Quantum algorithms offer more enhanced computational efficiency in comparison to their classical counterparts when solving specific tasks.In this study,we implement the quantum permutation algorithm utilizing a polar ...Quantum algorithms offer more enhanced computational efficiency in comparison to their classical counterparts when solving specific tasks.In this study,we implement the quantum permutation algorithm utilizing a polar molecule within an external electric field.The selection of the molecular qutrit involves the utilization of field-dressed states generated through the pendular modes of SrO.Through the application of multi-target optimal control theory,we strategically design microwave pulses to execute logical operations,including Fourier transform,oracle U_(f)operation,and inverse Fourier transform within a three-level molecular qutrit structure.The observed high fidelity of our outcomes is intricately linked to the concept of the quantum speed limit,which quantifies the maximum speed of quantum state manipulation.Subsequently,we design the optimized pulse sequence to successfully simulate the quantum permutation algorithm on a single SrO molecule,achieving remarkable fidelity.Consequently,a quantum circuit comprising a single qutrit suffices to determine permutation parity with just a single function evaluation.Therefore,our results indicate that the optimal control theory can be well applied to the quantum computation of polar molecular systems.展开更多
LiCoO_(2)is an important category of active cathode materials in lithium-ion batteries due to its high compacted electrode density,good thermal stability,and stable voltage platform.Recent works on LiCoO_(2)have focus...LiCoO_(2)is an important category of active cathode materials in lithium-ion batteries due to its high compacted electrode density,good thermal stability,and stable voltage platform.Recent works on LiCoO_(2)have focused on the realization of higher charging voltages to fully utilize its high theoretical capacity.However,an unambiguous atomic-level local probe is essential for the understanding of structure-function correlation.Here we employ highresolution solid-state nuclear magnetic resonance(NMR)spectroscopy to study the local atomic environments in LiCoO_(2)synthesized with three common sintering methods.While one-dimensional 7Li NMR shows distinct linewidth and subtle dependence on lithium over-stoichiometry,both 7Li and 59Co relaxation times are highly dependent on the sintering method.We prove that the two-step sintering method favors the elimination of unreacted Co3O4,thereby enabling the best discharge capacity in all-solid-state lithium batteries assembled with LiCoO_(2)/LGPS/LiIn,which is in accordance with its narrowest 7Li linewidth and the longest 7Li/59Co T1.展开更多
To simultaneously improve the critical factors in photocatalytic H_(2)production,the population of active photogenerated electrons,the adsorption and activation of H_(2)O molecules,and the surface dehydrogenation effi...To simultaneously improve the critical factors in photocatalytic H_(2)production,the population of active photogenerated electrons,the adsorption and activation of H_(2)O molecules,and the surface dehydrogenation efficiency,we propose a synergistic strategy for TiO_(2)modification by combining transition metal(TM)doping and N-doped carbon(N-C)coating.The targeted Cr-TiO_(2)@N-C heterojunction exhibits dramatically enhanced H_(2)production under blue light irradiation,contrasting sharply with a negligible production by pristine TiO_(2).Comprehensive structural characterization and theoretical calculations confirm the uniform substitution of Cr into the TiO_(2)lattice,promoting the formation of adjacent oxygen vacancies(VO).The synergistic effect of Cr doping and VO extends the light absorption range into the visible region.The coated N-C layer facilitates the efficient separation of photogenerated charge carriers,boosting the population of active electrons.Critically,the combined action of VO and N-C layer enhances the adsorption and activation of H_(2)O molecules while effectively improving the subsequent surface dehydrogenation efficiency.Significantly,this strategy demonstrates broad universality:Analogous TM-TiO_(2)@N-C heterojunctions(TM=Mn,Co,Ni,Cu,and Zn)synthesized via the same approach all show substantially improved H_(2)production performance over pristine TiO_(2).展开更多
The modulation transfer spectroscopy in an ytterbium hollow cathode lamp at 399 nm is measured. The error signal for frequency locking is optimized by measuring the dependences of its slope, linewidth and magnitude on...The modulation transfer spectroscopy in an ytterbium hollow cathode lamp at 399 nm is measured. The error signal for frequency locking is optimized by measuring the dependences of its slope, linewidth and magnitude on various parameters. Under the optimum condition, the laser frequency at 399 nm can be stabilized. The long-term stability of laser frequency is measured by monitoring the fluorescence signal of the ytterbium atomic beam induced by the locked laser. The laser frequency is shown to be tightly locked, and the stabilized laser is successfully applied to the cooling of ytterbium atoms.展开更多
Using two tripartite Greenberger-Horne-Zeilinger （GHZ） states as the shared channels, we investigate the noise effects on the deterministic joint remote preparation of an arbitrary two-qubit state. By unitary matrix...Using two tripartite Greenberger-Horne-Zeilinger （GHZ） states as the shared channels, we investigate the noise effects on the deterministic joint remote preparation of an arbitrary two-qubit state. By unitary matrix decomposition procedure, we first construct the quantum logic circuit of the deterministic joint remote state preparation protocol. Then, we analytically derive the fidelity and the average fidelity for the deterministic joint remote preparation of an arbitrary two- qubit state and of four types of special two-qubit states under the influence of the Pauli noises. It is found that the fidelity depends on the noise types, the qubit-environment coupling strength, and the state to be remotely prepared. Moreover, even if the two GHZ channels are subject to the same environmental noises, the average fidelities for remotely preparing different two-qubit states display different time evolution behaviors. The remote preparation of the identical two-qubit states also shows that the average fidelities affected by different noisy environments exhibit different evolution actions.展开更多
We present the experimental study of modulation transfer spectroscopy of ytterbium atoms in a hollow cathode lamp.The dependences of its linewidth,slope and magnitude on the various experimental parameters are measure...We present the experimental study of modulation transfer spectroscopy of ytterbium atoms in a hollow cathode lamp.The dependences of its linewidth,slope and magnitude on the various experimental parameters are measured and fitted by the well-known theoretical expressions.The experimental results are in good agreement with the theoretical prediction.We have observed the Dicke narrowing effect by increasing the current of the hollow cathode lamp.It is also found that there are the optimal current and laser power to generate the better modulation transfer spectroscopy signal,which can be employed for locking the laser frequency to the atomic transition.展开更多
A distributed feedback laser with a wavelength of 2.8μm was used to measure the species produced by water vapor glow discharge.Only the absorption spectra of OH radicals and transient H2O molecules were observed usin...A distributed feedback laser with a wavelength of 2.8μm was used to measure the species produced by water vapor glow discharge.Only the absorption spectra of OH radicals and transient H2O molecules were observed using concentration modulation(CM)spectroscopy.The intensities and orientations of the absorption peaks change with the demodulation phase,but the direction of one absorption peak of H2O is always opposite to the other peaks.The different spectral orientations of OH and H2O reflect the increase or the decrease of the number of particles in the energy levels.If more transient species can be detected in the discharge process,the dynamics of excitation,ionization,and decomposition of H2O can be better studied.This study shows that the demodulation phase relationship of CM spectrum can be used to study the population change of molecular energy levels.展开更多
Filament-and plasma-grating-induced breakdown spectroscopy(F-GIBS)was demonstrated as an efficient technique for sensitive detection of metals in water,where plasma gratings were established through synchronized nonli...Filament-and plasma-grating-induced breakdown spectroscopy(F-GIBS)was demonstrated as an efficient technique for sensitive detection of metals in water,where plasma gratings were established through synchronized nonlinear interaction of two noncollinear filaments and an additional filament was generated with another fs laser beam propagating along their bisector.A water jet was constructed vertically to the three coplanar filaments,overcoming side effects from violent plasma explosion and bubble generation.Three distinct regimes of different mechanisms were validated for nonlinear couplings of the third filament with plasma gratings.As the third filament was temporally overlapped with the two noncollinear filaments in the interaction zone,all the three filaments participated in synchronous nonlinear interaction and plasma grating structures were altered by the addition of the third filament.As the third filament was positively or negatively delayed,the as-formed plasma gratings were elongated by the delayed third filament,or plasma gratings were formed in the presence of plasma expansion of the ahead third filament,respectively.Using F-GIBS for trace metal detection in water,significant spectral line enhancements were observed.展开更多
A near-resonant, red-detuning laser-assisted Stark deceleration scheme is proposed to slow CaF in its high-fieldseeking rovibronic ground state. The assisting Gaussian laser beam can confine CaF molecules transversely...A near-resonant, red-detuning laser-assisted Stark deceleration scheme is proposed to slow CaF in its high-fieldseeking rovibronic ground state. The assisting Gaussian laser beam can confine CaF molecules transversely owing to the optical Stark effect. Simulations suggest that the present scheme is superior to previous Stark decelerators. Under typical experimental conditions, when the assisting laser frequency is red-detuned to the molecular transition(λ～606.3 nm) by5.0 GHz and the laser power is about 5.6 W, the proposed decelerator can achieve a total number at the order of 10~4 CaF molecules with a number density at the order of 10~8 cm^(-3). The equivalent temperature of the obtained cold CaF molecules is 2.3 mK. Additionally, the desired assisting laser power can be as low as about 1.2 W if keeping the red-detuning value to be 1.0 GHz, which further suggests its experimental feasibility.展开更多
1,3,5-Triazine molecules represent a class of molecules that may have been prebiotic information carriers in a primordial soup in early Earth and their excited state dynamics has received attention in recent years.In ...1,3,5-Triazine molecules represent a class of molecules that may have been prebiotic information carriers in a primordial soup in early Earth and their excited state dynamics has received attention in recent years.In our previous study,one component with lifetime longer than100 ps was discovered in 2-amino-1,3,5-trainzine(2-AT),but its nature has not been revealed.In this study,excited state dynamics of 2-AT is studied in different solvents by using femtosecond time-resolved transient absorption and fluorescence upconversion spectroscopy.Interestingly,an equilibrium state consisting of the brightππ^(*)and dark nπ^(*)states in 2-AT is directly observed in aqueous solution and its dynamics is solvent sensitive.The whole picture of the excited state deactivation mechanism of 2-AT is proposed based on our spectroscopy results.展开更多
The localized surface plasmon resonance properties of Al and Alcore/Al2O3shell nanosphere dimers with Al and Al core nanosphere radii of 20 nm and Al2O3 shell of 2 nm in the deep-ultraviolet region have been studied u...The localized surface plasmon resonance properties of Al and Alcore/Al2O3shell nanosphere dimers with Al and Al core nanosphere radii of 20 nm and Al2O3 shell of 2 nm in the deep-ultraviolet region have been studied using the finite difference time domain method. The extinction spectra and the electric field distribution profiles of the two dimers for various gap distances between two individual nanospheres are compared with those of the corresponding monomers to reveal the extent of plasmon coupling. It is found that with the interparticle distance decreasing, a strong plasmon coupling between two Al or Alcore/Al2O3shell nanospheres is observed accompanied by a significant red shift in the extinction spectra at the parallel polarization direction of the incident light related to the dimer axis, while for the case of the perpendicular polarization direction, a weak plasmon coupling arises characterized by a slight blue shift in the extinction spectra. The electric field distribution profiles show that benefiting from the dielectric Al2O3 shell, the gap distance of Alcore/Al2O3shell nanosphere dimers can be tailored to 〈 1 nm scale and results in a very high electric field enhancement. The estimated surface-enhanced Raman scattering enhancement factors suggests that the Alcore/Al2O3shell nanosphere dimers with the gap of 〈 1 nm gave rise to an enhancement as high as 8.1 × 10^7 for interparticle gap = 0.5 nm. Our studies reveal that the Alcore/Al2O3shell nanosphere dimers may be promising substrates for surface-enhanced spectroscopy in the deep-ultraviolet region.展开更多
We investigate controlled teleportation ofa qubit via a GHZ state with the influence of phase damping in the Bloch sphere representation. We use the average trace distance to describe how close the output state is to ...We investigate controlled teleportation ofa qubit via a GHZ state with the influence of phase damping in the Bloch sphere representation. We use the average trace distance to describe how close the output state is to the input state to be teleported. Our results show that the average trace distance is a function of decoherence rates and angles of the analyzer performed by the controller in the single-particle projective measurement. Moreover, for a fixed value of the decoherence rate, one can adjust the analyzer angle to achieve the optimal average trace distance.展开更多
As one of the biological endogenous pigments,biliverdin(BV)and its dimethyl ester(BVE)have extremely weak uorescence in solution with quantum yield less than 0.01%.However,the situation reverses with the addition of z...As one of the biological endogenous pigments,biliverdin(BV)and its dimethyl ester(BVE)have extremely weak uorescence in solution with quantum yield less than 0.01%.However,the situation reverses with the addition of zinc ions.The strength for uorescence of BVE-Zn^2+ complex is greatly enhanced and uorescence quantum yield can increase to5%.Herein,we studied ultrafast excited state dynamics of BVE-Zn^2+ complex in ethanol,npropanol,and DMSO solutions in order to reveal the mechanism of uorescence quantum yield enhancement.The results show that BVE can form a stable coordination complex with zinc with 1:1 stoichiometry in solution.BVE is structurally and energetically more stable in the complex.Using picosecond time-resolve uorescence and femtosecond transient absorption spectroscopy,we show that smaller non-radiative rate constant of BVE-Zn^2+ complex in DMSO is the key to increasing its uorescence quantum yield and the excited state decay mechanism is also revealed.These results provide valuable information about the uorescence property change after BVE binding to metal ions and may provide a guidance for the study of phytochromes or other uorescence proteins in which BV/BVE acts as chromophores.展开更多
Analytical chemistry plays an important role in the qualitive and quantitative analysis for molecules in the various circumstances,especially for the high-resolution analysis.The dual-comb spectroscopy(DCS)technology ...Analytical chemistry plays an important role in the qualitive and quantitative analysis for molecules in the various circumstances,especially for the high-resolution analysis.The dual-comb spectroscopy(DCS)technology with the characteristics of high resolution,high sensitivity and instantaneous sampling exhibited a great potential in high-resolution in-situ spectral methods and has been active in the fields of spatial ranging,air composition analysis,reaction monitoring and so on.In this review,we will summarize the principle of DCS according to the different wavelength coverage and overview the applications of DCS in analytical chemistry.展开更多
Using a quantum channel consisting of a GHZ state exposed to noisy environment,we investigate how toremotely prepare an entangled state and a qubit state,respectively.By solving the master equation in the Lindbladform...Using a quantum channel consisting of a GHZ state exposed to noisy environment,we investigate how toremotely prepare an entangled state and a qubit state,respectively.By solving the master equation in the Lindbladform,the influence of the various types of noises on the GHZ state is first discussed.Then we use the fidelity to describehow close the remotely prepared state and the initial state are.Our results show that the fidelity is a function of thedecoherence rates and the angles of the initial state.It is found that for each of the two RSP schemes,the influence ofthe noise acting simultaneously in x,y,and z directions on the average fidelity is the strongest while the influence of thenoise acting in x or z direction on the average fidelity is relatively weaker.展开更多
We present an optical scheme to almost completely teleport a bipartite entangled coherent state using afour-partite cluster-type entangled coherent state as quantum channel.The scheme is based on optical elements such...We present an optical scheme to almost completely teleport a bipartite entangled coherent state using afour-partite cluster-type entangled coherent state as quantum channel.The scheme is based on optical elements suchas beam splitters,phase shifters,and photon detectors.We also obtain the average fidelity of the teleportation process.It is shown that the average fidelity is quite close to unity if the mean photon number of the coherent state is not toosmall.展开更多
We present a scheme for conclusive teleportation of an arbitrary and unknown three-particle state by per-forming three Bell-state measurements at the sender's side and a positive operator-valued measurement at the...We present a scheme for conclusive teleportation of an arbitrary and unknown three-particle state by per-forming three Bell-state measurements at the sender's side and a positive operator-valued measurement at the receiver'sside.Moreover,we obtain the successful probability of teleportation and make a brief discussion on the average fidelityfor the conclusive teleportation scheme.展开更多
Chirality hold broad applications in life sciences,quantum devices,and various other areas.Traditionally,molecular chirality can be characterized by using steady-state circular dichroism spectroscopy.However,the techn...Chirality hold broad applications in life sciences,quantum devices,and various other areas.Traditionally,molecular chirality can be characterized by using steady-state circular dichroism spectroscopy.However,the techniques that can characterize excited state chirality are progressively capturing the public interest as it can provide the dynamic information for chirality generation and transfer.In this review,we focus on the theoretical background and the developmental history of femtosecond time-resolved circular dichroism spectroscopy(TRCD)techniques around the world.Additionally,we provide examples to showcase the utility of these techniques in the analysis of the dynamical molecular chemical structures,the investigation of molecular chirality generation,and the detection of electron spin dynamics in semiconductor quantum dots.展开更多
We theoretically demonstrate that the(2+1)resonance-enhanced multiphoton-ionization(REMPI)photoelectron spectrum in a cesium(Cs)atom can be effectively manipulated by two time-delayed femtosecond laser pulses,involvin...We theoretically demonstrate that the(2+1)resonance-enhanced multiphoton-ionization(REMPI)photoelectron spectrum in a cesium(Cs)atom can be effectively manipulated by two time-delayed femtosecond laser pulses,involving its photoelectron spectral structure and photoelectron energy.We show that the photoelectron spectrum exhibits interference fringes and the fringe spacing is determined by the time delay of the two laser pulses,and the photoelectron energy is periodically modulated and the modulation period is determined by the two-photon transition frequency of the excited state.Finally,we utilize the power spectrum of the two time-delayed laser pulses and the two-photon transition probability of the excited state to respectively explain the modulations of the photoelectron spectrum and photoelectron energy.展开更多
Size-controlled flow synthesis of nanoporous particles are of considerable interest for future industrial applications,however,is facing challenges due to lack of in-situ method for size-characterization in fluidic en...Size-controlled flow synthesis of nanoporous particles are of considerable interest for future industrial applications,however,is facing challenges due to lack of in-situ method for size-characterization in fluidic environment.We present that ultraviolet-visible(UV-vis)absorption spectroscopy can be integrated into a flow-synthesis system which was produced by femtosecond laser micro machining.The shift of the absorption peak position of the ex-situ and in-situ UV-vis spectra correlates to variation of size of porous metal-organic frameworks crystals.ZIF-67 crystals with a size in the range from 200 nm to1025 nm are fabricated with the assistance of tri-ethylamine under monitoring of in-situ UV-vis spectra.The ZIF-67 crystals are converted into nanoporous carbons particles with controlled sizes.These materials show size-dependent performance in Na-ion battery and size-independent performance in metal/H_(2)O seawater battery.展开更多
基金supported by the National Natural Science Foundation of China under Grant Nos.92265209,11174081 and 62305285the Natural Science Foundation of Chongqing under Grant No.CSTB2024NSCQ-MSX0643the Shanghai Municipal Science and Technology Major Project under Grant No.2019SHZDZX01。
文摘Quantum algorithms offer more enhanced computational efficiency in comparison to their classical counterparts when solving specific tasks.In this study,we implement the quantum permutation algorithm utilizing a polar molecule within an external electric field.The selection of the molecular qutrit involves the utilization of field-dressed states generated through the pendular modes of SrO.Through the application of multi-target optimal control theory,we strategically design microwave pulses to execute logical operations,including Fourier transform,oracle U_(f)operation,and inverse Fourier transform within a three-level molecular qutrit structure.The observed high fidelity of our outcomes is intricately linked to the concept of the quantum speed limit,which quantifies the maximum speed of quantum state manipulation.Subsequently,we design the optimized pulse sequence to successfully simulate the quantum permutation algorithm on a single SrO molecule,achieving remarkable fidelity.Consequently,a quantum circuit comprising a single qutrit suffices to determine permutation parity with just a single function evaluation.Therefore,our results indicate that the optimal control theory can be well applied to the quantum computation of polar molecular systems.
基金supported by grants from the National Natural Science Foundation of China(Nos.22172049,21874045)Shanghai Science and Technology Innovation Action Plan(No.19142202900)+1 种基金Fundamental Research Funds for Central Universities and Open Foundation of ECNU(42125102)ECNU multifunctional platform for innovation(EPR).
文摘LiCoO_(2)is an important category of active cathode materials in lithium-ion batteries due to its high compacted electrode density,good thermal stability,and stable voltage platform.Recent works on LiCoO_(2)have focused on the realization of higher charging voltages to fully utilize its high theoretical capacity.However,an unambiguous atomic-level local probe is essential for the understanding of structure-function correlation.Here we employ highresolution solid-state nuclear magnetic resonance(NMR)spectroscopy to study the local atomic environments in LiCoO_(2)synthesized with three common sintering methods.While one-dimensional 7Li NMR shows distinct linewidth and subtle dependence on lithium over-stoichiometry,both 7Li and 59Co relaxation times are highly dependent on the sintering method.We prove that the two-step sintering method favors the elimination of unreacted Co3O4,thereby enabling the best discharge capacity in all-solid-state lithium batteries assembled with LiCoO_(2)/LGPS/LiIn,which is in accordance with its narrowest 7Li linewidth and the longest 7Li/59Co T1.
基金supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.24KJA150003)the Xuzhou Key Research and Development Program(Social Development)(No.KC23298)+1 种基金the National Natural Science Foundation of China(No.22271122)Basic Research Program of Jiangsu(No.BK20253049).
文摘To simultaneously improve the critical factors in photocatalytic H_(2)production,the population of active photogenerated electrons,the adsorption and activation of H_(2)O molecules,and the surface dehydrogenation efficiency,we propose a synergistic strategy for TiO_(2)modification by combining transition metal(TM)doping and N-doped carbon(N-C)coating.The targeted Cr-TiO_(2)@N-C heterojunction exhibits dramatically enhanced H_(2)production under blue light irradiation,contrasting sharply with a negligible production by pristine TiO_(2).Comprehensive structural characterization and theoretical calculations confirm the uniform substitution of Cr into the TiO_(2)lattice,promoting the formation of adjacent oxygen vacancies(VO).The synergistic effect of Cr doping and VO extends the light absorption range into the visible region.The coated N-C layer facilitates the efficient separation of photogenerated charge carriers,boosting the population of active electrons.Critically,the combined action of VO and N-C layer enhances the adsorption and activation of H_(2)O molecules while effectively improving the subsequent surface dehydrogenation efficiency.Significantly,this strategy demonstrates broad universality:Analogous TM-TiO_(2)@N-C heterojunctions(TM=Mn,Co,Ni,Cu,and Zn)synthesized via the same approach all show substantially improved H_(2)production performance over pristine TiO_(2).
基金Project supported by the National Natural Science Foundation of China(Grant No.10774044)the National Key Basic Research and Development Program of China(Grant No.2010CB922903)+1 种基金the Science and Technology Commission of Shanghai Municipality of China(Grant No.07JC14019)Shanghai Pujiang Talent Program of China(Grant No.07PJ14038)
文摘The modulation transfer spectroscopy in an ytterbium hollow cathode lamp at 399 nm is measured. The error signal for frequency locking is optimized by measuring the dependences of its slope, linewidth and magnitude on various parameters. Under the optimum condition, the laser frequency at 399 nm can be stabilized. The long-term stability of laser frequency is measured by monitoring the fluorescence signal of the ytterbium atomic beam induced by the locked laser. The laser frequency is shown to be tightly locked, and the stabilized laser is successfully applied to the cooling of ytterbium atoms.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.11174081,11034002,11104075,and 11134003)the National Basic Research Program of China (Grant Nos.2011CB921602 and 2012CB821302)the Open Fund from the SKLPS of ECNU
文摘Using two tripartite Greenberger-Horne-Zeilinger （GHZ） states as the shared channels, we investigate the noise effects on the deterministic joint remote preparation of an arbitrary two-qubit state. By unitary matrix decomposition procedure, we first construct the quantum logic circuit of the deterministic joint remote state preparation protocol. Then, we analytically derive the fidelity and the average fidelity for the deterministic joint remote preparation of an arbitrary two- qubit state and of four types of special two-qubit states under the influence of the Pauli noises. It is found that the fidelity depends on the noise types, the qubit-environment coupling strength, and the state to be remotely prepared. Moreover, even if the two GHZ channels are subject to the same environmental noises, the average fidelities for remotely preparing different two-qubit states display different time evolution behaviors. The remote preparation of the identical two-qubit states also shows that the average fidelities affected by different noisy environments exhibit different evolution actions.
基金Supported by the National Natural Science Foundation of China under Grant No 10774044the National Key Basic Research Program of China under Grant No 2010CB922903Shanghai Pujiang Talent Program under Grant No 07PJ14038.
文摘We present the experimental study of modulation transfer spectroscopy of ytterbium atoms in a hollow cathode lamp.The dependences of its linewidth,slope and magnitude on the various experimental parameters are measured and fitted by the well-known theoretical expressions.The experimental results are in good agreement with the theoretical prediction.We have observed the Dicke narrowing effect by increasing the current of the hollow cathode lamp.It is also found that there are the optimal current and laser power to generate the better modulation transfer spectroscopy signal,which can be employed for locking the laser frequency to the atomic transition.
基金the National Natural Science Foundation of China(No.61625501,No.61427816)the Open Fund of the State Key Laboratory of High Field Laser Physics(SIOM)the Open Fund of the State Key Laboratory of Precision Spectroscopy。
文摘A distributed feedback laser with a wavelength of 2.8μm was used to measure the species produced by water vapor glow discharge.Only the absorption spectra of OH radicals and transient H2O molecules were observed using concentration modulation(CM)spectroscopy.The intensities and orientations of the absorption peaks change with the demodulation phase,but the direction of one absorption peak of H2O is always opposite to the other peaks.The different spectral orientations of OH and H2O reflect the increase or the decrease of the number of particles in the energy levels.If more transient species can be detected in the discharge process,the dynamics of excitation,ionization,and decomposition of H2O can be better studied.This study shows that the demodulation phase relationship of CM spectrum can be used to study the population change of molecular energy levels.
基金sponsored by Shanghai Rising-Star Program(Grant No.22QC1401000)the National Defense Administration of Science,Technology and Industry(Grant No.HTKJ2021KL504014)+2 种基金the National Key Research and Development Program(Grant No.2018YFB0504400)the National Natural Science Foundation of China(Grant Nos.11621404,11727812,and 62035005)Shanghai Municipal Science and Technology Major Project(Grant No.2019SHZDZX01-ZX05).
文摘Filament-and plasma-grating-induced breakdown spectroscopy(F-GIBS)was demonstrated as an efficient technique for sensitive detection of metals in water,where plasma gratings were established through synchronized nonlinear interaction of two noncollinear filaments and an additional filament was generated with another fs laser beam propagating along their bisector.A water jet was constructed vertically to the three coplanar filaments,overcoming side effects from violent plasma explosion and bubble generation.Three distinct regimes of different mechanisms were validated for nonlinear couplings of the third filament with plasma gratings.As the third filament was temporally overlapped with the two noncollinear filaments in the interaction zone,all the three filaments participated in synchronous nonlinear interaction and plasma grating structures were altered by the addition of the third filament.As the third filament was positively or negatively delayed,the as-formed plasma gratings were elongated by the delayed third filament,or plasma gratings were formed in the presence of plasma expansion of the ahead third filament,respectively.Using F-GIBS for trace metal detection in water,significant spectral line enhancements were observed.
基金Project supported by the National Natural Science Foundation of China(Grant No.11604164)
文摘A near-resonant, red-detuning laser-assisted Stark deceleration scheme is proposed to slow CaF in its high-fieldseeking rovibronic ground state. The assisting Gaussian laser beam can confine CaF molecules transversely owing to the optical Stark effect. Simulations suggest that the present scheme is superior to previous Stark decelerators. Under typical experimental conditions, when the assisting laser frequency is red-detuned to the molecular transition(λ～606.3 nm) by5.0 GHz and the laser power is about 5.6 W, the proposed decelerator can achieve a total number at the order of 10~4 CaF molecules with a number density at the order of 10~8 cm^(-3). The equivalent temperature of the obtained cold CaF molecules is 2.3 mK. Additionally, the desired assisting laser power can be as low as about 1.2 W if keeping the red-detuning value to be 1.0 GHz, which further suggests its experimental feasibility.
基金supported by Shanghai Rising-Star Program(No.19QA1402800)。
文摘1,3,5-Triazine molecules represent a class of molecules that may have been prebiotic information carriers in a primordial soup in early Earth and their excited state dynamics has received attention in recent years.In our previous study,one component with lifetime longer than100 ps was discovered in 2-amino-1,3,5-trainzine(2-AT),but its nature has not been revealed.In this study,excited state dynamics of 2-AT is studied in different solvents by using femtosecond time-resolved transient absorption and fluorescence upconversion spectroscopy.Interestingly,an equilibrium state consisting of the brightππ^(*)and dark nπ^(*)states in 2-AT is directly observed in aqueous solution and its dynamics is solvent sensitive.The whole picture of the excited state deactivation mechanism of 2-AT is proposed based on our spectroscopy results.
基金supported by the National Natural Science Foundation of China(Grant Nos.11104079 and 61378033)the National Key Scientific Instrument Project of China(Grant No.2012YQ150092)+1 种基金the Research Foundation for the Doctoral Program of Higher Education of China(Grant No.20110076120019)the State Key Laboratory of Luminescent Materials and Devices at South China University of Technology
文摘The localized surface plasmon resonance properties of Al and Alcore/Al2O3shell nanosphere dimers with Al and Al core nanosphere radii of 20 nm and Al2O3 shell of 2 nm in the deep-ultraviolet region have been studied using the finite difference time domain method. The extinction spectra and the electric field distribution profiles of the two dimers for various gap distances between two individual nanospheres are compared with those of the corresponding monomers to reveal the extent of plasmon coupling. It is found that with the interparticle distance decreasing, a strong plasmon coupling between two Al or Alcore/Al2O3shell nanospheres is observed accompanied by a significant red shift in the extinction spectra at the parallel polarization direction of the incident light related to the dimer axis, while for the case of the perpendicular polarization direction, a weak plasmon coupling arises characterized by a slight blue shift in the extinction spectra. The electric field distribution profiles show that benefiting from the dielectric Al2O3 shell, the gap distance of Alcore/Al2O3shell nanosphere dimers can be tailored to 〈 1 nm scale and results in a very high electric field enhancement. The estimated surface-enhanced Raman scattering enhancement factors suggests that the Alcore/Al2O3shell nanosphere dimers with the gap of 〈 1 nm gave rise to an enhancement as high as 8.1 × 10^7 for interparticle gap = 0.5 nm. Our studies reveal that the Alcore/Al2O3shell nanosphere dimers may be promising substrates for surface-enhanced spectroscopy in the deep-ultraviolet region.
基金The project supported by the State Key Basic Research and Development Program of China under Grant No.2006CB921604National Natural Science Foundation of China under Grant Nos.60708003,60578050,and 10434060+1 种基金the Science Foundation of Shanghai Science and Technology Committee under Grant No.07JC14017the Director Fund of State Key Laboratory of Precision Spectroscopy
文摘We investigate controlled teleportation ofa qubit via a GHZ state with the influence of phase damping in the Bloch sphere representation. We use the average trace distance to describe how close the output state is to the input state to be teleported. Our results show that the average trace distance is a function of decoherence rates and angles of the analyzer performed by the controller in the single-particle projective measurement. Moreover, for a fixed value of the decoherence rate, one can adjust the analyzer angle to achieve the optimal average trace distance.
基金the National Nature Science Foundation of China(No.11674101,No.21873030 and No.91850202)。
文摘As one of the biological endogenous pigments,biliverdin(BV)and its dimethyl ester(BVE)have extremely weak uorescence in solution with quantum yield less than 0.01%.However,the situation reverses with the addition of zinc ions.The strength for uorescence of BVE-Zn^2+ complex is greatly enhanced and uorescence quantum yield can increase to5%.Herein,we studied ultrafast excited state dynamics of BVE-Zn^2+ complex in ethanol,npropanol,and DMSO solutions in order to reveal the mechanism of uorescence quantum yield enhancement.The results show that BVE can form a stable coordination complex with zinc with 1:1 stoichiometry in solution.BVE is structurally and energetically more stable in the complex.Using picosecond time-resolve uorescence and femtosecond transient absorption spectroscopy,we show that smaller non-radiative rate constant of BVE-Zn^2+ complex in DMSO is the key to increasing its uorescence quantum yield and the excited state decay mechanism is also revealed.These results provide valuable information about the uorescence property change after BVE binding to metal ions and may provide a guidance for the study of phytochromes or other uorescence proteins in which BV/BVE acts as chromophores.
基金financially supported by National Natural Science Foundation of China(No.21974030)Medical Engineering Fund of Fudan University(No.XM03211184)。
文摘Analytical chemistry plays an important role in the qualitive and quantitative analysis for molecules in the various circumstances,especially for the high-resolution analysis.The dual-comb spectroscopy(DCS)technology with the characteristics of high resolution,high sensitivity and instantaneous sampling exhibited a great potential in high-resolution in-situ spectral methods and has been active in the fields of spatial ranging,air composition analysis,reaction monitoring and so on.In this review,we will summarize the principle of DCS according to the different wavelength coverage and overview the applications of DCS in analytical chemistry.
基金National Natural Science Foundation of China under Grant Nos.60708003,60578050,and 10434060the State Key Basic Research Program of China under Grant No.2006CB921604+1 种基金the Shanghai Science and Technology Committee under Grant No.07JC14017the Director Fund of State Key Laboratory of Precision Spectroscopy
文摘Using a quantum channel consisting of a GHZ state exposed to noisy environment,we investigate how toremotely prepare an entangled state and a qubit state,respectively.By solving the master equation in the Lindbladform,the influence of the various types of noises on the GHZ state is first discussed.Then we use the fidelity to describehow close the remotely prepared state and the initial state are.Our results show that the fidelity is a function of thedecoherence rates and the angles of the initial state.It is found that for each of the two RSP schemes,the influence ofthe noise acting simultaneously in x,y,and z directions on the average fidelity is the strongest while the influence of thenoise acting in x or z direction on the average fidelity is relatively weaker.
基金Supported by the National Natural Science Foundation of China under Grant No.60708003the National Key Basic Research Program of China under Grant No.2006CB921604the Basic Key Program of Shanghai Municipality under Grant No.07JC14017
文摘We present an optical scheme to almost completely teleport a bipartite entangled coherent state using afour-partite cluster-type entangled coherent state as quantum channel.The scheme is based on optical elements suchas beam splitters,phase shifters,and photon detectors.We also obtain the average fidelity of the teleportation process.It is shown that the average fidelity is quite close to unity if the mean photon number of the coherent state is not toosmall.
基金the State Key Basic Research and Development Program of China under Grant No.2006CB921604National Natural Science Foundation of China under Grant Nos.60708003,60578050,and 10434060+1 种基金the Science Foundation of Shanghai Science and Technology Committee under Grant No.07JC14017the Director Fund of State Key Laboratory of Precision Spectroscopy
文摘We present a scheme for conclusive teleportation of an arbitrary and unknown three-particle state by per-forming three Bell-state measurements at the sender's side and a positive operator-valued measurement at the receiver'sside.Moreover,we obtain the successful probability of teleportation and make a brief discussion on the average fidelityfor the conclusive teleportation scheme.
基金funded by the National Natural Science Foundation of China(No.92156024and No.92356307 to Jinquan Chen)Menghui Jia thanks the Materials Characterization Center and the Office of Laboratory and Equipment of East China Normal University for funding support(ECNUETR2023-13).
文摘Chirality hold broad applications in life sciences,quantum devices,and various other areas.Traditionally,molecular chirality can be characterized by using steady-state circular dichroism spectroscopy.However,the techniques that can characterize excited state chirality are progressively capturing the public interest as it can provide the dynamic information for chirality generation and transfer.In this review,we focus on the theoretical background and the developmental history of femtosecond time-resolved circular dichroism spectroscopy(TRCD)techniques around the world.Additionally,we provide examples to showcase the utility of these techniques in the analysis of the dynamical molecular chemical structures,the investigation of molecular chirality generation,and the detection of electron spin dynamics in semiconductor quantum dots.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11004060,11027403 and 51132004the Shanghai Rising-Star Program(No 12QA1400900).
文摘We theoretically demonstrate that the(2+1)resonance-enhanced multiphoton-ionization(REMPI)photoelectron spectrum in a cesium(Cs)atom can be effectively manipulated by two time-delayed femtosecond laser pulses,involving its photoelectron spectral structure and photoelectron energy.We show that the photoelectron spectrum exhibits interference fringes and the fringe spacing is determined by the time delay of the two laser pulses,and the photoelectron energy is periodically modulated and the modulation period is determined by the two-photon transition frequency of the excited state.Finally,we utilize the power spectrum of the two time-delayed laser pulses and the two-photon transition probability of the excited state to respectively explain the modulations of the photoelectron spectrum and photoelectron energy.
基金supported by National Natural Science Foundation of China(Nos.11674340,21473059)Key Project of the Shanghai Science and Technology Committee(No.18DZ1112700)。
文摘Size-controlled flow synthesis of nanoporous particles are of considerable interest for future industrial applications,however,is facing challenges due to lack of in-situ method for size-characterization in fluidic environment.We present that ultraviolet-visible(UV-vis)absorption spectroscopy can be integrated into a flow-synthesis system which was produced by femtosecond laser micro machining.The shift of the absorption peak position of the ex-situ and in-situ UV-vis spectra correlates to variation of size of porous metal-organic frameworks crystals.ZIF-67 crystals with a size in the range from 200 nm to1025 nm are fabricated with the assistance of tri-ethylamine under monitoring of in-situ UV-vis spectra.The ZIF-67 crystals are converted into nanoporous carbons particles with controlled sizes.These materials show size-dependent performance in Na-ion battery and size-independent performance in metal/H_(2)O seawater battery.
