Ten series of aromatic hydrocarbon compounds (biphenyl, naphthalene, phenanthrene, anthracene, retene, chrysene, benzoanthracene, dibenzofuran, fluorene, dibenzothiophene) isolated from seven Triassic and Jurassic lac...Ten series of aromatic hydrocarbon compounds (biphenyl, naphthalene, phenanthrene, anthracene, retene, chrysene, benzoanthracene, dibenzofuran, fluorene, dibenzothiophene) isolated from seven Triassic and Jurassic lacustrine mudstone samples and three swamp coal samples, as well as five crude oil samples collected in the Kuche depression of the Tarim Basin, NW China, have been analysed by GC-MS techniques. It is found that the relative abundances of dibenzofuran series are higher in the three swamp coal samples than those in the lacustrine mudstone samples. Based on the similar relative abundances of dibenzofuran series, especially dibenzofuran compound, in the TICs of aromatic hydrocarbons, crude oils from wells SA3 (K), YTK5 (E, K) and QL1 (E) are thought to have been derived predominantly from the coals of the Lower Jurassic Yangxia Formation or Middle Jurassic Kezilenuer Formation, whereas those from wells YM7 (O) and YH1 (E) were derived mainly from Triassic and Jurassic lacustrine mudstones in the Kuche depression. This is the first report about how to distinguish coal-generated oils from lacustrine mudstone-generated oils in the Kuche depression in terms of the dibenzofuran series. The present paper has enlightening and directive significance for further oil-source rock correlations and oil and/or gas exploration in the Kuche depression of the Tarim Basin.展开更多
A series of significant discoveries in marine carbonate rocks show great petroleum exploration potential in the Tarim Basin. However, the oil and gas fields discovered in the carbonate rocks are mainly distributed aro...A series of significant discoveries in marine carbonate rocks show great petroleum exploration potential in the Tarim Basin. However, the oil and gas fields discovered in the carbonate rocks are mainly distributed around the Manjiaer Sag in the eastern Tarim Basin. Some explorations occurred and no oil or gas field was discovered around the Awati Sag in the western Tarim Basin. Information from wells and outcrops reveals that there are excellent oil and gas source rock conditions around the Awati Sag. Transformed reef-shoal reservoirs could be formed in the Ordovician carbonate rocks with paleo-geographic background and hydrothermal conditions. Therefore, it is necessary to make a systematical study and overall evaluation of the potential of the periphery of the Awati Sag in terms of source rock evolution, resource potential, high-grade reservoir formation and distribution, and main factors controlling hydrocarbon migration and accumulation.展开更多
ABSTRACT： As one of the major exploration objects of marine deposit in Tarim basin, Silurian has been paid more attention from oil/gas exploration and geologists. However, due to the widely deposit and later erosion,...ABSTRACT： As one of the major exploration objects of marine deposit in Tarim basin, Silurian has been paid more attention from oil/gas exploration and geologists. However, due to the widely deposit and later erosion, it is difficult to restore the original basin. The surrounding tectonic activity and provenance systems of Silurian Tarim basin have a lot of controversy. Aid of detrital zircons U-Pb dating data obtained from well drilling of Tabei （塔北） and Tazhong （塔中） areas and Sishichang （四十场） and Xiangyangcun （向阳村） outcrop profiles, integrated with other geological and geophysical data, the tectothermal evolution and provenance nature of Silurian deposit have been revealed. Zircons U-Pb dating shows Tarim basin has experienced 5-6 significant tectothermal events： 3 500-3 000 Ma Paleo-Mesoarchean, around 2 500 and 1 800 Ma Paleoproterozoic, around 1 000 and 800 Ma Neoproterozoic, and 500--400 Ma Eopaleozoic tectothermal events. These tectothermal events reflected the evolution of Tarim microplates and Tarim basin, respectively, corresponded to the forming and spilitting process of Ur supercontinent, Kenorland, Columbia and Rodinia supercontinent. Differencebetween the samples of Tazhong and Tabei areas indicated that North and South Tarim microplates were different in Paleo-Mesoarchean, and later evolutions were more synchronous after Paleoproterozoic. Integrated with seismic data and outcrop interpretation, the U-Pb dating results also revealed that the surrounding tectonic activities were still very active during Silurian, and indicated different regions had different source systems. At Tadong （塔东） and Manjiaer （满加尔） depressions, major source systems came from Ordovician Altyn orogenic belts. At Tabei area and northwest of Tarim basin, majorsource systems came from recycling orogenic zone （the activity of South Tianshan （天山） Mountain） and Precambrian stable basement （local paleo-uplifts at north of Tabei）. The Ordovician uplift and orogenic zone at the south of Tarim basin and Precambrian granite basement provided lots of source systems to Tazhong area.展开更多
In a thermal simulation experiment of gold tubes of closed-system, calculating with the KINETICS and GOR-ISOTOPE KINETICS software, kinetic parameters of gas generation and methane carbon isotopic fractionation from T...In a thermal simulation experiment of gold tubes of closed-system, calculating with the KINETICS and GOR-ISOTOPE KINETICS software, kinetic parameters of gas generation and methane carbon isotopic fractionation from Triassic-Jurassic hydrocarbon source rocks in the Kuqa depression of Tarim Basin are obtained. The activation energies of methane generated from Jurassic coal, Jurassic mudstone and Triassic mudstone in the Kuqa Depression are 197-268 kJ/mol, 180-260 kJ/mol and 214-289 kJ/mol, respectively, and their frequency factors are 5.265×10^13 s^-1, 9.761×10^11 s^-1 and 2.270×10^14 s^-1. This reflects their differences of hydrocarbon generation behaviors. The kinetic parameters of methane carbon isotopic fractionation are also different in Jurassic coal, Jurassic mudstone and Triassic mudstone, whose average activation energies are 228 kJ/mol, 205 kJ/mol and 231 kJ/mol, respectively. Combined with the geological background, the origin of natural gas in the Yinan-2 gas pool is discussed, and an accumulation model of natural gas is thus established. The Yinan- 2 gas is primarily derived from Jurassic coal-bearing source rocks in the Yangxia Sag. Main gas accumulation time is 5-0 Ma and the corresponding Ro is in the range from 1.25 %-1.95 %. The loss rate of natural gas is 25 %-30 %.展开更多
Gypsum caprocks'sealing ability is affected by temperature-pressure coupling.Due to the limitations of experimental conditions,there is still a lack of triaxial stress-strain experiments that simultaneously consid...Gypsum caprocks'sealing ability is affected by temperature-pressure coupling.Due to the limitations of experimental conditions,there is still a lack of triaxial stress-strain experiments that simultaneously consider changes in temperature and pressure conditions,which limits the accuracy of the comprehensive evaluation of the brittle plastic evolution and sealing ability of gypsum rocks using temperature pressure coupling.Triaxial stress-strain tests were utilized to investigate the differences in the evolution of the confinement capacity of gypsum rocks under coupled temperaturepressure action and isothermal-variable pressure action on the basis of sample feasibility analysis.According to research,the gypsum rock's peak and residual strengths decrease under simultaneous increases in temperature and pressure over isothermal pressurization experimental conditions,and it becomes more ductile.This reduces the amount of time it takes for the rock to transition from brittle to plastic.When temperature is taken into account,both the brittle–plastic transformation's depth limit and the lithological transformation of gypsum rocks become shallower,and the evolution of gypsum rocks under variable temperature and pressure conditions is more complicated than that under isothermal pressurization.The sealing ability under the temperature-pressure coupling is more in line with the actual geological context when the application results of the Well#ZS5 are compared.This provides a theoretical basis for precisely determining the process of hydrocarbon accumulation and explains why the early hydrocarbon were not well preserved.展开更多
We investigated diagenesis of the sandstones from the DN2 Gas Field of the Kuqa Foreland Basin(KFB),in order to infer the timing of fluid migration and discuss the linkage between fluids and tectonics.The textures and...We investigated diagenesis of the sandstones from the DN2 Gas Field of the Kuqa Foreland Basin(KFB),in order to infer the timing of fluid migration and discuss the linkage between fluids and tectonics.The textures and chemical composition of authigenic minerals,fluid evidence from fluid inclusions and formation water measurements were all used to fulfill this aim.Eodiagenesis occurred with the participation of meteoric water and connate water.Mesodiagenesis is related to high salinity fluids,which were attributed as originating from the overlying Neogene Jidike Formation evaporite(principal minerals including halite,anhydrite,glauberite,carnallite and thenardite).The onset of high salinity fluid migration is inferred to occur during the late Miocene(12.4-9.2 Ma)through the use of homogenization temperatures measured in the present study and K-Ar dating of authigenetic illites from previous work.This period is consistent with the crucial phase(13-10 Ma)that witnessed the rapid uplift of the southern Tianshan Mts and the stage when calcite and anhydrite veins formed in the studied strata.We thus argue that diagenesis related to high salinity fluids occurred as a response to the Tianshan Mts'rapid uplift and related tectonic processes.The flow of high salinity fluids was probably driven by a density gradient and channeled and focused by fractures formed contemporaneously.展开更多
The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential...The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential to elucidate the evolutionary path of marine redox states and the biogeochemical nitrogen cycle within the water column of the Early Cambrian ocean.While existing research on this topic has predominantly focused on South China,the exploration of other continental margins has been limited,leaving contradictory hypotheses untested.In this study,pairedδ^(15)N andδ^(13)C org analyses were performed on the Lower Cambrian successions from the Shiairike section(inner ramp)and Well Tadong 2(deep shelf/basin)in the northwestern and eastern Tarim Basin,respectively.Our data from the Shiairike section reveal a discernible shift in the operation of different nitrogen cycles for the black chert-shale unit,also referred to as the black rock series in Chinese literature,of the Yurtus Formation(Fortunian stage to lower Stage 3).Oscillatingδ^(15)N values for its lower part are suggestive of alternating anaerobic assimilation of NH 4+and denitrification/anammox.This is likely attributed to a shallow,unstable chemocline consistent with the upwelling and incursion of deep,anoxic waters during a major transgression.In contrast,aerobic nitrogen cycling,indicated by positiveδ^(15)N values of>2‰,dominated the upper part alongside a reduction in upwelling intensity.On the other hand,theδ^(15)N signatures of Xishanbulake and Xidashan Formations of Well Tadong 2,which encompass a time interval from the Cambrian Fortunian Age to Age 4,are indicative of N_(2)fixation by diazotrophs as the major nitrogen source.The two studied intervals,although not time-equivalent,exhibit separated states of nitrogen cycling at least during the deposition of the Yurtus black rock series.The spatially different nitrogen cycling of the studied sections is compatible with a redox-stratified ocean during the deposition of the Yurtus black rock series.The build-up of a NO_(3)−reservoir and aerobic nitrogen cycling in seawater was largely restricted to near-shore settings whereas anaerobic nitrogen cycling dominated by N_(2)fixation served as the main nitrogen uptake pathway in off-shore settings.展开更多
Determining the timing of fracturing is crucial for understanding reservoir evolution and hydrocarbon accumulation in foreland basins.Using fracturing data from cores,borehole images,and outcrops,combined with the clu...Determining the timing of fracturing is crucial for understanding reservoir evolution and hydrocarbon accumulation in foreland basins.Using fracturing data from cores,borehole images,and outcrops,combined with the clumped isotope(D47)and fluid inclusion analyses of carbonate minerals filled in pores and fractures,this study ascertained the fracturing timing of the Jurassic reservoirs in the Dibei-Tuziluoke Gas Field,Kuqa Foreland Basin.Data from outcrops and borehole images show two dominant fracture sets in the study area:W-E and NE-SW striking fractures.Some W-E striking fractures are carbonate-filled,while NE-SW striking fractures lack mineral fillings.Bitumen veins,not easy to be identified in borehole images,are prevalent in cores.The petrographic analysis reveals that these bitumen veins formed before the calcite cementation in pores and display high viscosity and low maturity.Homogenization temperatures(T_(h))from primary fluid inclusion assemblages in two representative calcite vein samples were notably lower than T_(△47) values from corresponding samples.This suggests the △_(47) signature underwent alteration due to partial reordering during burial.Thus,△_(47)-derived temperatures(apparent temperatures)may not faithfully represent the mineral precipitation temperatures.When plotting these apparent temperatures vs.the burial history,only the possible latest ages of fracturing emerged.These ages were further refined by considering petroleum charging,tectonic evolution,and stress orientation.Bitumen-filled fractures likely resulted from the Late Cretaceous uplift,marking the migration of low-maturity hydrocarbons in the study area.Carbonate-filled E-W striking fractures emerged during the late Miocene(~13-6.5 Ma)alongside fold development.NE-striking fractures that crosscut W-E ones possibly formed recently due to stress reorientation.展开更多
The Lower Cretaceous Bashijiqike Formation,which is an important gas exploration target in the Kuqa Depression,Tarim Basin,China,is an excellent case illustrating the diagenesis and reservoir property variations of ti...The Lower Cretaceous Bashijiqike Formation,which is an important gas exploration target in the Kuqa Depression,Tarim Basin,China,is an excellent case illustrating the diagenesis and reservoir property variations of tight sandstone with burial depths ranging from 3500 m to 8000 m.Thus,integrated approaches incorporating thin-section petrographic characterization,mineral morphology and identification,X-ray diffraction analysis,reservoir property tests,and fluid inclusion analysis were applied to investigate the diagenesis and reservoir property variations of Bashijiqike sandstone with different burial depths.The main findings of this study were as follows.(1)Diagenesis of the Bashijiqike sandstone with a burial depth of less than 5000 m was mainly characterized by kaolinite,colloidal quartz,euhedral quartz,and the dissolution of feldspar,whereas diagenesis of the sandstone with a burial depth of more than 5000 m was primarily distinguished by albite,dolomite,calcite,illite,and chlorite.(2)The porosity and permeability rapidly decreased as the burial depth increased within the range of less than 5000 m,while they slowly decreased as the burial depth increased within the range of more than 5000 m,indicating that the reservoir properties have a nonlinear correlation with the burial depths ranging from 3500 m to 8000 m.(3)During the late stage of the Himalayan movement,the enhanced compaction of Bashijiqike sandstone with the increased burial depth resulted in a decrease in the number of intergranular pores,whereas the dissolution of feldspar and quartz led to the formation of secondary pores.Taken together,the findings of this study indicate that the Himalayan movement after the Neogene resulted in burial depth variations with regard to the studied sandstone,which represents the key controlling factor for both its diagenesis and its reservoir properties.展开更多
The ocean crust remnants of the Proto-Tethys were preserved as the Kudi ophiolites in the West Kunlun Orogenic Belt(WKOB),and its evolutionary history was mainly constructed by research on igneous or metamorphic rocks...The ocean crust remnants of the Proto-Tethys were preserved as the Kudi ophiolites in the West Kunlun Orogenic Belt(WKOB),and its evolutionary history was mainly constructed by research on igneous or metamorphic rocks in the WKOB.Sedimentary rocks in the WKOB received little attention in the past;however,they could provide important constraints on the evolution of the oceanic lithosphere.Here,a series of shales and greywackes found in the Kudi area of WKOB were studied to constrain their deposition ages and explore their significance in the evolution of the ProtoTethys oceanic crust.The U-Pb dating and europium anomaly(Eu/Eu^(*))were analyzed for detrital zircons from greywackes interlayers,while bulk rare earth elements and yttrium(REY)of the shales were measured.Detrital zircons U-Pb ages yield a maximum deposition age of 436 Ma for the greywackes and black shales,while the REY distribution patterns of the black shales are similar to those of the Tarim Ordovician Saergan shales.Accordingly,the studied WKOB black shales were deposited in the Proto-Tethys Ocean during the Late Ordovician-Early Silurian period.The maximum deposition age at 436 Ma may represent a minimum closure time of the Proto-Tethys Ocean,which is also supported by the absence of increases in Eu/Eu^(*)values during the Late Ordovician-Early Silurian.Besides,our Eu/Eu^(*)values in detrital zircons indicate diminished orogenesis during the Archean to Meso-Proterozoic,subduction-related accretion at the margins of the supercontinent Rodinia during the Neoproterozoic.展开更多
Fluids generated from the source rocks containing various kerogen types at different thermal maturity stages control diagenetic processes and reservoir quality in adjacent sandstone reservoirs.This study focuses on th...Fluids generated from the source rocks containing various kerogen types at different thermal maturity stages control diagenetic processes and reservoir quality in adjacent sandstone reservoirs.This study focuses on the carbonate cements in the sandstones of the Lower Jurassic Yangxia Formation and the Ahe Formation in the Tarim Basin.Theδ^(18)O,δ^(13)C,and ^(87)Sr/^(86)Sr data indicate that low‑temperature ferroan calcite and manganoan calcite—characterized by strongly negativeδ^(13)C values and enrichment in light rare‑earth elements(LREEs)—record CO_(2) released during the thermal degradation of organic matter predominantly composed of Type III kerogen in coal‑bearing source rocks and of Type Ⅱ kerogen in mudstone source rocks,respectively.High‑temperature ferroan calcite and manganoan calcite,which exhibit similarly strongly negativeδ^(13)C values and enrichment in middle rare‑earth elements(MREEs),record organic acids and CO_(2) produced during the thermal decarboxylation of these same source rocks.The diagenetic fluid evolution sequence comprises early‑stage CO_(2) from thermal degradation of both coal‑bearing and mudstone source rocks;mid‑stage organic acids and CO_(2) from thermal decarboxylation of coal‑bearing source rocks;and late‑stage organic acids and CO_(2) from thermal decarboxylation of mudstone source rocks.Fluids generated during the thermal degradation of mudstone and coal‑bearing source rocks precipitated extensive calcite cements,leading to reservoir densification.Clumped isotope thermometry indicates that the primary generation periods of late‑stage mudstone‑derived fluids coincided with the formation of effective fractures.Feldspar dissolution along these fractures produced an interconnected network of fractures and dissolution pores,significantly enhancing reservoir quality in the Ahe Formation.展开更多
文摘Ten series of aromatic hydrocarbon compounds (biphenyl, naphthalene, phenanthrene, anthracene, retene, chrysene, benzoanthracene, dibenzofuran, fluorene, dibenzothiophene) isolated from seven Triassic and Jurassic lacustrine mudstone samples and three swamp coal samples, as well as five crude oil samples collected in the Kuche depression of the Tarim Basin, NW China, have been analysed by GC-MS techniques. It is found that the relative abundances of dibenzofuran series are higher in the three swamp coal samples than those in the lacustrine mudstone samples. Based on the similar relative abundances of dibenzofuran series, especially dibenzofuran compound, in the TICs of aromatic hydrocarbons, crude oils from wells SA3 (K), YTK5 (E, K) and QL1 (E) are thought to have been derived predominantly from the coals of the Lower Jurassic Yangxia Formation or Middle Jurassic Kezilenuer Formation, whereas those from wells YM7 (O) and YH1 (E) were derived mainly from Triassic and Jurassic lacustrine mudstones in the Kuche depression. This is the first report about how to distinguish coal-generated oils from lacustrine mudstone-generated oils in the Kuche depression in terms of the dibenzofuran series. The present paper has enlightening and directive significance for further oil-source rock correlations and oil and/or gas exploration in the Kuche depression of the Tarim Basin.
文摘A series of significant discoveries in marine carbonate rocks show great petroleum exploration potential in the Tarim Basin. However, the oil and gas fields discovered in the carbonate rocks are mainly distributed around the Manjiaer Sag in the eastern Tarim Basin. Some explorations occurred and no oil or gas field was discovered around the Awati Sag in the western Tarim Basin. Information from wells and outcrops reveals that there are excellent oil and gas source rock conditions around the Awati Sag. Transformed reef-shoal reservoirs could be formed in the Ordovician carbonate rocks with paleo-geographic background and hydrothermal conditions. Therefore, it is necessary to make a systematical study and overall evaluation of the potential of the periphery of the Awati Sag in terms of source rock evolution, resource potential, high-grade reservoir formation and distribution, and main factors controlling hydrocarbon migration and accumulation.
基金supported by the Fundamental Research Funds for the Central Universities of China(No.2010ZD07)the Key National Natural Science Foundation of China(No.41130422)+1 种基金the National Natural Science Foundation of China(No. 40372056)the State Key Development Program for Basic Research of China(Nos.2011CB201103,2006CB202302)
文摘ABSTRACT： As one of the major exploration objects of marine deposit in Tarim basin, Silurian has been paid more attention from oil/gas exploration and geologists. However, due to the widely deposit and later erosion, it is difficult to restore the original basin. The surrounding tectonic activity and provenance systems of Silurian Tarim basin have a lot of controversy. Aid of detrital zircons U-Pb dating data obtained from well drilling of Tabei （塔北） and Tazhong （塔中） areas and Sishichang （四十场） and Xiangyangcun （向阳村） outcrop profiles, integrated with other geological and geophysical data, the tectothermal evolution and provenance nature of Silurian deposit have been revealed. Zircons U-Pb dating shows Tarim basin has experienced 5-6 significant tectothermal events： 3 500-3 000 Ma Paleo-Mesoarchean, around 2 500 and 1 800 Ma Paleoproterozoic, around 1 000 and 800 Ma Neoproterozoic, and 500--400 Ma Eopaleozoic tectothermal events. These tectothermal events reflected the evolution of Tarim microplates and Tarim basin, respectively, corresponded to the forming and spilitting process of Ur supercontinent, Kenorland, Columbia and Rodinia supercontinent. Differencebetween the samples of Tazhong and Tabei areas indicated that North and South Tarim microplates were different in Paleo-Mesoarchean, and later evolutions were more synchronous after Paleoproterozoic. Integrated with seismic data and outcrop interpretation, the U-Pb dating results also revealed that the surrounding tectonic activities were still very active during Silurian, and indicated different regions had different source systems. At Tadong （塔东） and Manjiaer （满加尔） depressions, major source systems came from Ordovician Altyn orogenic belts. At Tabei area and northwest of Tarim basin, majorsource systems came from recycling orogenic zone （the activity of South Tianshan （天山） Mountain） and Precambrian stable basement （local paleo-uplifts at north of Tabei）. The Ordovician uplift and orogenic zone at the south of Tarim basin and Precambrian granite basement provided lots of source systems to Tazhong area.
基金supported by the National Natural Science Foundation of China(No.40572085)Open Fund of State Key Laboratory of Organic Geochemistry,Guangzhou Institute of Geochemistry,Chinese Academy of Sciences(No.OGL-200403)+2 种基金State Key Technologies R&D Program during the 10th Five-Year Plan Period(No.2001BA605A02-03-01 and 2004BA616A02-01-01)New-century Excellent Talent Program of Ministry of Education(No.NCET-06-0204)China Postdoctoral Science Foundation(No.2002031282).
文摘In a thermal simulation experiment of gold tubes of closed-system, calculating with the KINETICS and GOR-ISOTOPE KINETICS software, kinetic parameters of gas generation and methane carbon isotopic fractionation from Triassic-Jurassic hydrocarbon source rocks in the Kuqa depression of Tarim Basin are obtained. The activation energies of methane generated from Jurassic coal, Jurassic mudstone and Triassic mudstone in the Kuqa Depression are 197-268 kJ/mol, 180-260 kJ/mol and 214-289 kJ/mol, respectively, and their frequency factors are 5.265×10^13 s^-1, 9.761×10^11 s^-1 and 2.270×10^14 s^-1. This reflects their differences of hydrocarbon generation behaviors. The kinetic parameters of methane carbon isotopic fractionation are also different in Jurassic coal, Jurassic mudstone and Triassic mudstone, whose average activation energies are 228 kJ/mol, 205 kJ/mol and 231 kJ/mol, respectively. Combined with the geological background, the origin of natural gas in the Yinan-2 gas pool is discussed, and an accumulation model of natural gas is thus established. The Yinan- 2 gas is primarily derived from Jurassic coal-bearing source rocks in the Yangxia Sag. Main gas accumulation time is 5-0 Ma and the corresponding Ro is in the range from 1.25 %-1.95 %. The loss rate of natural gas is 25 %-30 %.
基金funded by the National Natural Science Foundation of China(Grant No.42172147)PetroChina Major Science and Technology Project(Grant No.ZD2019-183-002).
文摘Gypsum caprocks'sealing ability is affected by temperature-pressure coupling.Due to the limitations of experimental conditions,there is still a lack of triaxial stress-strain experiments that simultaneously consider changes in temperature and pressure conditions,which limits the accuracy of the comprehensive evaluation of the brittle plastic evolution and sealing ability of gypsum rocks using temperature pressure coupling.Triaxial stress-strain tests were utilized to investigate the differences in the evolution of the confinement capacity of gypsum rocks under coupled temperaturepressure action and isothermal-variable pressure action on the basis of sample feasibility analysis.According to research,the gypsum rock's peak and residual strengths decrease under simultaneous increases in temperature and pressure over isothermal pressurization experimental conditions,and it becomes more ductile.This reduces the amount of time it takes for the rock to transition from brittle to plastic.When temperature is taken into account,both the brittle–plastic transformation's depth limit and the lithological transformation of gypsum rocks become shallower,and the evolution of gypsum rocks under variable temperature and pressure conditions is more complicated than that under isothermal pressurization.The sealing ability under the temperature-pressure coupling is more in line with the actual geological context when the application results of the Well#ZS5 are compared.This provides a theoretical basis for precisely determining the process of hydrocarbon accumulation and explains why the early hydrocarbon were not well preserved.
基金financially supported by the program of the National Natural Science Foundation of China(No.42072134)the Major Research Project on the Tethys Geodynamic System from the National Science Foundation of China(No.92055204)the Major Scientific and Technological Projects of the CNPC under Grant ZD2019-183-001。
文摘We investigated diagenesis of the sandstones from the DN2 Gas Field of the Kuqa Foreland Basin(KFB),in order to infer the timing of fluid migration and discuss the linkage between fluids and tectonics.The textures and chemical composition of authigenic minerals,fluid evidence from fluid inclusions and formation water measurements were all used to fulfill this aim.Eodiagenesis occurred with the participation of meteoric water and connate water.Mesodiagenesis is related to high salinity fluids,which were attributed as originating from the overlying Neogene Jidike Formation evaporite(principal minerals including halite,anhydrite,glauberite,carnallite and thenardite).The onset of high salinity fluid migration is inferred to occur during the late Miocene(12.4-9.2 Ma)through the use of homogenization temperatures measured in the present study and K-Ar dating of authigenetic illites from previous work.This period is consistent with the crucial phase(13-10 Ma)that witnessed the rapid uplift of the southern Tianshan Mts and the stage when calcite and anhydrite veins formed in the studied strata.We thus argue that diagenesis related to high salinity fluids occurred as a response to the Tianshan Mts'rapid uplift and related tectonic processes.The flow of high salinity fluids was probably driven by a density gradient and channeled and focused by fractures formed contemporaneously.
基金supported by the Fundamental Research Funds for the Central Universities(No.B200202009).
文摘The Early Cambrian represents a critical time period characterized by extraordinary biological innovations and dynamic redox conditions in seawaters.Nitrogen isotopic signatures of ancient sediments have the potential to elucidate the evolutionary path of marine redox states and the biogeochemical nitrogen cycle within the water column of the Early Cambrian ocean.While existing research on this topic has predominantly focused on South China,the exploration of other continental margins has been limited,leaving contradictory hypotheses untested.In this study,pairedδ^(15)N andδ^(13)C org analyses were performed on the Lower Cambrian successions from the Shiairike section(inner ramp)and Well Tadong 2(deep shelf/basin)in the northwestern and eastern Tarim Basin,respectively.Our data from the Shiairike section reveal a discernible shift in the operation of different nitrogen cycles for the black chert-shale unit,also referred to as the black rock series in Chinese literature,of the Yurtus Formation(Fortunian stage to lower Stage 3).Oscillatingδ^(15)N values for its lower part are suggestive of alternating anaerobic assimilation of NH 4+and denitrification/anammox.This is likely attributed to a shallow,unstable chemocline consistent with the upwelling and incursion of deep,anoxic waters during a major transgression.In contrast,aerobic nitrogen cycling,indicated by positiveδ^(15)N values of>2‰,dominated the upper part alongside a reduction in upwelling intensity.On the other hand,theδ^(15)N signatures of Xishanbulake and Xidashan Formations of Well Tadong 2,which encompass a time interval from the Cambrian Fortunian Age to Age 4,are indicative of N_(2)fixation by diazotrophs as the major nitrogen source.The two studied intervals,although not time-equivalent,exhibit separated states of nitrogen cycling at least during the deposition of the Yurtus black rock series.The spatially different nitrogen cycling of the studied sections is compatible with a redox-stratified ocean during the deposition of the Yurtus black rock series.The build-up of a NO_(3)−reservoir and aerobic nitrogen cycling in seawater was largely restricted to near-shore settings whereas anaerobic nitrogen cycling dominated by N_(2)fixation served as the main nitrogen uptake pathway in off-shore settings.
基金funded by the PetroChina Major Research Program on Deep Petroleum System in the Tarim Basin(No.ZD 2019-183-01-003)the Major Research Project on the Tethys Geodynamic System from the National Natural Science Foundation of China(No.92055204)the National Natural Science Foundation of China(No.42072134).
文摘Determining the timing of fracturing is crucial for understanding reservoir evolution and hydrocarbon accumulation in foreland basins.Using fracturing data from cores,borehole images,and outcrops,combined with the clumped isotope(D47)and fluid inclusion analyses of carbonate minerals filled in pores and fractures,this study ascertained the fracturing timing of the Jurassic reservoirs in the Dibei-Tuziluoke Gas Field,Kuqa Foreland Basin.Data from outcrops and borehole images show two dominant fracture sets in the study area:W-E and NE-SW striking fractures.Some W-E striking fractures are carbonate-filled,while NE-SW striking fractures lack mineral fillings.Bitumen veins,not easy to be identified in borehole images,are prevalent in cores.The petrographic analysis reveals that these bitumen veins formed before the calcite cementation in pores and display high viscosity and low maturity.Homogenization temperatures(T_(h))from primary fluid inclusion assemblages in two representative calcite vein samples were notably lower than T_(△47) values from corresponding samples.This suggests the △_(47) signature underwent alteration due to partial reordering during burial.Thus,△_(47)-derived temperatures(apparent temperatures)may not faithfully represent the mineral precipitation temperatures.When plotting these apparent temperatures vs.the burial history,only the possible latest ages of fracturing emerged.These ages were further refined by considering petroleum charging,tectonic evolution,and stress orientation.Bitumen-filled fractures likely resulted from the Late Cretaceous uplift,marking the migration of low-maturity hydrocarbons in the study area.Carbonate-filled E-W striking fractures emerged during the late Miocene(~13-6.5 Ma)alongside fold development.NE-striking fractures that crosscut W-E ones possibly formed recently due to stress reorientation.
基金the National Science and Technology Major Project(2016ZX05003-0012017ZX05001-002)Science and Technology Project of the China Petroleum and Natural Gas Co.,Ltd.(KT2018-02-06).
文摘The Lower Cretaceous Bashijiqike Formation,which is an important gas exploration target in the Kuqa Depression,Tarim Basin,China,is an excellent case illustrating the diagenesis and reservoir property variations of tight sandstone with burial depths ranging from 3500 m to 8000 m.Thus,integrated approaches incorporating thin-section petrographic characterization,mineral morphology and identification,X-ray diffraction analysis,reservoir property tests,and fluid inclusion analysis were applied to investigate the diagenesis and reservoir property variations of Bashijiqike sandstone with different burial depths.The main findings of this study were as follows.(1)Diagenesis of the Bashijiqike sandstone with a burial depth of less than 5000 m was mainly characterized by kaolinite,colloidal quartz,euhedral quartz,and the dissolution of feldspar,whereas diagenesis of the sandstone with a burial depth of more than 5000 m was primarily distinguished by albite,dolomite,calcite,illite,and chlorite.(2)The porosity and permeability rapidly decreased as the burial depth increased within the range of less than 5000 m,while they slowly decreased as the burial depth increased within the range of more than 5000 m,indicating that the reservoir properties have a nonlinear correlation with the burial depths ranging from 3500 m to 8000 m.(3)During the late stage of the Himalayan movement,the enhanced compaction of Bashijiqike sandstone with the increased burial depth resulted in a decrease in the number of intergranular pores,whereas the dissolution of feldspar and quartz led to the formation of secondary pores.Taken together,the findings of this study indicate that the Himalayan movement after the Neogene resulted in burial depth variations with regard to the studied sandstone,which represents the key controlling factor for both its diagenesis and its reservoir properties.
基金financially supported by the National Major Science and Technology Project of China(No.2016ZX05004-004)the State Scholarship Grant from the China Scholarship Council(CSC)to Yinggang Zhang。
文摘The ocean crust remnants of the Proto-Tethys were preserved as the Kudi ophiolites in the West Kunlun Orogenic Belt(WKOB),and its evolutionary history was mainly constructed by research on igneous or metamorphic rocks in the WKOB.Sedimentary rocks in the WKOB received little attention in the past;however,they could provide important constraints on the evolution of the oceanic lithosphere.Here,a series of shales and greywackes found in the Kudi area of WKOB were studied to constrain their deposition ages and explore their significance in the evolution of the ProtoTethys oceanic crust.The U-Pb dating and europium anomaly(Eu/Eu^(*))were analyzed for detrital zircons from greywackes interlayers,while bulk rare earth elements and yttrium(REY)of the shales were measured.Detrital zircons U-Pb ages yield a maximum deposition age of 436 Ma for the greywackes and black shales,while the REY distribution patterns of the black shales are similar to those of the Tarim Ordovician Saergan shales.Accordingly,the studied WKOB black shales were deposited in the Proto-Tethys Ocean during the Late Ordovician-Early Silurian period.The maximum deposition age at 436 Ma may represent a minimum closure time of the Proto-Tethys Ocean,which is also supported by the absence of increases in Eu/Eu^(*)values during the Late Ordovician-Early Silurian.Besides,our Eu/Eu^(*)values in detrital zircons indicate diminished orogenesis during the Archean to Meso-Proterozoic,subduction-related accretion at the margins of the supercontinent Rodinia during the Neoproterozoic.
基金supported by the National Natural Science Foundation of China(Grant No.42488101)the Taishan Scholars Program(Grant No.tsqn202306125)+1 种基金the Open Research Fund of the State Key Laboratory of Deep Oil and Gas(Grant No.SKLDOG2024-KFZD-02)the PetroChina Major Research Program on Deep Petroleum Systems in the Tarim Basin(Grant No.ZD2019-183-01-003).
文摘Fluids generated from the source rocks containing various kerogen types at different thermal maturity stages control diagenetic processes and reservoir quality in adjacent sandstone reservoirs.This study focuses on the carbonate cements in the sandstones of the Lower Jurassic Yangxia Formation and the Ahe Formation in the Tarim Basin.Theδ^(18)O,δ^(13)C,and ^(87)Sr/^(86)Sr data indicate that low‑temperature ferroan calcite and manganoan calcite—characterized by strongly negativeδ^(13)C values and enrichment in light rare‑earth elements(LREEs)—record CO_(2) released during the thermal degradation of organic matter predominantly composed of Type III kerogen in coal‑bearing source rocks and of Type Ⅱ kerogen in mudstone source rocks,respectively.High‑temperature ferroan calcite and manganoan calcite,which exhibit similarly strongly negativeδ^(13)C values and enrichment in middle rare‑earth elements(MREEs),record organic acids and CO_(2) produced during the thermal decarboxylation of these same source rocks.The diagenetic fluid evolution sequence comprises early‑stage CO_(2) from thermal degradation of both coal‑bearing and mudstone source rocks;mid‑stage organic acids and CO_(2) from thermal decarboxylation of coal‑bearing source rocks;and late‑stage organic acids and CO_(2) from thermal decarboxylation of mudstone source rocks.Fluids generated during the thermal degradation of mudstone and coal‑bearing source rocks precipitated extensive calcite cements,leading to reservoir densification.Clumped isotope thermometry indicates that the primary generation periods of late‑stage mudstone‑derived fluids coincided with the formation of effective fractures.Feldspar dissolution along these fractures produced an interconnected network of fractures and dissolution pores,significantly enhancing reservoir quality in the Ahe Formation.
