Petrophysical well log data help to predict hydrocarbon reserves before field development which involves huge financial commitment.In this study,reservoir characterization was performed with a view to obtain informati...Petrophysical well log data help to predict hydrocarbon reserves before field development which involves huge financial commitment.In this study,reservoir characterization was performed with a view to obtain information on the geological formation type and petrophysical parameters.Wireline log data obtained from five wells were used to develop a 3D model of X-field in the Baram Delta which was in turn evaluated using the PETREL software.Suites of gamma ray,sonic,density,resistivity and neutron logs aided the delineation and correlation of the sandstone formation.Fourteen hydrocarbon-bearing sands were defined from well log data and divided into two-reservoir zones,shallow and deep.Well correlation assisted in the delineation of the reservoir sands across the wells.The quality of the reservoir formation was evaluated from average petrophysical properties:with an average thickness of 62 m,an average porosity of 0.19,an average net-to-gross ratio of 0.068,an average V-shale of 0.45,and an average water saturation of 0.95.A rollover anticline structure was identified across the field using the fault as a description tool.Variation of petrophysical parameters and uncertainty in the reservoir properties were included to predict the effect on the volume of oil in place.This study revealed that the discovered hydrocarbon reserve resource accumulations in the Field X for the fourteen-mapped reservoir sands have a total proven reserve resource estimate of 740MMSTB at P90,655MMSTB at P50 and 593MMSTB at P10.Reservoirs A and B are the only intervals with the highest recoverable oil,a volume of 256MMSTB at P90,215MMSTB at P50 and 181MMSTB at P10,respectively.These analyses facilitated an improved reservoir description of shaly sandstone,which contributes to better planning of hydrocarbon re-development and future recovery,and thereby improving the energy supply security of the regions.展开更多
Photoredox dual reaction of organic synthesis and H2 evolution opens up a novel pathway for collaboratively generating clean fuels and high-quality chemicals,providing a more effective approach of solar energy convers...Photoredox dual reaction of organic synthesis and H2 evolution opens up a novel pathway for collaboratively generating clean fuels and high-quality chemicals,providing a more effective approach of solar energy conversion.Herein,a surface defect-engineered ZnCoS/ZnCdS heterostructure with zinc blende(ZB)/wurtzite(WZ)phase junctions is synthesized for photocatalytic cooperative coupling of benzaldehyde(BAD)and H_(2) production.This surface defect-engineered ZnCoS/ZnCdS heterostructure elaborately integrates the mixed phase junction advantage of ZnCdS semiconductor and the cocatalytic function of ZnCoS possessing Zn(VZn-ZnCoS/ZnCdS)or S vacancies(VS-ZnCoS/ZnCdS).The optimum VS-ZnCoS/ZnCdS simultaneously exhibits a superior H2 production rate of 14.23 mmol h^(-1) g^(-1) accompanied with BAD formation rate of 12.29 mmol h^(-1) g^(-1) under visible-light irradiation,which is approximately two-fold greater than that of pristine ZnCdS.Under simulated sunlight irradiation(AM 1.5),VS-ZnCoS/ZnCdS achieves H2 evolution(27.43 mmol gcat^(-1) h^(-1))with 0.52%of STH efficiency,accompany with 26.31 mmol gcat^(-1) h^(-1) of BAD formation rate.The underlying solar-driven mechanism is elucidated by a series of in-situ characterization and control experiments,which reveals the synergistic effect of interfacial ZB/WZ phase junctions in ZnCdS and S vacancies of ZnCoS on enhancement of the photoredox dual reaction.The VS-ZnCoS/ZnCdS follows a predominant oxygen-centered radical integrating with carbon-centered radical pathways for BAD formation and a simultaneous electron-driven proton reduction for H_(2) production.Interestingly,the nature of surface vacancies not only facilitates the separation of photoinduced charge carriers but also able to selectively adjust the mechanism pathway for BAD production via tuning the oxygen-centered radical and carbon-centered radical formation.展开更多
The habitual use of smartphones during meals has become a common behavior,raising concerns about its potential impact on eating habits and metabolic health.The present narrative review investigates how using a smartph...The habitual use of smartphones during meals has become a common behavior,raising concerns about its potential impact on eating habits and metabolic health.The present narrative review investigates how using a smartphone or tablet during meals can cause distractions and negatively affect metabolic health.A comprehensive narrative review was conducted by synthesizing peer-reviewed studies on the interplay between smartphone use during meals,eating behaviors,and metabolic health.Relevant literature was identified through searches in electronic databases and organized thematically to highlight trends and research gaps.By synthesizing evidence from existing literature,this review highlights that smartphone use during meals is associated with increased caloric intake,altered food composition,and disruptions in postprandial metabolic responses.These effects are mediated by reduced meal awareness and psychological distractions,including multitasking.Variability in findings arises from differences in study designs and populations.This review identifies critical research gaps,including the lack of longitudinal studies and the need to explore mechanisms underlying these relationships.By summarizing trends and patterns,this narrative review offers valuable insights into the complex interplay between digital device use,eating habits,and metabolic health,providing a foundation for future research and interventions.展开更多
This perspective review explores the transformative potential of personalized herbal medicine,examines the integration of ancient herbal knowledge with modern personalized medicine,delves into the principles of person...This perspective review explores the transformative potential of personalized herbal medicine,examines the integration of ancient herbal knowledge with modern personalized medicine,delves into the principles of personalized medicine particularly in the context of herbal treatments,and investigates the principles of personalized medicine and elucidates how they are being applied to herbal medicine.It emphasizes the individualized nature of this approach and how it is facilitated through genetic analysis and health profiling.This review also highlights key advancements in herbal medicine,such as deoxyribonucleic acid(DNA)analysis and bioinformatics,and their role in the development of precise and personalized herbal remedies.The outcomes of personalized herbal medicine reveal how genetic variations are being considered to tailor treatments,create target-specific therapies,and customize dosage regimens.Furthermore,this review illustrates the evolution of herbal medicine with technological advancements,particularly DNA analysis and bioinformatics,to enhance precision and personalization.The challenge associated with implementing personalized herbal medicine more broadly includes issues of accessibility,regulation,education and ethics.It underscores the transformative potential of personalized herbal medicine.It calls for continued exploration,research and collaboration in this burgeoning field.This emerging field encourages researchers,practitioners,and stakeholders to engage in advancing healthcare practices that are increasingly personalized,evidence-based,and centered on patient's needs.展开更多
We utilize conventional wave-vector-resolved Brillouin light scattering technology to investigate the spin wave response in YIG thin films under high-power microwave excitation. By varying the microwave frequency, ext...We utilize conventional wave-vector-resolved Brillouin light scattering technology to investigate the spin wave response in YIG thin films under high-power microwave excitation. By varying the microwave frequency, external bias magnetic field, and in-plane wave vector, in addition to observing the dipole-exchange spin waves excited by parallel parametric pumping, we further observe broadband spin wave excitation within the dipole-exchange spin wave spectrum. This broadband excitation results from the combined effects of parallel and perpendicular parametric pumping, induced by irregularities in the excitation geometry, as well as magnon–magnon scattering arising from the absence of certain spin wave modes. Our findings offer new insights into the mechanisms of energy dissipation and relaxation processes caused by spin wave excitation in magnetic devices operating at high power.展开更多
Homojunction engineering is a promising modification strategy to improve charge carrier separation and photocatalytic performance of carbon nitrides.Leveraging intrinsic heptazine/triazine phase and face-to-face conta...Homojunction engineering is a promising modification strategy to improve charge carrier separation and photocatalytic performance of carbon nitrides.Leveraging intrinsic heptazine/triazine phase and face-to-face contact,crystalline C_(3)N_(5)(CC3N5)was combined with protonated g-C_(3)N_(4)(pgCN)through electrostatic self-assembly to achieve robust 2D/2D homojunction interfaces.The highest photocatalytic performance was obtained through crystallinity and homojunction engineering,by controlling the pgCN:CC3N5 ratio.The 25:100 pgCN:CC3N5 homo-junction(25CgCN)had the highest hydrogen production(1409.51 μmol h^(-1))and apparent quantum efficiency(25.04%,420 nm),8-fold and 180-fold higher than CC3N5 and pgCN,respectively.This photocatalytic homojunction improves benzaldehyde and hydrogen production activity,retaining 89%performance after 3 cycles(12 h)on a 3D-printed substrate.Electron paramagnetic resonance demonstrated higher·OH,·O_(2) and hole production of irradiated 25CgCN,attributed to crystallinity and homojunction interaction.Thus,electrostatic self-assembly to couple CC3N5 and pgCN in a 2D/2D homojunction interface ameliorates the performance of multifunctional solar-driven applications.展开更多
This review provided an updated synthesis of current knowledge regarding the processing, chemical constituents, pharmacological properties, and clinical applications of white tea (Camellia sinensis), commonly known as...This review provided an updated synthesis of current knowledge regarding the processing, chemical constituents, pharmacological properties, and clinical applications of white tea (Camellia sinensis), commonly known as WT. Information was collated from reliable sources, including Google, Google Scholar, PubMed, PubMed Central, Science Direct, PubChem, J-Stage, the Directory of Open Access Journals (DOAJ), and the China National Knowledge Infrastructure (CNKI). In China, WT, referred to as “Bai Cha”, is a prized spring tea harvested during early spring when the young tea plant leaf buds are still covered with delicate, downy white hairs. Fujian Province serves as the primary production region. WT processing is minimal, involving withering as the most crucial step, followed by drying. This simple process preserves its unique qualities and chemical integrity. The dominant phenolic compounds in WT are flavonoids, including catechins, dimeric catechins, flavones, flavonols, and flavanones. Additional constituents encompass phenolic acids, alkaloids, glycosides, and amino acids. These bioactive compounds contribute to WT’s diverse pharmacological properties, including anti-diabetic, anti-cancer, hepatoprotective, neuroprotective, anti-obesity, and male reproductive health benefits. To date, seven clinical studies have investigated the therapeutic potential of WT. These include two studies each on its use as a mouth rinse and its anti-obesity effects, and one study each focusing on its applications in managing diabetes, periodontitis, and depression. Perspectives on WT’s broader implications and opportunities for future research are also explored, highlighting its potential for expanded therapeutic applications.展开更多
By harnessing the power of MoS_(2) as a cocatalyst to enhance electron transfer and charge carrier separation,a groundbreaking two-in-one redox photocatalytic system was developed.This innovative system integrated 2D ...By harnessing the power of MoS_(2) as a cocatalyst to enhance electron transfer and charge carrier separation,a groundbreaking two-in-one redox photocatalytic system was developed.This innovative system integrated 2D MoS_(2) nanosheets onto hydrangea-like Zn_(3)In_(2)S_(6) nanosheets,forming a 2D/3D heterostructure that established a stable and intimate interface.This unique architecture significantly improved cooperative photocatalytic performance,enabling the simultaneous production of hydrogen and benzaldehyde under light irradiation≥420 nm.Notably,the system achieved remarkable yields of hydrogen(41.9 mmol g^(-1) h^(-1))and benzaldehyde(38.9 mmol g^(-1) h^(-1)),surpassing the pristine Zn_(3)In_(2)S_(6) by 22.4 times.An impressive electron-hole pair utilization rate of approximately 93%was attained,underscoring the high efficiency of this two-in-one redox system.Additionally,the targeted 10 wt%-MoS_(2) loaded Zn_(3)In_(2)S_(6)(10MZ)nanohybrids at 400 nm obtained an apparent quantum yield(AQY)value of 17.66%without sacrificial agents or noble metals.The exceptional performance was attributed to improved charge carrier separation and reduced recombination,facilitated by cocatalyst integration and evidenced via photoluminescence,photoelectrochemical and Kelvin probe force microscopy measurements.This work highlighted the critical role of two-in-one redox-functioning heterojunctions in optimizing electron-hole pair utilization,offering a promising approach for sustainable energy production and organic synthesis.By demonstrating the potential for efficient,simultaneous generation of valuable chemicals and fuels,this research paves the way for the development of next-generation photocatalytic systems.展开更多
Despite advances in photocatalytic half-reduction reactions,challenges remain in effectively utilizing electron-hole pairs in concurrent redox processes.The present study involved the construction of a p-n junction Co...Despite advances in photocatalytic half-reduction reactions,challenges remain in effectively utilizing electron-hole pairs in concurrent redox processes.The present study involved the construction of a p-n junction Co_(3)O_(4)/Zn_(3)In_(2)S_(6)(CoZ)hybrid with a complementary band edge potential.The photocatalyst formed by the 2D assembled-nanostructure portrayed an optimal yield of 13.8(H_(2))and 13.1(benzaldehyde)mmol g^(-1)h^(-1)when exposed to light(λ>420 nm),surpassing 1%Pt-added ZIS(12.4(H_(2))and 10.71(benzaldehyde)mmol g^(-1)h^(-1)).Around 95%of the electron-hole utilization rate was achieved.The solar-to-hydrogen(STH)and apparent quantum yield(AQY)values of 0.466%and 4.96%(420nm)achieved by this system in the absence of sacrificial agents exceeded those of previous works.The exceptional performance was mostly ascribed to the synergistic development of adjoining p-n heterojunctions and the built-in electric field for effective charge separation.Moreover,scavenger studies elucidated the intricate mechanistic enigma of the dual-redox process,in which benzaldehyde was produced via O-H activation and subsequent C-H cleavage of benzyl alcohol over CoZ hybrids.Furthermore,the widespread use of the optimal 1-CoZ composites was confirmed in multiple photoredox systems.This work presents an innovative perspective on the construction of dual-functioning p-n heterojunctions for practical photoredox applications.展开更多
The self-attention mechanism of Transformers,which captures long-range contextual information,has demonstrated significant potential in image segmentation.However,their ability to learn local,contextual relationships ...The self-attention mechanism of Transformers,which captures long-range contextual information,has demonstrated significant potential in image segmentation.However,their ability to learn local,contextual relationships between pixels requires further improvement.Previous methods face challenges in efficiently managing multi-scale fea-tures of different granularities from the encoder backbone,leaving room for improvement in their global representation and feature extraction capabilities.To address these challenges,we propose a novel Decoder with Multi-Head Feature Receptors(DMHFR),which receives multi-scale features from the encoder backbone and organizes them into three feature groups with different granularities:coarse,fine-grained,and full set.These groups are subsequently processed by Multi-Head Feature Receptors(MHFRs)after feature capture and modeling operations.MHFRs include two Three-Head Feature Receptors(THFRs)and one Four-Head Feature Receptor(FHFR).Each group of features is passed through these MHFRs and then fed into axial transformers,which help the model capture long-range dependencies within the features.The three MHFRs produce three distinct feature outputs.The output from the FHFR serves as auxiliary auxiliary features in the prediction head,and the prediction output and their losses will eventually be aggregated.Experimental results show that the Transformer using DMHFR outperforms 15 state of the arts(SOTA)methods on five public datasets.Specifically,it achieved significant improvements in mean DICE scores over the classic Parallel Reverse Attention Network(PraNet)method,with gains of 4.1%,2.2%,1.4%,8.9%,and 16.3%on the CVC-ClinicDB,Kvasir-SEG,CVC-T,CVC-ColonDB,and ETIS-LaribPolypDB datasets,respectively.展开更多
Amidst environmental pollution and the energy crisis,photocatalytic technology has emerged as a potent tool for promoting clean energy and environmental preservation.However,the promotion and widespread adoption of ph...Amidst environmental pollution and the energy crisis,photocatalytic technology has emerged as a potent tool for promoting clean energy and environmental preservation.However,the promotion and widespread adoption of photocatalysis encounter the formidable challenge of synthesizing high-quality photocatalysts in a cost-effective and expedited manner.Thus,we have compiled an analysis elucidating the efficacy and heating mechanisms of microwaves,validating their superiority as a heat source.Furthermore,this review presents a comprehensive overview of microwave-assisted synthesis techniques for photocatalysts,marking the inaugural attempt to do so,and extensively discusses the merits of diverse microwave-based preparation methodologies.Moreover,we systematically examine approaches for modifying photocatalysts using microwave-assisted methods,providing insights into their pivotal role in photocatalyst enhancement.We aspire that this review will serve as a seminal reference,facilitating the judicious application of microwave-assisted synthesis techniques for the controlled and efficient production of photocatalysts,thereby advancing the dissemination and adoption of photocatalysis.展开更多
Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of...Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of catalytical materials.In 2019,we discussed the development trend of this field,and wrote a roadmap on this topic in Chinese Chemical Letters(30(2019)2065-2088).Nowadays,we discuss it again from a new viewpoint along this road.In this paper,several subtopics are discussed,e.g.,photocatalysis based on titanium dioxide,violet phosphorus,graphitic carbon and covalent organic frameworks,electrocatalysts based on carbon,metal-and covalent-organic framework.Finally,we hope that this roadmap can enrich the development of two-dimensional materials in environmental catalysis with novel understanding,and give useful inspiration to explore new catalysts for practical applications.展开更多
As one of the most appealing and attractive technologies, photocatalysis is widely used as a promising method to circumvent the environmental and energy problems. Due to its chemical stability and unique physicochemic...As one of the most appealing and attractive technologies, photocatalysis is widely used as a promising method to circumvent the environmental and energy problems. Due to its chemical stability and unique physicochemical, graphitic carbon nitride (g-C3N4) has become research hotspots in the community. However, g-C3N4 photocatalyst still suffers from many problems, resulting in unsatisfactory photocatalytic activity such as low specific surface area, high charge recombination and insufficient visible light utilization. Since 2009, g-C3N4-based heterostructures have attracted the attention of scientists worldwide for their greatly enhanced photocatalytic performance. Overall, this review summarizes the recent advances of g-C3N4-based nanocomposites modified with transition metal sulfide (TMS), including (1) preparation of pristine g-C3N4,(2) modification strategies of g-C3N4,(3) design principles of TMS-modified g-C3N4 heterostructured photocatalysts, and (4) applications in energy conversion. What is more, the characteristics and transfer mechanisms of each classification of the metal sulfide heterojunction system will be critically reviewed, spanning from the following categories:(1) Type I heterojunction,(2) Type II heterojunction,(3) p-n heterojunction,(4) Schottky junction and (5) Z-scheme heterojunction. Apart from that, the application of g-C3N4-based heterostructured photocatalysts in H2 evolution, CO2 reduction, N2 fixation and pollutant degradation will also be systematically presented. Last but not least, this review will conclude with invigorating perspectives, limitations and prospects for further advancing g-C3N4-based heterostructured photocatalysts toward practical benefits for a sustainable future.展开更多
Ursolic acid(UA) is a pentacyclic triterpene of the ursane type. As a common chemical constituent among species of the family Lamiaceae, UA possesses a broad spectrum of pharmacological properties. This overview focus...Ursolic acid(UA) is a pentacyclic triterpene of the ursane type. As a common chemical constituent among species of the family Lamiaceae, UA possesses a broad spectrum of pharmacological properties. This overview focuses on the anticancer properties of UA against breast cancer(BC) and colorectal cancer(CRC)that are most common among women and men, respectively. In vitro studies have shown that UA inhibited the growth of BC and CRC cell lines through various molecular targets and signaling pathways.There are several in vivo studies on the cytotoxic activity of UA against BC and CRC. UA also inhibits the growth of other types of cancer. Studies on structural modifications of UA have shown that the –OH groups at C3 and at C28 are critical factors influencing the cytotoxic activity of UA and its derivatives.Some needs for future research are suggested. Sources of information were from ScienceDirect, Google Scholar and PubMed.展开更多
Green energy generation is an indispensable task to concurrently resolve fossil fuel depletion and environmental issues to align with the global goals of achieving carbon neutrality.Photocatalysis,a process that trans...Green energy generation is an indispensable task to concurrently resolve fossil fuel depletion and environmental issues to align with the global goals of achieving carbon neutrality.Photocatalysis,a process that transforms solar energy into clean fuels through a photocatalyst,represents a felicitous direction toward sustainability.Eco-rich metal-free graphitic carbon nitride(g-C_(3)N_(4))is profiled as an attractive photocatalyst due to its fascinating properties,including excellent chemical and thermal stability,moderate band gap,visible light-active nature,and ease of fabrication.Nonetheless,the shortcomings of g-C_(3)N_(4)include fast charge recombination and limited surface-active sites,which adversely affect photocatalytic reactions.Among the modification strategies,point-to-face contact engineering of 2D g-C_(3)N_(4)with 0D nanomaterials represents an innovative and promising synergy owing to several intriguing attributes such as the high specific surface area,short effective charge-transfer pathways,and quantum confinement effects.This review introduces recent advances achieved in experimental and computational studies on the interfacial design of 0D nanostructures on 2D g-C_(3)N_(4)in the construction of point-to-face heterojunction interfaces.Notably,0D materials such as metals,metal oxides,metal sulfides,metal selenides,metal phosphides,and nonmetals on g-C_(3)N_(4)with different charge-transfer mechanisms are systematically discussed along with controllable synthesis strategies.The applications of 0D/2D g-C_(3)N_(4)-based photocatalysts are focused on solar-to-energy conversion via the hydrogen evolution reaction,the CO_(2)reduction reaction,and the N2 reduction reaction to evaluate the photocatalyst activity and elucidate reaction pathways.Finally,future perspectives for developing high-efficiency 0D/2D photocatalysts are proposed to explore potential emerging carbon nitride allotropes,large-scale production,machine learning integration,and multidisciplinary advances for technological breakthroughs.展开更多
Flavonoids are by far the most dominant class of phenolic compounds isolated from Morus alba leaves(MAL). Other classes of compounds are benzofurans, phenolic acids, alkaloids, coumarins, chalcones and stilbenes. Majo...Flavonoids are by far the most dominant class of phenolic compounds isolated from Morus alba leaves(MAL). Other classes of compounds are benzofurans, phenolic acids, alkaloids, coumarins, chalcones and stilbenes. Major flavonoids are kuwanons, moracinflavans, moragrols and morkotins. Other major compounds include moracins(benzofurans), caffeoylquinic acids(phenolic acids) and morachalcones(chalcones). Research on the anticancer properties of MAL entailed in vitro and in vivo cytotoxicity of extracts or isolated compounds. Flavonoids, benzofurans, chalcones and alkaloids are classes of compounds from MAL that have been found to be cytotoxic towards human cancer cell lines. Further studies on the phytochemistry and anticancer of MAL are suggested. Sources of information were Pub Med,Pub Med Central, Science Direct, Google, Google Scholar, J-Stage, Pub Chem and China National Knowledge Infrastructure.展开更多
Tetrandrine(TET) and fangchinoline(FAN) are dominant bisbenzylisoquinoline(BBIQ) alkaloids from the roots of Stephania tetrandra of the family Menispermaceae. BBIQ alkaloids comprise two benzylisoquinoline units linke...Tetrandrine(TET) and fangchinoline(FAN) are dominant bisbenzylisoquinoline(BBIQ) alkaloids from the roots of Stephania tetrandra of the family Menispermaceae. BBIQ alkaloids comprise two benzylisoquinoline units linked by oxygen bridges. The molecular structures of TET and FAN are exactly the same, except that TET has a methoxy(-OCH3) group, while FAN has a hydroxyl(-OH) group at C7. In this overview,the current knowledge on the chemistry, pharmacology and anticancer properties of TET and FAN have been updated. The focus is on colon and breast cancer cells, because they are most susceptible to TET and FAN, respectively. Against colon cancer cells, TET inhibits cell proliferation and tumor growth by inducing apoptosis and G1 cell cycle arrest, and suppresses adhesion, migration and invasion of cells.Against breast cancer cells, FAN inhibits cell proliferation by inducing apoptosis, G1-phase cell cycle arrest and inhibits cell migration. The processes involve various molecular mechanisms and signaling pathways. Some insights on the ability of TET and FAN to reverse multi-drug resistance in cancer cells and suggestions for future research are provided.展开更多
Two-dimensional(2D)materials have come to light due to their unique thickness that owns abundant exposed edges with enhanced electrocatalytic properties.2D molybdenum disulfide(MoS_(2))nanosheet has aroused considerab...Two-dimensional(2D)materials have come to light due to their unique thickness that owns abundant exposed edges with enhanced electrocatalytic properties.2D molybdenum disulfide(MoS_(2))nanosheet has aroused considerable attention due to its tunable surface chemistry and high electrochemical sur-face area.Nonetheless,several shortcomings associated with MoS_(2),such as its naturally existing semi-conducting 2H phase,which has limited active sites due to the inert basal plane,restrict its application in water electrocatalysis.Taking into account the benefits of the 1T/2H phase of MoS_(2),as well as the importance of engineering 2D/2D heterojunction interface for boosted electrocatalysis,metallic Ti_(3)C_(2)Tx was integrated with 1T/2H MoS_(2) to develop 2D/2D 1T/2H MoS_(2)/Ti_(3)C_(2)Tx heterostructured nanocompos-ites.Herein,with only 25%of the intercalating agent,1T/2H MoS_(2) with the highest 1T phase content of~82%was successfully synthesized.It was further incorporated with 1 wt%of Ti_(3)C_(2)Tx through a com-bination of ultrasonication and mechanical stirring process.The 1T/2H MoS_(2)(25D)/Ti_(3)C_(2)Tx-1(MTC-1)manifested outstanding electrocatalytic performance with an overpotential and Tafel slope of 280 mV(83.80 mV dec^(-1))and 300 mV(117.2 mV dec^(-1)),for catalyzing acidic and alkaline medium HER,respec-tively.Pivotally,the as-prepared catalysts also illustrated long-term stability for more than 40 h.The coupling method for the 2D nanosheets is crucial to suppress the oxidation of Ti_(3)C_(2)Tx and the restack-ing issue of 2D nanosheets.The superior HER activity is ascribed to the synergistic effect between the heterostructure,enhancing the electronic structure and charge separation capability.The intrinsic prop-erty of the catalyst further confirms by turnover frequency(TOF)calculation.As such,this research paves the way for designing high-efficiency 2D electrocatalysts and sheds light on the further advancement of tunable 2D electrocatalysts for robust water splitting and beyond.展开更多
文摘Petrophysical well log data help to predict hydrocarbon reserves before field development which involves huge financial commitment.In this study,reservoir characterization was performed with a view to obtain information on the geological formation type and petrophysical parameters.Wireline log data obtained from five wells were used to develop a 3D model of X-field in the Baram Delta which was in turn evaluated using the PETREL software.Suites of gamma ray,sonic,density,resistivity and neutron logs aided the delineation and correlation of the sandstone formation.Fourteen hydrocarbon-bearing sands were defined from well log data and divided into two-reservoir zones,shallow and deep.Well correlation assisted in the delineation of the reservoir sands across the wells.The quality of the reservoir formation was evaluated from average petrophysical properties:with an average thickness of 62 m,an average porosity of 0.19,an average net-to-gross ratio of 0.068,an average V-shale of 0.45,and an average water saturation of 0.95.A rollover anticline structure was identified across the field using the fault as a description tool.Variation of petrophysical parameters and uncertainty in the reservoir properties were included to predict the effect on the volume of oil in place.This study revealed that the discovered hydrocarbon reserve resource accumulations in the Field X for the fourteen-mapped reservoir sands have a total proven reserve resource estimate of 740MMSTB at P90,655MMSTB at P50 and 593MMSTB at P10.Reservoirs A and B are the only intervals with the highest recoverable oil,a volume of 256MMSTB at P90,215MMSTB at P50 and 181MMSTB at P10,respectively.These analyses facilitated an improved reservoir description of shaly sandstone,which contributes to better planning of hydrocarbon re-development and future recovery,and thereby improving the energy supply security of the regions.
文摘Photoredox dual reaction of organic synthesis and H2 evolution opens up a novel pathway for collaboratively generating clean fuels and high-quality chemicals,providing a more effective approach of solar energy conversion.Herein,a surface defect-engineered ZnCoS/ZnCdS heterostructure with zinc blende(ZB)/wurtzite(WZ)phase junctions is synthesized for photocatalytic cooperative coupling of benzaldehyde(BAD)and H_(2) production.This surface defect-engineered ZnCoS/ZnCdS heterostructure elaborately integrates the mixed phase junction advantage of ZnCdS semiconductor and the cocatalytic function of ZnCoS possessing Zn(VZn-ZnCoS/ZnCdS)or S vacancies(VS-ZnCoS/ZnCdS).The optimum VS-ZnCoS/ZnCdS simultaneously exhibits a superior H2 production rate of 14.23 mmol h^(-1) g^(-1) accompanied with BAD formation rate of 12.29 mmol h^(-1) g^(-1) under visible-light irradiation,which is approximately two-fold greater than that of pristine ZnCdS.Under simulated sunlight irradiation(AM 1.5),VS-ZnCoS/ZnCdS achieves H2 evolution(27.43 mmol gcat^(-1) h^(-1))with 0.52%of STH efficiency,accompany with 26.31 mmol gcat^(-1) h^(-1) of BAD formation rate.The underlying solar-driven mechanism is elucidated by a series of in-situ characterization and control experiments,which reveals the synergistic effect of interfacial ZB/WZ phase junctions in ZnCdS and S vacancies of ZnCoS on enhancement of the photoredox dual reaction.The VS-ZnCoS/ZnCdS follows a predominant oxygen-centered radical integrating with carbon-centered radical pathways for BAD formation and a simultaneous electron-driven proton reduction for H_(2) production.Interestingly,the nature of surface vacancies not only facilitates the separation of photoinduced charge carriers but also able to selectively adjust the mechanism pathway for BAD production via tuning the oxygen-centered radical and carbon-centered radical formation.
文摘The habitual use of smartphones during meals has become a common behavior,raising concerns about its potential impact on eating habits and metabolic health.The present narrative review investigates how using a smartphone or tablet during meals can cause distractions and negatively affect metabolic health.A comprehensive narrative review was conducted by synthesizing peer-reviewed studies on the interplay between smartphone use during meals,eating behaviors,and metabolic health.Relevant literature was identified through searches in electronic databases and organized thematically to highlight trends and research gaps.By synthesizing evidence from existing literature,this review highlights that smartphone use during meals is associated with increased caloric intake,altered food composition,and disruptions in postprandial metabolic responses.These effects are mediated by reduced meal awareness and psychological distractions,including multitasking.Variability in findings arises from differences in study designs and populations.This review identifies critical research gaps,including the lack of longitudinal studies and the need to explore mechanisms underlying these relationships.By summarizing trends and patterns,this narrative review offers valuable insights into the complex interplay between digital device use,eating habits,and metabolic health,providing a foundation for future research and interventions.
基金Research Management Centre,Xiamen University Malaysia(No.XMUMRF/2020-C6/ITCM/0004)。
文摘This perspective review explores the transformative potential of personalized herbal medicine,examines the integration of ancient herbal knowledge with modern personalized medicine,delves into the principles of personalized medicine particularly in the context of herbal treatments,and investigates the principles of personalized medicine and elucidates how they are being applied to herbal medicine.It emphasizes the individualized nature of this approach and how it is facilitated through genetic analysis and health profiling.This review also highlights key advancements in herbal medicine,such as deoxyribonucleic acid(DNA)analysis and bioinformatics,and their role in the development of precise and personalized herbal remedies.The outcomes of personalized herbal medicine reveal how genetic variations are being considered to tailor treatments,create target-specific therapies,and customize dosage regimens.Furthermore,this review illustrates the evolution of herbal medicine with technological advancements,particularly DNA analysis and bioinformatics,to enhance precision and personalization.The challenge associated with implementing personalized herbal medicine more broadly includes issues of accessibility,regulation,education and ethics.It underscores the transformative potential of personalized herbal medicine.It calls for continued exploration,research and collaboration in this burgeoning field.This emerging field encourages researchers,practitioners,and stakeholders to engage in advancing healthcare practices that are increasingly personalized,evidence-based,and centered on patient's needs.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 52471200, 12174165, and 52201219)。
文摘We utilize conventional wave-vector-resolved Brillouin light scattering technology to investigate the spin wave response in YIG thin films under high-power microwave excitation. By varying the microwave frequency, external bias magnetic field, and in-plane wave vector, in addition to observing the dipole-exchange spin waves excited by parallel parametric pumping, we further observe broadband spin wave excitation within the dipole-exchange spin wave spectrum. This broadband excitation results from the combined effects of parallel and perpendicular parametric pumping, induced by irregularities in the excitation geometry, as well as magnon–magnon scattering arising from the absence of certain spin wave modes. Our findings offer new insights into the mechanisms of energy dissipation and relaxation processes caused by spin wave excitation in magnetic devices operating at high power.
基金the financial support provided by the Ministry of Higher Education(MOHE)Malaysia under the Fundamental Research Grant Scheme(FRGS)(Ref no:FRGS/1/2020/TK0/XMU/02/1)The authors would like to thank the Ministry of Science,Technology and Innovation(MOSTI)Malaysia under the Strategic Research Fund(SRF-APP NanoMalaysia BICEP Project 4,S.22015)+5 种基金The authors gratefully acknowledge Agilent Technologies Malaysia Sdn.Bhd.for their contribution through chromatography.This research was supported by the National Natural Science Foundation of China(Ref no:22202168)Guangdong Basic and Applied Basic Research Foundation(Ref no:2021A1515111019)We would also like to acknowledge the financial support from the State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University(Ref.no:2023X11)The authors are thankful to the Embassy of the People's Republic of China in Malaysia for the financial support(Grant no:EENG/0045)This work was also funded by Xiamen University Malaysia Investigatorship Grant(Grant no:IENG/0038)Xiamen University Malaysia Research Fund(ICOE/0001 and XMUMRF/2021-C8/IENG/0041).
文摘Homojunction engineering is a promising modification strategy to improve charge carrier separation and photocatalytic performance of carbon nitrides.Leveraging intrinsic heptazine/triazine phase and face-to-face contact,crystalline C_(3)N_(5)(CC3N5)was combined with protonated g-C_(3)N_(4)(pgCN)through electrostatic self-assembly to achieve robust 2D/2D homojunction interfaces.The highest photocatalytic performance was obtained through crystallinity and homojunction engineering,by controlling the pgCN:CC3N5 ratio.The 25:100 pgCN:CC3N5 homo-junction(25CgCN)had the highest hydrogen production(1409.51 μmol h^(-1))and apparent quantum efficiency(25.04%,420 nm),8-fold and 180-fold higher than CC3N5 and pgCN,respectively.This photocatalytic homojunction improves benzaldehyde and hydrogen production activity,retaining 89%performance after 3 cycles(12 h)on a 3D-printed substrate.Electron paramagnetic resonance demonstrated higher·OH,·O_(2) and hole production of irradiated 25CgCN,attributed to crystallinity and homojunction interaction.Thus,electrostatic self-assembly to couple CC3N5 and pgCN in a 2D/2D homojunction interface ameliorates the performance of multifunctional solar-driven applications.
文摘This review provided an updated synthesis of current knowledge regarding the processing, chemical constituents, pharmacological properties, and clinical applications of white tea (Camellia sinensis), commonly known as WT. Information was collated from reliable sources, including Google, Google Scholar, PubMed, PubMed Central, Science Direct, PubChem, J-Stage, the Directory of Open Access Journals (DOAJ), and the China National Knowledge Infrastructure (CNKI). In China, WT, referred to as “Bai Cha”, is a prized spring tea harvested during early spring when the young tea plant leaf buds are still covered with delicate, downy white hairs. Fujian Province serves as the primary production region. WT processing is minimal, involving withering as the most crucial step, followed by drying. This simple process preserves its unique qualities and chemical integrity. The dominant phenolic compounds in WT are flavonoids, including catechins, dimeric catechins, flavones, flavonols, and flavanones. Additional constituents encompass phenolic acids, alkaloids, glycosides, and amino acids. These bioactive compounds contribute to WT’s diverse pharmacological properties, including anti-diabetic, anti-cancer, hepatoprotective, neuroprotective, anti-obesity, and male reproductive health benefits. To date, seven clinical studies have investigated the therapeutic potential of WT. These include two studies each on its use as a mouth rinse and its anti-obesity effects, and one study each focusing on its applications in managing diabetes, periodontitis, and depression. Perspectives on WT’s broader implications and opportunities for future research are also explored, highlighting its potential for expanded therapeutic applications.
基金support provided by the Ministry of Higher Education Malaysia under the Xiamen University Malaysia.-Fundamental Research Grant Scheme(FRGS)(Ref no.FRGS/1/2024/TK08/XMU/02/1)supported by the PETRONAS-Academia Collaboration Dialogue(PACD 2023)grant,provided by PETRONAS Research Sdn.Bhd.(PRSB)+6 种基金the Ministry of Science,Technology and Innovation(MOSTI)Malaysia under the Strategic Research Fund(SRF)(S.22015)supported by the National Natural Science Foundation of China(Ref no:22202168)Guangdong Basic and Applied Basic Research Foundation(Ref no:2021A1515111019)the financial support from the State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University(Ref no:2023X11)supported by the Xiamen University,Embassy of the People's Republic of China in Malaysia(EENG/0045)funded by Xiamen University Malaysia Investigatorship Grant(Grant no:IENG/0038)Xiamen University Malaysia Research Fund(ICOE/0001,XMUMRF/2021-C8/IENG/0041 and XMUMRF/2025-C15/IENG/0080).
文摘By harnessing the power of MoS_(2) as a cocatalyst to enhance electron transfer and charge carrier separation,a groundbreaking two-in-one redox photocatalytic system was developed.This innovative system integrated 2D MoS_(2) nanosheets onto hydrangea-like Zn_(3)In_(2)S_(6) nanosheets,forming a 2D/3D heterostructure that established a stable and intimate interface.This unique architecture significantly improved cooperative photocatalytic performance,enabling the simultaneous production of hydrogen and benzaldehyde under light irradiation≥420 nm.Notably,the system achieved remarkable yields of hydrogen(41.9 mmol g^(-1) h^(-1))and benzaldehyde(38.9 mmol g^(-1) h^(-1)),surpassing the pristine Zn_(3)In_(2)S_(6) by 22.4 times.An impressive electron-hole pair utilization rate of approximately 93%was attained,underscoring the high efficiency of this two-in-one redox system.Additionally,the targeted 10 wt%-MoS_(2) loaded Zn_(3)In_(2)S_(6)(10MZ)nanohybrids at 400 nm obtained an apparent quantum yield(AQY)value of 17.66%without sacrificial agents or noble metals.The exceptional performance was attributed to improved charge carrier separation and reduced recombination,facilitated by cocatalyst integration and evidenced via photoluminescence,photoelectrochemical and Kelvin probe force microscopy measurements.This work highlighted the critical role of two-in-one redox-functioning heterojunctions in optimizing electron-hole pair utilization,offering a promising approach for sustainable energy production and organic synthesis.By demonstrating the potential for efficient,simultaneous generation of valuable chemicals and fuels,this research paves the way for the development of next-generation photocatalytic systems.
基金support provided by the Ministry of Higher Education Malaysia under the Fundamental Research Grant Scheme(FRGS)(No.FRGS/1/2024/TK08/XMU/02/1)supported by the PETRONAS-Academia Collaboration Dialogue(PACD 2023)grant,provided by PETRONAS Research Sdn.Bhd.(PRSB)+6 种基金the Ministry of Science,Technology and Innovation(MOSTI)Malaysia under the Strategic Research Fund(SRF)(S.22015)supported by the National Natural Science Foundation of China(No.22202168)Guangdong Basic and Applied Basic Research Foundation(No.2021A1515111019)support from the State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University(No.2023X11)supported by the Embassy of the People's Republic of China in Malaysia(EENG/0045)funded by Xiamen University Malaysia Investigatorship Grant(No.IENG/0038)Xiamen University Malaysia Research Fund(ICOE/0001,XMUMRF/2021-C8/IENG/0041 and XMUMRF/2025-C15/IENG/0080).
文摘Despite advances in photocatalytic half-reduction reactions,challenges remain in effectively utilizing electron-hole pairs in concurrent redox processes.The present study involved the construction of a p-n junction Co_(3)O_(4)/Zn_(3)In_(2)S_(6)(CoZ)hybrid with a complementary band edge potential.The photocatalyst formed by the 2D assembled-nanostructure portrayed an optimal yield of 13.8(H_(2))and 13.1(benzaldehyde)mmol g^(-1)h^(-1)when exposed to light(λ>420 nm),surpassing 1%Pt-added ZIS(12.4(H_(2))and 10.71(benzaldehyde)mmol g^(-1)h^(-1)).Around 95%of the electron-hole utilization rate was achieved.The solar-to-hydrogen(STH)and apparent quantum yield(AQY)values of 0.466%and 4.96%(420nm)achieved by this system in the absence of sacrificial agents exceeded those of previous works.The exceptional performance was mostly ascribed to the synergistic development of adjoining p-n heterojunctions and the built-in electric field for effective charge separation.Moreover,scavenger studies elucidated the intricate mechanistic enigma of the dual-redox process,in which benzaldehyde was produced via O-H activation and subsequent C-H cleavage of benzyl alcohol over CoZ hybrids.Furthermore,the widespread use of the optimal 1-CoZ composites was confirmed in multiple photoredox systems.This work presents an innovative perspective on the construction of dual-functioning p-n heterojunctions for practical photoredox applications.
基金supported by Xiamen Medical and Health Guidance Project in 2021(No.3502Z20214ZD1070)supported by a grant from Guangxi Key Laboratory of Machine Vision and Intelligent Control,China(No.2023B02).
文摘The self-attention mechanism of Transformers,which captures long-range contextual information,has demonstrated significant potential in image segmentation.However,their ability to learn local,contextual relationships between pixels requires further improvement.Previous methods face challenges in efficiently managing multi-scale fea-tures of different granularities from the encoder backbone,leaving room for improvement in their global representation and feature extraction capabilities.To address these challenges,we propose a novel Decoder with Multi-Head Feature Receptors(DMHFR),which receives multi-scale features from the encoder backbone and organizes them into three feature groups with different granularities:coarse,fine-grained,and full set.These groups are subsequently processed by Multi-Head Feature Receptors(MHFRs)after feature capture and modeling operations.MHFRs include two Three-Head Feature Receptors(THFRs)and one Four-Head Feature Receptor(FHFR).Each group of features is passed through these MHFRs and then fed into axial transformers,which help the model capture long-range dependencies within the features.The three MHFRs produce three distinct feature outputs.The output from the FHFR serves as auxiliary auxiliary features in the prediction head,and the prediction output and their losses will eventually be aggregated.Experimental results show that the Transformer using DMHFR outperforms 15 state of the arts(SOTA)methods on five public datasets.Specifically,it achieved significant improvements in mean DICE scores over the classic Parallel Reverse Attention Network(PraNet)method,with gains of 4.1%,2.2%,1.4%,8.9%,and 16.3%on the CVC-ClinicDB,Kvasir-SEG,CVC-T,CVC-ColonDB,and ETIS-LaribPolypDB datasets,respectively.
基金supported by the National Natural Science Foundation of China(Grant Nos.52370109,52401227 and 52200122)the Natural Science Foundation of Chongqing(Grant No.CSTB2025NSCQ-GPX0827,CSTB2023NSCQ-MSX0096 and CSTB2024NSCQMSX1045)+3 种基金Research Project of Chongqing Education Commission Foundation(No.KJQN201800826 and KJQN202200806)Science and Technology Research Program of Chongqing Municipal Education Commission of China(No.KJZD-K202100801 and KJZD-M202400802)Post-doctoral Program Funded by Chongqing,and Chongqing University Innovation Research Group project(No.CXQT21023)the Startup Research Grant(No.F1240093)from Chongqing Jiaotong University.
文摘Amidst environmental pollution and the energy crisis,photocatalytic technology has emerged as a potent tool for promoting clean energy and environmental preservation.However,the promotion and widespread adoption of photocatalysis encounter the formidable challenge of synthesizing high-quality photocatalysts in a cost-effective and expedited manner.Thus,we have compiled an analysis elucidating the efficacy and heating mechanisms of microwaves,validating their superiority as a heat source.Furthermore,this review presents a comprehensive overview of microwave-assisted synthesis techniques for photocatalysts,marking the inaugural attempt to do so,and extensively discusses the merits of diverse microwave-based preparation methodologies.Moreover,we systematically examine approaches for modifying photocatalysts using microwave-assisted methods,providing insights into their pivotal role in photocatalyst enhancement.We aspire that this review will serve as a seminal reference,facilitating the judicious application of microwave-assisted synthesis techniques for the controlled and efficient production of photocatalysts,thereby advancing the dissemination and adoption of photocatalysis.
基金supported by the National Natural Science Foundation of China(Nos.52272290,21972030,52073119,and 52373210)the Natural Science Foundation of Jilin Province(No.20230101029JC)+1 种基金the Fundamental Research Program of Shanxi Province(No.202303021212159)the Monash University Malaysia–ASEAN grant(No.ASE-000010)。
文摘Environmental catalysis has been considered one of the important research topics.Some technologies(e.g.,photocatalysis and electrocatalysis)have been intensively developed with the advance of synthetic technologies of catalytical materials.In 2019,we discussed the development trend of this field,and wrote a roadmap on this topic in Chinese Chemical Letters(30(2019)2065-2088).Nowadays,we discuss it again from a new viewpoint along this road.In this paper,several subtopics are discussed,e.g.,photocatalysis based on titanium dioxide,violet phosphorus,graphitic carbon and covalent organic frameworks,electrocatalysts based on carbon,metal-and covalent-organic framework.Finally,we hope that this roadmap can enrich the development of two-dimensional materials in environmental catalysis with novel understanding,and give useful inspiration to explore new catalysts for practical applications.
基金supported by Xiamen University Malaysia Research Fund (XMUMRF/2019-C3/IENG/0013)financial assistance and faculty start-up grants/supports from Xiamen University~~
文摘As one of the most appealing and attractive technologies, photocatalysis is widely used as a promising method to circumvent the environmental and energy problems. Due to its chemical stability and unique physicochemical, graphitic carbon nitride (g-C3N4) has become research hotspots in the community. However, g-C3N4 photocatalyst still suffers from many problems, resulting in unsatisfactory photocatalytic activity such as low specific surface area, high charge recombination and insufficient visible light utilization. Since 2009, g-C3N4-based heterostructures have attracted the attention of scientists worldwide for their greatly enhanced photocatalytic performance. Overall, this review summarizes the recent advances of g-C3N4-based nanocomposites modified with transition metal sulfide (TMS), including (1) preparation of pristine g-C3N4,(2) modification strategies of g-C3N4,(3) design principles of TMS-modified g-C3N4 heterostructured photocatalysts, and (4) applications in energy conversion. What is more, the characteristics and transfer mechanisms of each classification of the metal sulfide heterojunction system will be critically reviewed, spanning from the following categories:(1) Type I heterojunction,(2) Type II heterojunction,(3) p-n heterojunction,(4) Schottky junction and (5) Z-scheme heterojunction. Apart from that, the application of g-C3N4-based heterostructured photocatalysts in H2 evolution, CO2 reduction, N2 fixation and pollutant degradation will also be systematically presented. Last but not least, this review will conclude with invigorating perspectives, limitations and prospects for further advancing g-C3N4-based heterostructured photocatalysts toward practical benefits for a sustainable future.
基金funding from UCSI University (Proj-In-FAS-049 Proj-In-FAS-052)+1 种基金the Ministry of Higher Education (MOHE),Malaysia (FRGS/2/2014/SG01/UCSI/02/2 FRGS/1/2018/TK10/UCSI/02/1) for supporting our research group
文摘Ursolic acid(UA) is a pentacyclic triterpene of the ursane type. As a common chemical constituent among species of the family Lamiaceae, UA possesses a broad spectrum of pharmacological properties. This overview focuses on the anticancer properties of UA against breast cancer(BC) and colorectal cancer(CRC)that are most common among women and men, respectively. In vitro studies have shown that UA inhibited the growth of BC and CRC cell lines through various molecular targets and signaling pathways.There are several in vivo studies on the cytotoxic activity of UA against BC and CRC. UA also inhibits the growth of other types of cancer. Studies on structural modifications of UA have shown that the –OH groups at C3 and at C28 are critical factors influencing the cytotoxic activity of UA and its derivatives.Some needs for future research are suggested. Sources of information were from ScienceDirect, Google Scholar and PubMed.
基金Ministry of Higher Education,Malaysia,Grant/Award Number:FRGS/1/2020/TK0/XMU/02/1Guangdong Basic and Applied Basic Research Foundation,Grant/Award Number:2021A1515111019+1 种基金Hengyuan International Sdn.Bhd.,Grant/Award Number:EENG/0003Xiamen University Malaysia,Grant/Award Numbers:IENG/0038,ICOE/0001,XMUMRF/2019-C3/IENG/0013,XMUMRF/2021-C8/IENG/0041。
文摘Green energy generation is an indispensable task to concurrently resolve fossil fuel depletion and environmental issues to align with the global goals of achieving carbon neutrality.Photocatalysis,a process that transforms solar energy into clean fuels through a photocatalyst,represents a felicitous direction toward sustainability.Eco-rich metal-free graphitic carbon nitride(g-C_(3)N_(4))is profiled as an attractive photocatalyst due to its fascinating properties,including excellent chemical and thermal stability,moderate band gap,visible light-active nature,and ease of fabrication.Nonetheless,the shortcomings of g-C_(3)N_(4)include fast charge recombination and limited surface-active sites,which adversely affect photocatalytic reactions.Among the modification strategies,point-to-face contact engineering of 2D g-C_(3)N_(4)with 0D nanomaterials represents an innovative and promising synergy owing to several intriguing attributes such as the high specific surface area,short effective charge-transfer pathways,and quantum confinement effects.This review introduces recent advances achieved in experimental and computational studies on the interfacial design of 0D nanostructures on 2D g-C_(3)N_(4)in the construction of point-to-face heterojunction interfaces.Notably,0D materials such as metals,metal oxides,metal sulfides,metal selenides,metal phosphides,and nonmetals on g-C_(3)N_(4)with different charge-transfer mechanisms are systematically discussed along with controllable synthesis strategies.The applications of 0D/2D g-C_(3)N_(4)-based photocatalysts are focused on solar-to-energy conversion via the hydrogen evolution reaction,the CO_(2)reduction reaction,and the N2 reduction reaction to evaluate the photocatalyst activity and elucidate reaction pathways.Finally,future perspectives for developing high-efficiency 0D/2D photocatalysts are proposed to explore potential emerging carbon nitride allotropes,large-scale production,machine learning integration,and multidisciplinary advances for technological breakthroughs.
文摘Flavonoids are by far the most dominant class of phenolic compounds isolated from Morus alba leaves(MAL). Other classes of compounds are benzofurans, phenolic acids, alkaloids, coumarins, chalcones and stilbenes. Major flavonoids are kuwanons, moracinflavans, moragrols and morkotins. Other major compounds include moracins(benzofurans), caffeoylquinic acids(phenolic acids) and morachalcones(chalcones). Research on the anticancer properties of MAL entailed in vitro and in vivo cytotoxicity of extracts or isolated compounds. Flavonoids, benzofurans, chalcones and alkaloids are classes of compounds from MAL that have been found to be cytotoxic towards human cancer cell lines. Further studies on the phytochemistry and anticancer of MAL are suggested. Sources of information were Pub Med,Pub Med Central, Science Direct, Google, Google Scholar, J-Stage, Pub Chem and China National Knowledge Infrastructure.
文摘Tetrandrine(TET) and fangchinoline(FAN) are dominant bisbenzylisoquinoline(BBIQ) alkaloids from the roots of Stephania tetrandra of the family Menispermaceae. BBIQ alkaloids comprise two benzylisoquinoline units linked by oxygen bridges. The molecular structures of TET and FAN are exactly the same, except that TET has a methoxy(-OCH3) group, while FAN has a hydroxyl(-OH) group at C7. In this overview,the current knowledge on the chemistry, pharmacology and anticancer properties of TET and FAN have been updated. The focus is on colon and breast cancer cells, because they are most susceptible to TET and FAN, respectively. Against colon cancer cells, TET inhibits cell proliferation and tumor growth by inducing apoptosis and G1 cell cycle arrest, and suppresses adhesion, migration and invasion of cells.Against breast cancer cells, FAN inhibits cell proliferation by inducing apoptosis, G1-phase cell cycle arrest and inhibits cell migration. The processes involve various molecular mechanisms and signaling pathways. Some insights on the ability of TET and FAN to reverse multi-drug resistance in cancer cells and suggestions for future research are provided.
基金Ministry of Higher Education(MOHE)Malaysia under the Fundamental Research Grant Scheme(FRGS)(Ref No:FRGS/1/2020/TK0/XMU/02/1)We would also like to thank the Ministry of Science,Technology and Innovation(MOSTI)Malaysia under the Strategic Research Fund(SRF-APP)(S.22015)+5 种基金The authors would also like to acknowledge the financial support provided by the National Natural Science Foundation of China(Ref No.22202168)Guangdong Basic and Applied Basic Re-search Foundation(Ref No.2021A1515111019)We would also like to acknowledge the financial support from the State Key Labo-ratory of Physical Chemistry of Solid Surfaces,Xiamen University(No.2023X11)This work is also funded by Xiamen University Malaysia Investigatorship Grant(Grant No.IENG/0038)Xiamen University Malaysia Research Fund(ICOE/0001,XMUMRF/2021-C8/IENG/0041 and XMUMRF/2019-C3/IENG/0013)Hengyuan International Sdn.Bhd.(Grant No.EENG/0003).
文摘Two-dimensional(2D)materials have come to light due to their unique thickness that owns abundant exposed edges with enhanced electrocatalytic properties.2D molybdenum disulfide(MoS_(2))nanosheet has aroused considerable attention due to its tunable surface chemistry and high electrochemical sur-face area.Nonetheless,several shortcomings associated with MoS_(2),such as its naturally existing semi-conducting 2H phase,which has limited active sites due to the inert basal plane,restrict its application in water electrocatalysis.Taking into account the benefits of the 1T/2H phase of MoS_(2),as well as the importance of engineering 2D/2D heterojunction interface for boosted electrocatalysis,metallic Ti_(3)C_(2)Tx was integrated with 1T/2H MoS_(2) to develop 2D/2D 1T/2H MoS_(2)/Ti_(3)C_(2)Tx heterostructured nanocompos-ites.Herein,with only 25%of the intercalating agent,1T/2H MoS_(2) with the highest 1T phase content of~82%was successfully synthesized.It was further incorporated with 1 wt%of Ti_(3)C_(2)Tx through a com-bination of ultrasonication and mechanical stirring process.The 1T/2H MoS_(2)(25D)/Ti_(3)C_(2)Tx-1(MTC-1)manifested outstanding electrocatalytic performance with an overpotential and Tafel slope of 280 mV(83.80 mV dec^(-1))and 300 mV(117.2 mV dec^(-1)),for catalyzing acidic and alkaline medium HER,respec-tively.Pivotally,the as-prepared catalysts also illustrated long-term stability for more than 40 h.The coupling method for the 2D nanosheets is crucial to suppress the oxidation of Ti_(3)C_(2)Tx and the restack-ing issue of 2D nanosheets.The superior HER activity is ascribed to the synergistic effect between the heterostructure,enhancing the electronic structure and charge separation capability.The intrinsic prop-erty of the catalyst further confirms by turnover frequency(TOF)calculation.As such,this research paves the way for designing high-efficiency 2D electrocatalysts and sheds light on the further advancement of tunable 2D electrocatalysts for robust water splitting and beyond.
