In this work, pyrolysis photoionization time-of-flight mass spectrometry （Py-PI-TOFMS） was applied to study the behavior of ammonia poisoning on H-form ultra stable Y （HUSY） zeolite for the catalytic pyrolysis of ...In this work, pyrolysis photoionization time-of-flight mass spectrometry （Py-PI-TOFMS） was applied to study the behavior of ammonia poisoning on H-form ultra stable Y （HUSY） zeolite for the catalytic pyrolysis of polypropylene （PP）. Firstly, ammonia poisoning on HUSY was performed to obtain the suitable catalysts with different strength and amounts of acid sites. Secondly, online photoionization mass spectra for the pyrolysis products of PP and HUSY with various acid strength were recorded at different pyrolysis temperatures. Finally, the formation curves of various pyrolysates of PP/HUSY with the increase of temperature were determined. Our results indicate that the formation temperatures, yields and selectivity of the pyrolysis products of PP demonstrate obvious relationship with the acid strength of HUSY.展开更多
Ordered macroporous semiconductors CdS and ZnS with regular arrays of spherical pores have been fabricated by poly (styrene-acrylic) (PSA) colloidal crystal template. It was found that the exact three-dimensional (3D...Ordered macroporous semiconductors CdS and ZnS with regular arrays of spherical pores have been fabricated by poly (styrene-acrylic) (PSA) colloidal crystal template. It was found that the exact three-dimensional (3D) structure of the template had been imprinted in the final material.展开更多
The highly ordered macroporous Au and Pd with regular arrays of spherical pores have been synthesized by poly (styrene-co-acrylic) (PSA) colloidal crystal template. The pore size is tuneable in the range of 100-400 nm...The highly ordered macroporous Au and Pd with regular arrays of spherical pores have been synthesized by poly (styrene-co-acrylic) (PSA) colloidal crystal template. The pore size is tuneable in the range of 100-400 nm according to the size of PSA latex. The mechanism is based on the in-situ impregnating and reducing of metal ions in the interspaces of the PSA spheres then removing the template.展开更多
A kinetic modeling of pollutant formation in hydrocarbon flames is presented through analysis of hierar- chical structures. Based on the newly released GRI-Mech 3.0, it was mainly taken from Dean and Bozzelli (DB) and...A kinetic modeling of pollutant formation in hydrocarbon flames is presented through analysis of hierar- chical structures. Based on the newly released GRI-Mech 3.0, it was mainly taken from Dean and Bozzelli (DB) and Wang mechanism respectively for the nitrogen chemistry, the for- mation and growth of polycyclic aromatic hydrocarbons (PAH). The modeling was improved by considering C4 and Howard’s PAH chemistry. The mechanism consists of 121 species in 731 reactions. Two premixed flame structures are predicted, and the computed results are compared with the experimental ones. It is shown that the mechanism predicts reasonably well the concentration profiles of major, key in- termediate and minor species.展开更多
In order to study the interference effect of rare- faction wave on the laminar flame propagating structure and pressure characteristics of methane-air mixture, a small scale combustion chamber has been built. The tech...In order to study the interference effect of rare- faction wave on the laminar flame propagating structure and pressure characteristics of methane-air mixture, a small scale combustion chamber has been built. The techniques of high speed Schlieren photograph, pressure measurement and so on, are used to study the influence of rarefaction wave on the laminar flame propagating through methane-air mixture. The results show that, after the rarefaction wave acts on the propagation laminar flame, the laminar combustion is fully transformed into turbulent combustion just during several milliseconds, which leads to a sharp increase in the burning surface area and the pressure rise rate.展开更多
Results obtained using conditional moment closure (CMC) approach to modeling a lifted turbulent hy-drogen flame are presented. Predictions are based on k-ε-g turbulent closure, a 23-step chemical mechanism and a ra-d...Results obtained using conditional moment closure (CMC) approach to modeling a lifted turbulent hy-drogen flame are presented. Predictions are based on k-ε-g turbulent closure, a 23-step chemical mechanism and a ra-dially averaged CMC model. The objectives are to find out how radially averaged CMC can represent a lifted flame and which mechanism of flame stabilization can be described by this modeling method. As a first stage of the study of multi-dimensional CMC for large eddy simulation (LES) of the lifted turbulent flames, the effect of turbulence upon combustion is included, the high-order compact finite- difference scheme (Padé) is used and previously developed characteristic-wave-based boundary conditions for multi- component perfect gas mixtures are here extended to their conditional forms but the heat release due to combustion is not part of the turbulent calculations. Attention is focused to the lift-off region of the flame which is commonly considered as a cold flow. Comparison with published experimental data and the computational results shows that the lift-off height can be accurately determined, and Favre averaged radial profiles of temperature and species mole fractions are also reasonably well predicted. Some of the current flame stabili-zation mechanisms are discussed.展开更多
The near field dynamics of buoyant reactive jets with adjacent sidewalls is investigated by time-dependent three-dimensional direct simulations. The physical problem is a fuel jet issuing vertically into an oxidant am...The near field dynamics of buoyant reactive jets with adjacent sidewalls is investigated by time-dependent three-dimensional direct simulations. The physical problem is a fuel jet issuing vertically into an oxidant ambient envi- ronment in a corner configuration with sidewall boundaries. Simulation results are presented for two cases with different jet nozzle geometries: a corner-round reactive jet and a cor- ner-square reactive jet with the same cross-sectional area on the nozzle plane. Buoyancy-induced large vortical structures evolve spatially in the flow field and transition to turbulence occurs downstream. Calculation of the mean flow properties shows that entrainment of the corner-round jet is stronger than that of the corner-square jet due to the stronger vortex deformation in the corner-round case.展开更多
A computational model of three-dimensional, time-dependent flame spread in microgravity environment is presented. The solid is assumed to be a thermally-thin, pyrolysing cellulosic sheet. The gas phase model includes ...A computational model of three-dimensional, time-dependent flame spread in microgravity environment is presented. The solid is assumed to be a thermally-thin, pyrolysing cellulosic sheet. The gas phase model includes the full Navier-Stokes equations with density and pressure variations and six-flus model of radiation heat transfer. The solid phase model consists of continuity and energy eqllations whose solution provides boundary conditions for the gas phase equations. In the numerical procedure, the gas-and solid-phase equations are solved sepaxately and iteratively at each time step. Predictions have been made of flame spread in slow forced flow under gravitational acceleration normal to fuel surface and flame spread in a quiescent environment in an enclosed chamber under gravitational acceleration parallel to fuel surface. Numerical simulations show that, under microgravity, slow-flow conditions, flame spread process is highly unsteady with the upstream flame spreads faster than the downstream flame after a period of ignition. It has also been shown that the level of microgravity has a significant effect on the name spread process.展开更多
This paper presents the zone modeling analysis of a single compartment flashover fire. Two criteria are ap- plied in the model to judge the onset of ignition for different combustibles. By calculating the total receiv...This paper presents the zone modeling analysis of a single compartment flashover fire. Two criteria are ap- plied in the model to judge the onset of ignition for different combustibles. By calculating the total received energy through radiation or the surface temperature of the combus- tible, the fire growth can be quantitatively determined. The improved zone fire model shows the influence of different combustibles upon the fire growth. This model is better than the traditional zone model because the common criteria of flashover, i.e. an upper layer temperature of 600℃ and the heat radiation intensity received by the floor of 20 kW/m2, have not been applied in it.展开更多
文摘In this work, pyrolysis photoionization time-of-flight mass spectrometry （Py-PI-TOFMS） was applied to study the behavior of ammonia poisoning on H-form ultra stable Y （HUSY） zeolite for the catalytic pyrolysis of polypropylene （PP）. Firstly, ammonia poisoning on HUSY was performed to obtain the suitable catalysts with different strength and amounts of acid sites. Secondly, online photoionization mass spectra for the pyrolysis products of PP and HUSY with various acid strength were recorded at different pyrolysis temperatures. Finally, the formation curves of various pyrolysates of PP/HUSY with the increase of temperature were determined. Our results indicate that the formation temperatures, yields and selectivity of the pyrolysis products of PP demonstrate obvious relationship with the acid strength of HUSY.
基金This work is financially supported by the National Natural Science Foundation of China (No. 59572031 and 19772049).
文摘Ordered macroporous semiconductors CdS and ZnS with regular arrays of spherical pores have been fabricated by poly (styrene-acrylic) (PSA) colloidal crystal template. It was found that the exact three-dimensional (3D) structure of the template had been imprinted in the final material.
基金The work is financially supported by the National Natural Science Foundation of China(No.50003008)the China NKBRSF project(No.2001 CB409600)Anhui"the tenth five years"tackle key problems project.
文摘The highly ordered macroporous Au and Pd with regular arrays of spherical pores have been synthesized by poly (styrene-co-acrylic) (PSA) colloidal crystal template. The pore size is tuneable in the range of 100-400 nm according to the size of PSA latex. The mechanism is based on the in-situ impregnating and reducing of metal ions in the interspaces of the PSA spheres then removing the template.
基金This work was supported by the National Natural Science Foundation of China(Grants No.50276057 and 50476027)the China NKBRSF project(No.2001CB409600).
文摘A kinetic modeling of pollutant formation in hydrocarbon flames is presented through analysis of hierar- chical structures. Based on the newly released GRI-Mech 3.0, it was mainly taken from Dean and Bozzelli (DB) and Wang mechanism respectively for the nitrogen chemistry, the for- mation and growth of polycyclic aromatic hydrocarbons (PAH). The modeling was improved by considering C4 and Howard’s PAH chemistry. The mechanism consists of 121 species in 731 reactions. Two premixed flame structures are predicted, and the computed results are compared with the experimental ones. It is shown that the mechanism predicts reasonably well the concentration profiles of major, key in- termediate and minor species.
基金This work was supposed by“100 Talents Project”of the Chinese Academy of SciencesChina NKBRSF Project(“973”Project,No.2OO1CB4O96O6).
文摘In order to study the interference effect of rare- faction wave on the laminar flame propagating structure and pressure characteristics of methane-air mixture, a small scale combustion chamber has been built. The techniques of high speed Schlieren photograph, pressure measurement and so on, are used to study the influence of rarefaction wave on the laminar flame propagating through methane-air mixture. The results show that, after the rarefaction wave acts on the propagation laminar flame, the laminar combustion is fully transformed into turbulent combustion just during several milliseconds, which leads to a sharp increase in the burning surface area and the pressure rise rate.
基金supported by the National Natural Science Foundation of China(Grant Nos.50276057 and 50476027)the China NKBRSF Project(No.2001 CB409600)..
文摘Results obtained using conditional moment closure (CMC) approach to modeling a lifted turbulent hy-drogen flame are presented. Predictions are based on k-ε-g turbulent closure, a 23-step chemical mechanism and a ra-dially averaged CMC model. The objectives are to find out how radially averaged CMC can represent a lifted flame and which mechanism of flame stabilization can be described by this modeling method. As a first stage of the study of multi-dimensional CMC for large eddy simulation (LES) of the lifted turbulent flames, the effect of turbulence upon combustion is included, the high-order compact finite- difference scheme (Padé) is used and previously developed characteristic-wave-based boundary conditions for multi- component perfect gas mixtures are here extended to their conditional forms but the heat release due to combustion is not part of the turbulent calculations. Attention is focused to the lift-off region of the flame which is commonly considered as a cold flow. Comparison with published experimental data and the computational results shows that the lift-off height can be accurately determined, and Favre averaged radial profiles of temperature and species mole fractions are also reasonably well predicted. Some of the current flame stabili-zation mechanisms are discussed.
文摘The near field dynamics of buoyant reactive jets with adjacent sidewalls is investigated by time-dependent three-dimensional direct simulations. The physical problem is a fuel jet issuing vertically into an oxidant ambient envi- ronment in a corner configuration with sidewall boundaries. Simulation results are presented for two cases with different jet nozzle geometries: a corner-round reactive jet and a cor- ner-square reactive jet with the same cross-sectional area on the nozzle plane. Buoyancy-induced large vortical structures evolve spatially in the flow field and transition to turbulence occurs downstream. Calculation of the mean flow properties shows that entrainment of the corner-round jet is stronger than that of the corner-square jet due to the stronger vortex deformation in the corner-round case.
文摘A computational model of three-dimensional, time-dependent flame spread in microgravity environment is presented. The solid is assumed to be a thermally-thin, pyrolysing cellulosic sheet. The gas phase model includes the full Navier-Stokes equations with density and pressure variations and six-flus model of radiation heat transfer. The solid phase model consists of continuity and energy eqllations whose solution provides boundary conditions for the gas phase equations. In the numerical procedure, the gas-and solid-phase equations are solved sepaxately and iteratively at each time step. Predictions have been made of flame spread in slow forced flow under gravitational acceleration normal to fuel surface and flame spread in a quiescent environment in an enclosed chamber under gravitational acceleration parallel to fuel surface. Numerical simulations show that, under microgravity, slow-flow conditions, flame spread process is highly unsteady with the upstream flame spreads faster than the downstream flame after a period of ignition. It has also been shown that the level of microgravity has a significant effect on the name spread process.
基金This work was supported by the China NKBRSF Project(No.2001CB409603).
文摘This paper presents the zone modeling analysis of a single compartment flashover fire. Two criteria are ap- plied in the model to judge the onset of ignition for different combustibles. By calculating the total received energy through radiation or the surface temperature of the combus- tible, the fire growth can be quantitatively determined. The improved zone fire model shows the influence of different combustibles upon the fire growth. This model is better than the traditional zone model because the common criteria of flashover, i.e. an upper layer temperature of 600℃ and the heat radiation intensity received by the floor of 20 kW/m2, have not been applied in it.
