Electroreduction of CO_(2) into CH_(4) under acidic conditions is a promising strategy for CO_(2) utilization,which allows for high CO_(2) conversion efficiency.However,the selectivity of CH_(4) is low because the hyd...Electroreduction of CO_(2) into CH_(4) under acidic conditions is a promising strategy for CO_(2) utilization,which allows for high CO_(2) conversion efficiency.However,the selectivity of CH_(4) is low because the hydrogen evolution reaction is enhanced under acidic conditions.Here,we report that the CO_(2) can be efficiently reduced into CH_(4) over a Cu catalyst by modifying with a glutamic acid molecule under acidic conditions.The CH_(4) Faradaic efficiency can reach 62.9% with a current density of 450 mA cm^(-2).Meanwhile,a single-pass carbon efficiency of 48.1% toward CH_(4) is achieved.Experiments revealed that the glutamic acid molecule can enhance the concentration of Kt on the surface of Cu,which can suppress the HER and promote CO_(2) reduction,resulting in high selectivity of CH_(4) under acidic conditions.展开更多
A clean environment with low carbon emissions is the goal of research on the development of green and sustainable buildings that use bio-sourced materials in conjunction with solar energy to create more sustainable ci...A clean environment with low carbon emissions is the goal of research on the development of green and sustainable buildings that use bio-sourced materials in conjunction with solar energy to create more sustainable cities.This is particularly true in Africa,where there aren’t many studies on the topic.The current study suggests a 90 m^(2) model of a sustainable building in a dry climate that is movable to address the issue of housing in remote areas,ensures comfort in harsh weather conditions,uses solar renewable resources—which are plentiful in Africa—uses biosourced materials,and examines how these materials relate to temperature and humidity control while emitting minimal carbon emissions.In order to solve the topic under consideration,the work is split into two sections:numerical and experimental approaches.Using TRNSYS and Revit,the suggested prototype building is examined numerically to examine the impact of orientation,envelope composition made of bio-sourced materials,and carbon emissions.Through a hygrothermal investigation,experiments are conducted to evaluate this prototype’s effectiveness.Furthermore,an examination of the photovoltaic system’s production,consumption,and several scenarios used tomaximize battery life is included in the paper.Because the biosourcedmaterial achieves a thermal transmittance of 0.15(W.m^(-2).K^(-1)),the results demonstrate an intriguing finding in terms of comfort.This value satisfies the requirements of passive building,energy autonomy of the dwelling,and injection in-network with an annual value of 15,757 kWh.Additionally,compared to the literature,the heating needs ratio is 6.38(kWh/m^(2).an)and the cooling needs ratio is 49(kWh/m^(2).an),both of which are good values.According to international norms,the inside temperature doesn’t go above 26℃,and the humidity level is within a comfortable range.展开更多
The increasing performance demands of modern aero engines necessitate the integrated design of compressor transition ducts with upstream components to reduce the axial length of the engine.However,this design approach...The increasing performance demands of modern aero engines necessitate the integrated design of compressor transition ducts with upstream components to reduce the axial length of the engine.However,this design approach narrows the spacing between the stator and the strut,making traditional research on transition ducts only with struts unsuitable.The numerical results and experimental oil flow visualization results were utilized to reconstruct the three-dimensional flow structures in the stator passages under various operating conditions.Additionally,numerical methods were employed to analyze the mechanisms of the strut's effect on the upstream stator in an aggressive transition duct.The results show that the strut potential field increases the load on the upstream stator,leading to severe blade surface separation and corner separation/stall,and redistributes the inflow angle of the upstream stators circumferentially,resulting in significant differences in the flow structures within the stator passages on both sides.The separation flows within the stator passages mainly manifest in five types:pressure surface separation vortex,suction surface concentrated shedding vortex,suction surface separation vortex,suction surface-corner stall separation vortex,and suction surface separation vortex pair.Under different operating conditions,the separation flows within the stator passages are always composed of a part of these five types or a transitional state between two of them.展开更多
The global drive for sustainable energy solutions intensified interest in anion exchange membrane water electrolysis(AEMWE),as a promising hydrogen production pathway,leveraging renewable energy sources.However,widesp...The global drive for sustainable energy solutions intensified interest in anion exchange membrane water electrolysis(AEMWE),as a promising hydrogen production pathway,leveraging renewable energy sources.However,widespread adoption is hindered by the high cost and non-optimised design of crucial components,such as porous transport layers(PTL)and flow fields.This study comprehensively investigates the interplay between structure,mechanics,and electrochemical performance of a low-cost knitted wire mesh PTL,focusing on its potential to enhance cell assembly and operation.Electrochemical characterisation was performed on a single 4 cm^(2)cell,using 1M KOH at 60℃.Knitted wire mesh PTL,characterised by approximately 70%porosity,2mm thickness,and 1.098 tortuosity,delivered a 33%improvement in current density compared to the standard cell configuration.Introducing a knitted PTL interlayer reduced cell voltage by 74 mV at 2 A cm^(−2)by improving compression force distribution across the active area,enhancing gas transport and maintaining optimal electrical and thermal conductivity.These findings highlight the significant potential of innovative PTL designs in AEMWE to improve mechanical and operational efficiency without increasing the cost.展开更多
We evaluated the performance of OpenFOAMGPT(GPT for generative pretrained transformers),which includes rating multiple large-language models.Some of the present models efficiently manage different computational fluid ...We evaluated the performance of OpenFOAMGPT(GPT for generative pretrained transformers),which includes rating multiple large-language models.Some of the present models efficiently manage different computational fluid dynamics(CFD)tasks,such as adjusting boundary conditions,turbulence models,and solver configurations,although their token cost and stability vary.Locally deployed smaller models such as the QwQ-32B(Q4 KM quantized model)struggled with generating valid solver files for complex processes.Zero-shot prompts commonly fail in simulations with intricate settings,even for large models.Challenges with boundary conditions and solver keywords stress the need for expert supervision,indicating that further development is needed to fully automate specialized CFD simulations.展开更多
The development of magnesium batteries strongly relies on the use of a Mg metal anode and its benefits of high volumetric capacity,reduction potential,low cost and improved safety,however,to date,it still lacks suffic...The development of magnesium batteries strongly relies on the use of a Mg metal anode and its benefits of high volumetric capacity,reduction potential,low cost and improved safety,however,to date,it still lacks sufficient cycling stability and reversibility.Along with the electrolyte selection,the interfacial processes can be affected by the anode itself applying electrode engineering strategies.In this study,six different Mg anode approaches–namely bare Mg metal,Mg foil with an organic and inorganic artificial solid electrolyte interphase,Mg alloy,Mg pellet and a tape-casted Mg slurry–are selected to be investigated by means of electrochemical impedance spectroscopy in Mg|Mg and Mg|S cells.While a plating/stripping overpotential asymmetry was observed and assigned to the desolvation during Mg plating,the impedance spectra of stripping and plating hardly differ for all applied anodes.In contrast,the sulfur species significantly influence the impedance response by altering the surface layer composition.By systematic process assignment of the gained spectra in Mg|Mg and Mg|S cells,specific equivalent circuit models for different anodes and cell conditions are derived.Overall,the study aims to give valuable insights into the interfacial processes of Mg anodes to support their further development toward long-lasting Mg batteries.展开更多
This study investigates the combustion characteristics of reactive aluminium alloys in combination with fluoropolymer oxidizers. Aluminium-magnesium(Al-Mg) and aluminium-titanium(Al-Ti) alloys were selected as metalli...This study investigates the combustion characteristics of reactive aluminium alloys in combination with fluoropolymer oxidizers. Aluminium-magnesium(Al-Mg) and aluminium-titanium(Al-Ti) alloys were selected as metallic fuels, while polyvinylidene fluoride(PVDF) was employed as the oxidizer. Composite samples were prepared using two methods: electrostatic spraying(ES) and physical mixing(PM). The ES method yielded samples with a PVDF-coated structure, whereas the PM method produced simple mixtures. The samples and their combustion products were characterized using scanning electron microscopy(SEM), X-ray diffraction(XRD), combustion experiments, and thermal analysis. The results indicate that compared to the PM samples, the ES-coated samples exhibited more effective dispersion of metallic particles, reduced particle agglomeration, increased combustion heat release temperature, decreased maximum flame area and height, and mitigated or eliminated explosive or micro-explosive phenomena during combustion, thereby achieving stable combustion. Additionally, the ES samples demonstrated a significant reduction in the particle size of condensed-phase products after combustion, alleviated sintering and agglomeration, decreased the formation of metal oxides, and minimized residual metallic fuel, allowing for the full release of combustion heat. Thermal analysis revealed that the coating structure of the ES samples lowered the activation energy for the reaction between the metallic fuel and PVDF, thereby enhancing the chemical reactivity.展开更多
The large amount of harmful particles in coal dust not only pollutes the production environment,affects the production efficiency and resource utilization of enterprises,but also poses a risk to human health.Effective...The large amount of harmful particles in coal dust not only pollutes the production environment,affects the production efficiency and resource utilization of enterprises,but also poses a risk to human health.Effectively controlling coal dust is of great significance to clean production.Water-based dust suppressants are extensively employed to mitigate coal dust.This paper provides a comprehensive review of the water-based dust suppression materials for coal dust control.Accord-ing to the difference of mechanism,the dust suppressants are divided into wetting type,hygroscopic coalescence type,cohesive agglomeration type,and composite type.The evaluation methods for dust suppressants key properties such as wettability,permeability,moisture absorption and water retention,and consolidation are summarized.The review results show that coal dust suppressants are no longer limited to a single dust suppression function.For example,it is necessary to develop multi-functional coal suppressants to meet the needs for synergistic suppression both coal dust and coal spon-taneous combustion.Driven by the concept of green,low-carbon and sustainable development,attention should be paid to the development of bio-based environmentally friendly coal dust suppressants.In addition,the evaluation method system for the key performance of water-based dust suppressants should also be improved,and further research is necessary.展开更多
With the statistical mechanical theory for square-well-chain fluids as the basic princi-ples,a molecular thermodynamic model including expressions for the Helmholtz function and thecompressibility factor for associate...With the statistical mechanical theory for square-well-chain fluids as the basic princi-ples,a molecular thermodynamic model including expressions for the Helmholtz function and thecompressibility factor for associated square-well-chain fluids has been developed.Employment ofthe shield-sticky concept enables the corporation of association bonds between in the model.Good agreement with computer-simulation results for dimer-linear quadrimer systems is obtained.Satisfactory correlation for vapor pressures and saturated liquid volumes of pure substances con-taining associated molecules(such as carboxylic acids,alcohols,amines,water,etc.)with four mo-lecular parameters indicates the applicability of the model.展开更多
Concentrated solar power(CSP)plants with thermal energy storage(TES)system are emerging as one kind of the most promising power plants in the future renewable energy system,since they can supply dispatchable and low-c...Concentrated solar power(CSP)plants with thermal energy storage(TES)system are emerging as one kind of the most promising power plants in the future renewable energy system,since they can supply dispatchable and low-cost electricity with abundant but intermittent solar energy.In order to significantly reduce the levelized cost of electricity(LCOE)of the present commercial CSP plants,the next generation CSP technology with higher process temperature and energy efficiency is being developed.The TES system in the next generation CSP plants works with new TES materials at higher temperatures(>565℃)compared to that with the commercial nitrate salt mixtures.This paper reviews recent progressin research and development of the next generation CSP and TES technology.Emphasis is given on theadvanced'TES technology based on molten chloride salt mixtures such as MgCl_(2)/NaCl/KCl which hassimilar thermo-physical properties as the commercial nitrate salt mixtures,higher thermal stability(>800℃),and lower costs(<0.35USD·kg^(-1)).Recent progress in the selection/optimization of chloridesalts,determination of molten chloride salt properties,and corrosion control of construction materials(eg.,alloys)in molten chlorides is reviewed.展开更多
Effective temperature level of stream, namely stream pseudo temperature, is determined by its actual temperature and heat transfer temperature difference contribution value. Heat transfer temperature difference con-tr...Effective temperature level of stream, namely stream pseudo temperature, is determined by its actual temperature and heat transfer temperature difference contribution value. Heat transfer temperature difference con-tribution value of a stream depends on its heat transfer film coefficient, cost per unit heat transfer area, actual tem-perature, and so on. In the determination of the suitable heat transfer temperature difference contribution values of the stream, the total annual cost of multistream heat exchanger network (MSHEN) is regarded as an objective func-tion, and genetic/simulated annealing algorithm (GA/SA) is adopted for optimizing the heat transfer temperature difference contribution values of the stream. The stream pseudo temperatures are subsequently obtained. On the ba-sis of stream pseudo temperature, optimized MSHEN can be attained by the temperature-enthalpy (T-H) diagram method. This approach is characterized with fewer decision variables and higher feasibility of solutions. The calcu-lation efficiency of GA/SA can be remarkably enhanced by this approach and more probability is shown in search-ing the global optimum solution. Hence this approach is presented for solving industrial-sized MSHEN which is difficult to deal by traditional algorithm. Moreover, in the optimization of stream heat transfer temperature differ-ence contribution values, the effects of the stream temperature, the heat transfer film coefficient, and the construc-tion material of heat exchangers are considered, therefore this approach can be used to optimize and design heat exchanger network (HEN) with unequal heat transfer film coefficients and different of construction materials. The performance of the proposed approach has been demonstrated with three examples and the obtained solutions are compared with those available in literatures. The results show that the large-scale MSHEN synthesis problems can be solved to obtain good solutions with the modest computational effort.展开更多
Lignin is one of the most important biomass resources. With the increasing consumption of petroleum resource, lignin transformation is of strategic significance and has attracted widely interest. As lignin is a random...Lignin is one of the most important biomass resources. With the increasing consumption of petroleum resource, lignin transformation is of strategic significance and has attracted widely interest. As lignin is a random construction of aromatic monomers, the degradation products are usually very complex, which limits the scaling application of lignin as feedstock for valuable chemicals. Thus, it is desperately desired to develop highly selective approach to lignin conversion. This review first gives a brief introduction to the structure of lignin, and then summarized the methods for selective transformation of lignin into phenols, aldehydes, carboxylic acids, alkanes and arenes. Finally, the challenges and opportunities of lignin selective transformation are discussed.展开更多
Geometric and working condition uncertainties are inevitable in a compressor,deviating the compressor performance from the design value.It’s necessary to explore the influence of geometric uncertainty on performance ...Geometric and working condition uncertainties are inevitable in a compressor,deviating the compressor performance from the design value.It’s necessary to explore the influence of geometric uncertainty on performance deviation under different working conditions.In this paper,the geometric uncertainty influences at near stall,peak efficiency,and near choke conditions under design speed and low speed are investigated.Firstly,manufacturing geometric uncertainties are analyzed.Next,correlation models between geometry and performance under different working conditions are constructed based on a neural network.Then the Shapley additive explanations(SHAP)method is introduced to explain the output of the neural network.Results show that under real manufacturing uncertainty,the efficiency deviation range is small under the near stall and peak efficiency conditions.However,under the near choke conditions,efficiency is highly sensitive to flow capacity changes caused by geometric uncertainty,leading to a significant increase in the efficiency deviation amplitude,up to a magnitude of-3.6%.Moreover,the tip leading-edge radius and tip thickness are two main factors affecting efficiency deviation.Therefore,to reduce efficiency uncertainty,a compressor should be avoided working near the choke condition,and the tolerances of the tip leading-edge radius and tip thickness should be strictly controlled.展开更多
基金supported by the National Key Research and Development Program of China(2020YFA0710201)the China Postdoctoral Science Foundation Funded Project(2021M701211)+1 种基金Fundamental Research Funds for the Central Universities,“Island Atmosphere and Ecology”Category Ⅳ Peak Discipline(No.QN202505)the National Natural Science Foundation of China(22293015,22121002).
文摘Electroreduction of CO_(2) into CH_(4) under acidic conditions is a promising strategy for CO_(2) utilization,which allows for high CO_(2) conversion efficiency.However,the selectivity of CH_(4) is low because the hydrogen evolution reaction is enhanced under acidic conditions.Here,we report that the CO_(2) can be efficiently reduced into CH_(4) over a Cu catalyst by modifying with a glutamic acid molecule under acidic conditions.The CH_(4) Faradaic efficiency can reach 62.9% with a current density of 450 mA cm^(-2).Meanwhile,a single-pass carbon efficiency of 48.1% toward CH_(4) is achieved.Experiments revealed that the glutamic acid molecule can enhance the concentration of Kt on the surface of Cu,which can suppress the HER and promote CO_(2) reduction,resulting in high selectivity of CH_(4) under acidic conditions.
文摘A clean environment with low carbon emissions is the goal of research on the development of green and sustainable buildings that use bio-sourced materials in conjunction with solar energy to create more sustainable cities.This is particularly true in Africa,where there aren’t many studies on the topic.The current study suggests a 90 m^(2) model of a sustainable building in a dry climate that is movable to address the issue of housing in remote areas,ensures comfort in harsh weather conditions,uses solar renewable resources—which are plentiful in Africa—uses biosourced materials,and examines how these materials relate to temperature and humidity control while emitting minimal carbon emissions.In order to solve the topic under consideration,the work is split into two sections:numerical and experimental approaches.Using TRNSYS and Revit,the suggested prototype building is examined numerically to examine the impact of orientation,envelope composition made of bio-sourced materials,and carbon emissions.Through a hygrothermal investigation,experiments are conducted to evaluate this prototype’s effectiveness.Furthermore,an examination of the photovoltaic system’s production,consumption,and several scenarios used tomaximize battery life is included in the paper.Because the biosourcedmaterial achieves a thermal transmittance of 0.15(W.m^(-2).K^(-1)),the results demonstrate an intriguing finding in terms of comfort.This value satisfies the requirements of passive building,energy autonomy of the dwelling,and injection in-network with an annual value of 15,757 kWh.Additionally,compared to the literature,the heating needs ratio is 6.38(kWh/m^(2).an)and the cooling needs ratio is 49(kWh/m^(2).an),both of which are good values.According to international norms,the inside temperature doesn’t go above 26℃,and the humidity level is within a comfortable range.
基金supported by the National Natural Science Foundation of China(No.52276025)the Science Center for Gas Turbine Project of China(Nos.P2022-A-Ⅱ-001-001,P2022-A-Ⅱ-002-001 and P2022-B-Ⅱ-002-001)。
文摘The increasing performance demands of modern aero engines necessitate the integrated design of compressor transition ducts with upstream components to reduce the axial length of the engine.However,this design approach narrows the spacing between the stator and the strut,making traditional research on transition ducts only with struts unsuitable.The numerical results and experimental oil flow visualization results were utilized to reconstruct the three-dimensional flow structures in the stator passages under various operating conditions.Additionally,numerical methods were employed to analyze the mechanisms of the strut's effect on the upstream stator in an aggressive transition duct.The results show that the strut potential field increases the load on the upstream stator,leading to severe blade surface separation and corner separation/stall,and redistributes the inflow angle of the upstream stators circumferentially,resulting in significant differences in the flow structures within the stator passages on both sides.The separation flows within the stator passages mainly manifest in five types:pressure surface separation vortex,suction surface concentrated shedding vortex,suction surface separation vortex,suction surface-corner stall separation vortex,and suction surface separation vortex pair.Under different operating conditions,the separation flows within the stator passages are always composed of a part of these five types or a transitional state between two of them.
基金supported by the European Union and the Clean Hydrogen Joint Undertaking(Grant no.101112055).
文摘The global drive for sustainable energy solutions intensified interest in anion exchange membrane water electrolysis(AEMWE),as a promising hydrogen production pathway,leveraging renewable energy sources.However,widespread adoption is hindered by the high cost and non-optimised design of crucial components,such as porous transport layers(PTL)and flow fields.This study comprehensively investigates the interplay between structure,mechanics,and electrochemical performance of a low-cost knitted wire mesh PTL,focusing on its potential to enhance cell assembly and operation.Electrochemical characterisation was performed on a single 4 cm^(2)cell,using 1M KOH at 60℃.Knitted wire mesh PTL,characterised by approximately 70%porosity,2mm thickness,and 1.098 tortuosity,delivered a 33%improvement in current density compared to the standard cell configuration.Introducing a knitted PTL interlayer reduced cell voltage by 74 mV at 2 A cm^(−2)by improving compression force distribution across the active area,enhancing gas transport and maintaining optimal electrical and thermal conductivity.These findings highlight the significant potential of innovative PTL designs in AEMWE to improve mechanical and operational efficiency without increasing the cost.
基金supported by the Royal Society(Grant No.RG\R1\251236)the Fundamental Research Funds for the Central Universities of China(Grant No.JKF-2025055317102).
文摘We evaluated the performance of OpenFOAMGPT(GPT for generative pretrained transformers),which includes rating multiple large-language models.Some of the present models efficiently manage different computational fluid dynamics(CFD)tasks,such as adjusting boundary conditions,turbulence models,and solver configurations,although their token cost and stability vary.Locally deployed smaller models such as the QwQ-32B(Q4 KM quantized model)struggled with generating valid solver files for complex processes.Zero-shot prompts commonly fail in simulations with intricate settings,even for large models.Challenges with boundary conditions and solver keywords stress the need for expert supervision,indicating that further development is needed to fully automate specialized CFD simulations.
基金financially supported by the Federal Ministry for Education and Research of Germany(Bundesminis-terium für Bildung und Forschung,BMBF)and the European Commission within the projects“MagSiMal”(03XP0208)“E-MAGIC”(824066),respectively。
文摘The development of magnesium batteries strongly relies on the use of a Mg metal anode and its benefits of high volumetric capacity,reduction potential,low cost and improved safety,however,to date,it still lacks sufficient cycling stability and reversibility.Along with the electrolyte selection,the interfacial processes can be affected by the anode itself applying electrode engineering strategies.In this study,six different Mg anode approaches–namely bare Mg metal,Mg foil with an organic and inorganic artificial solid electrolyte interphase,Mg alloy,Mg pellet and a tape-casted Mg slurry–are selected to be investigated by means of electrochemical impedance spectroscopy in Mg|Mg and Mg|S cells.While a plating/stripping overpotential asymmetry was observed and assigned to the desolvation during Mg plating,the impedance spectra of stripping and plating hardly differ for all applied anodes.In contrast,the sulfur species significantly influence the impedance response by altering the surface layer composition.By systematic process assignment of the gained spectra in Mg|Mg and Mg|S cells,specific equivalent circuit models for different anodes and cell conditions are derived.Overall,the study aims to give valuable insights into the interfacial processes of Mg anodes to support their further development toward long-lasting Mg batteries.
基金National Natural Science Foundation of China (NSFC,Grant Nos.52176114 and 52306145)Natural Science Foundation of Jiangsu Province (Grant No.BK20230929)+2 种基金China Postdoctoral Science Foundation (Grant No.2024M764222)Fundamental Research Funds for the Central Universities (Grant No.30924010505)Jiangsu Funding Program for Excellent Postdoctoral Talent。
文摘This study investigates the combustion characteristics of reactive aluminium alloys in combination with fluoropolymer oxidizers. Aluminium-magnesium(Al-Mg) and aluminium-titanium(Al-Ti) alloys were selected as metallic fuels, while polyvinylidene fluoride(PVDF) was employed as the oxidizer. Composite samples were prepared using two methods: electrostatic spraying(ES) and physical mixing(PM). The ES method yielded samples with a PVDF-coated structure, whereas the PM method produced simple mixtures. The samples and their combustion products were characterized using scanning electron microscopy(SEM), X-ray diffraction(XRD), combustion experiments, and thermal analysis. The results indicate that compared to the PM samples, the ES-coated samples exhibited more effective dispersion of metallic particles, reduced particle agglomeration, increased combustion heat release temperature, decreased maximum flame area and height, and mitigated or eliminated explosive or micro-explosive phenomena during combustion, thereby achieving stable combustion. Additionally, the ES samples demonstrated a significant reduction in the particle size of condensed-phase products after combustion, alleviated sintering and agglomeration, decreased the formation of metal oxides, and minimized residual metallic fuel, allowing for the full release of combustion heat. Thermal analysis revealed that the coating structure of the ES samples lowered the activation energy for the reaction between the metallic fuel and PVDF, thereby enhancing the chemical reactivity.
基金supported by the National Natural Science Foundation of China(52474226,52322404)Basic scientific research projects in higher education institutions of Liaoning Province(JYTZD2023079)。
文摘The large amount of harmful particles in coal dust not only pollutes the production environment,affects the production efficiency and resource utilization of enterprises,but also poses a risk to human health.Effectively controlling coal dust is of great significance to clean production.Water-based dust suppressants are extensively employed to mitigate coal dust.This paper provides a comprehensive review of the water-based dust suppression materials for coal dust control.Accord-ing to the difference of mechanism,the dust suppressants are divided into wetting type,hygroscopic coalescence type,cohesive agglomeration type,and composite type.The evaluation methods for dust suppressants key properties such as wettability,permeability,moisture absorption and water retention,and consolidation are summarized.The review results show that coal dust suppressants are no longer limited to a single dust suppression function.For example,it is necessary to develop multi-functional coal suppressants to meet the needs for synergistic suppression both coal dust and coal spon-taneous combustion.Driven by the concept of green,low-carbon and sustainable development,attention should be paid to the development of bio-based environmentally friendly coal dust suppressants.In addition,the evaluation method system for the key performance of water-based dust suppressants should also be improved,and further research is necessary.
基金Supported by the National Natural Science Foundation of China and the Doctorate Research Foundation sponsored by the National Education Commission of China.
文摘With the statistical mechanical theory for square-well-chain fluids as the basic princi-ples,a molecular thermodynamic model including expressions for the Helmholtz function and thecompressibility factor for associated square-well-chain fluids has been developed.Employment ofthe shield-sticky concept enables the corporation of association bonds between in the model.Good agreement with computer-simulation results for dimer-linear quadrimer systems is obtained.Satisfactory correlation for vapor pressures and saturated liquid volumes of pure substances con-taining associated molecules(such as carboxylic acids,alcohols,amines,water,etc.)with four mo-lecular parameters indicates the applicability of the model.
文摘Concentrated solar power(CSP)plants with thermal energy storage(TES)system are emerging as one kind of the most promising power plants in the future renewable energy system,since they can supply dispatchable and low-cost electricity with abundant but intermittent solar energy.In order to significantly reduce the levelized cost of electricity(LCOE)of the present commercial CSP plants,the next generation CSP technology with higher process temperature and energy efficiency is being developed.The TES system in the next generation CSP plants works with new TES materials at higher temperatures(>565℃)compared to that with the commercial nitrate salt mixtures.This paper reviews recent progressin research and development of the next generation CSP and TES technology.Emphasis is given on theadvanced'TES technology based on molten chloride salt mixtures such as MgCl_(2)/NaCl/KCl which hassimilar thermo-physical properties as the commercial nitrate salt mixtures,higher thermal stability(>800℃),and lower costs(<0.35USD·kg^(-1)).Recent progress in the selection/optimization of chloridesalts,determination of molten chloride salt properties,and corrosion control of construction materials(eg.,alloys)in molten chlorides is reviewed.
基金Supported by the Deutsche Forschungsgemeinschaft (DFG No.RO 294/9).
文摘Effective temperature level of stream, namely stream pseudo temperature, is determined by its actual temperature and heat transfer temperature difference contribution value. Heat transfer temperature difference con-tribution value of a stream depends on its heat transfer film coefficient, cost per unit heat transfer area, actual tem-perature, and so on. In the determination of the suitable heat transfer temperature difference contribution values of the stream, the total annual cost of multistream heat exchanger network (MSHEN) is regarded as an objective func-tion, and genetic/simulated annealing algorithm (GA/SA) is adopted for optimizing the heat transfer temperature difference contribution values of the stream. The stream pseudo temperatures are subsequently obtained. On the ba-sis of stream pseudo temperature, optimized MSHEN can be attained by the temperature-enthalpy (T-H) diagram method. This approach is characterized with fewer decision variables and higher feasibility of solutions. The calcu-lation efficiency of GA/SA can be remarkably enhanced by this approach and more probability is shown in search-ing the global optimum solution. Hence this approach is presented for solving industrial-sized MSHEN which is difficult to deal by traditional algorithm. Moreover, in the optimization of stream heat transfer temperature differ-ence contribution values, the effects of the stream temperature, the heat transfer film coefficient, and the construc-tion material of heat exchangers are considered, therefore this approach can be used to optimize and design heat exchanger network (HEN) with unequal heat transfer film coefficients and different of construction materials. The performance of the proposed approach has been demonstrated with three examples and the obtained solutions are compared with those available in literatures. The results show that the large-scale MSHEN synthesis problems can be solved to obtain good solutions with the modest computational effort.
基金supported by the National Natural Science Foundation of China (No. 21603235)National Key Research and Development Program of China (No. 2017YFA0403103)Chinese Academy of Sciences (No. QYZDY-SSW-SLH013)
文摘Lignin is one of the most important biomass resources. With the increasing consumption of petroleum resource, lignin transformation is of strategic significance and has attracted widely interest. As lignin is a random construction of aromatic monomers, the degradation products are usually very complex, which limits the scaling application of lignin as feedstock for valuable chemicals. Thus, it is desperately desired to develop highly selective approach to lignin conversion. This review first gives a brief introduction to the structure of lignin, and then summarized the methods for selective transformation of lignin into phenols, aldehydes, carboxylic acids, alkanes and arenes. Finally, the challenges and opportunities of lignin selective transformation are discussed.
基金supported by the National Science and Technology Major Project,China(No.2017-II-0004-0016)。
文摘Geometric and working condition uncertainties are inevitable in a compressor,deviating the compressor performance from the design value.It’s necessary to explore the influence of geometric uncertainty on performance deviation under different working conditions.In this paper,the geometric uncertainty influences at near stall,peak efficiency,and near choke conditions under design speed and low speed are investigated.Firstly,manufacturing geometric uncertainties are analyzed.Next,correlation models between geometry and performance under different working conditions are constructed based on a neural network.Then the Shapley additive explanations(SHAP)method is introduced to explain the output of the neural network.Results show that under real manufacturing uncertainty,the efficiency deviation range is small under the near stall and peak efficiency conditions.However,under the near choke conditions,efficiency is highly sensitive to flow capacity changes caused by geometric uncertainty,leading to a significant increase in the efficiency deviation amplitude,up to a magnitude of-3.6%.Moreover,the tip leading-edge radius and tip thickness are two main factors affecting efficiency deviation.Therefore,to reduce efficiency uncertainty,a compressor should be avoided working near the choke condition,and the tolerances of the tip leading-edge radius and tip thickness should be strictly controlled.
