China under Grant Nos.52274387 and 52311530772.
文摘Metallic scaffolds with lightweight,low elastic modulus,and high energy-absorbing capacity are widely utilized in industrial applications but usually require post-heat treatment to enhance their comprehen-sive mechanical properties.However,it is unclear how to utilize the impact ofβ-Nb on the surrounding matrix for NiTiNb ternary alloys to achieve strength-ductility-superelasticity enhancement.Here,we pre-pared rhomboidal dodecahedral NiTiNb porous scaffolds with a porosity of 85.9%by additive manufac-turing.Subsequently,annealing treatment was employed to drastically reduce the phase transformation temperatures and expand the thermal hysteresis.Interestingly,the 850℃ annealed scaffold exhibited exceeding double compressive strength of the as-built sample,with a remarkable improvement in ductil-ity and superelasticity.From the microstructure perspective,high-temperature annealing caused a further eutectic reaction of the unmelted Nb particles with the NiTi matrix and the transformation of mesh-likeβ-Nb into dispersedly distributed sphericalβ-Nb particles.The microstructure evolution after defor-mation indicated that stress-induced martensitic transformation occurred in the matrix away from the NiTi-Nb eutectic region whereas almost no martensite formed nearbyβ-Nb particles.Atom probe tomog-raphy characterization revealed an element diffusion zone in several nanometers surrounding theβ-Nb particle,where the substitution of Nb with Ti led to a higher Ni:Ti atomic ratio,lowering transforma-tion temperatures.Molecular dynamics simulations illustrated thatβ-Nb particles can not only entangle dislocations internally,acting as reinforcements but also hinder the twin growth,contributing to strain hardening.This work elucidates the influence ofβ-Nb particles on the deformation mechanism of the NiTi-Nb eutectic region through in-depth atomic-scale investigation,which can provide inspiration for the improvement of comprehensive mechanical properties of NiTiNb alloys.
基金supported by the National Natural Science Foundation of China(No.52005475,62305321)the Natural Science Foundation of Anhui Province(No.JZ2024AKZR0561,2308085QE167)Opening Project of the Key Laboratory of Bionic Engineering(Ministry of Education),Jilin University(K202204).
文摘Smart windows(SWs)garner significant potential in green buildings owing to their capability of on-demand tuning the solar gains.Apart from solar regulation,people always desire a type of slippery SW which can repel the surface hydrous contaminants for anti-fouling application.Unfortunately,the up-to-date slippery SWs that respond to electrical/thermal stimuli have drawbacks of inferior durability and high energy-consumption,which greatly constrain their practical usability.This article presents our current work on an ultra-robust and energy-efficient near-infrared-responsive smart window(NIR-SW)which can regulate the optical transmittance and droplet’s adhesion in synergy.Significantly,laser-printing strategy enables us to seed the shape-memory photothermal microwalls on a transparent substrate,which can promote daylighting while maintaining privacy by near-infrared(NIR)switching between being transparent and opaque.As a light manipulator,it turns transparent with NIR-activated erect microwalls like an open louver;however,it turns opaque with the pressure-fixed bent microwalls akin to a closed louver.Simultaneously,the droplets can easily slip on the surface of erect microwalls similar to a classical lotus effect;by contrast,the droplets will tightly pin on the surface of bent microwalls analogous to the prevalent rose effect.Owing to shape-memory effect,this optical/wettability regulation is thus reversible and reconfigurable in response to the alternate NIR/pressure trigger.Moreover,NIR-SW unfolds a superior longevity despite suffering from the raindrop’s impacting more than 10000 cycles.Remarkably,such a new-type SW is competent for thermal management,anti-icing system,peep-proof screen,and programmable optics.This work renders impetus for the researchers striving for self-cleaning intelligent windows,energy-efficient greenhouse,and so forth.
