In this paper, an experimental study on SO2 removal by nanosecond rising edge pulse dielectric barrier discharge (DBD) plasma, generated by multi-needle-to-plane electrodes, is carried out. The mechanism of the effe...In this paper, an experimental study on SO2 removal by nanosecond rising edge pulse dielectric barrier discharge (DBD) plasma, generated by multi-needle-to-plane electrodes, is carried out. The mechanism of the effect of various factors, such as gap size between dielectric barrier and discharge needles, environmental humidity, and inlet speed of gas flow upon the removal efficiency of air purification is analyzed. The studies show that SOs removal efficiency improves with the increase in the gap size between dielectric barrier and discharge needles in the case of a fixed space between two electrodes, and also improves with the increase in the environmental humidity. For a mixed gas with a fixed concentration, there is an optimal inlet speed of gas flow, which leads to the best removal efficiency.展开更多
Nitrogen-containing heterocyclic compounds are important motifs of pharmaceuticals and functional materials, and there has been a growing interest in new synthetic methods for their preparations. In this paper, we rep...Nitrogen-containing heterocyclic compounds are important motifs of pharmaceuticals and functional materials, and there has been a growing interest in new synthetic methods for their preparations. In this paper, we report a direct cross-coupling reaction of indole with N-aryl tetrahydroisoquinolines in the presence of gold catalyst. The reaction is compatible with a wide range of substituted indoles, to enable the tbrmation of various alkylated heteroarenest, nder very mild reaction conditions.展开更多
In an effort to find highly efficient ligands for hepatic asialoglycoprotein receptor (ASGPR), four cluster galactosides with different scaffolds were synthesized in this paper. The affinity of these compounds for A...In an effort to find highly efficient ligands for hepatic asialoglycoprotein receptor (ASGPR), four cluster galactosides with different scaffolds were synthesized in this paper. The affinity of these compounds for ASGPR was analyzed by binding study in vitro. The results showed that trivalent cluster galactosides behaved better than divalent analogues and the cluster galactosides with aryl groups on their scaffolds presented better binding affinity than those with aliphatic chain scaffolds.展开更多
基金the National Science Foundation for Distinguished Young Scholars of China (No.50525722)the Science and Technology research key project of MOE
文摘In this paper, an experimental study on SO2 removal by nanosecond rising edge pulse dielectric barrier discharge (DBD) plasma, generated by multi-needle-to-plane electrodes, is carried out. The mechanism of the effect of various factors, such as gap size between dielectric barrier and discharge needles, environmental humidity, and inlet speed of gas flow upon the removal efficiency of air purification is analyzed. The studies show that SOs removal efficiency improves with the increase in the gap size between dielectric barrier and discharge needles in the case of a fixed space between two electrodes, and also improves with the increase in the environmental humidity. For a mixed gas with a fixed concentration, there is an optimal inlet speed of gas flow, which leads to the best removal efficiency.
文摘Nitrogen-containing heterocyclic compounds are important motifs of pharmaceuticals and functional materials, and there has been a growing interest in new synthetic methods for their preparations. In this paper, we report a direct cross-coupling reaction of indole with N-aryl tetrahydroisoquinolines in the presence of gold catalyst. The reaction is compatible with a wide range of substituted indoles, to enable the tbrmation of various alkylated heteroarenest, nder very mild reaction conditions.
基金Project supported by the Program for New Century Excellent Talents in University (No. NCET-04-0649) and the National Natural Science Foundation of China (No. 20475030).
文摘In an effort to find highly efficient ligands for hepatic asialoglycoprotein receptor (ASGPR), four cluster galactosides with different scaffolds were synthesized in this paper. The affinity of these compounds for ASGPR was analyzed by binding study in vitro. The results showed that trivalent cluster galactosides behaved better than divalent analogues and the cluster galactosides with aryl groups on their scaffolds presented better binding affinity than those with aliphatic chain scaffolds.