In the presence of inhibitors, the macroscopical oxidation kinetics of calcium sulfite, the main byproduct in wet limestone scrubbing, was studied for the first time by adding different inhibitors and varying pH, conc...In the presence of inhibitors, the macroscopical oxidation kinetics of calcium sulfite, the main byproduct in wet limestone scrubbing, was studied for the first time by adding different inhibitors and varying pH, concentration of calcium sulfite, oxygen partial pressure, concentration of inhibitors and temperature. The mathematical model about the general oxidation reaction was established, which was controlled by three steps involving dissolution of calcium sulfite, mass transfer of oxygen and chemical reaction in the solution. It was concluded that the general reaction was controlled by mass transfer of oxygen under uncatalyzed conditions, while it was controlled by dissolution of calcium sulfite after adding three kinds of inhibitors. Thus, the theory was provided for investigating the mechanism and oxidation kinetics of sulfite. The beneficial references were also supplied for design of oxidation technics in the wet limestone scrubbing.展开更多
Through analyzing the proportion of SO2 emission from thermal power plants in the nationwide SO2 emis- sion in USA, Japan etc. developed countries, and the developmental course of thermal power installed capacity and ...Through analyzing the proportion of SO2 emission from thermal power plants in the nationwide SO2 emis- sion in USA, Japan etc. developed countries, and the developmental course of thermal power installed capacity and the FGD capacity in USA, the FGD capacity of thermal power plants in China is forecasted from two angles. One is to predict FGD capacity in accordance with the policy in force in China. The other is to predict FGD capacity based upon the emission right trading policy. As compared, it is held that FGD equipment should be mainly installed on the large size units burning high sulfur coal according to the emission right trading policy. Such a method of work not only can economize large amount of investments and operation costs, but also can realize the same environmental effect.展开更多
基金The National Basic Research Program(973) of China(No. JK00020)
文摘In the presence of inhibitors, the macroscopical oxidation kinetics of calcium sulfite, the main byproduct in wet limestone scrubbing, was studied for the first time by adding different inhibitors and varying pH, concentration of calcium sulfite, oxygen partial pressure, concentration of inhibitors and temperature. The mathematical model about the general oxidation reaction was established, which was controlled by three steps involving dissolution of calcium sulfite, mass transfer of oxygen and chemical reaction in the solution. It was concluded that the general reaction was controlled by mass transfer of oxygen under uncatalyzed conditions, while it was controlled by dissolution of calcium sulfite after adding three kinds of inhibitors. Thus, the theory was provided for investigating the mechanism and oxidation kinetics of sulfite. The beneficial references were also supplied for design of oxidation technics in the wet limestone scrubbing.
文摘Through analyzing the proportion of SO2 emission from thermal power plants in the nationwide SO2 emis- sion in USA, Japan etc. developed countries, and the developmental course of thermal power installed capacity and the FGD capacity in USA, the FGD capacity of thermal power plants in China is forecasted from two angles. One is to predict FGD capacity in accordance with the policy in force in China. The other is to predict FGD capacity based upon the emission right trading policy. As compared, it is held that FGD equipment should be mainly installed on the large size units burning high sulfur coal according to the emission right trading policy. Such a method of work not only can economize large amount of investments and operation costs, but also can realize the same environmental effect.
