Copper nanoparticle was synthesized in the presence of heptadecafluorononanoic acid by the conventional solution immersion method at room temperature from the copper plate, as a resource material. The bulk etching rat...Copper nanoparticle was synthesized in the presence of heptadecafluorononanoic acid by the conventional solution immersion method at room temperature from the copper plate, as a resource material. The bulk etching rate was calculated by the weight loss method. The pale green colored Cu-HDFN was characterized by Fourier transform infrared spectroscopy, UV-Visible spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and contact angle measurements and the results are critically analyzed.展开更多
The increase in the concentration of carbon dioxide (CO2) in the atmosphere has led the scientific community to investigate the adverse effects on humanity and nature, including the greenhouse effect, which contribute...The increase in the concentration of carbon dioxide (CO2) in the atmosphere has led the scientific community to investigate the adverse effects on humanity and nature, including the greenhouse effect, which contributes to global warming and can lead to climate change, besides the risks associated with human health. Due to the importance of metrological issues in the current scenario, the Laboratory of Gas Analysis (Lanag) of the National Institute of Metrology, Quality and Technology (Inmetro) is developing the methodology of preparation of such primary standard gas mixtures through gravimetry. For the preparation of these standards, an analysis verification step is necessary, carried out by means of an analytical technique of comparison, at low levels of concentration, by cavity ringdown (CRDS) and by gas chromatography using a flame ionization detector coupled to a methaniser catalyst (GC-FIDmeth). This work presents the method validation of both methodologies developed to analyze a range of concentration of atmospheric standards of CO2 at a matrix of synthetic clean dry air (SCDA) by CRDS and GC-FIDmeth, of which the analysis results can compromise the measurements on atmospheric air quality. The objective is to compare results of method validation of both analytical methods for low CO2 concentration through the use of primary reference mixtures developed and also by certified reference material. The validation measurement results were analyzed according to the requirements of ISO 5725: 1994 parts 1 and 2, and the calculation of measurement uncertainty followed the methodology described in ISO 6143:2001, with results showing satisfactory consistent between both selected techniques. According to the work presented here, the obtained validation results for CRDS are better than the GC results, such as the relative uncertainty of samples evaluated for CRDS was 0.4% and 2.7% for GC_FID meth.展开更多
Collision between particles plays an important role in determining the hydrodynamic characteristics of gas-solid flow in a fluidized bed. In the present work, earlier work （Loha, Chattopadhyay, ＆ Chatterjee, 2013） ...Collision between particles plays an important role in determining the hydrodynamic characteristics of gas-solid flow in a fluidized bed. In the present work, earlier work （Loha, Chattopadhyay, ＆ Chatterjee, 2013） was extended to study the effect of the elasticity of particle collision on the hydrodynamic behavior of a bubbling fluidized bed filled with 530-~m particles. The Eulerian-Eulerian two-fluid model was used to simulate the hydrodynamics of the bubbling fluidized bed, where the solid-phase properties were calculated by applying the kinetic theory of granular flow. To investigate the effect of the elasticity of particle collision, different values of the coefficient of restitution were applied in the simulation and their effects were studied in detail. Simulations were performed for two different solid-phase wall boundary conditions. No bubble formation was observed for perfectly elastic collision. The bubble formation started as soon as the coefficient of restitution was set below 1.0, and the space occupied by bubbles in the bed increased with a decrease in the coefficient of restitution. Simulation results were also compared with experimental data available in the literature, and good agreement was found for coefficients of restitution of 0.95 and 0.99.展开更多
Transient numerical simulations are carried out to investigate the liquid-gas interfacecharacteristics associated with liquid film cooling flows.A two-dimensional axisymmetricmulti-phase numerical model using finite v...Transient numerical simulations are carried out to investigate the liquid-gas interfacecharacteristics associated with liquid film cooling flows.A two-dimensional axisymmetricmulti-phase numerical model using finite volume formulation is developed.The model hasbeen validated against available experimental data for liquid-film cooling flows inside tubes.The model has been used to predict the interface characteristics for a variety of imposedparameters and momentum flux ratios under cold flow conditions wherein both the coolant andmainstream are maintained at the same temperature.Disturbance waves are observed at theliquid-gas interface for coolant flows above a critical value and after a finite distance from theinlet.The distance toward the wave inception point increased with the increase of momentumflux ratio.However,at higher momentum flux ratios,the properties of the disturbance wavesdid not vary significantly.The parameters related to the liquid-gas interface waves,namely,wave velocity,frequency,amplitude and wave length have been analyzed in detail.Analysisindicates that the liquid entrainment is due to the shearing of the disturbance wave crest.展开更多
文摘Copper nanoparticle was synthesized in the presence of heptadecafluorononanoic acid by the conventional solution immersion method at room temperature from the copper plate, as a resource material. The bulk etching rate was calculated by the weight loss method. The pale green colored Cu-HDFN was characterized by Fourier transform infrared spectroscopy, UV-Visible spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and contact angle measurements and the results are critically analyzed.
文摘The increase in the concentration of carbon dioxide (CO2) in the atmosphere has led the scientific community to investigate the adverse effects on humanity and nature, including the greenhouse effect, which contributes to global warming and can lead to climate change, besides the risks associated with human health. Due to the importance of metrological issues in the current scenario, the Laboratory of Gas Analysis (Lanag) of the National Institute of Metrology, Quality and Technology (Inmetro) is developing the methodology of preparation of such primary standard gas mixtures through gravimetry. For the preparation of these standards, an analysis verification step is necessary, carried out by means of an analytical technique of comparison, at low levels of concentration, by cavity ringdown (CRDS) and by gas chromatography using a flame ionization detector coupled to a methaniser catalyst (GC-FIDmeth). This work presents the method validation of both methodologies developed to analyze a range of concentration of atmospheric standards of CO2 at a matrix of synthetic clean dry air (SCDA) by CRDS and GC-FIDmeth, of which the analysis results can compromise the measurements on atmospheric air quality. The objective is to compare results of method validation of both analytical methods for low CO2 concentration through the use of primary reference mixtures developed and also by certified reference material. The validation measurement results were analyzed according to the requirements of ISO 5725: 1994 parts 1 and 2, and the calculation of measurement uncertainty followed the methodology described in ISO 6143:2001, with results showing satisfactory consistent between both selected techniques. According to the work presented here, the obtained validation results for CRDS are better than the GC results, such as the relative uncertainty of samples evaluated for CRDS was 0.4% and 2.7% for GC_FID meth.
文摘Collision between particles plays an important role in determining the hydrodynamic characteristics of gas-solid flow in a fluidized bed. In the present work, earlier work （Loha, Chattopadhyay, ＆ Chatterjee, 2013） was extended to study the effect of the elasticity of particle collision on the hydrodynamic behavior of a bubbling fluidized bed filled with 530-~m particles. The Eulerian-Eulerian two-fluid model was used to simulate the hydrodynamics of the bubbling fluidized bed, where the solid-phase properties were calculated by applying the kinetic theory of granular flow. To investigate the effect of the elasticity of particle collision, different values of the coefficient of restitution were applied in the simulation and their effects were studied in detail. Simulations were performed for two different solid-phase wall boundary conditions. No bubble formation was observed for perfectly elastic collision. The bubble formation started as soon as the coefficient of restitution was set below 1.0, and the space occupied by bubbles in the bed increased with a decrease in the coefficient of restitution. Simulation results were also compared with experimental data available in the literature, and good agreement was found for coefficients of restitution of 0.95 and 0.99.
文摘Transient numerical simulations are carried out to investigate the liquid-gas interfacecharacteristics associated with liquid film cooling flows.A two-dimensional axisymmetricmulti-phase numerical model using finite volume formulation is developed.The model hasbeen validated against available experimental data for liquid-film cooling flows inside tubes.The model has been used to predict the interface characteristics for a variety of imposedparameters and momentum flux ratios under cold flow conditions wherein both the coolant andmainstream are maintained at the same temperature.Disturbance waves are observed at theliquid-gas interface for coolant flows above a critical value and after a finite distance from theinlet.The distance toward the wave inception point increased with the increase of momentumflux ratio.However,at higher momentum flux ratios,the properties of the disturbance wavesdid not vary significantly.The parameters related to the liquid-gas interface waves,namely,wave velocity,frequency,amplitude and wave length have been analyzed in detail.Analysisindicates that the liquid entrainment is due to the shearing of the disturbance wave crest.
