The present state and the significance of research on explosion seismic waves are discussed, and meanwhile the main contents and the basic problems to be solved in the study of explosion seismic waves are analyzed. Th...The present state and the significance of research on explosion seismic waves are discussed, and meanwhile the main contents and the basic problems to be solved in the study of explosion seismic waves are analyzed. The spectra characteristics of explosion seismic waves, functions of the isolated-seismic grooves and influences of the detonating methods on explosion seismic waves are investigated by experiments. The experimental method is introduced. Some experimental results are presented which are concerned with the influences of topographical conditions, explosive charges, ignition patterns, isolated-seismic grooves and the other related factors on the characteristics of seismic waves.展开更多
An analytical method is presented to fit parameters of Jones-Wilkins-Lee （JWL） equation of state （EOS） for the chemical process of aluminum-polytetrafluoroethylene （ AI/PTFE ） mixture. Subroutine codes for both ...An analytical method is presented to fit parameters of Jones-Wilkins-Lee （JWL） equation of state （EOS） for the chemical process of aluminum-polytetrafluoroethylene （ AI/PTFE ） mixture. Subroutine codes for both strength model and EOS were developed in explicit-FE code AUTODYN. Firstly, the shock Hugoniot data of reactive A1/PTFE mixture was analytically derived by implemen- ting this methodology. The JWL EOS was verified to fit shock Hugoniot data of both reacted and un- reacted A1/PTFE mixture, which gives reasonable results. Furthermore, to numerically ascertain the reaction phases of ignition and growth and quasi detonation of A1/PTFE mixture, characterized ex- periment was setup to validate the reaction phases and coefficients of JWL EOS for A1/PTFE mix- ture. From the test, a promising example of reactive mixture A1/PTFE is capable to enhance lethality of weapons, the status computation in clude quasi-detonation pressure and temperature of A1/PTFE mixture in different chemical reaction phases is validated.展开更多
This paper presents the results of an experimental investigation on explosive breaching of p-section concrete beams. Twenty three p-section concrete beams with a 100 cm length were tested. TNT charges were placed at t...This paper presents the results of an experimental investigation on explosive breaching of p-section concrete beams. Twenty three p-section concrete beams with a 100 cm length were tested. TNT charges were placed at three positions: contact detonation in the center, contact detonation above the web and close-in detonation in the center. The external and internal breach parameters of the panels were evaluated by measuring the diameter of the ejection crater, spalling crater and breach hole created by the charge detonation. The experimental results were compared to predict values obtained by the analytical models proposed by McVay, Morishita and Remennikov. A modified breach with crater limit line and breach without crater limit line were put forward based on the experimental results. The maximum cross-sectional destruction area ratio(MCDAR) values were used to evaluate the damage degree. The maximum value of MCDAR reached 0.331 corresponding to the C5 experimental condition, of which explosion occurred above the web.展开更多
The dynamic formation,shock-induced inhomogeneous temperature rise and corresponding chemical reaction behaviors of PTFE/Al reactive liner shaped charge jet(RLSCJ)are investigated by the combination of mesoscale simul...The dynamic formation,shock-induced inhomogeneous temperature rise and corresponding chemical reaction behaviors of PTFE/Al reactive liner shaped charge jet(RLSCJ)are investigated by the combination of mesoscale simulation,reaction kinetics and chemical energy release test.A two-dimensional granular model is developed with the randomly normal distribution of aluminum particle sizes and the particle delivery program.Then,the granular model is employed to study the shock-induced thermal behavior during the formation and extension processes of RLSCJ,as well as the temperature history curves of aluminum particles.The simulation results visualize the motion and temperature responses of the RLSCJ at the grain level,and further indicate that the aluminum particles are more likely to gather in the last two-thirds of the jet along its axis.Further analysis shows that the shock,collision,friction and deformation behaviors are all responsible for the steep temperature rise of the reactive jet.In addition,a shock-induced chemical reaction extent model of RLSCJ is built based on the combination of the Arrhenius model and the Avrami-Erofeev kinetic model,by which the chemical reaction growth behavior during the formation and extension stages is described quantitatively.The model indicates the reaction extent highly corresponds to the aluminum particle temperature history at the formation and extension stages.At last,a manometry chamber and the corresponding energy release model are used together to study the macroscopic chemical energy release characteristics of RLSCJ,by which the reaction extent model is verified.展开更多
Parent compounds of cyclopentadienyltitanium substituted heteropolytungstates with Keggin structure,An[(CpTi)XW11O39]·xH2O(A=Me4N,K;X=P,Si,Co;Cp=η5-C5H5) were synthesized in aqueous phase.By allowing parent hete...Parent compounds of cyclopentadienyltitanium substituted heteropolytungstates with Keggin structure,An[(CpTi)XW11O39]·xH2O(A=Me4N,K;X=P,Si,Co;Cp=η5-C5H5) were synthesized in aqueous phase.By allowing parent heteropoly compounds to react with protonated 8-quinolinol,the title supermolecular compounds(C9H8NO)mAn[(CpTi)XW11O39]·xH2O(A=Me4N,H;X=P,Si,Co) were synthesized.The title compounds were characterized by means of elementary analysis,IR,UV,1H NMR,XRD and TG-DSC.The results indicate that the title compounds are new heteropoly compounds,and there is a charge transfer interaction between the organic cation and heteropoly anion.The results obtained from thermal analysis show that QCpTiPW,QCpTiSiW and QCpTiCoW begin to decompose at 212.4,194.2 and 171.2 ℃,respectively.The results obtained from antibacterial test reveal that QCpTiSiW has the best antibacterial activity,and the MIC values of QCpTiSiW against Escherichia coli and Staphylococcus aurous are 64.0 and 0.500 μg·mL-1,respectively.展开更多
AutoReaGas was used for the simulations of premixed gas/air mixtures explosion characteristics in obstacle-filled tubes with a cross-section of 0.2 m×0.2 m and the length of 28 m. Numerical analyses provide a qua...AutoReaGas was used for the simulations of premixed gas/air mixtures explosion characteristics in obstacle-filled tubes with a cross-section of 0.2 m×0.2 m and the length of 28 m. Numerical analyses provide a quantitative description of dependence of flame propagation speed and explosion overpressure on obstacles number, blockage ratio and interval distance. Computational results indicate that the obstacles play a significant role in determining the flame transmission speed and explosion overpressure in gas explosions. With the increase of blockage ratio, the explosion overpressure gradually rises. Nevertheless, the flame speed does not always increase along with increasing blockage ratio, but subsequently begins to decrease as the blockage ratio increases to some extend. Also, the interval distance between obstacles strongly influences flame behavior and explosion overpressure. When the obstacle interval distance is equal to inner diameter of the tube, the average flame speed in the obstacle zone and the peak overpressure in tube all reach maximum values.展开更多
The numerical simulation on explosion in concrete and soil is performed by using the three-dimension finite element code LS-DYNA, into which a continuum damage model which can well describe the fracture of concrete is...The numerical simulation on explosion in concrete and soil is performed by using the three-dimension finite element code LS-DYNA, into which a continuum damage model which can well describe the fracture of concrete is implemented. As a consequence, wave propagation and attenuation in concrete and on soil-concrete interface are obtained respectively. Moreover, the damage regions of concrete at different thicknesses of soil （TOS） and depths of charge （DOC） are procured. The existent soil reduces damage region of concrete. Numerical results provide reference for design of warhead and protective structure and blasting.展开更多
There are few report on the directly measurement of the initial shock pressure of explosive charge at its interface of water for underwater explosion. The special technologies have been taken to the measurement system...There are few report on the directly measurement of the initial shock pressure of explosive charge at its interface of water for underwater explosion. The special technologies have been taken to the measurement system with manganin piezoresistive gauge （PRG） in order to measure the initial shock pressure at the interface and its near field of TNT chare and water. The free-holding PRG film gauge can directly determine the shock peak pressure at the interface and near field of TNT charge up to 12.85 GPa, which is satisfying for the good agreement to the 12.97 GPa with one dimensional theoretical analysis and 12.86 GPa with numerical simulation. The maximum discrepancy is 0.93 %. The results show that it is precise and reliable to determine the initial shock pressure of underwater explosion charge with the PRG technology.展开更多
Abstract： In order to study the flammability and explosion property of gases during the propane oxidation to acrylic acid process, the explosion limits and the safety oxygen content of gases at the recycle gas compre...Abstract： In order to study the flammability and explosion property of gases during the propane oxidation to acrylic acid process, the explosion limits and the safety oxygen content of gases at the recycle gas compressor outlet, the reactor inlet, and the reactor outlet were theoretically calculated and experimentally tested. Finally, the inert limit was also determined. It showed that gases at the recycle gas compressor outlet and the reactor outlet were nonflammable based on three indicators： the explosion limits, the safety oxygen content and the inert limit. The C3H6 and O2 contents were higher at the reactor inlet, which made the mixed gases easily ignitable. However, the large amount of inert gases suppressed the possibility of explo- sion effectively. As a consequence, no explosion phenomenon would happen in all three locations. But gases at the reactor inlet are most dangerous, where more supervision on the concentration of gases and more strict control on the temperature and pressure should be implemented. Besides this, open flame, hot surfaces and other sources of ignition are prohibited in working spaces. The experimental results can be applied to similar process for oxidation of propane.展开更多
Zirconium,titanium,and other hexagonally close-packed(HCP)metals and their alloys are representative high specific strength,high reaction enthalpy,and high thermal conductivity structural materials.In this study,two t...Zirconium,titanium,and other hexagonally close-packed(HCP)metals and their alloys are representative high specific strength,high reaction enthalpy,and high thermal conductivity structural materials.In this study,two typical HCP metals,zirconium,and titanium,were applied to reactive materials(RMs)to prepare Zr/PTFE/W RMs and Ti/PTFE/W RMs,validating the feasibility of HCP metal/PTFE/W RMs.The impact response process of typical HCP metal/PTFE/W RMs under high-velocity dynamic loads was studied using shock equations of state(EOS)based on porous mixtures and chemical reaction kinetics equations.An improved hemispherical quasi-sealed test chamber was employed to measure the energy release characteristic curves of 10 types of Zr/PTFE/W RMs and Ti/PTFE/W RMs under impact velocities ranging from 500 m/s to 1300 m/s.The datasets of the impact-induced energy release characteristics of HCP metal/PTFE/W RMs were established.Additionally,the energy release efficiency of HCP metal/PTFE/W RMs under impact was predicted using the support vector regression(SVR)kernel function model.The datasets of Zr/PTFE/W RMs and Ti/PTFE/W RMs with W contents of 0%,25%,50%,and 75%were used as test sets,respectively.The model predictions showed a high degree of agreement with the experimental data,with mean absolute errors(MAE)of 4.8,6.5,4.6,and 4.1,respectively.展开更多
The stratification phenomenon resulting from differences in the physical properties of solid-liquid components seriously affect the final combustion and explosion characteristics of mixed fuel under the action of osci...The stratification phenomenon resulting from differences in the physical properties of solid-liquid components seriously affect the final combustion and explosion characteristics of mixed fuel under the action of oscillation.The effects of oscillation on the physical stability of mixed fuel with two solid-liquid ratios and three liquid component distribution ratios have been investigated using a self-designed experimental system at oscillation frequencies of 60-300 r/min.The explosion characteristics of mixed fuel before and after oscillation are gained from a 20 L spherical explosion container system.When the mass ratio of liquid components is controlled at 66.9%,64.7%,62.6%the final explosion characteristics are stable,with a maximum difference of only 0.71%.The volume of liquid fuel precipitation increases with increasing oscillation frequency when the mass ratio of liquid components reaches 71.7%,69.6%,67.7%.The fuel explosion overpressure after oscillation decreases with increasing liquid precipitation volume,and the repeatability is poor,with a maximum standard deviation of 82.736,which is much higher than the ratio without stratification.Properly controlling the mass ratio of liquid components of the mixed fuel can effectively combat the impact of oscillation on the physical state and maintain the stability of the final explosion characteristics.展开更多
The high speed cameral and schlieren images methods were used to record the photograph of flame propagation process.Meanwhile,the ionization current probes were set up to detect the reaction intensity of the reaction ...The high speed cameral and schlieren images methods were used to record the photograph of flame propagation process.Meanwhile,the ionization current probes were set up to detect the reaction intensity of the reaction zone.The characteristics of methane/air flame propagation and microstructure were analyzed in detail by the experi- mental results coupled with chemical reaction thermodynamics.The high speed schlieren image showed the transition from laminar flame to turbulence combustion.The ion current curves disclosed the reaction intensity and combustion characteristic of flame front.In the test,the particular tulip flame was formed clearly,which was induced to some extent by turbulent combustion.Based on the schlieren images and iron current result,it can be drawn that the small scale turbulence combustion also appears in laminar flame,which thickens the flame front,but makes little influence on the flame front shape.During the laminar-turbulent transition,the explosion pressure plays an important role on the flame structure change.展开更多
It is important to understand the characteristics of explosive sympathetic detonation for explosive safety.Sympathetic reaction test of GHL(RDX/Al/Binder)explosive charges with shell are conducted.A model of the sympa...It is important to understand the characteristics of explosive sympathetic detonation for explosive safety.Sympathetic reaction test of GHL(RDX/Al/Binder)explosive charges with shell are conducted.A model of the sympathetic reaction test is established.The elements-apart method and nodes random-failure method are used in the model to describe the expansion progress of shell expanding and the randomly forming process of fragments.Random detonation phenomena of acceptor charge are simulated.展开更多
The recent research progress of structure- and size-controlled micro/nano-energetic materials is reviewed, which properties are fundamentally different from those of their corresponding bulk materials. The development...The recent research progress of structure- and size-controlled micro/nano-energetic materials is reviewed, which properties are fundamentally different from those of their corresponding bulk materials. The development of the construction strategies for achieving zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) micro/nanostructures from energetic molecules is introduced. Also, an overview of the unique properties induced by micro/nanostructures and size effects is provided. Special emphasis is focused on the size-dependent properties that are different from those of the conventional micro-sized energetic materials, such as thermal decomposition, sensitivity, combustion and detonation, and compaction behaviors. A conclusion and our view of the future development of micro/nano-energetic materials and devices are given.展开更多
In this study, the blast performance of steel reinforced concrete(RC) beams was experimentally and analytically investigated. The experiment consists of a total of 10 one-half-scale beams subjected to different levels...In this study, the blast performance of steel reinforced concrete(RC) beams was experimentally and analytically investigated. The experiment consists of a total of 10 one-half-scale beams subjected to different levels of blast loading using live explosives. The reflected pressure-time histories were recorded and different damage levels and modes were observed. The blast resilience of the damaged beams was quantified by measuring the time-dependent displacements. Experiment results show that the damage in steel reinforced concrete beams with higher explosive mass is enhanced compared with that of the beams with smaller explosive mass at the same scaled distance. Based on the experiment data, an empirical expression is developed via dimensional analysis to correct the relationship between the midspan displacement and scaled distance. Besides, a complex single degree of freedom model(SDOF)incorporating complex features of the material behavior, high strain-rate effect and the column geometry was proposed and validated by test results.展开更多
Under the background of vigorously developing facilities of island/reef in the world,the economic value and strategic significance of the island/reef have become increasingly important.Unfortunately,they may easily be...Under the background of vigorously developing facilities of island/reef in the world,the economic value and strategic significance of the island/reef have become increasingly important.Unfortunately,they may easily become the attacking target of missiles in the war time.Therefore,aiming at the damage quantification of the targets in the island/reef under the missile attacking,a macroscopic damage assessment model for the target area is proposed in this paper.The model focuses on the construction of the assessment model framework.Firstly,the analytic hierarchy process and the grey relational analysis are applied to measure the importance of each target in the region through four indicators of the target hazard,striking urgency,damage advantage and mission relevance,respectively.Secondly,based on the damage mechanism of shock wave and fragments to target,the corresponding damage model is established,and the damage grade of each target in the evaluated area is obtained according to the damage criteria and grading standard.Finally,the model obtains the overall damage grade of the target area by employing the fuzzy comprehensive evaluation method,with synthesizing the importance and the damage grade of each target.Through the verification of an example,it demonstrates the certain feasibility of the model and provides a certain basis and reference for the subsequent research.展开更多
Polyurea is widely employed as a protective coating in many fields because of its superior ability to improve the anti-blast and anti-impact capability of structures.In this study,the mechanical properties of polyurea...Polyurea is widely employed as a protective coating in many fields because of its superior ability to improve the anti-blast and anti-impact capability of structures.In this study,the mechanical properties of polyurea XS-350 were investigated via systematic experimentation over a wide range of strain rates(0.001-7000 s^-1)by using an MTS,Instron VHS,and split-Hopkinson bars.The stress-strain behavior of polyurea was obtained for various strain rates,and the effects of strain rate on the primary mechanical properties were analyzed.Additionally,a modified rate-dependent constitutive model is proposed based on the nine-parameter Mooney-Rivlin model.The results show that the stress-strain curves can be divided into three distinct regions:the linear-elastic stage,the highly elastic stage,and an approximate linear region terminating in fracture.The mechanical properties of the polyurea material were found to be highly dependent on the strain rate.Furthermore,a comparison between model predictions and the experimental stress-strain curves demonstrated that the proposed model can characterize the mechanical properties of polyurea over a wide range of strain rates.展开更多
In this research,the effect of the sintering and cooling process on geometry distortion and mechanical properties of PTFE/Al reactive material is investigated.Six particularly selected sintering temperatures,three dif...In this research,the effect of the sintering and cooling process on geometry distortion and mechanical properties of PTFE/Al reactive material is investigated.Six particularly selected sintering temperatures,three different cooling modes(annealing cooling,normalizing cooling and rapid cooling),three different initial cooling temperature s,as well as six different final cooling temperatures were designed to compare the effects of sintering temperature,cooling rate,initial cooling temperature and final cooling temperature on the properties of reactive materials.Geometry distortion was quantitatively analyzed by a statistic on the dimensional changes of the specimens and microscopic morphology.A mechanical response properties transition from brittle to ductile was found and analyzed.By combining the thermodynamic properties of PTFE and unsteady heat conduction theory,mechanisms of cooling induced morphology change,temperature induced distortion and strength decrease were obtained.The results showed that the cooling rate has the most significant effect on the morphology transformation,while initial cooling temperature has more significant effect on the dimensional distortion than final cooling temperature.As to the mechanical properties transition from brittle to plastic,a more prominent effect of initial cooling temperature than cooling rate and final temperature was revealed.展开更多
The hot deformation behavior of TC18 alloy at strain rates ranging from 1 × 10-4 to 1 x 10-2 s-1 and temperatures ranging from 25 to 800 ℃ was studied using a WDW-300 electronic universal testing machine. The re...The hot deformation behavior of TC18 alloy at strain rates ranging from 1 × 10-4 to 1 x 10-2 s-1 and temperatures ranging from 25 to 800 ℃ was studied using a WDW-300 electronic universal testing machine. The relationships between true flow stress decreases with stress and true strain show that the increase of temperature and increases as strain rate increases. The effect of strain rate on the flow stress becomes pronounced at higher temper- atures. At room temperature, the river pattern characteristic of brittle fracture and the dimple pattern typical of ductile fracture are found to exist in different regions of fracture surfaces of the samples. An improved constitutive rela- tionship is proposed to accurately describe the flow stress of TC18 by considering the effect of strain. And a micro- scopic model is also deduced which can link the physical mechanisms to the macroscopic experimental results. A good agreement is obtained between the predictions of the microscopic model and the results of the macroscopic experiment.展开更多
A novel supported polyoxometalate （POM）, phosphotungstic acid immobilized into yttrium-doped TiO2 （HPW-Y-TiO2） nano photocatalyst was prepared via sol-gel and impregnation method. The samples were characterized us...A novel supported polyoxometalate （POM）, phosphotungstic acid immobilized into yttrium-doped TiO2 （HPW-Y-TiO2） nano photocatalyst was prepared via sol-gel and impregnation method. The samples were characterized using Fourier transform in- frared spectroscopy （FT-IR）, X-ray diffraction （XRD） and N2 absorption-desorption analysis. The results showed that the supported POM exhibited Keggin structure and anatase phase with large BET surface area. The influences of inorganic anions and organic addi- tives on the photocatalytic degradation of azo dye methyl orange with HPW-Y-TiO2 as photocatalyst under UV light （2〉365 urn） were investigated. Results showed that inorganic anions CI, 504^2-, CO32 and NO3 had inhibition effect on the degradation of methyl orange. A great enhancement of degradation rate was obtained while H202 and ethyl alcohol were applied. The degradation rates improved with the increase of H202 concentration. The optimum additive amount of ethyl alcohol was 0.5 mol/L. The possible mechanisms of the effects of additives on methyl orange degradation were discussed.展开更多
文摘The present state and the significance of research on explosion seismic waves are discussed, and meanwhile the main contents and the basic problems to be solved in the study of explosion seismic waves are analyzed. The spectra characteristics of explosion seismic waves, functions of the isolated-seismic grooves and influences of the detonating methods on explosion seismic waves are investigated by experiments. The experimental method is introduced. Some experimental results are presented which are concerned with the influences of topographical conditions, explosive charges, ignition patterns, isolated-seismic grooves and the other related factors on the characteristics of seismic waves.
基金Supported by Specialized Research Fund for the Doctoral Program of Higher Education(20091101120009)the Project of State Key Laboratory of Science and Technology(YBKT09-03)+1 种基金the National Natural Science Foundation of China(11032002)National Basic Research Program of China(2010CB832706)
文摘An analytical method is presented to fit parameters of Jones-Wilkins-Lee （JWL） equation of state （EOS） for the chemical process of aluminum-polytetrafluoroethylene （ AI/PTFE ） mixture. Subroutine codes for both strength model and EOS were developed in explicit-FE code AUTODYN. Firstly, the shock Hugoniot data of reactive A1/PTFE mixture was analytically derived by implemen- ting this methodology. The JWL EOS was verified to fit shock Hugoniot data of both reacted and un- reacted A1/PTFE mixture, which gives reasonable results. Furthermore, to numerically ascertain the reaction phases of ignition and growth and quasi detonation of A1/PTFE mixture, characterized ex- periment was setup to validate the reaction phases and coefficients of JWL EOS for A1/PTFE mix- ture. From the test, a promising example of reactive mixture A1/PTFE is capable to enhance lethality of weapons, the status computation in clude quasi-detonation pressure and temperature of A1/PTFE mixture in different chemical reaction phases is validated.
基金supported by The National Natural Science Foundation of China under Grant No.11390362 and No. 11221202
文摘This paper presents the results of an experimental investigation on explosive breaching of p-section concrete beams. Twenty three p-section concrete beams with a 100 cm length were tested. TNT charges were placed at three positions: contact detonation in the center, contact detonation above the web and close-in detonation in the center. The external and internal breach parameters of the panels were evaluated by measuring the diameter of the ejection crater, spalling crater and breach hole created by the charge detonation. The experimental results were compared to predict values obtained by the analytical models proposed by McVay, Morishita and Remennikov. A modified breach with crater limit line and breach without crater limit line were put forward based on the experimental results. The maximum cross-sectional destruction area ratio(MCDAR) values were used to evaluate the damage degree. The maximum value of MCDAR reached 0.331 corresponding to the C5 experimental condition, of which explosion occurred above the web.
基金supported by the National Natural Science Foundation of China (No. 12172052)the China Postdoctoral Science Foundation (No. 3020036722021)
文摘The dynamic formation,shock-induced inhomogeneous temperature rise and corresponding chemical reaction behaviors of PTFE/Al reactive liner shaped charge jet(RLSCJ)are investigated by the combination of mesoscale simulation,reaction kinetics and chemical energy release test.A two-dimensional granular model is developed with the randomly normal distribution of aluminum particle sizes and the particle delivery program.Then,the granular model is employed to study the shock-induced thermal behavior during the formation and extension processes of RLSCJ,as well as the temperature history curves of aluminum particles.The simulation results visualize the motion and temperature responses of the RLSCJ at the grain level,and further indicate that the aluminum particles are more likely to gather in the last two-thirds of the jet along its axis.Further analysis shows that the shock,collision,friction and deformation behaviors are all responsible for the steep temperature rise of the reactive jet.In addition,a shock-induced chemical reaction extent model of RLSCJ is built based on the combination of the Arrhenius model and the Avrami-Erofeev kinetic model,by which the chemical reaction growth behavior during the formation and extension stages is described quantitatively.The model indicates the reaction extent highly corresponds to the aluminum particle temperature history at the formation and extension stages.At last,a manometry chamber and the corresponding energy release model are used together to study the macroscopic chemical energy release characteristics of RLSCJ,by which the reaction extent model is verified.
基金supported by the chemical materials institute China academy of engineering physics,the doctoral innovation research assistance program of science and technology review
文摘Parent compounds of cyclopentadienyltitanium substituted heteropolytungstates with Keggin structure,An[(CpTi)XW11O39]·xH2O(A=Me4N,K;X=P,Si,Co;Cp=η5-C5H5) were synthesized in aqueous phase.By allowing parent heteropoly compounds to react with protonated 8-quinolinol,the title supermolecular compounds(C9H8NO)mAn[(CpTi)XW11O39]·xH2O(A=Me4N,H;X=P,Si,Co) were synthesized.The title compounds were characterized by means of elementary analysis,IR,UV,1H NMR,XRD and TG-DSC.The results indicate that the title compounds are new heteropoly compounds,and there is a charge transfer interaction between the organic cation and heteropoly anion.The results obtained from thermal analysis show that QCpTiPW,QCpTiSiW and QCpTiCoW begin to decompose at 212.4,194.2 and 171.2 ℃,respectively.The results obtained from antibacterial test reveal that QCpTiSiW has the best antibacterial activity,and the MIC values of QCpTiSiW against Escherichia coli and Staphylococcus aurous are 64.0 and 0.500 μg·mL-1,respectively.
文摘AutoReaGas was used for the simulations of premixed gas/air mixtures explosion characteristics in obstacle-filled tubes with a cross-section of 0.2 m×0.2 m and the length of 28 m. Numerical analyses provide a quantitative description of dependence of flame propagation speed and explosion overpressure on obstacles number, blockage ratio and interval distance. Computational results indicate that the obstacles play a significant role in determining the flame transmission speed and explosion overpressure in gas explosions. With the increase of blockage ratio, the explosion overpressure gradually rises. Nevertheless, the flame speed does not always increase along with increasing blockage ratio, but subsequently begins to decrease as the blockage ratio increases to some extend. Also, the interval distance between obstacles strongly influences flame behavior and explosion overpressure. When the obstacle interval distance is equal to inner diameter of the tube, the average flame speed in the obstacle zone and the peak overpressure in tube all reach maximum values.
基金Sponsored by Excellent Young Scholars Research Fund of Beijing Institute of Technology (000Y02-11)
文摘The numerical simulation on explosion in concrete and soil is performed by using the three-dimension finite element code LS-DYNA, into which a continuum damage model which can well describe the fracture of concrete is implemented. As a consequence, wave propagation and attenuation in concrete and on soil-concrete interface are obtained respectively. Moreover, the damage regions of concrete at different thicknesses of soil （TOS） and depths of charge （DOC） are procured. The existent soil reduces damage region of concrete. Numerical results provide reference for design of warhead and protective structure and blasting.
基金Sponsored by the National"973"Program Project(51335030103)
文摘There are few report on the directly measurement of the initial shock pressure of explosive charge at its interface of water for underwater explosion. The special technologies have been taken to the measurement system with manganin piezoresistive gauge （PRG） in order to measure the initial shock pressure at the interface and its near field of TNT chare and water. The free-holding PRG film gauge can directly determine the shock peak pressure at the interface and near field of TNT charge up to 12.85 GPa, which is satisfying for the good agreement to the 12.97 GPa with one dimensional theoretical analysis and 12.86 GPa with numerical simulation. The maximum discrepancy is 0.93 %. The results show that it is precise and reliable to determine the initial shock pressure of underwater explosion charge with the PRG technology.
基金financially supported by the National Science and Technology Support Program of China(2012BAK13B01)
文摘Abstract： In order to study the flammability and explosion property of gases during the propane oxidation to acrylic acid process, the explosion limits and the safety oxygen content of gases at the recycle gas compressor outlet, the reactor inlet, and the reactor outlet were theoretically calculated and experimentally tested. Finally, the inert limit was also determined. It showed that gases at the recycle gas compressor outlet and the reactor outlet were nonflammable based on three indicators： the explosion limits, the safety oxygen content and the inert limit. The C3H6 and O2 contents were higher at the reactor inlet, which made the mixed gases easily ignitable. However, the large amount of inert gases suppressed the possibility of explo- sion effectively. As a consequence, no explosion phenomenon would happen in all three locations. But gases at the reactor inlet are most dangerous, where more supervision on the concentration of gases and more strict control on the temperature and pressure should be implemented. Besides this, open flame, hot surfaces and other sources of ignition are prohibited in working spaces. The experimental results can be applied to similar process for oxidation of propane.
基金sponsored by the National Natural Science Foundation of China(Grant Nos.U2241285,62201267)。
文摘Zirconium,titanium,and other hexagonally close-packed(HCP)metals and their alloys are representative high specific strength,high reaction enthalpy,and high thermal conductivity structural materials.In this study,two typical HCP metals,zirconium,and titanium,were applied to reactive materials(RMs)to prepare Zr/PTFE/W RMs and Ti/PTFE/W RMs,validating the feasibility of HCP metal/PTFE/W RMs.The impact response process of typical HCP metal/PTFE/W RMs under high-velocity dynamic loads was studied using shock equations of state(EOS)based on porous mixtures and chemical reaction kinetics equations.An improved hemispherical quasi-sealed test chamber was employed to measure the energy release characteristic curves of 10 types of Zr/PTFE/W RMs and Ti/PTFE/W RMs under impact velocities ranging from 500 m/s to 1300 m/s.The datasets of the impact-induced energy release characteristics of HCP metal/PTFE/W RMs were established.Additionally,the energy release efficiency of HCP metal/PTFE/W RMs under impact was predicted using the support vector regression(SVR)kernel function model.The datasets of Zr/PTFE/W RMs and Ti/PTFE/W RMs with W contents of 0%,25%,50%,and 75%were used as test sets,respectively.The model predictions showed a high degree of agreement with the experimental data,with mean absolute errors(MAE)of 4.8,6.5,4.6,and 4.1,respectively.
文摘The stratification phenomenon resulting from differences in the physical properties of solid-liquid components seriously affect the final combustion and explosion characteristics of mixed fuel under the action of oscillation.The effects of oscillation on the physical stability of mixed fuel with two solid-liquid ratios and three liquid component distribution ratios have been investigated using a self-designed experimental system at oscillation frequencies of 60-300 r/min.The explosion characteristics of mixed fuel before and after oscillation are gained from a 20 L spherical explosion container system.When the mass ratio of liquid components is controlled at 66.9%,64.7%,62.6%the final explosion characteristics are stable,with a maximum difference of only 0.71%.The volume of liquid fuel precipitation increases with increasing oscillation frequency when the mass ratio of liquid components reaches 71.7%,69.6%,67.7%.The fuel explosion overpressure after oscillation decreases with increasing liquid precipitation volume,and the repeatability is poor,with a maximum standard deviation of 82.736,which is much higher than the ratio without stratification.Properly controlling the mass ratio of liquid components of the mixed fuel can effectively combat the impact of oscillation on the physical state and maintain the stability of the final explosion characteristics.
基金the Open Foundation of State Key Lab of Explosion Science and Technology(KFJJ07-06)the Open Project of State Key Lab of Fire Science(HZ2007-KF06)
文摘The high speed cameral and schlieren images methods were used to record the photograph of flame propagation process.Meanwhile,the ionization current probes were set up to detect the reaction intensity of the reaction zone.The characteristics of methane/air flame propagation and microstructure were analyzed in detail by the experi- mental results coupled with chemical reaction thermodynamics.The high speed schlieren image showed the transition from laminar flame to turbulence combustion.The ion current curves disclosed the reaction intensity and combustion characteristic of flame front.In the test,the particular tulip flame was formed clearly,which was induced to some extent by turbulent combustion.Based on the schlieren images and iron current result,it can be drawn that the small scale turbulence combustion also appears in laminar flame,which thickens the flame front,but makes little influence on the flame front shape.During the laminar-turbulent transition,the explosion pressure plays an important role on the flame structure change.
文摘It is important to understand the characteristics of explosive sympathetic detonation for explosive safety.Sympathetic reaction test of GHL(RDX/Al/Binder)explosive charges with shell are conducted.A model of the sympathetic reaction test is established.The elements-apart method and nodes random-failure method are used in the model to describe the expansion progress of shell expanding and the randomly forming process of fragments.Random detonation phenomena of acceptor charge are simulated.
基金Sponsored by National Natural Science Foundation of China (21231002,21276026,21271023,21173021,91022006,11202193,11172276,and 11072225)the 111 Project ( B07012)+1 种基金the Program of Cooperation of the Beijing Education Commission ( 20091739006)Specialized Research Fund for the Doctoral Program of Higher Education ( 20101101110031)
文摘The recent research progress of structure- and size-controlled micro/nano-energetic materials is reviewed, which properties are fundamentally different from those of their corresponding bulk materials. The development of the construction strategies for achieving zero-dimensional (0D), one-dimensional (1D), two-dimensional (2D), and three-dimensional (3D) micro/nanostructures from energetic molecules is introduced. Also, an overview of the unique properties induced by micro/nanostructures and size effects is provided. Special emphasis is focused on the size-dependent properties that are different from those of the conventional micro-sized energetic materials, such as thermal decomposition, sensitivity, combustion and detonation, and compaction behaviors. A conclusion and our view of the future development of micro/nano-energetic materials and devices are given.
基金supported by The National Natural Science Foundation of China under Grant No.11390362 and No.11221202
文摘In this study, the blast performance of steel reinforced concrete(RC) beams was experimentally and analytically investigated. The experiment consists of a total of 10 one-half-scale beams subjected to different levels of blast loading using live explosives. The reflected pressure-time histories were recorded and different damage levels and modes were observed. The blast resilience of the damaged beams was quantified by measuring the time-dependent displacements. Experiment results show that the damage in steel reinforced concrete beams with higher explosive mass is enhanced compared with that of the beams with smaller explosive mass at the same scaled distance. Based on the experiment data, an empirical expression is developed via dimensional analysis to correct the relationship between the midspan displacement and scaled distance. Besides, a complex single degree of freedom model(SDOF)incorporating complex features of the material behavior, high strain-rate effect and the column geometry was proposed and validated by test results.
文摘Under the background of vigorously developing facilities of island/reef in the world,the economic value and strategic significance of the island/reef have become increasingly important.Unfortunately,they may easily become the attacking target of missiles in the war time.Therefore,aiming at the damage quantification of the targets in the island/reef under the missile attacking,a macroscopic damage assessment model for the target area is proposed in this paper.The model focuses on the construction of the assessment model framework.Firstly,the analytic hierarchy process and the grey relational analysis are applied to measure the importance of each target in the region through four indicators of the target hazard,striking urgency,damage advantage and mission relevance,respectively.Secondly,based on the damage mechanism of shock wave and fragments to target,the corresponding damage model is established,and the damage grade of each target in the evaluated area is obtained according to the damage criteria and grading standard.Finally,the model obtains the overall damage grade of the target area by employing the fuzzy comprehensive evaluation method,with synthesizing the importance and the damage grade of each target.Through the verification of an example,it demonstrates the certain feasibility of the model and provides a certain basis and reference for the subsequent research.
基金the Provincial Basic Research Program of China(NO.2016209A003,NO·2016602B003)
文摘Polyurea is widely employed as a protective coating in many fields because of its superior ability to improve the anti-blast and anti-impact capability of structures.In this study,the mechanical properties of polyurea XS-350 were investigated via systematic experimentation over a wide range of strain rates(0.001-7000 s^-1)by using an MTS,Instron VHS,and split-Hopkinson bars.The stress-strain behavior of polyurea was obtained for various strain rates,and the effects of strain rate on the primary mechanical properties were analyzed.Additionally,a modified rate-dependent constitutive model is proposed based on the nine-parameter Mooney-Rivlin model.The results show that the stress-strain curves can be divided into three distinct regions:the linear-elastic stage,the highly elastic stage,and an approximate linear region terminating in fracture.The mechanical properties of the polyurea material were found to be highly dependent on the strain rate.Furthermore,a comparison between model predictions and the experimental stress-strain curves demonstrated that the proposed model can characterize the mechanical properties of polyurea over a wide range of strain rates.
基金The authors are very grateful for the support received from the National Natural Science Foundation of China(No.11202030)State Key Laboratory of the State Key Laboratory of Explosion Science and Technology(QNKT19-03).
文摘In this research,the effect of the sintering and cooling process on geometry distortion and mechanical properties of PTFE/Al reactive material is investigated.Six particularly selected sintering temperatures,three different cooling modes(annealing cooling,normalizing cooling and rapid cooling),three different initial cooling temperature s,as well as six different final cooling temperatures were designed to compare the effects of sintering temperature,cooling rate,initial cooling temperature and final cooling temperature on the properties of reactive materials.Geometry distortion was quantitatively analyzed by a statistic on the dimensional changes of the specimens and microscopic morphology.A mechanical response properties transition from brittle to ductile was found and analyzed.By combining the thermodynamic properties of PTFE and unsteady heat conduction theory,mechanisms of cooling induced morphology change,temperature induced distortion and strength decrease were obtained.The results showed that the cooling rate has the most significant effect on the morphology transformation,while initial cooling temperature has more significant effect on the dimensional distortion than final cooling temperature.As to the mechanical properties transition from brittle to plastic,a more prominent effect of initial cooling temperature than cooling rate and final temperature was revealed.
基金financially supported by the National Natural Science Foundation of China(Nos.91016013 and 11221202)the Opening Research Fund of State Key Laboratory of Porous Metal Materials(No.PMM-SKL-1-2012)the Project of State Key Laboratory of Explosion Science and Technology(No.SKLEST-13-07)
文摘The hot deformation behavior of TC18 alloy at strain rates ranging from 1 × 10-4 to 1 x 10-2 s-1 and temperatures ranging from 25 to 800 ℃ was studied using a WDW-300 electronic universal testing machine. The relationships between true flow stress decreases with stress and true strain show that the increase of temperature and increases as strain rate increases. The effect of strain rate on the flow stress becomes pronounced at higher temper- atures. At room temperature, the river pattern characteristic of brittle fracture and the dimple pattern typical of ductile fracture are found to exist in different regions of fracture surfaces of the samples. An improved constitutive rela- tionship is proposed to accurately describe the flow stress of TC18 by considering the effect of strain. And a micro- scopic model is also deduced which can link the physical mechanisms to the macroscopic experimental results. A good agreement is obtained between the predictions of the microscopic model and the results of the macroscopic experiment.
基金supported by the Basic Research Foundation of Beijing Institute of Technology (20110242020)
文摘A novel supported polyoxometalate （POM）, phosphotungstic acid immobilized into yttrium-doped TiO2 （HPW-Y-TiO2） nano photocatalyst was prepared via sol-gel and impregnation method. The samples were characterized using Fourier transform in- frared spectroscopy （FT-IR）, X-ray diffraction （XRD） and N2 absorption-desorption analysis. The results showed that the supported POM exhibited Keggin structure and anatase phase with large BET surface area. The influences of inorganic anions and organic addi- tives on the photocatalytic degradation of azo dye methyl orange with HPW-Y-TiO2 as photocatalyst under UV light （2〉365 urn） were investigated. Results showed that inorganic anions CI, 504^2-, CO32 and NO3 had inhibition effect on the degradation of methyl orange. A great enhancement of degradation rate was obtained while H202 and ethyl alcohol were applied. The degradation rates improved with the increase of H202 concentration. The optimum additive amount of ethyl alcohol was 0.5 mol/L. The possible mechanisms of the effects of additives on methyl orange degradation were discussed.
