Dipyrido [3, 2-a:2,3-c] phenazine moiety has been introduced as neutral ligand in europium complex. Therefore, a new europium complex with saturated emission, strong fluorescent intensity and good solubility was desi...Dipyrido [3, 2-a:2,3-c] phenazine moiety has been introduced as neutral ligand in europium complex. Therefore, a new europium complex with saturated emission, strong fluorescent intensity and good solubility was designed and synthesized for the first time. Its photoluminescence and UV properties were examined. The experimental results showed that this new Eu-complex could be used as red electroluminescent materials.展开更多
A novel cyclometalated iridium complex with 1, 3, 4-oxadiazole moiety was synthesizedand characterized. Its UV and photoluminescent properties were studied. The strong UVabsorption intensity around 462 nm attributed t...A novel cyclometalated iridium complex with 1, 3, 4-oxadiazole moiety was synthesizedand characterized. Its UV and photoluminescent properties were studied. The strong UVabsorption intensity around 462 nm attributed to spin-forbidden triplet metal–ligand charge transferband and photoluminescence at 518 nm were observed. This indicated that achieved iridiumcomplex could be used as an efficient electrophosphorescent material.展开更多
We displayed that the low-cost natural zeolite with molecular sieve structure can be used as the carrier of sulfur in lithium-sulfur batteries.Meanwhile,a simple salt-washing method was implemented on zeolite for dred...We displayed that the low-cost natural zeolite with molecular sieve structure can be used as the carrier of sulfur in lithium-sulfur batteries.Meanwhile,a simple salt-washing method was implemented on zeolite for dredging the internal microchannel to improve the ability of adsorption,ion exchange and sulfur loading.The experimental results show that the first specific discharge capacities of zeolite/S and salt-washed zeolite/S cathode under 0.2 C current density are 950.7 and1116.8 mAh/g,respectively,and corresponding discharge capacities remain at 350.6 and 604.2 mAh/g after 300 cycles.The first specific discharge capacity of salt-washed zeolite/S composite is 17.5%higher than that sample without salt-washing,and the corresponding ionic conductivity is improved.展开更多
The paper submits a method to calculate thermal deformation and manufacture error in surface grinding. The author established a simplified temperature field model, and derived the thermal deformation of the ground wor...The paper submits a method to calculate thermal deformation and manufacture error in surface grinding. The author established a simplified temperature field model, and derived the thermal deformation of the ground workpiece. It is found that there exists not only a upwarp thermal deformation, but also a parallel expansion thermal deformation. A upwarp thermal deformation causes a concave shape error on the profile of the workpiece, and a parallel expansion thermal deformation causes a dimension error in height. The calculations of examples are given and compared with presented experiment data.展开更多
The as-quenched microstructures of low carbon steels were observed by scanning electron microscope, and the thin foil specimen was examined by transmission electron microscopy. It is found that the space morphology of...The as-quenched microstructures of low carbon steels were observed by scanning electron microscope, and the thin foil specimen was examined by transmission electron microscopy. It is found that the space morphology of low carbon martensite is not lath-like but thin sheet-like, which is designated as sheet-like martensite or packet thin sheet martensite. A three-dimensional model was presented. The reason for exhibiting two apparent morphologies, i.e. double contrast packet and simple contrast packet, in as-quenched low carbon steels was analyzed in detail. It is suggested that the data of martensitic habit plane measured by other procedures should be further inspected using optical metallographic method. The apparent morphologies of low carbon martensite confirm that its habit plane should be {557}_r, rather than {111}_r, {345}_r, nor {213}_r.展开更多
The aim of this paper is to derive the power law type nonlinear viscoelastic crack-tip fields.For the requirement of later derivation,the HRR singular fields and the high-order asymp- totic fields are first examined.T...The aim of this paper is to derive the power law type nonlinear viscoelastic crack-tip fields.For the requirement of later derivation,the HRR singular fields and the high-order asymp- totic fields are first examined.That they are essentially the isotropic,incompressible,power law type nonlinear elastic crack-tip fields is illustrated.After a concise review of the elasticity recov- ery correspondence principle for solving the nonlinear viscoelastic problems,the correspondence principle for solving the crack problems of power law type nonlinear viscoelastic materials under the first type boundary condition is proposed.The solution of the crack-tip stress,strain fields for the power law type nonlinear viscoelastic materials,especially for the modified polypropylene, is obtained.展开更多
The application of a new type of moving bed reactor with draft tube for coal gasification was investigated. Successful coal gasification experiments were achieved using the coal gasifier. Product gas containing hydrog...The application of a new type of moving bed reactor with draft tube for coal gasification was investigated. Successful coal gasification experiments were achieved using the coal gasifier. Product gas containing hydrogen as high as 60% was obtained, and the calorific value of the product of 10 MJ·m-3 was obtained using air as oxidant. The reaction temperature of coal gasification in the moving bed was maintained at 870 °C which was comparatively low for coal gasification. Maximum coal gasification efficiency of 92% was obtained.展开更多
A semi analytical method was proposed to solve the mechanics problem of stamping a sheet on elastic die. The sheet was divided into four parts according to its deformation and contact with the punch and elastic die. ...A semi analytical method was proposed to solve the mechanics problem of stamping a sheet on elastic die. The sheet was divided into four parts according to its deformation and contact with the punch and elastic die. Analytical solutions were derived individually for each part by using elastic large deflection and plastic large deformation. Solutions were found out with MATLAB by developing a numerical algorithm. Interface forces were obtained by iteration under the compatibility conditions between the neighboring parts of the sheet. Computation shows the method is efficient.展开更多
The diamond films have been deposited by the hot filament CVD method on molybdenum substrates from the mixture reactant gas of acetone and hydrogen.The surface morphologies of the obtained diamond films under various ...The diamond films have been deposited by the hot filament CVD method on molybdenum substrates from the mixture reactant gas of acetone and hydrogen.The surface morphologies of the obtained diamond films under various deposition conditions have been observed by scanning electron microscope(SEM).The experimental results strongly indicate that the surface morphologies of the resulting films have closely related to the deposition conditions,i.e.,reaction pressure.For molybdenum substrates,under the lower reaction pressure the surface morphologies of the grains comprising the resulting films mainly display the small single crystal cubo-octahedron and double small crystal cubo-octahedron;under the higher reaction pressure,the surface morphologies mainly display the large cauliflower-like.These results show that there are various crystal habits for CVD diamond under various deposition conditions.展开更多
In this paper, the existence theorem of the cone weak subdifferential of set valued mapping in locally convex topological vector space is proved. Received March 30,1998. 1991 MR Subject Classification: 4...In this paper, the existence theorem of the cone weak subdifferential of set valued mapping in locally convex topological vector space is proved. Received March 30,1998. 1991 MR Subject Classification: 47H17,90C29.展开更多
基金This work was supported by the National Natural Science Foundation of China (No29992530-6) and Provincial Natural Science Foundation of Hunan (00JJY2043).
文摘Dipyrido [3, 2-a:2,3-c] phenazine moiety has been introduced as neutral ligand in europium complex. Therefore, a new europium complex with saturated emission, strong fluorescent intensity and good solubility was designed and synthesized for the first time. Its photoluminescence and UV properties were examined. The experimental results showed that this new Eu-complex could be used as red electroluminescent materials.
基金This work was supported by the National Natural Science Foundation of China(No.20272014)the Project of National Education Ministry(Project No.204097)National 973 Project of China(Project No.2002CB613400-5).
文摘A novel cyclometalated iridium complex with 1, 3, 4-oxadiazole moiety was synthesizedand characterized. Its UV and photoluminescent properties were studied. The strong UVabsorption intensity around 462 nm attributed to spin-forbidden triplet metal–ligand charge transferband and photoluminescence at 518 nm were observed. This indicated that achieved iridiumcomplex could be used as an efficient electrophosphorescent material.
基金Funded by the National Natural Science Foundation of China(Nos.11627801,51772254,11502225,and 51375017)the Natural Science Foundation of Hunan Province of China(No.2019JJ50578)。
文摘We displayed that the low-cost natural zeolite with molecular sieve structure can be used as the carrier of sulfur in lithium-sulfur batteries.Meanwhile,a simple salt-washing method was implemented on zeolite for dredging the internal microchannel to improve the ability of adsorption,ion exchange and sulfur loading.The experimental results show that the first specific discharge capacities of zeolite/S and salt-washed zeolite/S cathode under 0.2 C current density are 950.7 and1116.8 mAh/g,respectively,and corresponding discharge capacities remain at 350.6 and 604.2 mAh/g after 300 cycles.The first specific discharge capacity of salt-washed zeolite/S composite is 17.5%higher than that sample without salt-washing,and the corresponding ionic conductivity is improved.
文摘The paper submits a method to calculate thermal deformation and manufacture error in surface grinding. The author established a simplified temperature field model, and derived the thermal deformation of the ground workpiece. It is found that there exists not only a upwarp thermal deformation, but also a parallel expansion thermal deformation. A upwarp thermal deformation causes a concave shape error on the profile of the workpiece, and a parallel expansion thermal deformation causes a dimension error in height. The calculations of examples are given and compared with presented experiment data.
文摘The as-quenched microstructures of low carbon steels were observed by scanning electron microscope, and the thin foil specimen was examined by transmission electron microscopy. It is found that the space morphology of low carbon martensite is not lath-like but thin sheet-like, which is designated as sheet-like martensite or packet thin sheet martensite. A three-dimensional model was presented. The reason for exhibiting two apparent morphologies, i.e. double contrast packet and simple contrast packet, in as-quenched low carbon steels was analyzed in detail. It is suggested that the data of martensitic habit plane measured by other procedures should be further inspected using optical metallographic method. The apparent morphologies of low carbon martensite confirm that its habit plane should be {557}_r, rather than {111}_r, {345}_r, nor {213}_r.
基金Project supported by the Hunan Natural Science Foundation(Nos.01JJY3001 and 01JJY2001)Research Item of the Hunan Education Committee(No.01C083)and the Key Item of Hunan Science and Technology Department.
文摘The aim of this paper is to derive the power law type nonlinear viscoelastic crack-tip fields.For the requirement of later derivation,the HRR singular fields and the high-order asymp- totic fields are first examined.That they are essentially the isotropic,incompressible,power law type nonlinear elastic crack-tip fields is illustrated.After a concise review of the elasticity recov- ery correspondence principle for solving the nonlinear viscoelastic problems,the correspondence principle for solving the crack problems of power law type nonlinear viscoelastic materials under the first type boundary condition is proposed.The solution of the crack-tip stress,strain fields for the power law type nonlinear viscoelastic materials,especially for the modified polypropylene, is obtained.
文摘The application of a new type of moving bed reactor with draft tube for coal gasification was investigated. Successful coal gasification experiments were achieved using the coal gasifier. Product gas containing hydrogen as high as 60% was obtained, and the calorific value of the product of 10 MJ·m-3 was obtained using air as oxidant. The reaction temperature of coal gasification in the moving bed was maintained at 870 °C which was comparatively low for coal gasification. Maximum coal gasification efficiency of 92% was obtained.
文摘A semi analytical method was proposed to solve the mechanics problem of stamping a sheet on elastic die. The sheet was divided into four parts according to its deformation and contact with the punch and elastic die. Analytical solutions were derived individually for each part by using elastic large deflection and plastic large deformation. Solutions were found out with MATLAB by developing a numerical algorithm. Interface forces were obtained by iteration under the compatibility conditions between the neighboring parts of the sheet. Computation shows the method is efficient.
文摘The diamond films have been deposited by the hot filament CVD method on molybdenum substrates from the mixture reactant gas of acetone and hydrogen.The surface morphologies of the obtained diamond films under various deposition conditions have been observed by scanning electron microscope(SEM).The experimental results strongly indicate that the surface morphologies of the resulting films have closely related to the deposition conditions,i.e.,reaction pressure.For molybdenum substrates,under the lower reaction pressure the surface morphologies of the grains comprising the resulting films mainly display the small single crystal cubo-octahedron and double small crystal cubo-octahedron;under the higher reaction pressure,the surface morphologies mainly display the large cauliflower-like.These results show that there are various crystal habits for CVD diamond under various deposition conditions.
文摘In this paper, the existence theorem of the cone weak subdifferential of set valued mapping in locally convex topological vector space is proved. Received March 30,1998. 1991 MR Subject Classification: 47H17,90C29.
