Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to miti...Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to mitigate the freshwater,energy and food crises.However,the performance of solar-driven systems decreases significantly during operation due to uncontrollable weather.This study proposes an integrated water/electricity cogeneration-cultivation system with superior thermal management.The energy storage evaporator,consisting of energy storage microcapsules/hydrogel composites,is optimally designed for sustainable desalination,achieving an evaporation rate of around 1.91 kg m^(-2)h^(-1).In the dark,heat released from the phase-change layer supported an evaporation rate of around 0.54kg m^(-2)h^(-1).Reverse electrodialysis harnessed the salinity-gradient energy enhanced during desalination,enabling the long-running WEC system to achieve a power output of~0.3 W m^(-2),which was almost three times higher than that of conventional seawater/surface water mixing.Additionally,an integrated crop irrigation platform utilized system drainage for real-time,on-demand wheat cultivation without secondary contaminants,facilitating seamless WEF integration.This work presents a novel approach to all-day solar water production,electricity generation and crop irrigation,offering a solution and blueprint for the sustainable development of WEF.展开更多
Effective groundwater management is crucial for economic sustainable development,particularly as climate change and population growth increase the uncertainty of aquifer dynamics.Due to limited geological data,Punjab&...Effective groundwater management is crucial for economic sustainable development,particularly as climate change and population growth increase the uncertainty of aquifer dynamics.Due to limited geological data,Punjab's complex hydrogeological conditions and Quaternary alluvial deposits present significant challenges for groundwater management.This study employs cost-effective numerical techniques as alternatives to traditional methods to safeguard groundwater quality,quantity,and accessibility.It introduces an edit-embedded transition frequency model that integrates regional datasets and utilizes algorithms such as GAMEAS,MCMOD,and TSIM to evaluate aquifer heterogeneity and simulate spatial variations using one-dimensional and three-dimensional Markov chains.Findings show that sand exhibits the highest self-transition(33.112 m),indicating strong stability,followed by silt,clay,and gravel,suggesting overall hydrofacies stability both horizontally and vertically.The model's predictions are largely consistent with actual material distribution,with a slight under-prediction of clay(-0.750%)and an over-prediction of sand(2.985%),which accounts for 58.77%of the aquifer material.It also highlights significant heterogeneity in the northern mountainous regions and minor variations in the south.The study emphasizes Punjab's severe water crisis,with groundwater reserves of 3502.3 BCM,declining water levels(0.38–33.62 m),and low hydraulic conductivity,urging government action on rainwater harvesting and sustainable groundwater management policies.展开更多
Groundwater level(GWL)is a key indicator used to accurately assess groundwater resources and form the foundation for ef-fective groundwater management.This paper integrates a Gate Recurrent Unit(GRU)model with a Multi...Groundwater level(GWL)is a key indicator used to accurately assess groundwater resources and form the foundation for ef-fective groundwater management.This paper integrates a Gate Recurrent Unit(GRU)model with a Multi-head Self-attention mechan-ism(MSAM-GRU)to simulate GWLs in both confined and unconfined aquifers simultaneously.The model innovatively captures the lag times between GWLs in the unconfined aquifer and precipitation,as well as between GWLs in the confined aquifer and the upper aquifer.We have assessed the effectiveness of the proposed model using a case study in the Beijing Plain,China from January 2005 to December 2020.With the consideration of lag times,the results indicated that the MSAM-GRU model exhibits a maximum 67%and 73%reduction in RMSE compared to the Attention mechanism-GRU(AM-GRU)and GRU model,respectively.MSAM-GRU model exhibited a 31%reduction in RMSE and a 0.12 increase in R^(2) compared to the same model that do not account for lag time.In Region I,the shortest lag time of GWL in the unconfined aquifer was two months,while that in the confined aquifer was three months,indicating a longer delayed response in the confined aquifer.MSAM-GRU model considering lag time,was then applied to simulate the GWLs in the unconfined aquifer under different scenarios and to analyze whether GWL fluctuations affect subway operations.The simulation res-ults showed that under the scenario 1,the GWL in the unconfined aquifer would rise above the depth of subway station floor,threaten-ing the operation of subways.This study can provide reliable technical support for the accurate simulation of GWLs in multi-aquifer systems.展开更多
As a major source of freshwater in Central Asia,Tajikistan is endowed with abundant glaciers and water resources.However,the country faces multiple challenges,including accelerated glacier retreat,complex inter-govern...As a major source of freshwater in Central Asia,Tajikistan is endowed with abundant glaciers and water resources.However,the country faces multiple challenges,including accelerated glacier retreat,complex inter-government water resource management,and inefficient water use.Existing research has predominantly focused on individual hydrological processes,such as glacier retreat,snow cover change,or transboundary water issues,but it has yet to fully capture the overall complexity of water system.Tajikistan’s water system functions as an integrated whole from mountain runoff to downstream supply,but a comprehensive study of its water resource has yet to be conducted.To address this research gap,this study systematically examined the status,challenges,and sustainable management strategies of Tajikistan’s water resources based on a literature review,remote sensing data analysis,and case studies.Despite Tajikistan’s relative abundance of water resources,global warming is accelerating glacier melting and altering the hydrological cycles,which have resulted in unstable runoff patterns and heightened risks of extreme events.In Tajikistan,outdated infrastructure and poor management are primary causes of low water-use efficiency in the agricultural sector,which accounts for 85.00%of the total water withdrawals.At the governance level,Tajikistan faces challenges in balancing the water-energy-food nexus and transboundary water resource issues.To address these issues,this study proposes core paths for Tajikistan to achieve sustainable water resource management,such as accelerating technological innovation,promoting water-saving agricultural technologies,improving water resource utilization efficiency,and establishing a community participation-based comprehensive management framework.Additionally,strengthening cross-border cooperation and improving real-time monitoring systems have been identified as critical steps to advance sustainable water resource utilization and evidence-based decision-making in Tajikistan and across Central Asia.展开更多
High‐entropy amorphous catalysts(HEACs)integrate multielement synergy with structural disorder,making them promising candidates for water splitting.Their distinctive features—including flexible coordination environm...High‐entropy amorphous catalysts(HEACs)integrate multielement synergy with structural disorder,making them promising candidates for water splitting.Their distinctive features—including flexible coordination environments,tunable electronic structures,abundant unsaturated active sites,and dynamic structural reassembly—collectively enhance electrochemical activity and durability under operating conditions.This review summarizes recent advances in HEACs for hydrogen evolution,oxygen evolution,and overall water splitting,highlighting their disorder-driven advantages over crystalline counterparts.Catalytic performance benchmarks are presented,and mechanistic insights are discussed,focusing on how multimetallic synergy,amorphization effect,and in‐situ reconstruction cooperatively regulate reaction pathways.These insights provide guidance for the rational design of next‐generation amorphous high‐entropy electrocatalysts with improved efficiency and durability.展开更多
Enzyme-Induced Carbonate Precipitation(EICP)is an innovative technique to improve soil strength and reduce permeability.However,the use of EICP for reinforcing underwater sand beds remains largely unexplored.To advanc...Enzyme-Induced Carbonate Precipitation(EICP)is an innovative technique to improve soil strength and reduce permeability.However,the use of EICP for reinforcing underwater sand beds remains largely unexplored.To advance EICP implementation in various geotechnical applications,this paper develops a model box system to investigate the effectiveness of the EICP technique in reinforcing underwater sand beds.An"injection-extraction"system is designed to facilitate the flow of the EICP solution through underwater sand layers.Key parameters,including conductivity,pH,and Ca^(2+)concentration of the solution,are measured and analyzed.Electrical resistivity tomography(ERT)is utilized to evaluate the reinforcement effect in the underwater sand bed.The permeability of the model is tested to verify the feasibility of EICP technology for strengthening underwater sands.Furthermore,scanning electron microscope(SEM)is performed to investigate the growth mechanisms of calcium carbonate(CaCO_(3))crystals.The results show that the permeability of the model decreases from 1.28×10^(-2)m/s to 9.66×10^(-5)m/s,representing a reduction of approximately three orders of magnitude.This verifies that the EICP technology can greatly reduce the permeability of underwater sand beds.With increasing grouting cycles,the resistivity of the underwater sand initially decreases and then increases.This variation in sand resistivity is significantly influenced by the ion concentration in the solution,resulting in marked differences in resistivity at various depths and positions within the sand.The findings from this study offer a theoretical basis for the application of EICP technology in reinforcing seabed foundations and supporting marine infrastructure such as offshore pipelines,wind turbines,and oil platforms.展开更多
Clarifying the mechanisms through which coal mining affects groundwater storage(GWS)variations is crucial for water resource conservation and sustainable development.The Ordos Mining Region in China,a key energy base ...Clarifying the mechanisms through which coal mining affects groundwater storage(GWS)variations is crucial for water resource conservation and sustainable development.The Ordos Mining Region in China,a key energy base in China with significant strategic importance,has undergone intensive coal mining activities that have substantially disrupted regional groundwater circulation.This study integrated data from the Gravity Recovery and Climate Experiment Satellite(GRACE)and Famine Early Warning Systems Network(FEWS NET)Land Data Assimilation System(FLDAS)models,combined with weighted downscaling methodology and water balance principles,to reconstruct high-resolution(0.01°)terrestrial water storage(TWS)and GWS changes in the Ordos Mining Region,China from April 2002 to December 2021.The accuracy of GWS variations were validated through pumping test measurements.Subsequently,Geodetector analysis was implemented to quantify the contributions of natural and anthropogenic factors to groundwater storage dynamics.Key findings include:1)TWS in the study area showed a fluctuating but overall decreasing trend,with a total reduction of 8901.11 mm during study period.The most significant annual decrease occurred in 2021,reaching 1696.77 mm.2)GWS exhibited an accelerated decline,with an average annual change rate of 44.35 mm/yr,totaling a decrease of 887.05 mm.The lowest annual groundwater storage level was recorded in 2020,reaching 185.69 mm.3)Precipitation(PRE)contributed the most to GWS variation(q=0.52),followed by coal mining water consumption(MWS)(q=0.41).The interaction between PRE and MWS exhibited a nonlinear enhancement effect on GWS changes(0.54).The synergistic effect of natural hydrological factors has a great influence on the change of GWS,but coal mining water consumption will continue to reduce GWS.These findings provide critical references for the management and regulation of groundwater resource in mining regions.展开更多
The majority of water utilities,particularly public service providers such as Gidole town,are struggling to deliver a sufficient and consistent supply of water in Ethiopia's developing towns.The primary objective ...The majority of water utilities,particularly public service providers such as Gidole town,are struggling to deliver a sufficient and consistent supply of water in Ethiopia's developing towns.The primary objective of this study was to assess the hydraulic performance of water supply distribution system in Gidole Town,Ethiopia,a representative case of the challenges facing public water utilities in developing towns.The WaterGEMS v8i hydraulic model was utilized to simulate and evaluate the distribution network's performance.The system was configured as a looped network and analyzed against standard permitted pressure and velocity values in the distribution system.The model was effectively calibrated(coefficient of determination(R^(2))=0.969)using measured and observed pressure data.The model simulation run was conducted at peak and low hourly demand with 1.9 and 0.25 hourly factors,respectively.The estimated water demand of the town is 1284.3m^(3)/day(48.4 liters per capita per day),and it would be increased to 3099.77m^(3)/day(66.03 l/c/d)by the 2037 design period.The system experiences significant non-revenue water losses(75,434.11m^(3)/year),accounting for 29.9%of total water production;as a result,the present water supply coverage of the town is only 33.6%.Hydraulic simulations under peak and low demand scenarios revealed nodes with pressures outside the normal range,indicating system-wide inefficiencies.These findings highlight a combined issue of large physical losses and insufficient capacity of the water supply in the town,which is typical of many municipal systems in developing regions.The study concludes that strategic infrastructure rehabilitation,with an emphasis on pressure management and leak reduction,is not only a town necessity but a fundamental requirement for improving water security and financial sustainability for utilities in Ethiopia and similar contexts.The findings and methodology have been forwarded to town's water supply project and institutional development departments for immediate future implementation and provide a replicable framework for evidence-based investment and planning in other struggling municipalities in similar situations.展开更多
reshwater essential for civilization faces risk from untreated effluents discharged by industries,agriculture,urban areas,and other sources.Increasing demand and abstraction of freshwater deteriorate the pollution sce...reshwater essential for civilization faces risk from untreated effluents discharged by industries,agriculture,urban areas,and other sources.Increasing demand and abstraction of freshwater deteriorate the pollution scenario more.Hence,water quality analysis(WQA)is an important task for researchers and policymakers to maintain sustainability and public health.This study aims to gather and discuss the methods used for WQA by the researchers,focusing on their advantages and limitations.Simultaneously,this study compares different WQA methods,discussing their trends and future directions.Publications from the past decade on WQA are reviewed,and insights are explored to aggregate them in particular categories.Three major approaches,namely—water quality indexing,water quality modeling(WQM)and artificial intelligence-based WQM,are recognized.Different methodologies adopted to execute these three approaches are presented in this study,which leads to formulate a comparative discussion.Using statistical operations and soft computing techniques have been done by researchers to combat the subjectivity error in indexing.To achieve better results,WQMs are being modified to incorporate the physical processes influencing water quality more robustly.The utilization of artificial intelligence was primarily restricted to conventional networks,but in the last 5 years,implications of deep learning have increased rapidly and exhibited good results with the hybridization of feature extracting and time series modeling.Overall,this study is a valuable resource for researchers dedicated to WQA.展开更多
Microbial communities play indispensable roles in the biogeochemical cycling of river ecosystems.However,the response patterns of microbial community diversity,niche breadth,and assembly to rainfall disturbances in co...Microbial communities play indispensable roles in the biogeochemical cycling of river ecosystems.However,the response patterns of microbial community diversity,niche breadth,and assembly to rainfall disturbances in complex mountainous riverine reservoirs remain inadequately understood.We employed high-throughput sequencing of 16S and 18S ribosomal RNA genes,along with multivariate statistical methods to systematically investigate prokaryotic and eukaryotic microorganisms in the riverine Zhaoshandu Reservoir,Wenzhou,Zhejiang,East China.Results show significant temporal heterogeneity in both prokaryotic and eukaryotic microbial communities,with eukaryotic microbes showing more pronounced temporal variation.Canonical correspondence analysis revealed that rainfall and water temperature were the key drivers shaping microbial communities.Additionally,eukaryotic microorganisms exhibited a more pronounced response to rainfall and water temperature compared to prokaryotes.Modified stochasticity ratio model indicated that deterministic processes predominantly governed microbial community assembly,with stronger deterministic processes in eukaryotic compared to prokaryotic microorganisms.Rainfall has significantly altered water quality,notably increasing phosphorus concentration in the water column.Total phosphorus and total nitrogen showed significant correlations with the niche breadth of prokaryotic and eukaryotic microorganisms,and phosphorus nutrients served as keystones and playing indispensable roles in their co-occurrence networks.A structural equation model confirmed the notable impacts of rainfall and water temperature on microbial community diversity,further revealing that rainfall indirectly influenced the niche breadth and co-occurrence relationships of microbial communities by altering phosphorus concentrations.The findings underscore the influence of rainfall and water temperature on microbial distribution,highlighting the sensitivity of riverine reservoir ecosystems to climate change.展开更多
In recent years, the rational utilization of saline water resources for agricultural irrigation has emerged as an effective strategy to alleviate water scarcity. To safely and efficiently exploit saline water resource...In recent years, the rational utilization of saline water resources for agricultural irrigation has emerged as an effective strategy to alleviate water scarcity. To safely and efficiently exploit saline water resources over the long term, it is crucial to understand the effects of salinity on crops and develop optimal water-salinity irrigation strategies for processing tomatoes. A two-year field experiment was conducted in 2018 and 2019 to explore the impact of water salinity levels(S1: 1 g L^(–1), S2: 3 g L^(–1), and S3: 5 g L^(–1)) and irrigation amounts(W1: 305 mm, W2: 485 mm, and W3: 611 mm) on the soil volumetric water content and soil salinity, as well as processing tomato growth, yield, and water use efficiency. The results showed that irrigation with low to moderately saline water(<3 g L^(–1)) enhanced plant wateruptake and utilization capacity, with the soil water content(SWC) reduced by 6.5–7.62% and 10.52–13.23% for the S1 and S2 levels, respectively, compared to the S3 level in 2018. Under S1 condition, the soil salt content(SSC) accumulation rate gradually declined with an increase in the irrigation amount. For example, W3 decreased by 85.00 and 77.94% compared with W1 and W2 in 2018, and by 82.60 and 73.68% in 2019, respectively. Leaching effects were observed at the W3 level under S1, which gradually diminished with increasing water salinity and duration. In 2019, the salt contents of soil under each of the treatments increased by 10.81–89.72% compared with the contents in 2018. The yield of processing tomatoes increased with an increasing irrigation amount and peaked in the S1W3 treatment for the two years, reaching 125,304.85 kg ha^(–1)in 2018 and 128,329.71 kg ha^(–1)in 2019. Notably, in the first year, the S2W3 treatment achieved relatively high yields, exhibiting only a 2.85% reduction compared to the S1W3 treatment. However, the yield of the S2W3 treatment declined significantly in two years, and it was 15.88% less than that of the S1W3 treatment. Structural equation modeling(SEM) revealed that soil environmental factors(SWC and SSC) directly influence yield while also exerting indirect impacts on the growth indicators of processing tomatoes(plant height, stem diameter, and leaf area index). The TOPSIS method identified S1W3, S1W2, and S2W2 as the top three treatments. The single-factor marginal effect function also revealed that irrigation water salinity contributed to the composite evaluation scores(CES) when it was below 0.96 g L^(–1). Using brackish water with a salinity of 3 g L^(–1)at an irrigation amount of 485 mm over one year ensured that processing tomatoes maintained high yields with a relatively high CES(0.709). However, using brackish water for more than one year proved unfeasible.展开更多
The wettability of coarse-grained soils has been studied previously.However,soil drying in arid regions due to limited precipitation or irrigation has resulted in soil water repellency to some extent in fine-grained s...The wettability of coarse-grained soils has been studied previously.However,soil drying in arid regions due to limited precipitation or irrigation has resulted in soil water repellency to some extent in fine-grained soils.In this study,laboratory experiments were conducted to investigate the effects of plane(Platanus orientalis L.)leaf biochar with fine(<0.1 mm)and coarse grains(0.1-0.5 mm)on the wettability of a silty clay soil irrigated with saline and non-saline water.Eleven rates of each biochar,ranging from 0 to 10%with 1%intervals,were investigated along with five ionic strengths of water,including 0,0.2,0.4,0.6,and 0.8 mol L^(-1),prepared using sodium and calcium chloride,which are two dominant salts in arid regions.The results showed that application of 5%-10%fine-grained biochar changed the soil hydrophobicity class from strongly to slightly water-repellent,while only 4%coarse-grained biochar was sufficient for the same change in soil wettability.Furthermore,the use of 10%coarse-grained biochar made the soil hydrophilic.The positive effect of plane leaf biochar on soil water repellency reduction was limited by water salinity.The sodium chloride solution was more effective in decreasing the soil wettability than calcium chloride solution and increased the demand for biochar for soil water repellency reduction.In conclusion,plane leaf biochar could be beneficial in managing the hydrophobicity of fine-grained soils.However,water quality as well as biochar particle size determined the quantity of biochar required for improving soil wettability.展开更多
The escalating global issues of water scarcity and pollution emphasize the critical need for the rapid development of efficient and eco-friendly water treatment technologies.Photoelectrocatalytic technology has emerge...The escalating global issues of water scarcity and pollution emphasize the critical need for the rapid development of efficient and eco-friendly water treatment technologies.Photoelectrocatalytic technology has emerged as a promising solution for effectively degrading refractory organic pollutants in water under light conditions.This review delves into the advancements made in the field,focusing on strategies to enhance the generation of active species by modulating the micro-interface of the photoanode.Strategies,such as morphological control,element doping,introduction of surface oxygen vacancies,and construction of heterostructures,significantly improve the separation efficiency of photogenerated charges and the generation of active species,thereby boosting the efficiency of photoelectrocatalytic performance.Furthermore,the review explores the potential applications of photoelectrocatalytic technology in organic pollutant degradation in solutions.It also outlines the current challenges and future development directions.Despite its remarkable laboratory success,practical implementation of photoelectrocatalytic technology encounters obstacles related to stability,cost-effectiveness,and operational efficiency.Future investigations need to focus on optimizing the performance of photoelectrocatalytic materials and exploring strategies for upscaling their application in real water treatment scenarios.展开更多
The coupled chemo-mechanical impact of supercritical CO_(2)-H_(2)O(ScCO_(2)-H_(2)O)reactions on fracture geometry and nonlinear flow regimes in deep shale under confining pressures remains inadequately quantified.This...The coupled chemo-mechanical impact of supercritical CO_(2)-H_(2)O(ScCO_(2)-H_(2)O)reactions on fracture geometry and nonlinear flow regimes in deep shale under confining pressures remains inadequately quantified.This study systematically investigates the effects of ScCO_(2)-H_(2)O-shale interactions on fracture morphology and flow properties under confining pressures from 15 MPa to 40 MPa by integrating XRD(X-ray diffraction),micro-CT,3D surface profilometry,and multistage steady-state flow experiments.The results demonstrate that ScCO_(2)-H_(2)O exposure drives pyrite/feldspar dissolution and localized clay precipitation,resulting in fracture branching and macroscopic aperture regularization.Critically,confining pressure dictates the net hydraulic response:under low confining pressure(15-25 MPa),dissolution dominates,enhancing permeability,flow efficiency(Q/VP),and pre-linear flow behavior(n<1).At high confining pressures(30-40 MPa)mechanical compaction and mineral precipitation amplify flow resistance,shifting the flow regime toward quasi-linear behavior,as inertial effects become negligible compared to dominant viscous forces and increased flow resistance.Confining pressure thus critically mediates the dissolution-precipitation balance during ScCO_(2)-H_(2)O treatment,with an optimal window of 15-25 MPa identified for enhancing conductivity while minimizing clogging risk.These findings provide a quantitative framework for predicting stress-dependent flow evolution in chemically altered shale fractures.展开更多
This study investigates climate-and human-induced hydrological changes in the Zavkhan River-Khyargas Lake Basin,a highly sensitive arid and semi-arid region of Central Asia.Using Mann-Kendall,innovative trend analysis...This study investigates climate-and human-induced hydrological changes in the Zavkhan River-Khyargas Lake Basin,a highly sensitive arid and semi-arid region of Central Asia.Using Mann-Kendall,innovative trend analysis,and Sen's slope estimation methods,historical climate trends(1980-2100)were analyzed,while land cover changes represented human impacts.Future projections were simulated using the MIROC model with Shared Socioeconomic Pathways(SSPs)and the Tank model.Results show that during the past 40 years,air temperature significantly increased(Z=3.93^(***)),while precipitation(Z=-1.54^(*))and river flow(Z=-1.73^(*))both declined.The Khyargas Lake water level dropped markedly(Z=-5.57***).Land cover analysis reveals expanded cropland and impervious areas due to human activity.Under the SSP1.26 scenario,which assumes minimal climate change,air temperature is projected to rise by 2.0℃,precipitation by 21.8 mm,and river discharge by 1.61 m^(3)/s between 2000 and 2100.These findings indicate that both global warming and intensified land use have substantially altered hydrological and climatic processes in the basin,highlighting the vulnerability of western Mongolia's water resources to combined climatic and anthropogenic influence.展开更多
Water scarcity and environment deterioration have become main constraints to sustainable economic and social development.Scientifically assessing Water Resources Carrying Capacity(WRCC)is essential for the optimal all...Water scarcity and environment deterioration have become main constraints to sustainable economic and social development.Scientifically assessing Water Resources Carrying Capacity(WRCC)is essential for the optimal allocation of regional water resources.The hilly area at the northern foot of Yanshan Mountains is a key water conservation zone and an important water source for Beijing,Tianjin and Hebei.Grasping the current status and temporal trends of water quality and WRCC in representative small watersheds within this region is crucial for supporting rational water resources allocation and environment protection efforts.This study focuses on Pingquan City,a typical watershed in northern Hebei Province.Firstly,evaluation index systems for surface water quality,groundwater quality and WRCC were estab-lished based on the Pressure-State-Response(PSR)framework.Then,comprehensive evaluations of water quality and WRCC at the sub-watershed scale were conducted using the Varying Fuzzy Pattern Recogni-tion(VFPR)model.Finally,the rationality of the evaluation results was verified,and future scenarios were projected.Results showed that:(1)The average comprehensive evaluation scores for surface water and groundwater quality in the sub-watersheds were 1.44 and 1.46,respectively,indicating that both met the national Class II water quality standard and reflected a high-quality water environment.(2)From 2010 to 2020,the region's WRCC steadily improved,with scores rising from 2.99 to 2.83 and an average of 2.90,suggesting effective water resources management in Pingquan City.(3)According to scenario-based predic-tion,WRCC may slightly decline between 2025 and 2030,reaching 2.92 and 2.94,respectively,relative to 2020 levels.Therefore,future efforts should focus on strengthening scientific management and promoting the efficient use of water resources.Proactive measures are necessary to mitigate emerging contradiction and ensure the long-term stability and sustainability of the water resources system in the region.The evalua-tion system and spatiotemporal evolution patterns proposed in this study can provide a scientific basis for refined water resource management and ecological conservation in similar hilly areas.展开更多
River ethics,a significant advancement inspired by Chinese President XI Jinping's ecological civilization thought,embodies the philosophical essence of river governance and represents a legacy of innovation by gen...River ethics,a significant advancement inspired by Chinese President XI Jinping's ecological civilization thought,embodies the philosophical essence of river governance and represents a legacy of innovation by generations of water resources professionals.Rooted in river ecology,it offers a framework for advancing modern water governance systems and capabilities.This paper examines eight dimensions of river ethics to provide actionable recommendations:enhancing knowledge systems on water,rivers,and lakes;addressing critical challenges in water governance to strengthen the foundational role of water authorities in ensuring water security,resource management,ecological sustainability and environmental protection;optimizing water project planning to mitigate ecological impacts;ensuring high standards in the lifecycle management of water projects;refining water diversion strategies for precise scheduling;utilizing ecosystem complexity for river and lake restoration;implementing tiered management of water-related disasters;and driving reforms to modernize water governance systems and mechanisms.展开更多
Understanding the levels,causes,and sources of fluoride in groundwater is critical for public health,effective water resource management,and sustainable utilization.This study employs multivariate statistical methods,...Understanding the levels,causes,and sources of fluoride in groundwater is critical for public health,effective water resource management,and sustainable utilization.This study employs multivariate statistical methods,hazard quotient assessment,and geochemical analyses,such as mineral saturation index,ionic activities,and Gibbs diagrams,to investigate the hydrochemical characteristics,causes,and noncarcinogenic risks of fluoride in Red bed groundwater and geothermal water in the Guang'an area and neighboring regions.Approximately 9%of the Red bed groundwater samples contain fluoride concentrations exceeding 1 mg·L^(-1).The predominant water types identified are Cl-Na and HCO_(3)-Na,primarily influenced by evapotranspiration.Low-fluoride groundwater and high-fluoride geothermal water exhibit distinct hydrochemical types HCO_(3)-Ca and SO_(4)-Ca,respectively,which are mainly related to the weathering of carbonate,sulfate,and fluorite-containing rocks.Correlation analysis reveals that fluoride content in Red bed groundwater is positively associated with Na^(+),Cl^(-),SO_(4)^(2-),and TDS(r^(2)=0.45-0.64,p<0.01),while in geothermal water,it correlates strongly with pH,K^(+),Ca^(2+),and Mg^(2+)(r^(2)=0.52-0.80,p<0.05).Mineral saturation indices and ionic activities indicate that ion exchange processes and the dissolution of minerals such as carbonatite and fluorite are important sources of fluoride in groundwater.The enrichment of fluorine in the Red bed groundwater is linked to evaporation,cation exchange and dissolution of fluorite,caused by the lithologic characteristics of the red bed in this area.However,it exhibits minimal correlation with the geothermal water in the adjacent area.The noncarcinogenic health risk assessment indicates that 7%(n=5)of Red bed groundwater points exceed the fluoride safety limit for adults,while 12%(n=8)exceed the limit for children.These findings underscore the importance of avoiding highly fluoridated red bed groundwater as a direct drinking source and enhancing groundwater monitoring to mitigate health risks associated with elevated fluoride levels.展开更多
Water demand increases continuously with an increasing population and economic development. As a result, the difference between water supply and demand becomes a sig- nificant issue, especially in arid regions. To fig...Water demand increases continuously with an increasing population and economic development. As a result, the difference between water supply and demand becomes a sig- nificant issue, especially in arid regions. To figure out the utilization of water resources in the arid region of northwestern China （ARNWC）, and also to provide methodologies to predict the water use in future, three models were established in this study to calculate agricultural irri- gation, industrial and domestic water use in the ARNWC from the late 1980s to 2010. Based on river discharges in the region, the supply and demand of water resources at the river basin level were analyzed. The results indicated that agricultural irrigation demand occupies more than 90% of the total water use in the ARNWC. Total water demand increased from 31.97 km3 in the late 1980s to 48.19 km3 in 2010. Most river basins in this arid region were under me- dium and high water stress. Severe-risk river basins, such as the Shiyang river basin and the eastern part of the northern piedmont of the Tianshan Mountains, were found in this region. It was revealed that the water supply became critical from April to May, which was the season of the lowest water supply as determined by comparing monthly water consumption.展开更多
Prediction of water inflow into a tunnel is a crucial prerequisite for the waterproof and drainage design of mountain tunnels in water-rich areas.Based on the proposed Baiyun Mountain Tunnel project in Guangzhou,a num...Prediction of water inflow into a tunnel is a crucial prerequisite for the waterproof and drainage design of mountain tunnels in water-rich areas.Based on the proposed Baiyun Mountain Tunnel project in Guangzhou,a numerical percolation model of random fractured rock of a tunnel underpassing a water reservoir is established to study the seepage characteristics of surrounding rock,the law of water inflow,and the change of lining water pressure,considering the local artificial boundary conditions for seepage in large rock mass,.In addition,the influences of rock permeability,fracture aperture,grouting circle thickness,and penetration are analyzed.The results show that:(1)Only fractures with aperture wider than 0.1 mm can play a significant role in water conduction in rocks with the permeability lower than 10^(-11)m^(2);(2)The greater the permeability difference between the fractures and rocks,the more remarkable the effects of fractures on the surrounding rock seepage field and cavern water inflow;(3)The sensitivity of grouting waterproof function to grouting circle thickness,grouting ring penetration,and rock permeability is significantly higher than that of tunnel buried depth and fracture aperture;(4)The lining water head is much more sensitive to the grouting circle thickness and penetration than to the tunnel buried depth;(5)With the grouting range enlarging,the impact of grouting circle permeability on the precipitation pressure role of the grouting ring increases;(6)For the interesting tunnel designed to be built at the depth of 70 m,the grouting circle with the thickness of 0.5 m and permeability of 10-^(14)m^(2)is recommended.展开更多
基金supported by the National Natural Science Foundation of China(No.52070057)China Postdoctoral Science Foundation(No.2023M730855)Heilongjiang Postdoctoral Fund(No.LBH-Z22183)for financial support。
文摘Sustainable water,energy and food(WEF)supplies are the bedrock upon which human society depends.Solar-driven interfacial evaporation,combined with electricity generation and cultivation,is a promising approach to mitigate the freshwater,energy and food crises.However,the performance of solar-driven systems decreases significantly during operation due to uncontrollable weather.This study proposes an integrated water/electricity cogeneration-cultivation system with superior thermal management.The energy storage evaporator,consisting of energy storage microcapsules/hydrogel composites,is optimally designed for sustainable desalination,achieving an evaporation rate of around 1.91 kg m^(-2)h^(-1).In the dark,heat released from the phase-change layer supported an evaporation rate of around 0.54kg m^(-2)h^(-1).Reverse electrodialysis harnessed the salinity-gradient energy enhanced during desalination,enabling the long-running WEC system to achieve a power output of~0.3 W m^(-2),which was almost three times higher than that of conventional seawater/surface water mixing.Additionally,an integrated crop irrigation platform utilized system drainage for real-time,on-demand wheat cultivation without secondary contaminants,facilitating seamless WEF integration.This work presents a novel approach to all-day solar water production,electricity generation and crop irrigation,offering a solution and blueprint for the sustainable development of WEF.
基金supported by the K.C.Wong Education Foundation(GJTD-2020-14)the National Natural Science Foundation of China(42071245)+3 种基金Third Xinjiang Scientific Expedition Program(2021XJKK1400)the China-Pakistan Joint Research Center on Earth Sciences that supported the implementation of this studythe Chinese Academy of Sciences(CAS)the CSC Scholarship for Young Talents(Doctor Program)for the financial support of this study。
文摘Effective groundwater management is crucial for economic sustainable development,particularly as climate change and population growth increase the uncertainty of aquifer dynamics.Due to limited geological data,Punjab's complex hydrogeological conditions and Quaternary alluvial deposits present significant challenges for groundwater management.This study employs cost-effective numerical techniques as alternatives to traditional methods to safeguard groundwater quality,quantity,and accessibility.It introduces an edit-embedded transition frequency model that integrates regional datasets and utilizes algorithms such as GAMEAS,MCMOD,and TSIM to evaluate aquifer heterogeneity and simulate spatial variations using one-dimensional and three-dimensional Markov chains.Findings show that sand exhibits the highest self-transition(33.112 m),indicating strong stability,followed by silt,clay,and gravel,suggesting overall hydrofacies stability both horizontally and vertically.The model's predictions are largely consistent with actual material distribution,with a slight under-prediction of clay(-0.750%)and an over-prediction of sand(2.985%),which accounts for 58.77%of the aquifer material.It also highlights significant heterogeneity in the northern mountainous regions and minor variations in the south.The study emphasizes Punjab's severe water crisis,with groundwater reserves of 3502.3 BCM,declining water levels(0.38–33.62 m),and low hydraulic conductivity,urging government action on rainwater harvesting and sustainable groundwater management policies.
基金Under the auspices of the National Key Research and Development Program of China(No.2024YFC3713102)。
文摘Groundwater level(GWL)is a key indicator used to accurately assess groundwater resources and form the foundation for ef-fective groundwater management.This paper integrates a Gate Recurrent Unit(GRU)model with a Multi-head Self-attention mechan-ism(MSAM-GRU)to simulate GWLs in both confined and unconfined aquifers simultaneously.The model innovatively captures the lag times between GWLs in the unconfined aquifer and precipitation,as well as between GWLs in the confined aquifer and the upper aquifer.We have assessed the effectiveness of the proposed model using a case study in the Beijing Plain,China from January 2005 to December 2020.With the consideration of lag times,the results indicated that the MSAM-GRU model exhibits a maximum 67%and 73%reduction in RMSE compared to the Attention mechanism-GRU(AM-GRU)and GRU model,respectively.MSAM-GRU model exhibited a 31%reduction in RMSE and a 0.12 increase in R^(2) compared to the same model that do not account for lag time.In Region I,the shortest lag time of GWL in the unconfined aquifer was two months,while that in the confined aquifer was three months,indicating a longer delayed response in the confined aquifer.MSAM-GRU model considering lag time,was then applied to simulate the GWLs in the unconfined aquifer under different scenarios and to analyze whether GWL fluctuations affect subway operations.The simulation res-ults showed that under the scenario 1,the GWL in the unconfined aquifer would rise above the depth of subway station floor,threaten-ing the operation of subways.This study can provide reliable technical support for the accurate simulation of GWLs in multi-aquifer systems.
基金supported by the National Natural Science Foundation of China(W2412135)the Youth Innovation Promotion Association of the Chinese Academy of Sciences.
文摘As a major source of freshwater in Central Asia,Tajikistan is endowed with abundant glaciers and water resources.However,the country faces multiple challenges,including accelerated glacier retreat,complex inter-government water resource management,and inefficient water use.Existing research has predominantly focused on individual hydrological processes,such as glacier retreat,snow cover change,or transboundary water issues,but it has yet to fully capture the overall complexity of water system.Tajikistan’s water system functions as an integrated whole from mountain runoff to downstream supply,but a comprehensive study of its water resource has yet to be conducted.To address this research gap,this study systematically examined the status,challenges,and sustainable management strategies of Tajikistan’s water resources based on a literature review,remote sensing data analysis,and case studies.Despite Tajikistan’s relative abundance of water resources,global warming is accelerating glacier melting and altering the hydrological cycles,which have resulted in unstable runoff patterns and heightened risks of extreme events.In Tajikistan,outdated infrastructure and poor management are primary causes of low water-use efficiency in the agricultural sector,which accounts for 85.00%of the total water withdrawals.At the governance level,Tajikistan faces challenges in balancing the water-energy-food nexus and transboundary water resource issues.To address these issues,this study proposes core paths for Tajikistan to achieve sustainable water resource management,such as accelerating technological innovation,promoting water-saving agricultural technologies,improving water resource utilization efficiency,and establishing a community participation-based comprehensive management framework.Additionally,strengthening cross-border cooperation and improving real-time monitoring systems have been identified as critical steps to advance sustainable water resource utilization and evidence-based decision-making in Tajikistan and across Central Asia.
基金supported by the Australian Research Council(ARC)Projects(DP220101139,DP220101142,and LP240100542).
文摘High‐entropy amorphous catalysts(HEACs)integrate multielement synergy with structural disorder,making them promising candidates for water splitting.Their distinctive features—including flexible coordination environments,tunable electronic structures,abundant unsaturated active sites,and dynamic structural reassembly—collectively enhance electrochemical activity and durability under operating conditions.This review summarizes recent advances in HEACs for hydrogen evolution,oxygen evolution,and overall water splitting,highlighting their disorder-driven advantages over crystalline counterparts.Catalytic performance benchmarks are presented,and mechanistic insights are discussed,focusing on how multimetallic synergy,amorphization effect,and in‐situ reconstruction cooperatively regulate reaction pathways.These insights provide guidance for the rational design of next‐generation amorphous high‐entropy electrocatalysts with improved efficiency and durability.
基金supported by the National Youth Top-notch Talent Support Program of China(Grant No.00389335)the National Natural Science Foundation of China(Grant No.52378392)+1 种基金the“Foal Eagle Program”Youth Top-notch Talent Project of Fujian Province(Grant No.00387088)supports are gratefully acknowledged.
文摘Enzyme-Induced Carbonate Precipitation(EICP)is an innovative technique to improve soil strength and reduce permeability.However,the use of EICP for reinforcing underwater sand beds remains largely unexplored.To advance EICP implementation in various geotechnical applications,this paper develops a model box system to investigate the effectiveness of the EICP technique in reinforcing underwater sand beds.An"injection-extraction"system is designed to facilitate the flow of the EICP solution through underwater sand layers.Key parameters,including conductivity,pH,and Ca^(2+)concentration of the solution,are measured and analyzed.Electrical resistivity tomography(ERT)is utilized to evaluate the reinforcement effect in the underwater sand bed.The permeability of the model is tested to verify the feasibility of EICP technology for strengthening underwater sands.Furthermore,scanning electron microscope(SEM)is performed to investigate the growth mechanisms of calcium carbonate(CaCO_(3))crystals.The results show that the permeability of the model decreases from 1.28×10^(-2)m/s to 9.66×10^(-5)m/s,representing a reduction of approximately three orders of magnitude.This verifies that the EICP technology can greatly reduce the permeability of underwater sand beds.With increasing grouting cycles,the resistivity of the underwater sand initially decreases and then increases.This variation in sand resistivity is significantly influenced by the ion concentration in the solution,resulting in marked differences in resistivity at various depths and positions within the sand.The findings from this study offer a theoretical basis for the application of EICP technology in reinforcing seabed foundations and supporting marine infrastructure such as offshore pipelines,wind turbines,and oil platforms.
基金Under the National Key R&D Program Key Project(No.2021YFC3201201)National Natural Science Foundation of China(No.52360032)+2 种基金Basic Scientific Research Business Fee Project of Colleges And Universities Directly Under the Inner Mongolia Autonomous Region(No.JBYYWF2022001)Development Plan of Innovation Team of Colleges And Universities in Inner Mongolia Autonomous Region(No.NMGIRT2313)the Innovation Team of‘Grassland Talents’。
文摘Clarifying the mechanisms through which coal mining affects groundwater storage(GWS)variations is crucial for water resource conservation and sustainable development.The Ordos Mining Region in China,a key energy base in China with significant strategic importance,has undergone intensive coal mining activities that have substantially disrupted regional groundwater circulation.This study integrated data from the Gravity Recovery and Climate Experiment Satellite(GRACE)and Famine Early Warning Systems Network(FEWS NET)Land Data Assimilation System(FLDAS)models,combined with weighted downscaling methodology and water balance principles,to reconstruct high-resolution(0.01°)terrestrial water storage(TWS)and GWS changes in the Ordos Mining Region,China from April 2002 to December 2021.The accuracy of GWS variations were validated through pumping test measurements.Subsequently,Geodetector analysis was implemented to quantify the contributions of natural and anthropogenic factors to groundwater storage dynamics.Key findings include:1)TWS in the study area showed a fluctuating but overall decreasing trend,with a total reduction of 8901.11 mm during study period.The most significant annual decrease occurred in 2021,reaching 1696.77 mm.2)GWS exhibited an accelerated decline,with an average annual change rate of 44.35 mm/yr,totaling a decrease of 887.05 mm.The lowest annual groundwater storage level was recorded in 2020,reaching 185.69 mm.3)Precipitation(PRE)contributed the most to GWS variation(q=0.52),followed by coal mining water consumption(MWS)(q=0.41).The interaction between PRE and MWS exhibited a nonlinear enhancement effect on GWS changes(0.54).The synergistic effect of natural hydrological factors has a great influence on the change of GWS,but coal mining water consumption will continue to reduce GWS.These findings provide critical references for the management and regulation of groundwater resource in mining regions.
文摘The majority of water utilities,particularly public service providers such as Gidole town,are struggling to deliver a sufficient and consistent supply of water in Ethiopia's developing towns.The primary objective of this study was to assess the hydraulic performance of water supply distribution system in Gidole Town,Ethiopia,a representative case of the challenges facing public water utilities in developing towns.The WaterGEMS v8i hydraulic model was utilized to simulate and evaluate the distribution network's performance.The system was configured as a looped network and analyzed against standard permitted pressure and velocity values in the distribution system.The model was effectively calibrated(coefficient of determination(R^(2))=0.969)using measured and observed pressure data.The model simulation run was conducted at peak and low hourly demand with 1.9 and 0.25 hourly factors,respectively.The estimated water demand of the town is 1284.3m^(3)/day(48.4 liters per capita per day),and it would be increased to 3099.77m^(3)/day(66.03 l/c/d)by the 2037 design period.The system experiences significant non-revenue water losses(75,434.11m^(3)/year),accounting for 29.9%of total water production;as a result,the present water supply coverage of the town is only 33.6%.Hydraulic simulations under peak and low demand scenarios revealed nodes with pressures outside the normal range,indicating system-wide inefficiencies.These findings highlight a combined issue of large physical losses and insufficient capacity of the water supply in the town,which is typical of many municipal systems in developing regions.The study concludes that strategic infrastructure rehabilitation,with an emphasis on pressure management and leak reduction,is not only a town necessity but a fundamental requirement for improving water security and financial sustainability for utilities in Ethiopia and similar contexts.The findings and methodology have been forwarded to town's water supply project and institutional development departments for immediate future implementation and provide a replicable framework for evidence-based investment and planning in other struggling municipalities in similar situations.
基金State University Research Excellence(SURE),SERB,GOI,Grant/Award Number:SUR/2022/001557。
文摘reshwater essential for civilization faces risk from untreated effluents discharged by industries,agriculture,urban areas,and other sources.Increasing demand and abstraction of freshwater deteriorate the pollution scenario more.Hence,water quality analysis(WQA)is an important task for researchers and policymakers to maintain sustainability and public health.This study aims to gather and discuss the methods used for WQA by the researchers,focusing on their advantages and limitations.Simultaneously,this study compares different WQA methods,discussing their trends and future directions.Publications from the past decade on WQA are reviewed,and insights are explored to aggregate them in particular categories.Three major approaches,namely—water quality indexing,water quality modeling(WQM)and artificial intelligence-based WQM,are recognized.Different methodologies adopted to execute these three approaches are presented in this study,which leads to formulate a comparative discussion.Using statistical operations and soft computing techniques have been done by researchers to combat the subjectivity error in indexing.To achieve better results,WQMs are being modified to incorporate the physical processes influencing water quality more robustly.The utilization of artificial intelligence was primarily restricted to conventional networks,but in the last 5 years,implications of deep learning have increased rapidly and exhibited good results with the hybridization of feature extracting and time series modeling.Overall,this study is a valuable resource for researchers dedicated to WQA.
基金Supported by the Zhejiang Provincial Natural Science Foundation of China(No.LD21C030001)the Key Research and Development Program of National Natural Science Foundation of China(No.2021YFE0112000)+1 种基金the National Natural Science Foundation of China(Nos.32371634,31970219)the Scientific Research Project of the Shanghai Municipal Bureau of Ecology and Environment(No.202409)。
文摘Microbial communities play indispensable roles in the biogeochemical cycling of river ecosystems.However,the response patterns of microbial community diversity,niche breadth,and assembly to rainfall disturbances in complex mountainous riverine reservoirs remain inadequately understood.We employed high-throughput sequencing of 16S and 18S ribosomal RNA genes,along with multivariate statistical methods to systematically investigate prokaryotic and eukaryotic microorganisms in the riverine Zhaoshandu Reservoir,Wenzhou,Zhejiang,East China.Results show significant temporal heterogeneity in both prokaryotic and eukaryotic microbial communities,with eukaryotic microbes showing more pronounced temporal variation.Canonical correspondence analysis revealed that rainfall and water temperature were the key drivers shaping microbial communities.Additionally,eukaryotic microorganisms exhibited a more pronounced response to rainfall and water temperature compared to prokaryotes.Modified stochasticity ratio model indicated that deterministic processes predominantly governed microbial community assembly,with stronger deterministic processes in eukaryotic compared to prokaryotic microorganisms.Rainfall has significantly altered water quality,notably increasing phosphorus concentration in the water column.Total phosphorus and total nitrogen showed significant correlations with the niche breadth of prokaryotic and eukaryotic microorganisms,and phosphorus nutrients served as keystones and playing indispensable roles in their co-occurrence networks.A structural equation model confirmed the notable impacts of rainfall and water temperature on microbial community diversity,further revealing that rainfall indirectly influenced the niche breadth and co-occurrence relationships of microbial communities by altering phosphorus concentrations.The findings underscore the influence of rainfall and water temperature on microbial distribution,highlighting the sensitivity of riverine reservoir ecosystems to climate change.
基金funded by the National Key R&D Program of China (2022YFD1900405)。
文摘In recent years, the rational utilization of saline water resources for agricultural irrigation has emerged as an effective strategy to alleviate water scarcity. To safely and efficiently exploit saline water resources over the long term, it is crucial to understand the effects of salinity on crops and develop optimal water-salinity irrigation strategies for processing tomatoes. A two-year field experiment was conducted in 2018 and 2019 to explore the impact of water salinity levels(S1: 1 g L^(–1), S2: 3 g L^(–1), and S3: 5 g L^(–1)) and irrigation amounts(W1: 305 mm, W2: 485 mm, and W3: 611 mm) on the soil volumetric water content and soil salinity, as well as processing tomato growth, yield, and water use efficiency. The results showed that irrigation with low to moderately saline water(<3 g L^(–1)) enhanced plant wateruptake and utilization capacity, with the soil water content(SWC) reduced by 6.5–7.62% and 10.52–13.23% for the S1 and S2 levels, respectively, compared to the S3 level in 2018. Under S1 condition, the soil salt content(SSC) accumulation rate gradually declined with an increase in the irrigation amount. For example, W3 decreased by 85.00 and 77.94% compared with W1 and W2 in 2018, and by 82.60 and 73.68% in 2019, respectively. Leaching effects were observed at the W3 level under S1, which gradually diminished with increasing water salinity and duration. In 2019, the salt contents of soil under each of the treatments increased by 10.81–89.72% compared with the contents in 2018. The yield of processing tomatoes increased with an increasing irrigation amount and peaked in the S1W3 treatment for the two years, reaching 125,304.85 kg ha^(–1)in 2018 and 128,329.71 kg ha^(–1)in 2019. Notably, in the first year, the S2W3 treatment achieved relatively high yields, exhibiting only a 2.85% reduction compared to the S1W3 treatment. However, the yield of the S2W3 treatment declined significantly in two years, and it was 15.88% less than that of the S1W3 treatment. Structural equation modeling(SEM) revealed that soil environmental factors(SWC and SSC) directly influence yield while also exerting indirect impacts on the growth indicators of processing tomatoes(plant height, stem diameter, and leaf area index). The TOPSIS method identified S1W3, S1W2, and S2W2 as the top three treatments. The single-factor marginal effect function also revealed that irrigation water salinity contributed to the composite evaluation scores(CES) when it was below 0.96 g L^(–1). Using brackish water with a salinity of 3 g L^(–1)at an irrigation amount of 485 mm over one year ensured that processing tomatoes maintained high yields with a relatively high CES(0.709). However, using brackish water for more than one year proved unfeasible.
文摘The wettability of coarse-grained soils has been studied previously.However,soil drying in arid regions due to limited precipitation or irrigation has resulted in soil water repellency to some extent in fine-grained soils.In this study,laboratory experiments were conducted to investigate the effects of plane(Platanus orientalis L.)leaf biochar with fine(<0.1 mm)and coarse grains(0.1-0.5 mm)on the wettability of a silty clay soil irrigated with saline and non-saline water.Eleven rates of each biochar,ranging from 0 to 10%with 1%intervals,were investigated along with five ionic strengths of water,including 0,0.2,0.4,0.6,and 0.8 mol L^(-1),prepared using sodium and calcium chloride,which are two dominant salts in arid regions.The results showed that application of 5%-10%fine-grained biochar changed the soil hydrophobicity class from strongly to slightly water-repellent,while only 4%coarse-grained biochar was sufficient for the same change in soil wettability.Furthermore,the use of 10%coarse-grained biochar made the soil hydrophilic.The positive effect of plane leaf biochar on soil water repellency reduction was limited by water salinity.The sodium chloride solution was more effective in decreasing the soil wettability than calcium chloride solution and increased the demand for biochar for soil water repellency reduction.In conclusion,plane leaf biochar could be beneficial in managing the hydrophobicity of fine-grained soils.However,water quality as well as biochar particle size determined the quantity of biochar required for improving soil wettability.
基金financially supported by the National Natural Science Foundation of China (No.52100076)the Fundamental Research Funds for the Central Universities (No.2023MS064)。
文摘The escalating global issues of water scarcity and pollution emphasize the critical need for the rapid development of efficient and eco-friendly water treatment technologies.Photoelectrocatalytic technology has emerged as a promising solution for effectively degrading refractory organic pollutants in water under light conditions.This review delves into the advancements made in the field,focusing on strategies to enhance the generation of active species by modulating the micro-interface of the photoanode.Strategies,such as morphological control,element doping,introduction of surface oxygen vacancies,and construction of heterostructures,significantly improve the separation efficiency of photogenerated charges and the generation of active species,thereby boosting the efficiency of photoelectrocatalytic performance.Furthermore,the review explores the potential applications of photoelectrocatalytic technology in organic pollutant degradation in solutions.It also outlines the current challenges and future development directions.Despite its remarkable laboratory success,practical implementation of photoelectrocatalytic technology encounters obstacles related to stability,cost-effectiveness,and operational efficiency.Future investigations need to focus on optimizing the performance of photoelectrocatalytic materials and exploring strategies for upscaling their application in real water treatment scenarios.
基金support from the Science and Technology Innovation Program of Hunan Province(Grant No.2023RC1021)the Natural Science Foundation of Sichuan Province(Grant No.2025YFHZ0323).-。
文摘The coupled chemo-mechanical impact of supercritical CO_(2)-H_(2)O(ScCO_(2)-H_(2)O)reactions on fracture geometry and nonlinear flow regimes in deep shale under confining pressures remains inadequately quantified.This study systematically investigates the effects of ScCO_(2)-H_(2)O-shale interactions on fracture morphology and flow properties under confining pressures from 15 MPa to 40 MPa by integrating XRD(X-ray diffraction),micro-CT,3D surface profilometry,and multistage steady-state flow experiments.The results demonstrate that ScCO_(2)-H_(2)O exposure drives pyrite/feldspar dissolution and localized clay precipitation,resulting in fracture branching and macroscopic aperture regularization.Critically,confining pressure dictates the net hydraulic response:under low confining pressure(15-25 MPa),dissolution dominates,enhancing permeability,flow efficiency(Q/VP),and pre-linear flow behavior(n<1).At high confining pressures(30-40 MPa)mechanical compaction and mineral precipitation amplify flow resistance,shifting the flow regime toward quasi-linear behavior,as inertial effects become negligible compared to dominant viscous forces and increased flow resistance.Confining pressure thus critically mediates the dissolution-precipitation balance during ScCO_(2)-H_(2)O treatment,with an optimal window of 15-25 MPa identified for enhancing conductivity while minimizing clogging risk.These findings provide a quantitative framework for predicting stress-dependent flow evolution in chemically altered shale fractures.
基金The National University of Mongolia,No.P2024-4814The Mongolian Science and Technology Foundation,No.CHN-2022/274The‘Chey Institute for Advanced Studies’International Scholar Exchange Fellowship for the Academic Year of 2025-2026。
文摘This study investigates climate-and human-induced hydrological changes in the Zavkhan River-Khyargas Lake Basin,a highly sensitive arid and semi-arid region of Central Asia.Using Mann-Kendall,innovative trend analysis,and Sen's slope estimation methods,historical climate trends(1980-2100)were analyzed,while land cover changes represented human impacts.Future projections were simulated using the MIROC model with Shared Socioeconomic Pathways(SSPs)and the Tank model.Results show that during the past 40 years,air temperature significantly increased(Z=3.93^(***)),while precipitation(Z=-1.54^(*))and river flow(Z=-1.73^(*))both declined.The Khyargas Lake water level dropped markedly(Z=-5.57***).Land cover analysis reveals expanded cropland and impervious areas due to human activity.Under the SSP1.26 scenario,which assumes minimal climate change,air temperature is projected to rise by 2.0℃,precipitation by 21.8 mm,and river discharge by 1.61 m^(3)/s between 2000 and 2100.These findings indicate that both global warming and intensified land use have substantially altered hydrological and climatic processes in the basin,highlighting the vulnerability of western Mongolia's water resources to combined climatic and anthropogenic influence.
基金financially supported by China Geological Survey Project(No.DD20220954)Open Funding Project of the Key Laboratory of Groundwater Sciences and Engineering,Ministry of Natural Resources(No.SK202301-4)+2 种基金Science and Technology Innovation Foundation of Comprehensive Survey&Command Center for Natural Resources(No.KC20240003)Yanzhao Shanshui Science and Innovation Fund of Langfang Integrated Natural Resources Survey Center,China Geological Survey(No.YZSSJJ202401-001)Open Foundation of the Key Laboratory of Coupling Process and Effect of Natural Resources Elements(No.2022KFKTC009).
文摘Water scarcity and environment deterioration have become main constraints to sustainable economic and social development.Scientifically assessing Water Resources Carrying Capacity(WRCC)is essential for the optimal allocation of regional water resources.The hilly area at the northern foot of Yanshan Mountains is a key water conservation zone and an important water source for Beijing,Tianjin and Hebei.Grasping the current status and temporal trends of water quality and WRCC in representative small watersheds within this region is crucial for supporting rational water resources allocation and environment protection efforts.This study focuses on Pingquan City,a typical watershed in northern Hebei Province.Firstly,evaluation index systems for surface water quality,groundwater quality and WRCC were estab-lished based on the Pressure-State-Response(PSR)framework.Then,comprehensive evaluations of water quality and WRCC at the sub-watershed scale were conducted using the Varying Fuzzy Pattern Recogni-tion(VFPR)model.Finally,the rationality of the evaluation results was verified,and future scenarios were projected.Results showed that:(1)The average comprehensive evaluation scores for surface water and groundwater quality in the sub-watersheds were 1.44 and 1.46,respectively,indicating that both met the national Class II water quality standard and reflected a high-quality water environment.(2)From 2010 to 2020,the region's WRCC steadily improved,with scores rising from 2.99 to 2.83 and an average of 2.90,suggesting effective water resources management in Pingquan City.(3)According to scenario-based predic-tion,WRCC may slightly decline between 2025 and 2030,reaching 2.92 and 2.94,respectively,relative to 2020 levels.Therefore,future efforts should focus on strengthening scientific management and promoting the efficient use of water resources.Proactive measures are necessary to mitigate emerging contradiction and ensure the long-term stability and sustainability of the water resources system in the region.The evalua-tion system and spatiotemporal evolution patterns proposed in this study can provide a scientific basis for refined water resource management and ecological conservation in similar hilly areas.
基金Three Gorges Follow-up Work Fund,Grant/Award Number:WE0161A042024National Key Research Program of China,Grant/Award Number:2024YFC3210900。
文摘River ethics,a significant advancement inspired by Chinese President XI Jinping's ecological civilization thought,embodies the philosophical essence of river governance and represents a legacy of innovation by generations of water resources professionals.Rooted in river ecology,it offers a framework for advancing modern water governance systems and capabilities.This paper examines eight dimensions of river ethics to provide actionable recommendations:enhancing knowledge systems on water,rivers,and lakes;addressing critical challenges in water governance to strengthen the foundational role of water authorities in ensuring water security,resource management,ecological sustainability and environmental protection;optimizing water project planning to mitigate ecological impacts;ensuring high standards in the lifecycle management of water projects;refining water diversion strategies for precise scheduling;utilizing ecosystem complexity for river and lake restoration;implementing tiered management of water-related disasters;and driving reforms to modernize water governance systems and mechanisms.
基金supported by the China Geological Survey Project(Nos.DD20220864 and DD20243077).
文摘Understanding the levels,causes,and sources of fluoride in groundwater is critical for public health,effective water resource management,and sustainable utilization.This study employs multivariate statistical methods,hazard quotient assessment,and geochemical analyses,such as mineral saturation index,ionic activities,and Gibbs diagrams,to investigate the hydrochemical characteristics,causes,and noncarcinogenic risks of fluoride in Red bed groundwater and geothermal water in the Guang'an area and neighboring regions.Approximately 9%of the Red bed groundwater samples contain fluoride concentrations exceeding 1 mg·L^(-1).The predominant water types identified are Cl-Na and HCO_(3)-Na,primarily influenced by evapotranspiration.Low-fluoride groundwater and high-fluoride geothermal water exhibit distinct hydrochemical types HCO_(3)-Ca and SO_(4)-Ca,respectively,which are mainly related to the weathering of carbonate,sulfate,and fluorite-containing rocks.Correlation analysis reveals that fluoride content in Red bed groundwater is positively associated with Na^(+),Cl^(-),SO_(4)^(2-),and TDS(r^(2)=0.45-0.64,p<0.01),while in geothermal water,it correlates strongly with pH,K^(+),Ca^(2+),and Mg^(2+)(r^(2)=0.52-0.80,p<0.05).Mineral saturation indices and ionic activities indicate that ion exchange processes and the dissolution of minerals such as carbonatite and fluorite are important sources of fluoride in groundwater.The enrichment of fluorine in the Red bed groundwater is linked to evaporation,cation exchange and dissolution of fluorite,caused by the lithologic characteristics of the red bed in this area.However,it exhibits minimal correlation with the geothermal water in the adjacent area.The noncarcinogenic health risk assessment indicates that 7%(n=5)of Red bed groundwater points exceed the fluoride safety limit for adults,while 12%(n=8)exceed the limit for children.These findings underscore the importance of avoiding highly fluoridated red bed groundwater as a direct drinking source and enhancing groundwater monitoring to mitigate health risks associated with elevated fluoride levels.
基金National Key Project on Basic Research(973),No.2010CB951003The National Science and Technology Project,No.2014BAD10B06
文摘Water demand increases continuously with an increasing population and economic development. As a result, the difference between water supply and demand becomes a sig- nificant issue, especially in arid regions. To figure out the utilization of water resources in the arid region of northwestern China （ARNWC）, and also to provide methodologies to predict the water use in future, three models were established in this study to calculate agricultural irri- gation, industrial and domestic water use in the ARNWC from the late 1980s to 2010. Based on river discharges in the region, the supply and demand of water resources at the river basin level were analyzed. The results indicated that agricultural irrigation demand occupies more than 90% of the total water use in the ARNWC. Total water demand increased from 31.97 km3 in the late 1980s to 48.19 km3 in 2010. Most river basins in this arid region were under me- dium and high water stress. Severe-risk river basins, such as the Shiyang river basin and the eastern part of the northern piedmont of the Tianshan Mountains, were found in this region. It was revealed that the water supply became critical from April to May, which was the season of the lowest water supply as determined by comparing monthly water consumption.
文摘Prediction of water inflow into a tunnel is a crucial prerequisite for the waterproof and drainage design of mountain tunnels in water-rich areas.Based on the proposed Baiyun Mountain Tunnel project in Guangzhou,a numerical percolation model of random fractured rock of a tunnel underpassing a water reservoir is established to study the seepage characteristics of surrounding rock,the law of water inflow,and the change of lining water pressure,considering the local artificial boundary conditions for seepage in large rock mass,.In addition,the influences of rock permeability,fracture aperture,grouting circle thickness,and penetration are analyzed.The results show that:(1)Only fractures with aperture wider than 0.1 mm can play a significant role in water conduction in rocks with the permeability lower than 10^(-11)m^(2);(2)The greater the permeability difference between the fractures and rocks,the more remarkable the effects of fractures on the surrounding rock seepage field and cavern water inflow;(3)The sensitivity of grouting waterproof function to grouting circle thickness,grouting ring penetration,and rock permeability is significantly higher than that of tunnel buried depth and fracture aperture;(4)The lining water head is much more sensitive to the grouting circle thickness and penetration than to the tunnel buried depth;(5)With the grouting range enlarging,the impact of grouting circle permeability on the precipitation pressure role of the grouting ring increases;(6)For the interesting tunnel designed to be built at the depth of 70 m,the grouting circle with the thickness of 0.5 m and permeability of 10-^(14)m^(2)is recommended.
