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氨基氰在高温高压水流体中反应化学的实验研究 被引量:1
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作者 李统锦 BrillTB 《地球化学》 CAS CSCD 北大核心 1998年第1期20-26,共7页
氨基氰在水热环境,尤其在超临界水中的反应化学实验结果表明,氨基氰可以通过自聚合作用,生成较高分子量的氮杂环混合物,进而水解并最终转化成CO_2和NH_3。实验还证明,超临界水可以有效地破坏那些含有危险的或剧毒的有机废料,使之... 氨基氰在水热环境,尤其在超临界水中的反应化学实验结果表明,氨基氰可以通过自聚合作用,生成较高分子量的氮杂环混合物,进而水解并最终转化成CO_2和NH_3。实验还证明,超临界水可以有效地破坏那些含有危险的或剧毒的有机废料,使之转化成无毒无害的H_2O、CO_2、NH_3和无机盐等。根据实验结果,提出水解反应的可能机制是水的亲核加合。 展开更多
关键词 氨基氰 氮杂环化合物 超临界水 反应化学 水流体
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填埋场渗滤液水质特性在Fenton处理过程中的变化 被引量:12
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作者 张晖 Huang Chin-pao 《环境科学研究》 EI CAS CSCD 北大核心 2002年第2期48-51,共4页
在CSTR和间歇操作两种模式下考察了早、晚期渗滤液水质特性在Fenton处理过程前后的变化。结果表明NH3-N ,NO3- -N ,Cl- 质量浓度变化很小 ,F- 质量浓度则有较大的增加 ,而IC(无机碳 )值下降较多。渗滤液中的CODCr和TOC均得到不同程度的... 在CSTR和间歇操作两种模式下考察了早、晚期渗滤液水质特性在Fenton处理过程前后的变化。结果表明NH3-N ,NO3- -N ,Cl- 质量浓度变化很小 ,F- 质量浓度则有较大的增加 ,而IC(无机碳 )值下降较多。渗滤液中的CODCr和TOC均得到不同程度的去除 ,且晚期渗滤液的去除率高些 ,造成这种不同处理效果的原因主要是渗滤液中高分子量有机物 (HighMolecularWeightOrganicMatter ,HMWOM)与低分子量有机物(LowMolecularWeightOrganicMatter,LMWOM)的比例存在较大的差异。此外 ,文中CODCr和TOC的去除率大多低于文献 展开更多
关键词 渗滤液 水质特性 Fenton过程 垃圾
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Directional Spectrum of Wind Waves: Part Ⅱ- Comparison and Confirmation 被引量:3
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作者 LIUYuguang YANXiao-Hai SUMing-Yang 《Journal of Ocean University of Qingdao》 2003年第1期13-23,共11页
A model on the directional frequency spectrum of wind waves for deep water is introduced. The comparisons of the proposed model with other existing models show that the proposed model is very close to the JONSWAP mode... A model on the directional frequency spectrum of wind waves for deep water is introduced. The comparisons of the proposed model with other existing models show that the proposed model is very close to the JONSWAP model and DHH model for describing the developing waves under the normal spectral bandwidth, and has a better description for the transition of the unidirectional spectrum from ω -4 to ω -5 at a position around 3ω p, i.e., three time the peak frequency. Comparisons also show that the proposed model describes closely both field data measured by a four-frequency radar and a laser-optical sensor, and laboratory data measured by a laser slope gauge and an imaging optical method. The comparisons further demonstrate that the inverse spectral bandwidth as a new wave parameter is robust for describing the spectral steepness. Finally, the formula on the local spectral-peak angular frequency is confirmed using the observed two-dimensional spectra. 展开更多
关键词 wind waves directional spectrum spectral bandwidth wave age local spectral-peak angular frequency
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Sodium-Zinc Exchange Selectivity on Wyoming Montmorillonite in Different Background Anion Solutions
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作者 YOUYOUWEN G.F.VAXCE 《Pedosphere》 SCIE CAS CSCD 2002年第4期289-299,共11页
The effect of background anion on cation exchange reactions, suchas Na-Ca and Na-Cu exchange reac- tions, on montmorillonites has beenstudied, but the results are not always clear and discrepancies existin the literat... The effect of background anion on cation exchange reactions, suchas Na-Ca and Na-Cu exchange reac- tions, on montmorillonites has beenstudied, but the results are not always clear and discrepancies existin the literature. In this study, the exchange of zinc (Zn^2+) forsodium (Na^+) on Wyoming montmorillonite was investigated at 298 deg.K using Cl^-, ClO_4^-, NO_3^-, Oac^-, and SO_4~2- solution media at aconstant total metal charge concentration of 0.02000 mol_c L^-1.Results indicated that the clay CEC values were essential similar forCl^-, ClO_4^-, NO_3^- and SO_4~2- solution media with an average CECof 0.856±0.008 mol_c kg^-1; in an OAc^- solution the clay CEC wasmuch higher than that in other anion media. 展开更多
关键词 anion background cation exchange MONTMORILLONITE SODIUM ZINC
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Directional Spectrum of Wind Waves: Part Ⅰ- Model and Derivation
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作者 LIUYuguang YANXiao-Hai SUMing-Yang 《Journal of Ocean University of Qingdao》 2003年第1期1-12,共12页
A new model on the directional spectrum of wind waves for deep water is proposed based on the statistics of wind waves. This model contains three parameters: the wave age, the inverse spectral bandwidth and the local ... A new model on the directional spectrum of wind waves for deep water is proposed based on the statistics of wind waves. This model contains three parameters: the wave age, the inverse spectral bandwidth and the local spectral-peak angular frequency. The inverse spectral bandwidth is a robust parameter for describing the spectral steepness of wind waves. Using the inverse spectral bandwidth parameter, the proposed model can well describe various observations obtained from the open ocean and laboratory tank. 展开更多
关键词 wind waves directional spectrum spectral bandwidth wave age local spectral-peak angular frequency
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Effects of Layer Deposition Sequence on Microstructure and Magnetostatic Coupling of Spin-Valves with Amorphous CoNbZr Layer
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作者 支岐业 张怀武 +3 位作者 蒋向东 唐晓莉 钟智勇 JohnQ.Xiao 《Chinese Physics Letters》 SCIE CAS CSCD 2005年第3期690-693,共4页
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Bulk—like contribution of tunnel magnetoresistance in magnetic tunnel junctions
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作者 朱涛 詹文山 +4 位作者 沈峰 张泽 X.H.Xiang G.Landry JohnQ.Xiao 《Chinese Physics B》 SCIE EI CAS CSCD 2003年第6期665-668,共4页
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Electron Holography of Barrier Structures in Co/ZrAlOx/Co Magnetic Tunnel Junctions
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作者 张喆 朱涛 +4 位作者 沈峰 盛雯婷 王为刚 肖强 张泽 《Chinese Physics Letters》 SCIE CAS CSCD 2005年第7期1732-1735,共4页
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Doppler distributed clutter model of airborne radar and its parameters estimation 被引量:7
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作者 XUJia PENGYingning +2 位作者 WANQun WANGXiutan XIAXianggen 《Science in China(Series F)》 2004年第5期577-586,共10页
To characterize the clutter spectrum center-shift and spread of airborne radar caused by the platform motion, a novel Doppler Distributed Clutter (DDC) model is proposed to describe the clutter covariance matrix in te... To characterize the clutter spectrum center-shift and spread of airborne radar caused by the platform motion, a novel Doppler Distributed Clutter (DDC) model is proposed to describe the clutter covariance matrix in temporal domain. Based on this parametric model, maximum likelihood, subspace based method and other super- resolution methods are introduced into the Doppler parameters estimation, and more excellent performance is obtained than with the conventional approaches in frequency domain. The theoretical derivation and real experimental results are also provided to validate this novel model and methods of parameter estimating. 展开更多
关键词 airborne radar Doppler distributed clutter (DDC) model Doppler parameter estimation maxi-mum likelihood (ML) weighted subspace fitting (WSF).
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Two modified discrete chirp Fourier transform schemes 被引量:4
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作者 樊平毅 夏香根 《Science in China(Series F)》 2001年第5期329-341,共13页
This paper presents two modified discrete chirp Fourier transform (MDCFT) schemes. Some matched filter properties such as the optimal selection of the transform length, and its relation-ship to analog chirp-Fourier tr... This paper presents two modified discrete chirp Fourier transform (MDCFT) schemes. Some matched filter properties such as the optimal selection of the transform length, and its relation-ship to analog chirp-Fourier transform are studied. Compared to the DCFT proposed previously, theo-retical and simulation results have shown that the two MDCFTs can further improve the chirp rate reso-lution of the detected signals. 展开更多
关键词 discrete chirp Fourier transform signal detection spectrum estimation synthetic aperture radar.
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Novel parametric optimum processing method for airborne radar 被引量:1
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作者 XUJia PENGYingning +3 位作者 WANQun ZHANGLiping LINYan XIAXianggen 《Science in China(Series F)》 2004年第6期706-716,共11页
In radar target detection, an optimum processor needs to automatically adapt its weights to the environment change. Conventionally, the optimum weights are obtained by substantial independently and identically distrib... In radar target detection, an optimum processor needs to automatically adapt its weights to the environment change. Conventionally, the optimum weights are obtained by substantial independently and identically distributed (i.i.d.) interference samplings, which is not always realistic in an inhomogeneous clutter background of airborne radar. The lack of i.i.d. samplings will inevitably lead to performance deterioration for optimum processing. In this paper, a novel parametric adaptive processing method is proposed for airborne radar target detection based on the modified Doppler distributed clutter (DDC) model with contribution of clutter's internal motion. It is different from the conventional methods in that the adaptive weights are determined by two parameters of DDC model, i.e., angular center and spread. A low-complexity nonlinear operators approach is also proposed to estimate these parameters. Simulation and performance analysis are also provided to show that the proposed method can remarkably reduce the dependence of i.i.d. samplings and it is computationally efficient for practical use. 展开更多
关键词 airborne radar adaptive implementation of optimum processing (AIOP) Doppler distributed clutter (DDC) mode independently and identically distributed (i.i.d.) sampling nonlinear energy operator (NLOP).
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集成光学——理论和工艺学
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作者 R.G.Hunsperger 李国栋 《国外科技新书评介》 2005年第1期9-10,共2页
本书为施普林格出版社出版的《物理学先进教材丛书》中的一卷。这套丛书包含物理学流行和广泛关注的多种专题,也包含对现代物理学研究前沿的介绍。本书介绍光电子学器件及其在集成光学和纤维光学系统中的应用,特别强调这些应用中的物... 本书为施普林格出版社出版的《物理学先进教材丛书》中的一卷。这套丛书包含物理学流行和广泛关注的多种专题,也包含对现代物理学研究前沿的介绍。本书介绍光电子学器件及其在集成光学和纤维光学系统中的应用,特别强调这些应用中的物理学及相关的数学等。本书初版于1982年,分别在1984年、1991年和1995年出版第2、3、4版。本书为2002年出版的第5版。 展开更多
关键词 集成光学 工艺学 现代物理学 1984年 1995年 1991年 2002年 研究前沿 光学系统 光电子学 出版社 第5版 丛书 应用 器件
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