Friction stir additive manufacturing(FSAM)is an innovative additive manufacturing(AM)method.The various heat treatment conditions of aluminum-lithium alloys using this method have not been widely discussed.In this stu...Friction stir additive manufacturing(FSAM)is an innovative additive manufacturing(AM)method.The various heat treatment conditions of aluminum-lithium alloys using this method have not been widely discussed.In this study,the microstructure evolution and mechanical properties of FSAM 2195 aluminum-lithium alloy in different heat treatment conditions(T3 and T8)were investigated.The results demonstrated that the heat treatment state of 2195 Al-Li alloys was minimally influenced by FSAM as the FSAM temperature exceeded the solid solution temperature.After conducting a single-pass FSAM experiment,a notable grain refinement was observed in the nugget zone(NZ)region compared to the base material(BM).The average grain size of the 2195-T3 alloy decreased from 6.1 to 2.9µm,while the proportion of high-angle grain boundaries increased from 16.5%to 43.9%.Similarly,the average grain size of the 2195-T8 alloy decreased from 8.9 to 2.8µm,with an increase in high-angle grain boundary from 37.6%to 59.2%.The tensile strength of the 2195-T3 Al-Li alloy reached 466 and 478 MPa in the NZ of single-pass and lap experiments,respectively.In comparison,the tensile strength of the 2195-T8 Al-Li alloy in the NZ could reach 452 and 481 MPa in single-pass and lap experiments,respectively.These results demonstrate the significant improvements in microstructure and mechanical properties were achieved through the FSAM process.展开更多
Indium(In)has been used as a thermal interface material(TIM1)in high-performance central processing unit(CPU)for better heat dissipation.However,leakage or pump-out of liquid indium during the multiple reflow cycles l...Indium(In)has been used as a thermal interface material(TIM1)in high-performance central processing unit(CPU)for better heat dissipation.However,leakage or pump-out of liquid indium during the multiple reflow cycles limits its application in advanced flip chip ball gray array(FCBGA)packaging.Former researchers place a seal or dam structure to prevent In leakage,leading to the risk of In explosion,thermal degradation,or require additional keep-out zones.In this work,a copper foam(CF)matrix was embedded in In to absorb the liquid In and eliminate the leakage of In TIM1 during the multiple reflow cycles,as the CF capillary force.Au/Ni/Cu-Au/Ni/Cu joint was fabricated by soldering with the composite solder at 190℃for 2 min.After reflow cycles,good metallurgical bonding was formed at interfaces of joint.Rod-like Cu_(11)In_(9) formed at the CF and In interface,due to the re-dissolved of Cu_(11)In_(9) crystal.Small amount of Cu atoms from CF can reduce the activity of In,which inhibits the growth of Ni_(3)In_(7) intermetallic compound(IMC)at the interface of In and Au/Ni/Cu substrate.The CF matrix also improved the shear strength(22.9%)and thermal conductivity of the solder joints.Besides,the fracture behavior of solder joints without CF matrix was classified to be ductile type while that with CF matrix was changed to be ductile-brittle mixed type.展开更多
The asymmetric creep aging behaviors of a pre-treated Al-Zn-Mg-Cu alloy under high and low stresses have been investigated for high precision creep age forming application of aluminum integral panels.With the increase...The asymmetric creep aging behaviors of a pre-treated Al-Zn-Mg-Cu alloy under high and low stresses have been investigated for high precision creep age forming application of aluminum integral panels.With the increase of applied stress,the creep strains under the tensile stresses are higher than those of compressive stresses and the asymmetry of creep strain is more obvious.However,the mechanical properties of tensile stress creep aged samples are lower than those of compressive stress creep aged samples.Dislocation density,dislocation moving velocity and the proportion of precipitates directly lead to the asymmetry of creep strain and mechanical properties after tensile-compressive creep aging process.In addition,the tensile and compressive stresses have little effect on the width of the precipitate-free zone(PFZ).It indicates that in the high stress creep age forming process of the pretreated Al-Zn-Mg-Cu alloy,the tensile stress promotes the dislocation motion to obtain a better creep strain but weakens its mechanical properties compared with the compressive stress.In the field of civil aviation aircraft component manufacturing,the introduction of tension and compression stress asymmetry into the creep constitutive model may improve the accuracy of creep age forming components.展开更多
The analytical method based on "Hertz theory on normal contact of elastic solids" and the numerical method based on finite element method (FEM) calculating the contact stress of face-gear drive with spur inv...The analytical method based on "Hertz theory on normal contact of elastic solids" and the numerical method based on finite element method (FEM) calculating the contact stress of face-gear drive with spur involute pinion were introduced, and their relative errors are below 10%, except edge contact, which turns out that these two methods can compute contact stress of face-gear drive correctly and effectively. An agreement of the localized bearing contact stress is gotten for these two methods, making sure that the calculation results of FEM are reliable. The loaded meshing simulations of multi-tooth FEM model were developed, and the determination of the transmission error and the maximal load distribution factor of face-gear drive under torques were given. A formula for the maximal load distribution factor was proposed. By introducing the maximal load distribution factor in multi-tooth contact zone, a method for calculating the maximal contact stress in multi-tooth contact can be given. Compared to FEM, the results of these formulae are proved to be reliable, and the relative errors are below 10%.展开更多
Potassium ion batteries(PIBs)are regarded as one of promising low-cost energy storage technologies.Achieving long cycle life and high energy density has been considered as important tasks for developing high-performan...Potassium ion batteries(PIBs)are regarded as one of promising low-cost energy storage technologies.Achieving long cycle life and high energy density has been considered as important tasks for developing high-performance PIBs.The alloy-based anodes for PIBs have attracted great attentions because of their high theoretical capacity and relatively low operating voltage.In this review,the latest advance in the related alloy-based anodes was overviewed.Specifically,the correlations among the morphology and potassium storage performance,phase transition mechanisms,the formation of solid electrolyte interphases and ionic transport kinetics are critically discussed.It is expected that this review will provide meaningful guidance and possible pathways for the developments of alloy-based anodes for PIBs.展开更多
Creep aging behavior of retrogression and re-aged(RRAed)7150 aluminum alloy(AA7150)was systematically investigated using the creep aging experiments,mechanical properties tests,electrical conductivity tests and transm...Creep aging behavior of retrogression and re-aged(RRAed)7150 aluminum alloy(AA7150)was systematically investigated using the creep aging experiments,mechanical properties tests,electrical conductivity tests and transmission electron microscope(TEM)observations.Creep aging results show that the steady-state creep mechanism of RRAed alloys is mainly dislocation climb(stress exponent≈5.8),which is insensitive to the grain interior and boundary precipitates.However,the total creep deformation increases over the re-aging time.In addition,the yield strength and tensile strength of the four RRAed samples are essentially the same after creep aging at 140℃ for 16 h,but the elongation decreases slightly with the re-aging time.What’s more,the retrogression and re-aging treatment are beneficial to increase the hardness and electrical conductivity of the creep-aged 7150 aluminum alloy.It can be concluded that the retrogression and re-aging treatment before creep aging forming process can improve the microstructure within grain and at grain boundary,forming efficiency and comprehensive performance of mechanical properties and electrical conductivity of 7150 aluminum alloy.展开更多
Artificial ageing above 165℃directly after quenching induces the formation of^50 nm wide precipitatefree zone(PFZ)and^100 nm wide precipitate-sparse zone(PSZ)consisting of coarse precipitates with a gradient in size ...Artificial ageing above 165℃directly after quenching induces the formation of^50 nm wide precipitatefree zone(PFZ)and^100 nm wide precipitate-sparse zone(PSZ)consisting of coarse precipitates with a gradient in size and density toward the grain center in a commercial Al-Zn-Mg-Cu alloy.With the grain size decreasing,the fraction of PFZ and PSZ in a grain becomes larger and could even occupy the entire volume of the grain.This undesirable microstructure near the grain boundary is mitigated substantially by natural pre-ageing,leading to an exceptional enhancement of the age hardening potential at elevated temperatures.Natural ageing could fundamentally alter the precipitation near grain boundary,and is a promising method to optimize the precipitation hardening in high strength aluminum alloys with unconventionally small grains.展开更多
A complete mathematical model for logarithmic spiral type sprag one-way clutch design and analysis is given.It assumes that the motion of all clutch components can be expressed by a model of epicyclic gearing.It takes...A complete mathematical model for logarithmic spiral type sprag one-way clutch design and analysis is given.It assumes that the motion of all clutch components can be expressed by a model of epicyclic gearing.It takes advantage of Hunt-Crossley contact impact theory to calculate the contact forces between sprags and races,and it can be used for optimization of design and comparison with other types of sprag clutches.A good deal of analysis shows that the parameters of the steady windup angle,the steady contact force,the natural frequency and natural cycle of clutch have nothing to do with the initial velocity of outer race,while the parameters of the maximum transient windup angle,the maximum transient impact force and the steady engagement time increase linearly in the mode of engaging operation of clutch.It is also shown that the strut angle has great influence on the dynamic engagement performance of clutch.The parameters of the steady windup angle,the maximum transient windup angle,the steady engaging time,the steady contact force,the maximum transient impact force and the natural cycle of clutch decrease linearly nearly with the inner strut angle,while the natural frequency of the system increases linearly with the inner strut angle.展开更多
Studies show that the proper solid solution treatment(SST)is a key step in the precipitation strengthening of AA7150 Al alloy.Despite the superior characteristics of the fully dissolved phase,it has major drawbacks,in...Studies show that the proper solid solution treatment(SST)is a key step in the precipitation strengthening of AA7150 Al alloy.Despite the superior characteristics of the fully dissolved phase,it has major drawbacks,including high consumption of energy and low efficiency.Recently,electropulsing treatment(EPT)has been proposed to study dissolved precipitations and modify microstructures of AA7150 Al alloy faster than conventional SST.Experiments have been conducted in the present article,and the obtained results show that EPT can promote the rapid dissolution of theη’phase at relatively low temperatures in only 20 s.Meanwhile,the strength and ductility of electropulsed samples decrease drastically.Compared with conventional SST,EPT accelerates recrystallization and obtains relatively fine grains after 20 and 50 s electric pulses.Moreover,as the EPT time increases,the corresponding non-uniform local heating and the electron force promote dislocation generation and annihilation.展开更多
The influence of electropulsing on the creep behaviour,strength,and microstructure of an Al−Cu−Li alloy during creep ageing was investigated.Electropulsing assisted creep ageing(ECA)and conventional creep ageing(CCA)w...The influence of electropulsing on the creep behaviour,strength,and microstructure of an Al−Cu−Li alloy during creep ageing was investigated.Electropulsing assisted creep ageing(ECA)and conventional creep ageing(CCA)were carried out under various stress levels and time conditions.Applying electropulsing results in a noteworthy change of creep behaviour,including a variation in creep curves,an increased creep rate in early stage,and an improved creep strain.The ECA specimen experiences a shorter time to the peak strength,and an increase in elongation by~17.4% without loss of the peak-aged strength compared with CCA specimen.The ultrafine nano-size subgrains are observed to form under electropulsing,which can result in an increased creep strain by increasing grain-boundary sliding.The enhancement of both dislocation interactions and solute diffusion under electropulsing is considered as a primary cause of disappearance of a platform stage during early creep ageing.Some of T1 precipitates around the grain boundary are observed in the peak ECA sample,resulting in an occurrence of transgranular fracture,which is further responsible for an increased elongation of the ECA specimen.展开更多
A study was conducted to better understand how different parameters, namely, regression aging time and regression aging temperature, affect the creep aging properties, i.e., the creep deformation and performance of Al...A study was conducted to better understand how different parameters, namely, regression aging time and regression aging temperature, affect the creep aging properties, i.e., the creep deformation and performance of Al-Zn-MgCu alloy during regressive reaging. The corresponding creep strain and mechanical properties of samples were studied by conducting creep tests and uniaxial tensile tests. The electrical conductivity was measured using an eddy-current conductivity meter. The microstructures were observed by transmission electron microscopy(TEM). With the increase in regression aging time, the steady creep strain first increased and then decreased, and reached the maximum at 45 min.The steady creep strain increased with the increase in regression aging temperature, and reached the maximum at 200 ℃.The level of steady creep strain was determined by precipitation and dislocation recovery. Creep aging strengthens 7B50-RRA treated with regression aging time at 190 ℃ for 10 min, and the difference in the mechanical properties of alloy becomes smaller. The diffusion of solute atoms reduces the scattering of electrons, leading to a significant improvement in electrical conductivity and stress corrosion cracking(SCC) resistance after creep aging. The findings of this study could help in the application of creep aging forming(CAF) technology in Al-Zn-Mg-Cu alloy under RRA treatment.展开更多
The influence of Mg content on the microstructures and mechanical properties at room temperatures of A1-3.5Cu- （0.71-1.81）Mg alloys was studied. Precipitation phases in the alloys were identified by TEM and HRTEM. T...The influence of Mg content on the microstructures and mechanical properties at room temperatures of A1-3.5Cu- （0.71-1.81）Mg alloys was studied. Precipitation phases in the alloys were identified by TEM and HRTEM. The results show that when Mg contents increase from 0.71 to 1.81 wt%, the precipitates are transformed from S, S＂, 2, and 0 phases to S and St phases, and f2 phase is first observed in A1-3.48Cu-0.71 Mg alloy with Cu/Mg mass ratio of 5 during the conventional aging heat treatment （190 C/12 h）. Regard to aging hardness effect of the tested alloys, the hardness of the alloys improves with the increase of Mg content, but the increases become slow when Mg content is greater than 1.35 wt%.展开更多
Oxygen evolution reaction(OER) is admitted to an important half reaction in water splitting for sustainable hydrogen production.The sluggish four-electron process is known to be the bottleneck for enhancing the effici...Oxygen evolution reaction(OER) is admitted to an important half reaction in water splitting for sustainable hydrogen production.The sluggish four-electron process is known to be the bottleneck for enhancing the efficiency of OER.In this regard,tremendous efforts have been devoted to developing effective catalysts for OER.In addition to Ir-or Ru-based oxides taken as the benchmark,transition metal carbides have attracted ever-increasing interest due to the high activity and stability as low-cost OER electrocatalysts.In this review,the transition metal carbides for water oxidation electrocatalysis concerning design strategies and synthesis are briefly summarized.Some typical applications for various carbides are also highlighted.Besides,the development trends and outlook are also discussed.展开更多
Fiber metal laminates(FMLs),a kind of lightweight material with excellent comprehensive performance,have been successfully applied in aerospace.FMLs reinforced with carbon fiber have better mechanical properties than ...Fiber metal laminates(FMLs),a kind of lightweight material with excellent comprehensive performance,have been successfully applied in aerospace.FMLs reinforced with carbon fiber have better mechanical properties than those with glass or aramid fiber.However,carbon fiber binding metal may lead to galvanic corrosion which limits its application.In this paper,electrochemical methods,optical microscope and scanning electron microscope were used to analyze the corrosion evolution of carbon fiber reinforced aluminum laminate(CARALL)in corrosive environment and explore anti-corrosion ways to protect CARALL.The results show that the connection between carbon fiber and aluminum alloy changes electric potential,causing galvanic corrosion.The galvanic corrosion will obviously accelerate CARALL corroded in solution,leading to a 72.1%decrease in interlaminar shear strength,and the crevice corrosion has a greater impact on CARALL resulting in delamination.The reduction of interlaminar shear strength has a similar linear relationship with the corrosion time.In addition,the adhesive layers between carbon fiber and aluminum alloy cannot protect CARALL,while side edge protection can effectively slow down corrosion rate.Therefore,the exposed edges should be coated with anti-corrosion painting.CARALL has the potential to be used for aerospace components.展开更多
Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.Howe...Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.However,the as-built part usually exhibits undesirable microstructure and unsatisfactory performance.In this work,WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment.Although a high densification rate of 99.91%was achieved using suitable processes,the as-built parts exhibited anisotropic and layeredmicrostructure with heterogeneously precipitated Nd-rich intermetallic.After heat treatment,fine and nano-scaled Mg24Y5particles were precipitated.Meanwhile,theα-Mg grainsunderwent recrystallization and turned coarsened slightly,which effectively weakened thetexture intensity and reduced the anisotropy.As a consequence,the yield strength and ultimate tensile strength were significantly improved to(250.2±3.5)MPa and(312±3.7)MPa,respectively,while the elongation was still maintained at a high level of 15.2%.Furthermore,the homogenized microstructure reduced the tendency of localized corrosion and favoredthe development of uniform passivation film.Thus,the degradation rate of WE43 parts was decreased by an order of magnitude.Besides,in-vitro cell experiments proved their favorable biocompatibility.展开更多
Stress relaxation ageing behavior of pre-deformed AA2219 is studied through stress relaxation age experiments and finite element(FE)simulation.The results show that the stress can promote the process of ageing precipi...Stress relaxation ageing behavior of pre-deformed AA2219 is studied through stress relaxation age experiments and finite element(FE)simulation.The results show that the stress can promote the process of ageing precipitation,and shorten the time to reach the peak strength.Meanwhile,the residual stress and yield strength increase along with the increase in the initial stress.Based on microstructure evolution and ageing strengthening theory,a unified constitutive model is established and incorporated into the FE simulation model through a user subroutine.It is found that the relative error of the radius is 3.6%compared with the experimental result and the springback is 16.8%.This indicates that the proposed stress relaxation ageing constitutive model provides a good prediction on the springback of such stiffened panel during its ageing process.展开更多
The high-strength Al-Zn-Mg-Cu alloy provides much better dent resistance and weight-reduction potential compared to the conventional Al alloys used for the automobile body panels.However,natural ageing(NA)significantl...The high-strength Al-Zn-Mg-Cu alloy provides much better dent resistance and weight-reduction potential compared to the conventional Al alloys used for the automobile body panels.However,natural ageing(NA)significantly reduces the formability of Al-Zn-Mg-Cu alloy.The reversion of natural ageing has been systematically investigated by hardness test,tensile test,differential scanning calorimetry(DSC)and transmission electron microscopy(TEM).Substantial reversion of natural ageing and thus hardness decrease occurs immediately upon thermal treatment at 120–210℃in an Al-Zn-Mg-Cu alloy.Although the hardness of the most reverted state decreases with increasing temperature,the lowest hardness is still higher than the as-quenched state by 30 HV.As revealed by the complementary DSC and TEM observations,this is ascribed to the synchronization of the dissolution and the re-precipitation of the solutes in the NA clusters during reversion ageing.Reversion at 180–210℃for less than 30 s leads to a hardness decline of 40 HV.The hardening kinetics during NA after reversion is slower than that during first-time NA due to the reduced vacancy concentration.Artificial ageing at 180℃for 30 min after secondary NA of less than 24 h induces intensive precipitation of plate-like pre-ηphases and a giant strength increase of 188–204 MPa.Potential use of high strength Al-Zn-Mg-Cu alloy in automobile body panels could be realized by appropriate reversion treatment improving the formability and the quick bake hardening response.展开更多
The effect of temperature in range of 155-175 ℃ on the creep behavior, microstructural evolution, and precipitation of an Al-Cu-Li alloy was experimentally investigated during creep ageing deformation under 180 MPa f...The effect of temperature in range of 155-175 ℃ on the creep behavior, microstructural evolution, and precipitation of an Al-Cu-Li alloy was experimentally investigated during creep ageing deformation under 180 MPa for 20 h. Increasing temperature resulted in a noteworthy change in creep ageing behaviour, including a variation in creep curves, an improvement in creep rate during early creep ageing, and an increased creep strain. Tensile tests indicate that the specimen aged at higher temperature reached peak strength within a shorter time. Transmission electron microscopy(TEM) was employed to explore the effect of temperature on the microstructural evolution of the AA2198 during creep ageing deformation. Many larger dislocations and even tangled dislocation structures were observed in the sample aged at higher temperature. The number of T1 precipitates increased at higher ageing temperature at the same ageing time. Based on the analysed results, a new mechanism, considering the combined effects of the formation of larger dislocation structures induced by higher temperature and diffusion of solute atoms towards these larger or tangled dislocations, was proposed to explain the effect of temperature on microstructural evolution and creep behaviour.展开更多
A unified constitutive model is presented to predict the recently observed“multi-stage”creep behavior of Al−Li−S4 alloy.The corresponding microstructural variables related to the yield strength and creep deformation...A unified constitutive model is presented to predict the recently observed“multi-stage”creep behavior of Al−Li−S4 alloy.The corresponding microstructural variables related to the yield strength and creep deformation of the alloy during the creep ageing process,including dislocations and multiple precipitates,have been characterized in detail by X-ray diffraction(XRD)and transmission electron microscopy(TEM).For the yield strength,the model considers the multiphase strengthening behavior of the alloy based on strengthening mechanisms,which includes shearable T1 precipitate strengthening,non-shearable T1 precipitate strengthening andθ′precipitate strengthening.Based on creep deformation mechanism,the“multi-stage”creep behavior of the alloy is predicted by introducing the effects of interacting microstructural variables,including the radius of multiple precipitates,dislocation density and solute concentration,into the creep stress−strain model.It is concluded that the results calculated by the model are in a good agreement with the experimental data,which validates the proposed model.展开更多
基金Project(U22A20190)supported by International Science and Technology Cooperation under the National Natural Science Foundation of ChinaProjects(U2241248,52205379)supported by the National Natural Science Foundation of ChinaProject(BE2023026)supported by Jiangsu Provincial Key Research and Development Program and Nanjing Science and Technology Innovation Project for Overseas Scholars,China。
文摘Friction stir additive manufacturing(FSAM)is an innovative additive manufacturing(AM)method.The various heat treatment conditions of aluminum-lithium alloys using this method have not been widely discussed.In this study,the microstructure evolution and mechanical properties of FSAM 2195 aluminum-lithium alloy in different heat treatment conditions(T3 and T8)were investigated.The results demonstrated that the heat treatment state of 2195 Al-Li alloys was minimally influenced by FSAM as the FSAM temperature exceeded the solid solution temperature.After conducting a single-pass FSAM experiment,a notable grain refinement was observed in the nugget zone(NZ)region compared to the base material(BM).The average grain size of the 2195-T3 alloy decreased from 6.1 to 2.9µm,while the proportion of high-angle grain boundaries increased from 16.5%to 43.9%.Similarly,the average grain size of the 2195-T8 alloy decreased from 8.9 to 2.8µm,with an increase in high-angle grain boundary from 37.6%to 59.2%.The tensile strength of the 2195-T3 Al-Li alloy reached 466 and 478 MPa in the NZ of single-pass and lap experiments,respectively.In comparison,the tensile strength of the 2195-T8 Al-Li alloy in the NZ could reach 452 and 481 MPa in single-pass and lap experiments,respectively.These results demonstrate the significant improvements in microstructure and mechanical properties were achieved through the FSAM process.
基金Project(2023GK2063)supported by the Key R&D Program of Hunan Province,ChinaProject(2023GXGG006)supported by the Key Products in Manufacturing Industry of Hunan Province,ChinaProject(kq2102005)supported by Key Project of Science and Technology of Changsha,China。
文摘Indium(In)has been used as a thermal interface material(TIM1)in high-performance central processing unit(CPU)for better heat dissipation.However,leakage or pump-out of liquid indium during the multiple reflow cycles limits its application in advanced flip chip ball gray array(FCBGA)packaging.Former researchers place a seal or dam structure to prevent In leakage,leading to the risk of In explosion,thermal degradation,or require additional keep-out zones.In this work,a copper foam(CF)matrix was embedded in In to absorb the liquid In and eliminate the leakage of In TIM1 during the multiple reflow cycles,as the CF capillary force.Au/Ni/Cu-Au/Ni/Cu joint was fabricated by soldering with the composite solder at 190℃for 2 min.After reflow cycles,good metallurgical bonding was formed at interfaces of joint.Rod-like Cu_(11)In_(9) formed at the CF and In interface,due to the re-dissolved of Cu_(11)In_(9) crystal.Small amount of Cu atoms from CF can reduce the activity of In,which inhibits the growth of Ni_(3)In_(7) intermetallic compound(IMC)at the interface of In and Au/Ni/Cu substrate.The CF matrix also improved the shear strength(22.9%)and thermal conductivity of the solder joints.Besides,the fracture behavior of solder joints without CF matrix was classified to be ductile type while that with CF matrix was changed to be ductile-brittle mixed type.
基金Project(2021YFB3400900)supported by the National Key R&D Program of ChinaProjects(51905551,52205435)supported by the National Natural Science Foundation of China Youth Foundation+1 种基金Project(2022ZZTS0196)supported by the Fundamental Research Founds for the Central Universities,ChinaProject(CX20220282)supported by the Hunan Provincial Innovation Foundation for Postgraduate,China。
文摘The asymmetric creep aging behaviors of a pre-treated Al-Zn-Mg-Cu alloy under high and low stresses have been investigated for high precision creep age forming application of aluminum integral panels.With the increase of applied stress,the creep strains under the tensile stresses are higher than those of compressive stresses and the asymmetry of creep strain is more obvious.However,the mechanical properties of tensile stress creep aged samples are lower than those of compressive stress creep aged samples.Dislocation density,dislocation moving velocity and the proportion of precipitates directly lead to the asymmetry of creep strain and mechanical properties after tensile-compressive creep aging process.In addition,the tensile and compressive stresses have little effect on the width of the precipitate-free zone(PFZ).It indicates that in the high stress creep age forming process of the pretreated Al-Zn-Mg-Cu alloy,the tensile stress promotes the dislocation motion to obtain a better creep strain but weakens its mechanical properties compared with the compressive stress.In the field of civil aviation aircraft component manufacturing,the introduction of tension and compression stress asymmetry into the creep constitutive model may improve the accuracy of creep age forming components.
基金Project(50875263) supported by the National Natural Science Foundation of ChinaProject(2011CB706800) supported by the National Basic Research Program of ChinaProject(2010ssxt172) supported by the Natural Science Foundation of Hunan Province,China
文摘The analytical method based on "Hertz theory on normal contact of elastic solids" and the numerical method based on finite element method (FEM) calculating the contact stress of face-gear drive with spur involute pinion were introduced, and their relative errors are below 10%, except edge contact, which turns out that these two methods can compute contact stress of face-gear drive correctly and effectively. An agreement of the localized bearing contact stress is gotten for these two methods, making sure that the calculation results of FEM are reliable. The loaded meshing simulations of multi-tooth FEM model were developed, and the determination of the transmission error and the maximal load distribution factor of face-gear drive under torques were given. A formula for the maximal load distribution factor was proposed. By introducing the maximal load distribution factor in multi-tooth contact zone, a method for calculating the maximal contact stress in multi-tooth contact can be given. Compared to FEM, the results of these formulae are proved to be reliable, and the relative errors are below 10%.
基金financially supported by the National Natural Science Foundation of China(Nos.51302079 and 51702138)the Natural Science Foundation of Hunan Province(No.2017JJ1008)the Key Research and Development Program of Hunan Province of China(No.2018GK2031)。
文摘Potassium ion batteries(PIBs)are regarded as one of promising low-cost energy storage technologies.Achieving long cycle life and high energy density has been considered as important tasks for developing high-performance PIBs.The alloy-based anodes for PIBs have attracted great attentions because of their high theoretical capacity and relatively low operating voltage.In this review,the latest advance in the related alloy-based anodes was overviewed.Specifically,the correlations among the morphology and potassium storage performance,phase transition mechanisms,the formation of solid electrolyte interphases and ionic transport kinetics are critically discussed.It is expected that this review will provide meaningful guidance and possible pathways for the developments of alloy-based anodes for PIBs.
基金Project(2017YFB0306300)supported by the National Key Research and Development Program of ChinaProject(2017ZX04005001)supported by the National Science and Technology Major Project,China+2 种基金Project(JCKY2014203A001)supported by National Defense Program of ChinaProjects(51905551,51675538,51601060)supported by the National Natural Science Foundation of ChinaProjects(Kfkt2018-03,zzYJKT2019-11)supported by State Key Laboratory of High-Performance Complex Manufacturing,China。
文摘Creep aging behavior of retrogression and re-aged(RRAed)7150 aluminum alloy(AA7150)was systematically investigated using the creep aging experiments,mechanical properties tests,electrical conductivity tests and transmission electron microscope(TEM)observations.Creep aging results show that the steady-state creep mechanism of RRAed alloys is mainly dislocation climb(stress exponent≈5.8),which is insensitive to the grain interior and boundary precipitates.However,the total creep deformation increases over the re-aging time.In addition,the yield strength and tensile strength of the four RRAed samples are essentially the same after creep aging at 140℃ for 16 h,but the elongation decreases slightly with the re-aging time.What’s more,the retrogression and re-aging treatment are beneficial to increase the hardness and electrical conductivity of the creep-aged 7150 aluminum alloy.It can be concluded that the retrogression and re-aging treatment before creep aging forming process can improve the microstructure within grain and at grain boundary,forming efficiency and comprehensive performance of mechanical properties and electrical conductivity of 7150 aluminum alloy.
基金the National Natural Science Foundation of China(Nos.51601060,51675538 and 11872380)the Natural Science Foundation of Hunan Province(No.2018JJ3655)+3 种基金the National Key R&D Program of China(No.2017YFB0306300)the Innovation-driven Plan in Central South University(No.2015CX002)the Science and Technology Plan in Hunan Province(No.2016RS2015)the Fundamental Research Funds for the Central Universities of Central South University(No.2018zzts154)。
文摘Artificial ageing above 165℃directly after quenching induces the formation of^50 nm wide precipitatefree zone(PFZ)and^100 nm wide precipitate-sparse zone(PSZ)consisting of coarse precipitates with a gradient in size and density toward the grain center in a commercial Al-Zn-Mg-Cu alloy.With the grain size decreasing,the fraction of PFZ and PSZ in a grain becomes larger and could even occupy the entire volume of the grain.This undesirable microstructure near the grain boundary is mitigated substantially by natural pre-ageing,leading to an exceptional enhancement of the age hardening potential at elevated temperatures.Natural ageing could fundamentally alter the precipitation near grain boundary,and is a promising method to optimize the precipitation hardening in high strength aluminum alloys with unconventionally small grains.
基金Project(2011CB706800)supported by the National Basic Research Program of China
文摘A complete mathematical model for logarithmic spiral type sprag one-way clutch design and analysis is given.It assumes that the motion of all clutch components can be expressed by a model of epicyclic gearing.It takes advantage of Hunt-Crossley contact impact theory to calculate the contact forces between sprags and races,and it can be used for optimization of design and comparison with other types of sprag clutches.A good deal of analysis shows that the parameters of the steady windup angle,the steady contact force,the natural frequency and natural cycle of clutch have nothing to do with the initial velocity of outer race,while the parameters of the maximum transient windup angle,the maximum transient impact force and the steady engagement time increase linearly in the mode of engaging operation of clutch.It is also shown that the strut angle has great influence on the dynamic engagement performance of clutch.The parameters of the steady windup angle,the maximum transient windup angle,the steady engaging time,the steady contact force,the maximum transient impact force and the natural cycle of clutch decrease linearly nearly with the inner strut angle,while the natural frequency of the system increases linearly with the inner strut angle.
基金financially supported by the Fundamental Research Funds for the National Key R&D Program of China(No.2017YFB0306300)the Hunan Provincial Innovation Foundation for Postgraduate(No.CX20200185)+1 种基金the Fundamental Research Funds for the Central Universities of Central South University(No.2020zzts098)the National Natural Science Foundation of China(Nos.19055551,51675538 and 51601060)。
文摘Studies show that the proper solid solution treatment(SST)is a key step in the precipitation strengthening of AA7150 Al alloy.Despite the superior characteristics of the fully dissolved phase,it has major drawbacks,including high consumption of energy and low efficiency.Recently,electropulsing treatment(EPT)has been proposed to study dissolved precipitations and modify microstructures of AA7150 Al alloy faster than conventional SST.Experiments have been conducted in the present article,and the obtained results show that EPT can promote the rapid dissolution of theη’phase at relatively low temperatures in only 20 s.Meanwhile,the strength and ductility of electropulsed samples decrease drastically.Compared with conventional SST,EPT accelerates recrystallization and obtains relatively fine grains after 20 and 50 s electric pulses.Moreover,as the EPT time increases,the corresponding non-uniform local heating and the electron force promote dislocation generation and annihilation.
基金the financial supports by the National Key R&D Program of China(No.2017YFB0306300)the National Natural Science Foundation of China(Nos.51601060,51675538).
文摘The influence of electropulsing on the creep behaviour,strength,and microstructure of an Al−Cu−Li alloy during creep ageing was investigated.Electropulsing assisted creep ageing(ECA)and conventional creep ageing(CCA)were carried out under various stress levels and time conditions.Applying electropulsing results in a noteworthy change of creep behaviour,including a variation in creep curves,an increased creep rate in early stage,and an improved creep strain.The ECA specimen experiences a shorter time to the peak strength,and an increase in elongation by~17.4% without loss of the peak-aged strength compared with CCA specimen.The ultrafine nano-size subgrains are observed to form under electropulsing,which can result in an increased creep strain by increasing grain-boundary sliding.The enhancement of both dislocation interactions and solute diffusion under electropulsing is considered as a primary cause of disappearance of a platform stage during early creep ageing.Some of T1 precipitates around the grain boundary are observed in the peak ECA sample,resulting in an occurrence of transgranular fracture,which is further responsible for an increased elongation of the ECA specimen.
基金Project(2017YFB0306300) supported by the National key R&D Program of ChinaProjects(51675538, 51905551)supported by the National Natural Science Foundation of ChinaProject(ZZYJKT2019-11) supported by Free Exploration Project of State Key Laboratory of High performance Complex Manufacturing,China。
文摘A study was conducted to better understand how different parameters, namely, regression aging time and regression aging temperature, affect the creep aging properties, i.e., the creep deformation and performance of Al-Zn-MgCu alloy during regressive reaging. The corresponding creep strain and mechanical properties of samples were studied by conducting creep tests and uniaxial tensile tests. The electrical conductivity was measured using an eddy-current conductivity meter. The microstructures were observed by transmission electron microscopy(TEM). With the increase in regression aging time, the steady creep strain first increased and then decreased, and reached the maximum at 45 min.The steady creep strain increased with the increase in regression aging temperature, and reached the maximum at 200 ℃.The level of steady creep strain was determined by precipitation and dislocation recovery. Creep aging strengthens 7B50-RRA treated with regression aging time at 190 ℃ for 10 min, and the difference in the mechanical properties of alloy becomes smaller. The diffusion of solute atoms reduces the scattering of electrons, leading to a significant improvement in electrical conductivity and stress corrosion cracking(SCC) resistance after creep aging. The findings of this study could help in the application of creep aging forming(CAF) technology in Al-Zn-Mg-Cu alloy under RRA treatment.
基金financially supported by the National Basic Research Program of China(Nos.2012CB619500 and 2010CB731700)the National Natural Science Foundation of China(No.51375503)
文摘The influence of Mg content on the microstructures and mechanical properties at room temperatures of A1-3.5Cu- （0.71-1.81）Mg alloys was studied. Precipitation phases in the alloys were identified by TEM and HRTEM. The results show that when Mg contents increase from 0.71 to 1.81 wt%, the precipitates are transformed from S, S＂, 2, and 0 phases to S and St phases, and f2 phase is first observed in A1-3.48Cu-0.71 Mg alloy with Cu/Mg mass ratio of 5 during the conventional aging heat treatment （190 C/12 h）. Regard to aging hardness effect of the tested alloys, the hardness of the alloys improves with the increase of Mg content, but the increases become slow when Mg content is greater than 1.35 wt%.
基金supported by the National Natural Science Foundation of China(Nos.51302079,51702138)the Natural Science Foundation of Hunan Province(No.2017JJ1008)the Key Research and Development Program of Hunan Province of China(No.2018GK2031)。
文摘Oxygen evolution reaction(OER) is admitted to an important half reaction in water splitting for sustainable hydrogen production.The sluggish four-electron process is known to be the bottleneck for enhancing the efficiency of OER.In this regard,tremendous efforts have been devoted to developing effective catalysts for OER.In addition to Ir-or Ru-based oxides taken as the benchmark,transition metal carbides have attracted ever-increasing interest due to the high activity and stability as low-cost OER electrocatalysts.In this review,the transition metal carbides for water oxidation electrocatalysis concerning design strategies and synthesis are briefly summarized.Some typical applications for various carbides are also highlighted.Besides,the development trends and outlook are also discussed.
基金Project(51675538)supported by the National Natural Science Foundation of China。
文摘Fiber metal laminates(FMLs),a kind of lightweight material with excellent comprehensive performance,have been successfully applied in aerospace.FMLs reinforced with carbon fiber have better mechanical properties than those with glass or aramid fiber.However,carbon fiber binding metal may lead to galvanic corrosion which limits its application.In this paper,electrochemical methods,optical microscope and scanning electron microscope were used to analyze the corrosion evolution of carbon fiber reinforced aluminum laminate(CARALL)in corrosive environment and explore anti-corrosion ways to protect CARALL.The results show that the connection between carbon fiber and aluminum alloy changes electric potential,causing galvanic corrosion.The galvanic corrosion will obviously accelerate CARALL corroded in solution,leading to a 72.1%decrease in interlaminar shear strength,and the crevice corrosion has a greater impact on CARALL resulting in delamination.The reduction of interlaminar shear strength has a similar linear relationship with the corrosion time.In addition,the adhesive layers between carbon fiber and aluminum alloy cannot protect CARALL,while side edge protection can effectively slow down corrosion rate.Therefore,the exposed edges should be coated with anti-corrosion painting.CARALL has the potential to be used for aerospace components.
基金supported by the following funds:National Natural Science Foundation of China(51935014,52165043)Jiangxi Provincial Cultivation Program for Academic and Technical Leaders of Major Subjects(20225BCJ23008)+1 种基金Jiangxi Provincial Natural Science Foundation(20224ACB204013,20224ACB214008)Scientific Research Project of Anhui Universities(KJ2021A1106)。
文摘Magnesium(Mg)alloys are considered to be a new generation of revolutionary medical metals.Laser-beam powder bed fusion(PBF-LB)is suitable for fabricating metal implants withpersonalized and complicated structures.However,the as-built part usually exhibits undesirable microstructure and unsatisfactory performance.In this work,WE43 parts were firstly fabricated by PBF-LB and then subjected to heat treatment.Although a high densification rate of 99.91%was achieved using suitable processes,the as-built parts exhibited anisotropic and layeredmicrostructure with heterogeneously precipitated Nd-rich intermetallic.After heat treatment,fine and nano-scaled Mg24Y5particles were precipitated.Meanwhile,theα-Mg grainsunderwent recrystallization and turned coarsened slightly,which effectively weakened thetexture intensity and reduced the anisotropy.As a consequence,the yield strength and ultimate tensile strength were significantly improved to(250.2±3.5)MPa and(312±3.7)MPa,respectively,while the elongation was still maintained at a high level of 15.2%.Furthermore,the homogenized microstructure reduced the tendency of localized corrosion and favoredthe development of uniform passivation film.Thus,the degradation rate of WE43 parts was decreased by an order of magnitude.Besides,in-vitro cell experiments proved their favorable biocompatibility.
基金Project(2017YFB0306300)supported by the National Key Research and Development Program of ChinaProject(2014CB046602)supported by the National Basic Research Program of China+1 种基金Project(20120162110003)supported by Specialized Research Fund for the Doctoral Program of Higher Education of ChinaProject(51235010)supported by the National Natural Science Foundation of China
文摘Stress relaxation ageing behavior of pre-deformed AA2219 is studied through stress relaxation age experiments and finite element(FE)simulation.The results show that the stress can promote the process of ageing precipitation,and shorten the time to reach the peak strength.Meanwhile,the residual stress and yield strength increase along with the increase in the initial stress.Based on microstructure evolution and ageing strengthening theory,a unified constitutive model is established and incorporated into the FE simulation model through a user subroutine.It is found that the relative error of the radius is 3.6%compared with the experimental result and the springback is 16.8%.This indicates that the proposed stress relaxation ageing constitutive model provides a good prediction on the springback of such stiffened panel during its ageing process.
基金financial support from National Natural Science Foundation of China(Nos.U2032117,51675538,11872380)the National Key R&D Program of China(No.2017YFB0306300)+3 种基金Natural Science Foundation of Hunan Province(No.2018JJ3655)National Science and Technology Major Project(No.2017ZX04005001)the Fundamental Research Funds for the Central Universities of Central South University(2021zzts0638)the Innovation fund of National commercial aircraft manufacturing engineering technology centre(No.COMAC-SFGS-2019-4284)。
文摘The high-strength Al-Zn-Mg-Cu alloy provides much better dent resistance and weight-reduction potential compared to the conventional Al alloys used for the automobile body panels.However,natural ageing(NA)significantly reduces the formability of Al-Zn-Mg-Cu alloy.The reversion of natural ageing has been systematically investigated by hardness test,tensile test,differential scanning calorimetry(DSC)and transmission electron microscopy(TEM).Substantial reversion of natural ageing and thus hardness decrease occurs immediately upon thermal treatment at 120–210℃in an Al-Zn-Mg-Cu alloy.Although the hardness of the most reverted state decreases with increasing temperature,the lowest hardness is still higher than the as-quenched state by 30 HV.As revealed by the complementary DSC and TEM observations,this is ascribed to the synchronization of the dissolution and the re-precipitation of the solutes in the NA clusters during reversion ageing.Reversion at 180–210℃for less than 30 s leads to a hardness decline of 40 HV.The hardening kinetics during NA after reversion is slower than that during first-time NA due to the reduced vacancy concentration.Artificial ageing at 180℃for 30 min after secondary NA of less than 24 h induces intensive precipitation of plate-like pre-ηphases and a giant strength increase of 188–204 MPa.Potential use of high strength Al-Zn-Mg-Cu alloy in automobile body panels could be realized by appropriate reversion treatment improving the formability and the quick bake hardening response.
基金Project(2017YFB0306300)supported by the National Key R&D Program of ChinaProjects(51601060,51675538)supported by the National Natural Science Foundation of China。
文摘The effect of temperature in range of 155-175 ℃ on the creep behavior, microstructural evolution, and precipitation of an Al-Cu-Li alloy was experimentally investigated during creep ageing deformation under 180 MPa for 20 h. Increasing temperature resulted in a noteworthy change in creep ageing behaviour, including a variation in creep curves, an improvement in creep rate during early creep ageing, and an increased creep strain. Tensile tests indicate that the specimen aged at higher temperature reached peak strength within a shorter time. Transmission electron microscopy(TEM) was employed to explore the effect of temperature on the microstructural evolution of the AA2198 during creep ageing deformation. Many larger dislocations and even tangled dislocation structures were observed in the sample aged at higher temperature. The number of T1 precipitates increased at higher ageing temperature at the same ageing time. Based on the analysed results, a new mechanism, considering the combined effects of the formation of larger dislocation structures induced by higher temperature and diffusion of solute atoms towards these larger or tangled dislocations, was proposed to explain the effect of temperature on microstructural evolution and creep behaviour.
基金the National Key R&D Program of China(No.2017YFB0306300)the National Natural Science Foundation of China(Nos.51675538,51601060)+1 种基金the State Key Laboratory of High-performance Complex Manufacturing,China(No.ZZYJKT2018-18)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2018zzts151).
文摘A unified constitutive model is presented to predict the recently observed“multi-stage”creep behavior of Al−Li−S4 alloy.The corresponding microstructural variables related to the yield strength and creep deformation of the alloy during the creep ageing process,including dislocations and multiple precipitates,have been characterized in detail by X-ray diffraction(XRD)and transmission electron microscopy(TEM).For the yield strength,the model considers the multiphase strengthening behavior of the alloy based on strengthening mechanisms,which includes shearable T1 precipitate strengthening,non-shearable T1 precipitate strengthening andθ′precipitate strengthening.Based on creep deformation mechanism,the“multi-stage”creep behavior of the alloy is predicted by introducing the effects of interacting microstructural variables,including the radius of multiple precipitates,dislocation density and solute concentration,into the creep stress−strain model.It is concluded that the results calculated by the model are in a good agreement with the experimental data,which validates the proposed model.
基金Project(U22A20190)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development,Jiangsu Higher Education Institution,China。
