In the newly revised Environmental Protection Law of the People's Republic of China that has been implemented since January 1,2015,there is a lot of emphasis on environmental economic policies. In this paper,accor...In the newly revised Environmental Protection Law of the People's Republic of China that has been implemented since January 1,2015,there is a lot of emphasis on environmental economic policies. In this paper,according to the current situation of environmental pollution and protection in thermal power industry,it is proposed that based on the new environmental protection law,it is needed to study various environmental economic policies on thermal power industry and analyze the effects on environmental cost of thermal power enterprises at the macro level. At the micro level,it is necessary to control environmental cost of thermal power enterprises effectively,and establish a suitable environmental management system for environmental economic policies including environmental cost accounting and trading of emission rights,thereby improving environmental management level of thermal power enterprises.展开更多
Environmental problems like haze have brought great pressure to current environmental protection management. On the one hand, plan EIA should be promoted further in all industries; on the other hand, the current achie...Environmental problems like haze have brought great pressure to current environmental protection management. On the one hand, plan EIA should be promoted further in all industries; on the other hand, the current achievements and methods of plan EIA should be summarized and innovated. And the EIA supervision and project access can be improved further through the coordination between plan EIA and project EIA. In this study, from the three levels of plan EIA policy framework, five problems of plan EIA in power sector were analyzed according to the current situation of plan EIA in power sector. Based on the present achievements, five macroscopic suggestions were proposed from the view of innovation accord- ing to the new environmental protection situation and requirements at present.展开更多
The planning environmental impact assessment （EIA） of transmission and transformation power grid at levels of 500 and 220 kV had been finished completely in the 13 municipalities of Jiangsu Province by the end of 20...The planning environmental impact assessment （EIA） of transmission and transformation power grid at levels of 500 and 220 kV had been finished completely in the 13 municipalities of Jiangsu Province by the end of 2012, which played important roles in guiding and planning the following transmission and transformation projects in environmental protection. In this paper, through the detail analysis on the objective and significance of the planning EIA of transmission and transformation power grid, legal basis and planning EIA practices, some suggestions and thinking about the planning EIA of transmission and transformation power grid were put forward.展开更多
Starting from the historical evolution of China s regional coordinated development policy and practice,three stages of"enlightenment stage","development stage"and"maturity stage",as well ...Starting from the historical evolution of China s regional coordinated development policy and practice,three stages of"enlightenment stage","development stage"and"maturity stage",as well as the connotation,characteristics and content of implementing regional coordinated development strategy were analyzed.On this basis,from different aspects of industrial distribution,pollutant characteristics and regional environmental protection policy,the existing ecological and environmental protection problems in China s regional coordinated development in the new era were analyzed,and some suggestions for the next step were put forward.It is necessary to follow the"four ones"concept from the overall point of view,implement"three lines and one list"from the perspective of the width of the access red line,strengthen"joint prevention and control"from the perspective of the depth of regional regulation,deepen the"planning environmental impact assessment"from the perspective of the breadth of industrial distribution,and promote the"green-way model"from the perspective of ecological low carbon.展开更多
From the perspective of development background,concepts and related policies of ultra-low emission,according to work practice,some issues and difficulties that need to be paid attention to in the environmental impact ...From the perspective of development background,concepts and related policies of ultra-low emission,according to work practice,some issues and difficulties that need to be paid attention to in the environmental impact assessment of ultra-low-emission thermal power projects were discussed from the aspects of evaluation criteria,evaluation grade and scope,pollution control technical lines,environmental benefit accounting,and total emission control,and corresponding recommendations were put forward.展开更多
The three important historical development stages of China from"standing up","getting rich"to"becoming strong"were analyzed deeply.Regional coordinated development policies and strategies...The three important historical development stages of China from"standing up","getting rich"to"becoming strong"were analyzed deeply.Regional coordinated development policies and strategies have also gone through the"enlightenment stage","development stage"and"mature stage".On this basis,the problems of the coordination of China s regional coordinated development and joint prevention and control for environmental protection in the new era,as well as suggestions for the next step were further analyzed.展开更多
The emission of greenhouse gas generated by energy activity had the maximum influence on total emission. We introduced research content and method of inventory for greenhouse gas generated by energy activity in Jiangs...The emission of greenhouse gas generated by energy activity had the maximum influence on total emission. We introduced research content and method of inventory for greenhouse gas generated by energy activity in Jiangsu in 2005 and 2010, and obtained finial results. According to the sum of green gas emission from various parts, greenhouse gas emission of energy activity in Jiangsu occupied 76% -79% of total emission in 2005 and 2010. Meanwhile, the problems encountering in preparation process of inventory were summed and deeply analyzed, such as data ob- taining and processing, inconsistent statistical channel and actual measurement of emission factor. Finally, some suggestions about carrying out provincial greenhouse gas inventory work of energy activity in the future were put forward.展开更多
Based on a detailed analysis of China's current power installed capacity,power generation,power structure,as well as the world's power installed capacity,power generation,power structure,and power regional dis...Based on a detailed analysis of China's current power installed capacity,power generation,power structure,as well as the world's power installed capacity,power generation,power structure,and power regional distribution,some policy suggestions have been put forward through objective analysis and comparison.Firstly,power sectors in China should develop from high-speed growth to high-quality development,digest power excessive production capacity,control newly-added production capacity absolutely,and control the construction of power points orderly according to power planning.Secondly,non-fossil energy power generation needs to develop energetically,and should attach great importance to biomass power generation,in addition to gas power generation,wind power,and solar power.Lastly,on the basis of building a moderately prosperous society in all respects,electricity consumption per capita should be improved in the high-quality development stage in China,and the development of energy conservation and emission reduction,renewable energy,and distributed energy and so on should be considered collaboratively.展开更多
Since the atmospheric pollutants from thermal power plants account for a large proportion of the national total, knowing well the status of SO2 emissions of power industry is of great significance for making control s...Since the atmospheric pollutants from thermal power plants account for a large proportion of the national total, knowing well the status of SO2 emissions of power industry is of great significance for making control strategies and related environmental policies concerning SO2 and acid rain. Through introduction and analysis to some key links, such as the existing monitoring network, data sources, examining methods and procedures for statistic data and calculating methods of total national emissions, it is concluded that the data of SO2 emissions from the statistic database for power environment is reliable and can be a reference for decision-making both on power development and environmental protection.展开更多
The natural gas power generation(hereinafter referred to as gas power)industry is an important force in the development process of clean energy in China,and it not only plays an important role,but also faces many chal...The natural gas power generation(hereinafter referred to as gas power)industry is an important force in the development process of clean energy in China,and it not only plays an important role,but also faces many challenges in the process of transformation to low-carbon energy.In order to explore the sustainable development path of China's gas power industry in the process of low-carbon transformation,this paper studies the carbon emission intensity of gas power unit in different scenarios by taking GE's three mainstream types of gas turbine units(6F.03,9F.03 and 9HA.01)as examples,and then compares it with that of coal power unit in the same scenario based on industrial status and development trend.On this basis,the development path of gas power industry in the period of low-carbon transformation is proposed.And the following research results are obtained.First,the proposal of the time limit of carbon peak and carbon neutrality points out the goal and path of future lowcarbon transformation in China.As a kind of low-carbon clean energy,natural gas will play a more important role in the process of energy transformation in China.Second,compared with coal-fired power generation,gas power is much more advantageous in emission reduction,so the orderly development of gas-based cogeneration has good direct emission reduction effects.Third,as a kind of flexible power source,gas power provides good guarantee and promotion for the development of renewable energy sources and the active development of gas-powered peak-shaving power stations has a good effect of collaborative emission reduction.Fourth,moderately increasing the proportion of natural gas and gas power in energy consumption before carbon neutrality can effectively exert their collaborative emission reduction effects and generate collaborative emission reduction benefits,so as to optimize energy resource allocation and maximize social welfare.In conclusion,gas power is one of the important ways to utilize natural gas.展开更多
NH_(3)-SCR is an effective mean of NOxremoval in the non-electric industry, however, the high activation temperature and poor H_(2)O resistance of SCR catalysts posed a barrier to its application. In this work, a seri...NH_(3)-SCR is an effective mean of NOxremoval in the non-electric industry, however, the high activation temperature and poor H_(2)O resistance of SCR catalysts posed a barrier to its application. In this work, a series of three-dimensionally ordered macroporous(3DOM) catalysts were synthesized via a colloidal crystal template(CCT) method, and various characterizations were carried out to explore the physicochemical property of catalysts. The experiment results reveal that Ce_(0.2)Mn_(0.2)/3DOM-TiO_(2) catalyst presents the excellent low-temperature catalytic activity of nearly 100% at 100℃. Furthermore, the enhanced H_(2)O resistance is achieved, certified by the unaffected NO remove at 150℃ in the participation of 15 vol% H_(2)O. The characterizations results exhibit that the improved dispersion of the active component and enhanced redox ability are conducive to the low-temperature catalytic activity. N_(2) adsorption and desorption experiments indicate that catalyst with 3DOM support possesses a larger pore diameter and specific surface area, which may weaken the condensation of H_(2)O in the microporosity of catalysts and improved the H_(2)O resistance of the catalyst. In situ DRIFTS results manifest that Ce_(0.2)Mn_(0.2)/3DOM-TiO_(2) catalyst could not only absorb more NH_(3) and generate more surface-active sites, but inhibit the competitive adsorption between H_(2)O and SCR reactants.展开更多
In this study,a MnOx@TiO2 core‐shell catalyst prepared by a two‐step method was used for the low‐temperature selective catalytic reduction of NOx with NH3.The catalyst exhibits high activity,high stability,and exce...In this study,a MnOx@TiO2 core‐shell catalyst prepared by a two‐step method was used for the low‐temperature selective catalytic reduction of NOx with NH3.The catalyst exhibits high activity,high stability,and excellent N2 selectivity.Furthermore,it displays better SO2 and H2O tolerance than its MnOx,TiO2,and MnOx/TiO2 counterparts.The prepared catalyst was characterized systematically by transmission electron microscopy,high‐resolution transmission electron microscopy,X‐ray diffraction,Raman,BET,X‐ray photoelectron spectroscopy,NH3 temperature‐programmed desorption and H2 temperature‐programmed reduction analyses.The optimized MnOx@TiO2 catalyst exhibits an obvious core‐shell structure,where the TiO2 shell is evenly distributed over the MnOx nanorod core.The catalyst also presents abundant mesopores,Lewis‐acid sites,and high redox capability,all of which enhance its catalytic performance.According to the XPS results,the decrease in the number of Mn4+active centers after SO2 poisoning is significantly lower in MnOx@TiO2 than in MnOx/TiO2.The core‐shell structure is hence able to protect the catalytic active sites from H2O and SO2 poisoning.展开更多
Series of Mn/TiO2 catalysts modified with various contents of Nd for low-temperature SCR were synthesized.It can be found that the appropriate amount of Nd can markedly reduce the take-off temperature of Mn/TiO2 catal...Series of Mn/TiO2 catalysts modified with various contents of Nd for low-temperature SCR were synthesized.It can be found that the appropriate amount of Nd can markedly reduce the take-off temperature of Mn/TiO2 catalyst to 80℃and NOx conversion is stabilized over 90%in the wide temperature range of 100-2600 C.0.1 Nd-Mn/Ti shows higher N2 selectivity and better SO2 resistance than Mn/Ti catalyst.The results reveal that Nd-doped Mn/TiO2 catalyst exhibits larger BET surface area and better dispersion of active component Mn2O3.XPS results indicate that the optimal 0.1 Nd-Mn/Ti sample possesses higher concentration of Mn4+and larger amount of adsorbed oxygen at the surface compared with the unmodified counterpart.In situ DRIFTS show that the surface acidity is evidently increased after adding Nd,especially,the Lewis acid sites,and the intermediate(-NH2)is more stable.The reaction mechanism over Mn/Ti and 0.1 Nd-Mn/Ti catalysts obey the Eley-Rideal(E-R)mechanisms under low temperature reaction conditions.H2-TPR results show that Nd-Mn/TiO2 catalyst exhibits better lowtemperature redox properties.展开更多
Binary metal oxide（MnOx-A/TiO2）catalysts were prepared by adding the second metal to manganese oxides supported on titanium dioxide（TiO2）,where,A indicates Fe2O3,WO3,MoO3,and Cr2O3.Their catalytic activity,N2 sele...Binary metal oxide（MnOx-A/TiO2）catalysts were prepared by adding the second metal to manganese oxides supported on titanium dioxide（TiO2）,where,A indicates Fe2O3,WO3,MoO3,and Cr2O3.Their catalytic activity,N2 selectivity,and SO2 poisonous tolerance were investigated.The catalytic performance at low temperatures decreased in the following order：Mn-W/TiO2〉Mn-Fe/TiO2〉Mn-Cr/TiO2〉Mn-Mo/TiO2,whereas the N2 selectivity decreased in the order：Mn-Fe/TiO2〉Mn-W/TiO2〉Mn-Mo/TiO2〉Mn-Cr/TiO2.In the presence of 0.01%SO2 and 6%H2O,the NOx conversions in the presence of Mn-W/TiO2,Mn-Fe/TiO2,or Mn-Mo/TiO2 maintain 98.5%,95.8%and 94.2%, respectively,after 8 h at 120°C at GHSV 12600 h？ 1 .As effective promoters,WO3 and Fe2O3 can increase N2 selectivity and the resistance to SO2 of MnOx/TiO2 significantly.The Fourier transform infrared（FTIR）spectra of NH3 over WO3 show the presence of Lewis acid sites.The results suggest that WO3 is the best promoter of MnOx/TiO2,and Mn-W/TiO2 is one of the most active catalysts for the low temperature selective catalytic reduction of NO with NH3.展开更多
The performance of Mn-W/TiO2 for selective catalytic reduction（SCR） of NOx with NH3 and its resistance to different concentrations of SO2 at various temperatures were investigated. The results show that WO3 increase...The performance of Mn-W/TiO2 for selective catalytic reduction（SCR） of NOx with NH3 and its resistance to different concentrations of SO2 at various temperatures were investigated. The results show that WO3 increased the active sites and enhanced the strength of acid, so it was an effective promoter of MnOJTiO2. The NOx conversion on Mn-W/TiO2 ranges from 80.3% to 99.6% between 100 ℃to 350℃ at GHSV=18900 h 1, while N2 product selectivity changes from 100% to 98.7%. In the presence of 0.01% SO2 and 6% H20, NOx conversion maintained 98.5% at 120℃. The influence of more than 0.01% SO2 on the activity of MnOx-WO3/TiO2 will disappear if the temperature rises above 250℃. By means of heating and sweeping with He, the activity of the catalysts can be recovered. At 300℃, NOx conversion yielded 99% with 0.07% SO2 and reached the level of commercial V-W/TiO2 catalysts. The Mn-W/TiO2 catalyst showed excellent performance for SCR of NOx with NH3 in a wider range of temperature with strong tolerance to SO2.展开更多
A moist plume forms when the flue gas emitted from wet desulfurization equipment exits into the ambi- ent air, resulting in a waste of water resources and visual pollution. In addition, sulfur trioxide （SO3）, water ...A moist plume forms when the flue gas emitted from wet desulfurization equipment exits into the ambi- ent air, resulting in a waste of water resources and visual pollution. In addition, sulfur trioxide （SO3）, water with dissolved salts, and particles in the wet flue gas form secondary pollution in the surrounding atmosphere. In this study, a deep purification technology for flue gas involving phase-transition agglom- eration and dehumidification （PAD） is proposed. This deep purification technology includes two technical routes： the integrated technology of phase-transition agglomeration and a wet electrostatic precipitator （PAW）; and the integrated technology of phase-transition agglomeration and a mist eliminator （PAM）. Industrial applications of PAW and PAM were carried out on 630 and 1000 MW coal-fired units, respectively. The results show that the average amount of recycled water obtained from wet flue gas by means of PAD is more than 4 g.（kg.℃）-1 Decreasing the wet flue gas temperature by 1.5-5.3 ℃ allows 5%-20% of the moisture in the flue gas to be recycled; therefore, this process could effectively save water resources and significantly reduce water vapor emissions. In addition, the moist plume is effectively elim- inated. With the use of this process, the ion concentration in droplets of flue gas is decreased by more than 65%, the SO3 removal efficiency from flue gas is greater than 75%, and the removal efficiency of par- ticulate matter is 92.53%.展开更多
A two-dimensional numerical model is proposed to simulate the thermal discharge from a power plant in Jiangsu Province. The equations in the model consist of two-dimensional non-steady shallow water equations and ther...A two-dimensional numerical model is proposed to simulate the thermal discharge from a power plant in Jiangsu Province. The equations in the model consist of two-dimensional non-steady shallow water equations and thermal waste transport equations. Finite volume method （FVM） is used to discretize the shallow water equations, and flux difference splitting （FDS） scheme is applied. The calculated area with the same temperature increment shows the effect of thermal discharge on sea water. A comparison between simulated results and the experimental data shows good agreement. It indicates that this method can give high precision in the heat transfer simulation in coastal areas.展开更多
Since the implementation of the Action Plan for Air Pollution Prevention and Control , all regions of China have steadily promoted the prevention and control of air pollution and achieved results continuously. However...Since the implementation of the Action Plan for Air Pollution Prevention and Control , all regions of China have steadily promoted the prevention and control of air pollution and achieved results continuously. However, the atmospheric environment in key areas such as Beijing-Tianjin-Hebei region, the Yangtze River Delta region, and Fenwei Plain is still severe, and especially during the heating period heavy pollution occurs frequently, which has become the focus and difficulty of improving the quality of the atmospheric environment and is also the weakest link of China s air pollution control at present. How to alleviate air pollution, how to win the battle of pollution prevention and control, how to hold the fruits of the blue sky defense war, energy consumption is key.展开更多
Atmospheric particulate samples were collected from four densely populated places in a university,and then the concentration levels of indoor particulates were analyzed.Water-soluble cations and anions in the indoor p...Atmospheric particulate samples were collected from four densely populated places in a university,and then the concentration levels of indoor particulates were analyzed.Water-soluble cations and anions in the indoor particles were analyzed through ultrasonic extraction and ion chromatography(IC),and total organic carbon(TOC)content was analyzed by using a TOC analyzer.Organic compounds in the indoor particles were analyzed through ultrasonic extraction and GC-MS.The results showed that among the water-soluble ions,the mass concentration of SO2-4in indoor particles was the highest,so it was the main contributor of water-soluble anions,indicating that combustion of fossil fuels and industrial discharge were main sources of indoor particles at the four sampling points.Water-soluble organic carbon was the main component of water-soluble carbon in indoor particles.Among the four sampling points,the mass concentrations of the 18 organic compounds except for glycerol and phthalic acid were the highest in the cafeteria,so organic components in indoor atmospheric particles were mainly from food sources.展开更多
Using infrared sensors to detect ice clouds in different atmospheric layers is still a challenge.The different scattering and absorption properties of longwave and shortwave infrared channels can be utilized to fulfil...Using infrared sensors to detect ice clouds in different atmospheric layers is still a challenge.The different scattering and absorption properties of longwave and shortwave infrared channels can be utilized to fulfill this purpose.In this study,the release of Suomi-NPP Cross-track Infrared Sounder(Cr IS)full spectrum resolution is used to select and pair channels from longwave(~15μm)and shortwave(~4.3μm)CO2 absorption bands under stricter conditions,so as to better detect ice clouds.Besides,the differences of the weighting function peaks and cloud insensitive level altitudes of the paired channels are both within 50 h Pa so that the variances due to atmospheric conditions can be minimized.The training data of clear sky are determined by Visible Infrared Imaging Radiometer Suite(VIIRS)cloud mask product and used to find the linear relationship between the paired longwave and shortwave CO2 absorption channels.From the linear relationship,the so-called cloud emission and scattering index(CESI)is derived to detect ice clouds.CESI clearly captures the center and the ice cloud features of the Super Typhoon Hato located above 415 h Pa.Moreover,the CESI distributions agree with cloud top pressure from the VIIRS in both daytime and nighttime in different atmospheric layers.展开更多
基金Supported by the Special Project for Research on Technical Policies on Atmospheric Pollution Reduction in 2016 of Ministry of Environmenta Protection(2016A067)
文摘In the newly revised Environmental Protection Law of the People's Republic of China that has been implemented since January 1,2015,there is a lot of emphasis on environmental economic policies. In this paper,according to the current situation of environmental pollution and protection in thermal power industry,it is proposed that based on the new environmental protection law,it is needed to study various environmental economic policies on thermal power industry and analyze the effects on environmental cost of thermal power enterprises at the macro level. At the micro level,it is necessary to control environmental cost of thermal power enterprises effectively,and establish a suitable environmental management system for environmental economic policies including environmental cost accounting and trading of emission rights,thereby improving environmental management level of thermal power enterprises.
基金Supported by the Scientific Research Project of Environmental Protection Public Welfare Industry (201509021)
文摘Environmental problems like haze have brought great pressure to current environmental protection management. On the one hand, plan EIA should be promoted further in all industries; on the other hand, the current achievements and methods of plan EIA should be summarized and innovated. And the EIA supervision and project access can be improved further through the coordination between plan EIA and project EIA. In this study, from the three levels of plan EIA policy framework, five problems of plan EIA in power sector were analyzed according to the current situation of plan EIA in power sector. Based on the present achievements, five macroscopic suggestions were proposed from the view of innovation accord- ing to the new environmental protection situation and requirements at present.
基金Supported by the National Key Technology R&D Program(2012BAC20B1003)the Key National Social Science Fund Project(12&ZD214)the Special Fund Project for the Scientific Research of the Environmental Protection Welfare Industry(201209001)
文摘The planning environmental impact assessment （EIA） of transmission and transformation power grid at levels of 500 and 220 kV had been finished completely in the 13 municipalities of Jiangsu Province by the end of 2012, which played important roles in guiding and planning the following transmission and transformation projects in environmental protection. In this paper, through the detail analysis on the objective and significance of the planning EIA of transmission and transformation power grid, legal basis and planning EIA practices, some suggestions and thinking about the planning EIA of transmission and transformation power grid were put forward.
基金Supported by Special Project for Prevention and Control of Air Pollution from Fixed Sources of Ministry of Ecology and Environment,China(2020A060).
文摘Starting from the historical evolution of China s regional coordinated development policy and practice,three stages of"enlightenment stage","development stage"and"maturity stage",as well as the connotation,characteristics and content of implementing regional coordinated development strategy were analyzed.On this basis,from different aspects of industrial distribution,pollutant characteristics and regional environmental protection policy,the existing ecological and environmental protection problems in China s regional coordinated development in the new era were analyzed,and some suggestions for the next step were put forward.It is necessary to follow the"four ones"concept from the overall point of view,implement"three lines and one list"from the perspective of the width of the access red line,strengthen"joint prevention and control"from the perspective of the depth of regional regulation,deepen the"planning environmental impact assessment"from the perspective of the breadth of industrial distribution,and promote the"green-way model"from the perspective of ecological low carbon.
基金Supported by Special Project for Research on Prevention and Control of Air Pollution from Fire Coal in 2018 of Ministry of Ecology and Environment of the People’s Republic of China(2018A030)
文摘From the perspective of development background,concepts and related policies of ultra-low emission,according to work practice,some issues and difficulties that need to be paid attention to in the environmental impact assessment of ultra-low-emission thermal power projects were discussed from the aspects of evaluation criteria,evaluation grade and scope,pollution control technical lines,environmental benefit accounting,and total emission control,and corresponding recommendations were put forward.
基金Supported by National Key Research and Development Plan(2016YFC0208102)Special Project for Transformation of Scientific and Technological Achievements in Jiangsu Province(BA2020001)Special Project for Prevention and Control of Air Pollution from Fixed Sources of Ministry of Ecology and Environment,China in 2020(2020A060).
文摘The three important historical development stages of China from"standing up","getting rich"to"becoming strong"were analyzed deeply.Regional coordinated development policies and strategies have also gone through the"enlightenment stage","development stage"and"mature stage".On this basis,the problems of the coordination of China s regional coordinated development and joint prevention and control for environmental protection in the new era,as well as suggestions for the next step were further analyzed.
基金Supported by Clean Development Mechanism Fund Item of China(2012040)National Science and Technology Support Plan Project,China(2012BAC20B1003)
文摘The emission of greenhouse gas generated by energy activity had the maximum influence on total emission. We introduced research content and method of inventory for greenhouse gas generated by energy activity in Jiangsu in 2005 and 2010, and obtained finial results. According to the sum of green gas emission from various parts, greenhouse gas emission of energy activity in Jiangsu occupied 76% -79% of total emission in 2005 and 2010. Meanwhile, the problems encountering in preparation process of inventory were summed and deeply analyzed, such as data ob- taining and processing, inconsistent statistical channel and actual measurement of emission factor. Finally, some suggestions about carrying out provincial greenhouse gas inventory work of energy activity in the future were put forward.
文摘Based on a detailed analysis of China's current power installed capacity,power generation,power structure,as well as the world's power installed capacity,power generation,power structure,and power regional distribution,some policy suggestions have been put forward through objective analysis and comparison.Firstly,power sectors in China should develop from high-speed growth to high-quality development,digest power excessive production capacity,control newly-added production capacity absolutely,and control the construction of power points orderly according to power planning.Secondly,non-fossil energy power generation needs to develop energetically,and should attach great importance to biomass power generation,in addition to gas power generation,wind power,and solar power.Lastly,on the basis of building a moderately prosperous society in all respects,electricity consumption per capita should be improved in the high-quality development stage in China,and the development of energy conservation and emission reduction,renewable energy,and distributed energy and so on should be considered collaboratively.
文摘Since the atmospheric pollutants from thermal power plants account for a large proportion of the national total, knowing well the status of SO2 emissions of power industry is of great significance for making control strategies and related environmental policies concerning SO2 and acid rain. Through introduction and analysis to some key links, such as the existing monitoring network, data sources, examining methods and procedures for statistic data and calculating methods of total national emissions, it is concluded that the data of SO2 emissions from the statistic database for power environment is reliable and can be a reference for decision-making both on power development and environmental protection.
基金Project supported by the Scientific and Technological Innovation Project of China Energy Investment Corporation“Research on Clean Development and Index System”(No.:GJNY-20-110).
文摘The natural gas power generation(hereinafter referred to as gas power)industry is an important force in the development process of clean energy in China,and it not only plays an important role,but also faces many challenges in the process of transformation to low-carbon energy.In order to explore the sustainable development path of China's gas power industry in the process of low-carbon transformation,this paper studies the carbon emission intensity of gas power unit in different scenarios by taking GE's three mainstream types of gas turbine units(6F.03,9F.03 and 9HA.01)as examples,and then compares it with that of coal power unit in the same scenario based on industrial status and development trend.On this basis,the development path of gas power industry in the period of low-carbon transformation is proposed.And the following research results are obtained.First,the proposal of the time limit of carbon peak and carbon neutrality points out the goal and path of future lowcarbon transformation in China.As a kind of low-carbon clean energy,natural gas will play a more important role in the process of energy transformation in China.Second,compared with coal-fired power generation,gas power is much more advantageous in emission reduction,so the orderly development of gas-based cogeneration has good direct emission reduction effects.Third,as a kind of flexible power source,gas power provides good guarantee and promotion for the development of renewable energy sources and the active development of gas-powered peak-shaving power stations has a good effect of collaborative emission reduction.Fourth,moderately increasing the proportion of natural gas and gas power in energy consumption before carbon neutrality can effectively exert their collaborative emission reduction effects and generate collaborative emission reduction benefits,so as to optimize energy resource allocation and maximize social welfare.In conclusion,gas power is one of the important ways to utilize natural gas.
基金Project supported by National Key Research and Development Program of China(2021YFB3500601)。
文摘NH_(3)-SCR is an effective mean of NOxremoval in the non-electric industry, however, the high activation temperature and poor H_(2)O resistance of SCR catalysts posed a barrier to its application. In this work, a series of three-dimensionally ordered macroporous(3DOM) catalysts were synthesized via a colloidal crystal template(CCT) method, and various characterizations were carried out to explore the physicochemical property of catalysts. The experiment results reveal that Ce_(0.2)Mn_(0.2)/3DOM-TiO_(2) catalyst presents the excellent low-temperature catalytic activity of nearly 100% at 100℃. Furthermore, the enhanced H_(2)O resistance is achieved, certified by the unaffected NO remove at 150℃ in the participation of 15 vol% H_(2)O. The characterizations results exhibit that the improved dispersion of the active component and enhanced redox ability are conducive to the low-temperature catalytic activity. N_(2) adsorption and desorption experiments indicate that catalyst with 3DOM support possesses a larger pore diameter and specific surface area, which may weaken the condensation of H_(2)O in the microporosity of catalysts and improved the H_(2)O resistance of the catalyst. In situ DRIFTS results manifest that Ce_(0.2)Mn_(0.2)/3DOM-TiO_(2) catalyst could not only absorb more NH_(3) and generate more surface-active sites, but inhibit the competitive adsorption between H_(2)O and SCR reactants.
文摘In this study,a MnOx@TiO2 core‐shell catalyst prepared by a two‐step method was used for the low‐temperature selective catalytic reduction of NOx with NH3.The catalyst exhibits high activity,high stability,and excellent N2 selectivity.Furthermore,it displays better SO2 and H2O tolerance than its MnOx,TiO2,and MnOx/TiO2 counterparts.The prepared catalyst was characterized systematically by transmission electron microscopy,high‐resolution transmission electron microscopy,X‐ray diffraction,Raman,BET,X‐ray photoelectron spectroscopy,NH3 temperature‐programmed desorption and H2 temperature‐programmed reduction analyses.The optimized MnOx@TiO2 catalyst exhibits an obvious core‐shell structure,where the TiO2 shell is evenly distributed over the MnOx nanorod core.The catalyst also presents abundant mesopores,Lewis‐acid sites,and high redox capability,all of which enhance its catalytic performance.According to the XPS results,the decrease in the number of Mn4+active centers after SO2 poisoning is significantly lower in MnOx@TiO2 than in MnOx/TiO2.The core‐shell structure is hence able to protect the catalytic active sites from H2O and SO2 poisoning.
基金Project supported by the Key Research and Development Projects of Jiangsu Province(BE2017716)National Key R&D Program of China(2017YFB0603201)Environmental Nonprofit Industry Research subject(2016YFC0208102)。
文摘Series of Mn/TiO2 catalysts modified with various contents of Nd for low-temperature SCR were synthesized.It can be found that the appropriate amount of Nd can markedly reduce the take-off temperature of Mn/TiO2 catalyst to 80℃and NOx conversion is stabilized over 90%in the wide temperature range of 100-2600 C.0.1 Nd-Mn/Ti shows higher N2 selectivity and better SO2 resistance than Mn/Ti catalyst.The results reveal that Nd-doped Mn/TiO2 catalyst exhibits larger BET surface area and better dispersion of active component Mn2O3.XPS results indicate that the optimal 0.1 Nd-Mn/Ti sample possesses higher concentration of Mn4+and larger amount of adsorbed oxygen at the surface compared with the unmodified counterpart.In situ DRIFTS show that the surface acidity is evidently increased after adding Nd,especially,the Lewis acid sites,and the intermediate(-NH2)is more stable.The reaction mechanism over Mn/Ti and 0.1 Nd-Mn/Ti catalysts obey the Eley-Rideal(E-R)mechanisms under low temperature reaction conditions.H2-TPR results show that Nd-Mn/TiO2 catalyst exhibits better lowtemperature redox properties.
文摘Binary metal oxide（MnOx-A/TiO2）catalysts were prepared by adding the second metal to manganese oxides supported on titanium dioxide（TiO2）,where,A indicates Fe2O3,WO3,MoO3,and Cr2O3.Their catalytic activity,N2 selectivity,and SO2 poisonous tolerance were investigated.The catalytic performance at low temperatures decreased in the following order：Mn-W/TiO2〉Mn-Fe/TiO2〉Mn-Cr/TiO2〉Mn-Mo/TiO2,whereas the N2 selectivity decreased in the order：Mn-Fe/TiO2〉Mn-W/TiO2〉Mn-Mo/TiO2〉Mn-Cr/TiO2.In the presence of 0.01%SO2 and 6%H2O,the NOx conversions in the presence of Mn-W/TiO2,Mn-Fe/TiO2,or Mn-Mo/TiO2 maintain 98.5%,95.8%and 94.2%, respectively,after 8 h at 120°C at GHSV 12600 h？ 1 .As effective promoters,WO3 and Fe2O3 can increase N2 selectivity and the resistance to SO2 of MnOx/TiO2 significantly.The Fourier transform infrared（FTIR）spectra of NH3 over WO3 show the presence of Lewis acid sites.The results suggest that WO3 is the best promoter of MnOx/TiO2,and Mn-W/TiO2 is one of the most active catalysts for the low temperature selective catalytic reduction of NO with NH3.
文摘The performance of Mn-W/TiO2 for selective catalytic reduction（SCR） of NOx with NH3 and its resistance to different concentrations of SO2 at various temperatures were investigated. The results show that WO3 increased the active sites and enhanced the strength of acid, so it was an effective promoter of MnOJTiO2. The NOx conversion on Mn-W/TiO2 ranges from 80.3% to 99.6% between 100 ℃to 350℃ at GHSV=18900 h 1, while N2 product selectivity changes from 100% to 98.7%. In the presence of 0.01% SO2 and 6% H20, NOx conversion maintained 98.5% at 120℃. The influence of more than 0.01% SO2 on the activity of MnOx-WO3/TiO2 will disappear if the temperature rises above 250℃. By means of heating and sweeping with He, the activity of the catalysts can be recovered. At 300℃, NOx conversion yielded 99% with 0.07% SO2 and reached the level of commercial V-W/TiO2 catalysts. The Mn-W/TiO2 catalyst showed excellent performance for SCR of NOx with NH3 in a wider range of temperature with strong tolerance to SO2.
文摘A moist plume forms when the flue gas emitted from wet desulfurization equipment exits into the ambi- ent air, resulting in a waste of water resources and visual pollution. In addition, sulfur trioxide （SO3）, water with dissolved salts, and particles in the wet flue gas form secondary pollution in the surrounding atmosphere. In this study, a deep purification technology for flue gas involving phase-transition agglom- eration and dehumidification （PAD） is proposed. This deep purification technology includes two technical routes： the integrated technology of phase-transition agglomeration and a wet electrostatic precipitator （PAW）; and the integrated technology of phase-transition agglomeration and a mist eliminator （PAM）. Industrial applications of PAW and PAM were carried out on 630 and 1000 MW coal-fired units, respectively. The results show that the average amount of recycled water obtained from wet flue gas by means of PAD is more than 4 g.（kg.℃）-1 Decreasing the wet flue gas temperature by 1.5-5.3 ℃ allows 5%-20% of the moisture in the flue gas to be recycled; therefore, this process could effectively save water resources and significantly reduce water vapor emissions. In addition, the moist plume is effectively elim- inated. With the use of this process, the ion concentration in droplets of flue gas is decreased by more than 65%, the SO3 removal efficiency from flue gas is greater than 75%, and the removal efficiency of par- ticulate matter is 92.53%.
文摘A two-dimensional numerical model is proposed to simulate the thermal discharge from a power plant in Jiangsu Province. The equations in the model consist of two-dimensional non-steady shallow water equations and thermal waste transport equations. Finite volume method （FVM） is used to discretize the shallow water equations, and flux difference splitting （FDS） scheme is applied. The calculated area with the same temperature increment shows the effect of thermal discharge on sea water. A comparison between simulated results and the experimental data shows good agreement. It indicates that this method can give high precision in the heat transfer simulation in coastal areas.
基金Supported by Special Project for Research on Prevention and Control of Air Pollution from Fire Coal in 2018 of Ministry of Ecology and Environment of the People’s Republic of China(2018A030)National Natural Science Foundation of China(41771498)
文摘Since the implementation of the Action Plan for Air Pollution Prevention and Control , all regions of China have steadily promoted the prevention and control of air pollution and achieved results continuously. However, the atmospheric environment in key areas such as Beijing-Tianjin-Hebei region, the Yangtze River Delta region, and Fenwei Plain is still severe, and especially during the heating period heavy pollution occurs frequently, which has become the focus and difficulty of improving the quality of the atmospheric environment and is also the weakest link of China s air pollution control at present. How to alleviate air pollution, how to win the battle of pollution prevention and control, how to hold the fruits of the blue sky defense war, energy consumption is key.
文摘Atmospheric particulate samples were collected from four densely populated places in a university,and then the concentration levels of indoor particulates were analyzed.Water-soluble cations and anions in the indoor particles were analyzed through ultrasonic extraction and ion chromatography(IC),and total organic carbon(TOC)content was analyzed by using a TOC analyzer.Organic compounds in the indoor particles were analyzed through ultrasonic extraction and GC-MS.The results showed that among the water-soluble ions,the mass concentration of SO2-4in indoor particles was the highest,so it was the main contributor of water-soluble anions,indicating that combustion of fossil fuels and industrial discharge were main sources of indoor particles at the four sampling points.Water-soluble organic carbon was the main component of water-soluble carbon in indoor particles.Among the four sampling points,the mass concentrations of the 18 organic compounds except for glycerol and phthalic acid were the highest in the cafeteria,so organic components in indoor atmospheric particles were mainly from food sources.
基金National Key R&D Program(2018YFC1506904)Natural Science Foundation of China(41590873,41705089)。
文摘Using infrared sensors to detect ice clouds in different atmospheric layers is still a challenge.The different scattering and absorption properties of longwave and shortwave infrared channels can be utilized to fulfill this purpose.In this study,the release of Suomi-NPP Cross-track Infrared Sounder(Cr IS)full spectrum resolution is used to select and pair channels from longwave(~15μm)and shortwave(~4.3μm)CO2 absorption bands under stricter conditions,so as to better detect ice clouds.Besides,the differences of the weighting function peaks and cloud insensitive level altitudes of the paired channels are both within 50 h Pa so that the variances due to atmospheric conditions can be minimized.The training data of clear sky are determined by Visible Infrared Imaging Radiometer Suite(VIIRS)cloud mask product and used to find the linear relationship between the paired longwave and shortwave CO2 absorption channels.From the linear relationship,the so-called cloud emission and scattering index(CESI)is derived to detect ice clouds.CESI clearly captures the center and the ice cloud features of the Super Typhoon Hato located above 415 h Pa.Moreover,the CESI distributions agree with cloud top pressure from the VIIRS in both daytime and nighttime in different atmospheric layers.
