The measurement of crop transpiration (Tcrop</sub>) under field conditions and throughout the growing season is difficult to obtain. An available method uses stem flow gauge sensors, based on the conservation of...The measurement of crop transpiration (Tcrop</sub>) under field conditions and throughout the growing season is difficult to obtain. An available method uses stem flow gauge sensors, based on the conservation of energy and mass, where the calculated sap flow (F) is a direct measure of Tcrop</sub>. This method has been extensively tested on agronomic, horticultural, ornamental aspects and tree crops and the general consensus is that F is a measure of Tcrop</sub>. A new sap flow gauge (EXO-SkinTM</sup> Sap Flow) sensor, with different placement and number of thermocouples, compared to the original sensor, was introduced, resulting in a different energy balance equation to calculate F. Our objective was to compare values of Tcrop</sub> obtained with the new sensor on cotton (Gossypium hirsutum, L) plants to values measured with lysimeters. For this purpose, cotton plants were grown in 11-liter pots in a greenhouse experiment and hourly and daily values of Tcrop</sub> were compared for eight days. We used linear regression analysis to compare the hourly and daily values of Tcrop</sub> measured with the sensor to corresponding values measured with lysimeters on the same plant. Using a t-test (p > 0.05) we tested if the slope of the line was significantly different than 1 and if the intercept was significantly different than 0. This test indicated that there were no statistical differences between hourly and daily values of Tcrop</sub> measured with the new sensor and with the lysimeters. The main advantage of the new sensor is the flexibility of the new heater, allowing for better thermal contact between the plant stem and the temperature sensors. Further, the new sensor requires less wiring and copper connectors, and the number of channels used in a datalogger to record the output from the sensor is reduced by 25%. We conclude that the new sensor correctly measures Tcrop</sub> and that additional experiments with field grown plants are required to test the sensor at higher values of Tcrop</sub>.展开更多
In recent years, a significant number of environmental studies have been conducted in New Orleans, LA and surrounding Gulf Coast areas due in part to the occurrence of hurricanes Katrina and Rita. Data collected from ...In recent years, a significant number of environmental studies have been conducted in New Orleans, LA and surrounding Gulf Coast areas due in part to the occurrence of hurricanes Katrina and Rita. Data collected from studies in the New Orleans area indicate that inorganic contaminants including arsenic (As), iron (Fe), lead (Pb), and vanadium (V);high concentration of bioaerosols, particularly Cladosporium and Aspergillus, and several organic pollutants (PAHs, pesticides, and volatiles) may pose a risk to human health in New Orleans. While many of these results resemble historical data, a current quantitative exposure assessment has not been conducted. We engaged in one such assessment for lead (Pb) contamination in surface soils. We used Pb concentrations in surface soils ( μg/day to 102 μg/day for our study area within urbanNew Orleans. These data are concerning because children exposed to >33.5 μg/d Pb may cause their blood-Pb levels to exceed the Centers for Disease Control and Prevention (CDC) threshold for blood-Pb of 10 μg/dL. It has generally been accepted that a more protective blood Pb concentration threshold of 6 - μg/dL is warranted. Using the 6-μg/dL threshold puts children exposed to as little as 20.2 μg/day Pb at risk.展开更多
Inorganic phosphate is a common nutrient that is applied as a fertilizer to both agricultural fields as well as urban settings such as private yards, public parks and other urban landscaping. While phosphate typically...Inorganic phosphate is a common nutrient that is applied as a fertilizer to both agricultural fields as well as urban settings such as private yards, public parks and other urban landscaping. While phosphate typically binds tightly to soil, movement of phosphate off of application sites can occur through soil erosion. The soil and its bound phosphate can then end up in surface waters such as rivers and lakes. Phosphate found in surface water bodies exists both as bound to the suspended clay as well as that free in solution. Elevated phosphate concentration in surface waters can lead to algal blooms and eutrophication. While the phosphate bound to clay in suspension in surface water bodies can be removed by commercially available polymer flocculants, the phosphate that is free in solution is more challenging as it is usually found in low concentrations and other anionic salts are generally present in higher concentrations. To remove phosphate from contaminated water systems, where other anions exist at higher concentrations, it is favorable to have a method of removal that is selective for phosphate. As a proof of principle, thiourea derivatized polymer flocculants were examined for the selective removal of phosphate in the presence of competing anions. The polymer flocculants exhibited selectivity for phosphate through hydrogen bonding and were effective at removing up to 43% of phosphate from simulated wastewater. Computational studies and </span><sup><span style="font-family:Verdana;">1</span></sup><span style="font-family:Verdana;">H NMR were used to investigate the selectivity of the thiourea monomer for phosphate over competing anions such as chloride and sulfate.展开更多
The Conservation Reserve Program (CRP) is a USDA program introduced in 1985 to reduce soil erosion by increasing vegetative cover of highly erodible land. Participation in the CRP is done via contracts (10 - 15 years ...The Conservation Reserve Program (CRP) is a USDA program introduced in 1985 to reduce soil erosion by increasing vegetative cover of highly erodible land. Participation in the CRP is done via contracts (10 - 15 years in length) and currently the total area of land under contract is set to decline as per the 2014 Farm Bill. The Texas High Plains (THP) leads the US with >900,000 ha enrolled in CRP. A potential long- term benefit of CRP is to increase soil organic matter and to improve soil structure leading to increased water infiltration. Our objective was to evaluate the feasibility of using stable isotopes of water to measure and compare infiltration of rain in land under CRP management to land under continuous dryland cotton in the THP. For this purpose we selected two sites, with soils in the Amarillo series, enrolled in CRP, one for 25 years and the second site for 22 years. Results from several rain events showed that stable isotopes of water are a method that can be used to evaluate the depth of rainwater infiltration for soils under CRP and dryland management.展开更多
文摘The measurement of crop transpiration (Tcrop</sub>) under field conditions and throughout the growing season is difficult to obtain. An available method uses stem flow gauge sensors, based on the conservation of energy and mass, where the calculated sap flow (F) is a direct measure of Tcrop</sub>. This method has been extensively tested on agronomic, horticultural, ornamental aspects and tree crops and the general consensus is that F is a measure of Tcrop</sub>. A new sap flow gauge (EXO-SkinTM</sup> Sap Flow) sensor, with different placement and number of thermocouples, compared to the original sensor, was introduced, resulting in a different energy balance equation to calculate F. Our objective was to compare values of Tcrop</sub> obtained with the new sensor on cotton (Gossypium hirsutum, L) plants to values measured with lysimeters. For this purpose, cotton plants were grown in 11-liter pots in a greenhouse experiment and hourly and daily values of Tcrop</sub> were compared for eight days. We used linear regression analysis to compare the hourly and daily values of Tcrop</sub> measured with the sensor to corresponding values measured with lysimeters on the same plant. Using a t-test (p > 0.05) we tested if the slope of the line was significantly different than 1 and if the intercept was significantly different than 0. This test indicated that there were no statistical differences between hourly and daily values of Tcrop</sub> measured with the new sensor and with the lysimeters. The main advantage of the new sensor is the flexibility of the new heater, allowing for better thermal contact between the plant stem and the temperature sensors. Further, the new sensor requires less wiring and copper connectors, and the number of channels used in a datalogger to record the output from the sensor is reduced by 25%. We conclude that the new sensor correctly measures Tcrop</sub> and that additional experiments with field grown plants are required to test the sensor at higher values of Tcrop</sub>.
文摘In recent years, a significant number of environmental studies have been conducted in New Orleans, LA and surrounding Gulf Coast areas due in part to the occurrence of hurricanes Katrina and Rita. Data collected from studies in the New Orleans area indicate that inorganic contaminants including arsenic (As), iron (Fe), lead (Pb), and vanadium (V);high concentration of bioaerosols, particularly Cladosporium and Aspergillus, and several organic pollutants (PAHs, pesticides, and volatiles) may pose a risk to human health in New Orleans. While many of these results resemble historical data, a current quantitative exposure assessment has not been conducted. We engaged in one such assessment for lead (Pb) contamination in surface soils. We used Pb concentrations in surface soils ( μg/day to 102 μg/day for our study area within urbanNew Orleans. These data are concerning because children exposed to >33.5 μg/d Pb may cause their blood-Pb levels to exceed the Centers for Disease Control and Prevention (CDC) threshold for blood-Pb of 10 μg/dL. It has generally been accepted that a more protective blood Pb concentration threshold of 6 - μg/dL is warranted. Using the 6-μg/dL threshold puts children exposed to as little as 20.2 μg/day Pb at risk.
文摘Inorganic phosphate is a common nutrient that is applied as a fertilizer to both agricultural fields as well as urban settings such as private yards, public parks and other urban landscaping. While phosphate typically binds tightly to soil, movement of phosphate off of application sites can occur through soil erosion. The soil and its bound phosphate can then end up in surface waters such as rivers and lakes. Phosphate found in surface water bodies exists both as bound to the suspended clay as well as that free in solution. Elevated phosphate concentration in surface waters can lead to algal blooms and eutrophication. While the phosphate bound to clay in suspension in surface water bodies can be removed by commercially available polymer flocculants, the phosphate that is free in solution is more challenging as it is usually found in low concentrations and other anionic salts are generally present in higher concentrations. To remove phosphate from contaminated water systems, where other anions exist at higher concentrations, it is favorable to have a method of removal that is selective for phosphate. As a proof of principle, thiourea derivatized polymer flocculants were examined for the selective removal of phosphate in the presence of competing anions. The polymer flocculants exhibited selectivity for phosphate through hydrogen bonding and were effective at removing up to 43% of phosphate from simulated wastewater. Computational studies and </span><sup><span style="font-family:Verdana;">1</span></sup><span style="font-family:Verdana;">H NMR were used to investigate the selectivity of the thiourea monomer for phosphate over competing anions such as chloride and sulfate.
文摘The Conservation Reserve Program (CRP) is a USDA program introduced in 1985 to reduce soil erosion by increasing vegetative cover of highly erodible land. Participation in the CRP is done via contracts (10 - 15 years in length) and currently the total area of land under contract is set to decline as per the 2014 Farm Bill. The Texas High Plains (THP) leads the US with >900,000 ha enrolled in CRP. A potential long- term benefit of CRP is to increase soil organic matter and to improve soil structure leading to increased water infiltration. Our objective was to evaluate the feasibility of using stable isotopes of water to measure and compare infiltration of rain in land under CRP management to land under continuous dryland cotton in the THP. For this purpose we selected two sites, with soils in the Amarillo series, enrolled in CRP, one for 25 years and the second site for 22 years. Results from several rain events showed that stable isotopes of water are a method that can be used to evaluate the depth of rainwater infiltration for soils under CRP and dryland management.
