The modulation transfer spectroscopy in an ytterbium hollow cathode lamp at 399 nm is measured. The error signal for frequency locking is optimized by measuring the dependences of its slope, linewidth and magnitude on...The modulation transfer spectroscopy in an ytterbium hollow cathode lamp at 399 nm is measured. The error signal for frequency locking is optimized by measuring the dependences of its slope, linewidth and magnitude on various parameters. Under the optimum condition, the laser frequency at 399 nm can be stabilized. The long-term stability of laser frequency is measured by monitoring the fluorescence signal of the ytterbium atomic beam induced by the locked laser. The laser frequency is shown to be tightly locked, and the stabilized laser is successfully applied to the cooling of ytterbium atoms.展开更多
We present the experimental study of modulation transfer spectroscopy of ytterbium atoms in a hollow cathode lamp.The dependences of its linewidth,slope and magnitude on the various experimental parameters are measure...We present the experimental study of modulation transfer spectroscopy of ytterbium atoms in a hollow cathode lamp.The dependences of its linewidth,slope and magnitude on the various experimental parameters are measured and fitted by the well-known theoretical expressions.The experimental results are in good agreement with the theoretical prediction.We have observed the Dicke narrowing effect by increasing the current of the hollow cathode lamp.It is also found that there are the optimal current and laser power to generate the better modulation transfer spectroscopy signal,which can be employed for locking the laser frequency to the atomic transition.展开更多
The valence electron binding energy spectra and orbital electron momentum distributions of ethane(C2H6)have been measured by high resolution(ΔE=0.9eV,Δp=0.1 a.u.)symmetric non-coplanar electron momentum spectroscopy...The valence electron binding energy spectra and orbital electron momentum distributions of ethane(C2H6)have been measured by high resolution(ΔE=0.9eV,Δp=0.1 a.u.)symmetric non-coplanar electron momentum spectroscopy,at an impact energy of 1200eV+binding energy.The high energy resolution is adequate for us to be observe clearly the separated valence orbitals of C_(2)H_(6).展开更多
The first extensive electron momentum spectroscopy study of the satellite structure in the inner valence region of methane at 1200eV is reported.The experimental momentum profiles belonging to the(2a_(1))^(-1) satelli...The first extensive electron momentum spectroscopy study of the satellite structure in the inner valence region of methane at 1200eV is reported.The experimental momentum profiles belonging to the(2a_(1))^(-1) satellite state are presented at energies 25.3,28.5,31.5,35.5eV,and compared with the 146-G(CI)calculation.展开更多
The CS radical was generated by discharging the mixture gas of CS2 and Helium. The Doppler limited spectra of CS were recorded in the region of 12350-12950 cm^-1 using optical heterodyne concentration modulation absor...The CS radical was generated by discharging the mixture gas of CS2 and Helium. The Doppler limited spectra of CS were recorded in the region of 12350-12950 cm^-1 using optical heterodyne concentration modulation absorption spectroscopy. Three hundred and twenty-six lines were recorded and assigned to the d^3△-a^3П （8,1） band, in which eighty-three transitions were first observed. A set of improved molecular constants for the d^3△（v=8） and a^3П（v=1） levels were determined by a non-linear least-squares fitting of all the lines to the effective Hamiltonian.展开更多
An intracavity CO laser magnetic resonance spectrometer with homogeneous dc electric field applied via a pair of parallel Stark plates in the absorption cell is used to measure the electric dipole moments of free radi...An intracavity CO laser magnetic resonance spectrometer with homogeneous dc electric field applied via a pair of parallel Stark plates in the absorption cell is used to measure the electric dipole moments of free radicals.Taking advantage of high sensitivity and high resolution of this technique and the Stark effect,highly-resolved saturated absorption spectra of v=1-0 transition of ^(15)N^(16)O in the ground state X^(2)II_(3/2) have been successfully observed in the presence of a low electric field.The electric dipole moment of NO in the electronic ground state is determined asμ=0.1566±14 D(Debye)from the analysis of the observed spectra,confirming that,combined with the Stark field,the laser magnetic resonance technique can be an effective and reliable approach for the precise measurement of electric dipole moments of free radicals,especially the unstable ones.展开更多
Femtosecond laser-induced resonance-enhanced multiphoton-ionization photoelectron spectroscopy （REMPI-PS） is faced with two drawbacks of low spectral resolution and poor selective excitation due to the broad spectra...Femtosecond laser-induced resonance-enhanced multiphoton-ionization photoelectron spectroscopy （REMPI-PS） is faced with two drawbacks of low spectral resolution and poor selective excitation due to the broad spectral bandwidth. We propose a scheme to obtain a high-resolution selective excitation of （2＋1） REMPI-PS by com- bining 7r and cosinusoidal phase modulation. Our theoretical results indicate that the （2＋1） REMPI-PS signals related to neighboring excited states can be differentiated from their indistinguishable photoelectron spectra by the 7r phase modulation, and then their selective excitation can be realized by supplementally adding the cosi- nusoidal phase modulation. Furthermore, the physical mechanism of the high-resolution selective excitation of （2＋1） REMPI-PS is explained by considering the two-photon power spectrum.展开更多
Combinations of metal and lanthanide oxides have been done through casted films for potential medical applications. In this regard, samarium(Ⅲ) oxide/chromium(Ⅲ) oxide/graphene oxide(GO)/polycaprolactone(PCL) based ...Combinations of metal and lanthanide oxides have been done through casted films for potential medical applications. In this regard, samarium(Ⅲ) oxide/chromium(Ⅲ) oxide/graphene oxide(GO)/polycaprolactone(PCL) based films nano-composites(NCs) were fabricated, pointing their utilization as a biological scaffold for wound dressing purposes. Also, samarium(Ⅲ) oxide and chromium(Ⅲ) oxide have been merged as promising optical constituents due to their unique optical behavior. The structural and compositional examination of the studied NCs was executed by X-ray diffraction(XRD), Raman, and field emission scanning electron microscopy(FESEM). The Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL NC exhibits a surface with a lower roughness degree owing to the presence of GO. Cr_(2)O_(3)shows size reduction upon GO insertion to reach 1.2 μm as the average grain size, whilst Sm_(2)O_(3)records an average grain size of less than 1 μm. As well, the polymeric nano-compositions exhibit variation in contact angle values that hit 29.76°± 3.52°for Sm_(2)O_(3)/PCL, and 48.62°± 1.37°for Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL as the second lowest contact angle. The optical behavior contributes to absorption edge relocation along the x-axis from 1.7 eV for pure PCL, to 2.65 eV for Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL. Regarding biological responses, the cell exposed to 2.5 μg/m L of Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL shows cell viability of 119.31%, while 5 μg/m L hits 99.6%. Additionally, the resulting cell attachment micrographs show layers of fibroblast tissue, besides the proliferation and growth of cultivated cells. Thus, the Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL scaffold provides 3D proliferation of fibroblast cells endorsing the wound healing process.展开更多
Nanocomposite films consisting of carboxymethyl cellulose,polyethylene oxide(CMC/PEO),and anatase titanium diox-ide(TO)were produced by the use of sol-gel and solution casting techniques.TiO2 nanocrystals were effecti...Nanocomposite films consisting of carboxymethyl cellulose,polyethylene oxide(CMC/PEO),and anatase titanium diox-ide(TO)were produced by the use of sol-gel and solution casting techniques.TiO2 nanocrystals were effectively incorporated into CMC/PEO polymers,as shown by X-ray diffraction(XRD)and attenuated total reflectance fourier transform infrared(ATR-FTIR)analysis.The roughness growth is at high levels of TO nanocrystals(TO NCs),which means increasing active sites and defects in CMC/PEO.In differential scanning calorimetry(DSC)thermograms,the change in glass transition temperature(Tg)val-ues verifies that the polymer blend interacts with TO NCs.The increment proportions of TO NCs have a notable impact on the dielectric performances of the nanocomposites,as observed.The electrical properties of the CMC/PEO/TO nanocomposite undergo significant changes.The nanocomposite films exhibit a red alteration in the absorption edge as the concentration of TO NCs increases in the polymer blend.The decline in the energy gap is readily apparent as the weight percentage of TO NCs increases.The photoluminescence(PL)emission spectra indicate that the sites of the luminescence peak maximums show slight variation;peaks get wider,while their intensities decrease dramatically as the concentration of TO increases.These nanocomposite materials show potential for multifunctional applications including optoelectronics,antireflection coatings,pho-tocatalysis,light emitting diodes,and solid polymer electrolytes.展开更多
Developing a biomaterial for wound healing applications is still a challenge.Herein,dysprosium oxide(Dy_(2)O_(3)),aluminum oxide(Al_(2)O_(3)),and graphene oxide(GO)were embedded in cast films based on polycaprolactone...Developing a biomaterial for wound healing applications is still a challenge.Herein,dysprosium oxide(Dy_(2)O_(3)),aluminum oxide(Al_(2)O_(3)),and graphene oxide(GO)were embedded in cast films based on polycaprolactone(PCL)to be examined for wound dressing usage.Different techniques were used to characterize the fabricated films including X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),Raman,and scanning electron microscopy(SEM),besides their biological activity.The thermogravimetric analysis(TGA)exhibits high thermal stability as the scaffold weight decreases slightly to 98.6%after raising the temperature from room temperature to 280℃.The cell viability was investigated and it is shown that the viable cells grow up to approximately 93%at 75μg/mL.Meanwhile,the cell attachment shows excellent behavior as the cells attach on most of the surface of the modified PCL which shows high biocompatibility.展开更多
Poly(p-phenylenediamine)/chitosan (PPPDA/Chi) composite was prepared by in situ chemical oxidative polymerization of p-phenylenediamine (PPPDA) into chitosan (Chi) using ammonium persulphate (APS) as an oxidant. PPPDA...Poly(p-phenylenediamine)/chitosan (PPPDA/Chi) composite was prepared by in situ chemical oxidative polymerization of p-phenylenediamine (PPPDA) into chitosan (Chi) using ammonium persulphate (APS) as an oxidant. PPPDA and PPPDA/Chi composite were characterized by FT-IR spectra and SEM before and after copper loading. In batch adsorption method, the maximum removal of copper was experienced when 1 g/L of PPPDA and PPPDA/Chi composite dosages were used at pH 5.0 for PPPDA and 6.0 for PPPDA/Chi composite for 360 min for both sorbents. PPPDA showed adsorption capacity q<sub>e</sub><sup>max</sup> of 650 mg/g whereas its composite achieved q<sub>e</sub><sup>max</sup> of 573 mg/g. The experimental data correlate well with the Freundlich isotherm equation and the pseudo-second order kinetic model. The Cu(II), loaded PPPDA and its composite can be efficiently reused for as many as four cycles. The Cu(II)-loaded sorbents showed high antibacterial efficiency against Gram-positive and Gram-negative bacteria than their unloaded forms.展开更多
We propose a controllable high-efficiency electrostatic surface trap for cold polar molecules on a chip by using two insulator-embedded charged rings and a grounded conductor plate. We calculate Stark energy structure...We propose a controllable high-efficiency electrostatic surface trap for cold polar molecules on a chip by using two insulator-embedded charged rings and a grounded conductor plate. We calculate Stark energy structure pattern of ND3 molecules in an external electric field using the method of matrix diagonalization. We analyze how the voltages that are applied to the ring electrodes affect the depth of the efficient well and the controllability of the distance between the trap center and the surface of the chip. To obtain a better understanding, we simulate the dynamical loading and trapping processes of ND3 molecules in a ｜J, KM = ｜1,-1 state by using classical Monte–Carlo method. Our study shows that the loading efficiency of our trap can reach ～ 88%. Finally, we study the adiabatic cooling of cold molecules in our surface trap by linearly lowering the potential-well depth（i.e., lowering the trapping voltage）, and find that the temperature of the trapped ND3 molecules can be adiabatically cooled from 34.5 m K to ～ 5.8 m K when the trapping voltage is reduced from-35 k V to-3 k V.展开更多
In this study,ZnO/In_(2)O_(3)-heterostructured nanosheets were prepared using a one-step hydrothermal method.The effects of ZnO content on the gas-sensing performance were discussed,with ZnO/In_(2)O_(3)-2 exhibiting t...In this study,ZnO/In_(2)O_(3)-heterostructured nanosheets were prepared using a one-step hydrothermal method.The effects of ZnO content on the gas-sensing performance were discussed,with ZnO/In_(2)O_(3)-2 exhibiting the highest performance among the prepared sensors.The response of ZnO/In_(2)O_(3)-2 to n-butanol was 302 at 26℃,which was 11.93 times higher than that of pure In_(2)O_(3).Among the eight tested gases,ZnO/In_(2)O_(3)-2 displayed the highest response to n-butanol.Moreover,the lower detection limit of the ZnO/In_(2)O_(3)nanosheets was reduced from 10×10^(-6)to 0.1×10^(-6)(for pure In_(2)O_(3)nanosheets)toward n-butanol.This is because the doping of Zn2+increases the number of oxygen vacancies on the sensor surface and allows the formation of an n-n heterostructure between ZnO and In_(2)O_(3),which increases the initial resistance of the sensor.展开更多
Composites are composed of multiphase materials, where each phase has specific properties that differ from those of the other phases which can effect on the whole properties of composite. Nanocomposites are class of m...Composites are composed of multiphase materials, where each phase has specific properties that differ from those of the other phases which can effect on the whole properties of composite. Nanocomposites are class of materials that contain at least one phase in the nanometric size range and can be produced by any suitable technique for preparing nanomaterials. Composites are an interesting class of materials that have recently been used in numerous applications, including structural, biomedical, electronics, and environmental applications. In composites, reinforcements might be fibers, particulates, or whiskers. Mechanical alloying(MA) is a promising technique for producing nanocomposite materials that are difficult or impossible to prepare via conventional techniques. In this review, we provide an overview of nanocomposites prepared by the MA process. The mechanism of milling and other milling parameters are overviewed, and insights into sintering categories and parameters are also presented.展开更多
Taking the intrinsic decoherence effect into account, this paper investigates the entanglement of a two-qubit anisotropic Heisenberg XYZ model in the presence of nonuniform external magnetic fields by employing the co...Taking the intrinsic decoherence effect into account, this paper investigates the entanglement of a two-qubit anisotropic Heisenberg XYZ model in the presence of nonuniform external magnetic fields by employing the concurrence as entanglement measure. It is found that both the intrinsic decoherence and the anisotropy of the system give a significant suppression to the entanglement. Moreover it finds that the initial state of the system plays an important role in the time evolution of the entanglement, which means that the entanglement of the system is independent of the nonuniformity and uniformity of the magnetic field when the system is in the initial state ｜ψ （0）） = ｜00） and [ψ′ （0）） = m ｜01） ＋ n ｜10）, respectively.展开更多
We propose a scheme to remotely prepare a general two-particle entangled state by using a bipartite entangled state and a tripartite entangled W state as the quantum channel. Our scheme consists of one sender and two ...We propose a scheme to remotely prepare a general two-particle entangled state by using a bipartite entangled state and a tripartite entangled W state as the quantum channel. Our scheme consists of one sender and two remote receivers. The sender can help either one of the receivers to remotely reconstruct the original state with the assistance of the other receiver＇s single-partlcle orthogona/measurement. We obtain the total success probability and discuss the classical communication cost in our remote state preparation scheme.展开更多
We propose a simple scheme for trapping cold polar molecules in low-field seeking states on the surface of a chip by using a grounded metal plate and two finite-length charged wires that half embanked in an insulating...We propose a simple scheme for trapping cold polar molecules in low-field seeking states on the surface of a chip by using a grounded metal plate and two finite-length charged wires that half embanked in an insulating substrate, calculate the electric field distributions generated by our charged-wire layout in free space and the corresponding Stark potentials for ND3 molecules, and analyze the dependence of the trapping center position on the geometric parameters. Moreover, the loading and trapping processes of cold ND3 molecules are studied by using the Monte Carlo method. Our study shows that the loading efficiency of the trap scheme can reach 11.5%, and the corresponding temperature of the trapped cold molecules is about 26.4 mK.展开更多
An optical atomic clock with 171yb atoms is devised and tested. By using a two-stage Doppler cooling technique, the 171Yb atoms are cooled down to a temperature of 6 ± 3 μK, which is close to the Doppler limit. ...An optical atomic clock with 171yb atoms is devised and tested. By using a two-stage Doppler cooling technique, the 171Yb atoms are cooled down to a temperature of 6 ± 3 μK, which is close to the Doppler limit. Then, the cold 171Yb atoms are loaded into a one-dimensional optical lattice with a wavelength of 759 nm in the Lamb-Dicke regime. Furthermore, these cold 171yb atoms are excited from the ground-state 1S0 to the excited-state 3P0 by a clock laser with a wavelength of 578 nm. Finally, the 1S0-3P0 clock-transition spectrum of these 171yb atoms is obtained by measuring the dependence of the population of the ground-state 1 S0 upon the clock-laser detuning.展开更多
By means of the reduced-density linear entropy, we investigate the properties of dynamical entanglement of vibrations in integrable dimer and realistic small molecules which are initially in the two-mode squeezed vacu...By means of the reduced-density linear entropy, we investigate the properties of dynamical entanglement of vibrations in integrable dimer and realistic small molecules which are initially in the two-mode squeezed vacuum state. It is found that the entropy of the integrable dimer is periodic for weak coupling strength cl and small squeezing parameter r, and there exists a beat phenomenon for strong el and large r. Moreover, the entropy of the small molecules is quasi-periodic for small r, ＆nd the begt phenomenon occurs in the entropy evolution of the two molecules C2D2 and S02 for large r. Our results might be used for molecular quantum computing based on vibrational states.展开更多
Quantum teleportation via the entangled channel composed of a two-qubit Heisenberg XYZ model with Dzyaloshinski-Moriya （DM） interaction in the presence of intrinsic decoherence has been investigated. We find that th...Quantum teleportation via the entangled channel composed of a two-qubit Heisenberg XYZ model with Dzyaloshinski-Moriya （DM） interaction in the presence of intrinsic decoherence has been investigated. We find that the initial state of the channel plays an important role in the teleported state and the average fidelity of teleportation. When the initial channel is in the state ｜ψ1 （0）〉 = a｜00〉 ＋ b｜11〉, the average fidelity is equal to 1/3 constantly, which is independent of the DM interaction and the intrinsic decoherence effect. But when the channel is initially in the state ｜ψ2（0）〉 = a｜01〉 ＋ b｜10〉, the average fidelity is always larger than 2/3. Moreover, under a certain condition, the average fidelity can be enhanced by adjusting the DM interaction, and the intrinsic decoherence leads to a suppression of the fluctuation of the average fidelity.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.10774044)the National Key Basic Research and Development Program of China(Grant No.2010CB922903)+1 种基金the Science and Technology Commission of Shanghai Municipality of China(Grant No.07JC14019)Shanghai Pujiang Talent Program of China(Grant No.07PJ14038)
文摘The modulation transfer spectroscopy in an ytterbium hollow cathode lamp at 399 nm is measured. The error signal for frequency locking is optimized by measuring the dependences of its slope, linewidth and magnitude on various parameters. Under the optimum condition, the laser frequency at 399 nm can be stabilized. The long-term stability of laser frequency is measured by monitoring the fluorescence signal of the ytterbium atomic beam induced by the locked laser. The laser frequency is shown to be tightly locked, and the stabilized laser is successfully applied to the cooling of ytterbium atoms.
基金Supported by the National Natural Science Foundation of China under Grant No 10774044the National Key Basic Research Program of China under Grant No 2010CB922903Shanghai Pujiang Talent Program under Grant No 07PJ14038.
文摘We present the experimental study of modulation transfer spectroscopy of ytterbium atoms in a hollow cathode lamp.The dependences of its linewidth,slope and magnitude on the various experimental parameters are measured and fitted by the well-known theoretical expressions.The experimental results are in good agreement with the theoretical prediction.We have observed the Dicke narrowing effect by increasing the current of the hollow cathode lamp.It is also found that there are the optimal current and laser power to generate the better modulation transfer spectroscopy signal,which can be employed for locking the laser frequency to the atomic transition.
基金Supported by the National Natural Science Foundation of China under Grant No.19474029the Postdoctoral Science Foundation of China。
文摘The valence electron binding energy spectra and orbital electron momentum distributions of ethane(C2H6)have been measured by high resolution(ΔE=0.9eV,Δp=0.1 a.u.)symmetric non-coplanar electron momentum spectroscopy,at an impact energy of 1200eV+binding energy.The high energy resolution is adequate for us to be observe clearly the separated valence orbitals of C_(2)H_(6).
基金Supported by the National Natural Science Foundation of China under Grant No.19474029
文摘The first extensive electron momentum spectroscopy study of the satellite structure in the inner valence region of methane at 1200eV is reported.The experimental momentum profiles belonging to the(2a_(1))^(-1) satellite state are presented at energies 25.3,28.5,31.5,35.5eV,and compared with the 146-G(CI)calculation.
文摘The CS radical was generated by discharging the mixture gas of CS2 and Helium. The Doppler limited spectra of CS were recorded in the region of 12350-12950 cm^-1 using optical heterodyne concentration modulation absorption spectroscopy. Three hundred and twenty-six lines were recorded and assigned to the d^3△-a^3П （8,1） band, in which eighty-three transitions were first observed. A set of improved molecular constants for the d^3△（v=8） and a^3П（v=1） levels were determined by a non-linear least-squares fitting of all the lines to the effective Hamiltonian.
基金Supported by the National Natural Science Foundation of China under Grant No.19874072.
文摘An intracavity CO laser magnetic resonance spectrometer with homogeneous dc electric field applied via a pair of parallel Stark plates in the absorption cell is used to measure the electric dipole moments of free radicals.Taking advantage of high sensitivity and high resolution of this technique and the Stark effect,highly-resolved saturated absorption spectra of v=1-0 transition of ^(15)N^(16)O in the ground state X^(2)II_(3/2) have been successfully observed in the presence of a low electric field.The electric dipole moment of NO in the electronic ground state is determined asμ=0.1566±14 D(Debye)from the analysis of the observed spectra,confirming that,combined with the Stark field,the laser magnetic resonance technique can be an effective and reliable approach for the precise measurement of electric dipole moments of free radicals,especially the unstable ones.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11274116, 113740995 and 1132004, the Shanghai Science and Technology Commission under Grant Nos 11JC1403500 and 10XD1401800, the National Special Science Research Program of China under Grant Nos 2010CB923203 and 2011CB808105, and the Program of Introducing Talents of Discipline to Universities under Grant No B12024.
文摘Femtosecond laser-induced resonance-enhanced multiphoton-ionization photoelectron spectroscopy （REMPI-PS） is faced with two drawbacks of low spectral resolution and poor selective excitation due to the broad spectral bandwidth. We propose a scheme to obtain a high-resolution selective excitation of （2＋1） REMPI-PS by com- bining 7r and cosinusoidal phase modulation. Our theoretical results indicate that the （2＋1） REMPI-PS signals related to neighboring excited states can be differentiated from their indistinguishable photoelectron spectra by the 7r phase modulation, and then their selective excitation can be realized by supplementally adding the cosi- nusoidal phase modulation. Furthermore, the physical mechanism of the high-resolution selective excitation of （2＋1） REMPI-PS is explained by considering the two-photon power spectrum.
基金funded by the Scientific Research Deanship at University of Ha'il,Saudi Arabia through project number RG-21169。
文摘Combinations of metal and lanthanide oxides have been done through casted films for potential medical applications. In this regard, samarium(Ⅲ) oxide/chromium(Ⅲ) oxide/graphene oxide(GO)/polycaprolactone(PCL) based films nano-composites(NCs) were fabricated, pointing their utilization as a biological scaffold for wound dressing purposes. Also, samarium(Ⅲ) oxide and chromium(Ⅲ) oxide have been merged as promising optical constituents due to their unique optical behavior. The structural and compositional examination of the studied NCs was executed by X-ray diffraction(XRD), Raman, and field emission scanning electron microscopy(FESEM). The Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL NC exhibits a surface with a lower roughness degree owing to the presence of GO. Cr_(2)O_(3)shows size reduction upon GO insertion to reach 1.2 μm as the average grain size, whilst Sm_(2)O_(3)records an average grain size of less than 1 μm. As well, the polymeric nano-compositions exhibit variation in contact angle values that hit 29.76°± 3.52°for Sm_(2)O_(3)/PCL, and 48.62°± 1.37°for Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL as the second lowest contact angle. The optical behavior contributes to absorption edge relocation along the x-axis from 1.7 eV for pure PCL, to 2.65 eV for Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL. Regarding biological responses, the cell exposed to 2.5 μg/m L of Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL shows cell viability of 119.31%, while 5 μg/m L hits 99.6%. Additionally, the resulting cell attachment micrographs show layers of fibroblast tissue, besides the proliferation and growth of cultivated cells. Thus, the Sm_(2)O_(3)/Cr_(2)O_(3)/GO/PCL scaffold provides 3D proliferation of fibroblast cells endorsing the wound healing process.
文摘Nanocomposite films consisting of carboxymethyl cellulose,polyethylene oxide(CMC/PEO),and anatase titanium diox-ide(TO)were produced by the use of sol-gel and solution casting techniques.TiO2 nanocrystals were effectively incorporated into CMC/PEO polymers,as shown by X-ray diffraction(XRD)and attenuated total reflectance fourier transform infrared(ATR-FTIR)analysis.The roughness growth is at high levels of TO nanocrystals(TO NCs),which means increasing active sites and defects in CMC/PEO.In differential scanning calorimetry(DSC)thermograms,the change in glass transition temperature(Tg)val-ues verifies that the polymer blend interacts with TO NCs.The increment proportions of TO NCs have a notable impact on the dielectric performances of the nanocomposites,as observed.The electrical properties of the CMC/PEO/TO nanocomposite undergo significant changes.The nanocomposite films exhibit a red alteration in the absorption edge as the concentration of TO NCs increases in the polymer blend.The decline in the energy gap is readily apparent as the weight percentage of TO NCs increases.The photoluminescence(PL)emission spectra indicate that the sites of the luminescence peak maximums show slight variation;peaks get wider,while their intensities decrease dramatically as the concentration of TO increases.These nanocomposite materials show potential for multifunctional applications including optoelectronics,antireflection coatings,pho-tocatalysis,light emitting diodes,and solid polymer electrolytes.
基金funded by the Scientific Research Deanship at University of Ha'il,Saudi Arabia through project number RG-20-222。
文摘Developing a biomaterial for wound healing applications is still a challenge.Herein,dysprosium oxide(Dy_(2)O_(3)),aluminum oxide(Al_(2)O_(3)),and graphene oxide(GO)were embedded in cast films based on polycaprolactone(PCL)to be examined for wound dressing usage.Different techniques were used to characterize the fabricated films including X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR),Raman,and scanning electron microscopy(SEM),besides their biological activity.The thermogravimetric analysis(TGA)exhibits high thermal stability as the scaffold weight decreases slightly to 98.6%after raising the temperature from room temperature to 280℃.The cell viability was investigated and it is shown that the viable cells grow up to approximately 93%at 75μg/mL.Meanwhile,the cell attachment shows excellent behavior as the cells attach on most of the surface of the modified PCL which shows high biocompatibility.
文摘Poly(p-phenylenediamine)/chitosan (PPPDA/Chi) composite was prepared by in situ chemical oxidative polymerization of p-phenylenediamine (PPPDA) into chitosan (Chi) using ammonium persulphate (APS) as an oxidant. PPPDA and PPPDA/Chi composite were characterized by FT-IR spectra and SEM before and after copper loading. In batch adsorption method, the maximum removal of copper was experienced when 1 g/L of PPPDA and PPPDA/Chi composite dosages were used at pH 5.0 for PPPDA and 6.0 for PPPDA/Chi composite for 360 min for both sorbents. PPPDA showed adsorption capacity q<sub>e</sub><sup>max</sup> of 650 mg/g whereas its composite achieved q<sub>e</sub><sup>max</sup> of 573 mg/g. The experimental data correlate well with the Freundlich isotherm equation and the pseudo-second order kinetic model. The Cu(II), loaded PPPDA and its composite can be efficiently reused for as many as four cycles. The Cu(II)-loaded sorbents showed high antibacterial efficiency against Gram-positive and Gram-negative bacteria than their unloaded forms.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.10674047,10804031,10904037,10904060,10974055,11034002,and61205198)the National Key Basic Research and Development Program of China(Grant Nos.2006CB921604 and 2011CB921602)+2 种基金the Basic Key Program of Shanghai Municipality,China(Grant No.07JC14017)the Fundamental Research Funds for the Central Universitiesthe Shanghai Leading Academic Discipline Project,China(Grant No.B408)
文摘We propose a controllable high-efficiency electrostatic surface trap for cold polar molecules on a chip by using two insulator-embedded charged rings and a grounded conductor plate. We calculate Stark energy structure pattern of ND3 molecules in an external electric field using the method of matrix diagonalization. We analyze how the voltages that are applied to the ring electrodes affect the depth of the efficient well and the controllability of the distance between the trap center and the surface of the chip. To obtain a better understanding, we simulate the dynamical loading and trapping processes of ND3 molecules in a ｜J, KM = ｜1,-1 state by using classical Monte–Carlo method. Our study shows that the loading efficiency of our trap can reach ～ 88%. Finally, we study the adiabatic cooling of cold molecules in our surface trap by linearly lowering the potential-well depth（i.e., lowering the trapping voltage）, and find that the temperature of the trapped ND3 molecules can be adiabatically cooled from 34.5 m K to ～ 5.8 m K when the trapping voltage is reduced from-35 k V to-3 k V.
基金financially supported by the National R&D Program of China(No.2020YFB2008702)the National Natural Science Foundation of China(Nos.62033002,61833006,62071112 and 61973058)+4 种基金the 111 Project(No.B16009)the Fundamental Research Funds for the Central Universities in China(Nos.N180408018,N2004019 and N2004028)Liaoning Revitalization Talents Program(No.XLYC1807198)Liaoning Province Natural Science Foundation(No.2020-KF-11-04)Hebei Natural Science Foundation(No.F2020501040)。
文摘In this study,ZnO/In_(2)O_(3)-heterostructured nanosheets were prepared using a one-step hydrothermal method.The effects of ZnO content on the gas-sensing performance were discussed,with ZnO/In_(2)O_(3)-2 exhibiting the highest performance among the prepared sensors.The response of ZnO/In_(2)O_(3)-2 to n-butanol was 302 at 26℃,which was 11.93 times higher than that of pure In_(2)O_(3).Among the eight tested gases,ZnO/In_(2)O_(3)-2 displayed the highest response to n-butanol.Moreover,the lower detection limit of the ZnO/In_(2)O_(3)nanosheets was reduced from 10×10^(-6)to 0.1×10^(-6)(for pure In_(2)O_(3)nanosheets)toward n-butanol.This is because the doping of Zn2+increases the number of oxygen vacancies on the sensor surface and allows the formation of an n-n heterostructure between ZnO and In_(2)O_(3),which increases the initial resistance of the sensor.
文摘Composites are composed of multiphase materials, where each phase has specific properties that differ from those of the other phases which can effect on the whole properties of composite. Nanocomposites are class of materials that contain at least one phase in the nanometric size range and can be produced by any suitable technique for preparing nanomaterials. Composites are an interesting class of materials that have recently been used in numerous applications, including structural, biomedical, electronics, and environmental applications. In composites, reinforcements might be fibers, particulates, or whiskers. Mechanical alloying(MA) is a promising technique for producing nanocomposite materials that are difficult or impossible to prepare via conventional techniques. In this review, we provide an overview of nanocomposites prepared by the MA process. The mechanism of milling and other milling parameters are overviewed, and insights into sintering categories and parameters are also presented.
基金Project supported by the State Key Development Program for Basic Research of China (Grant No 2006CB921604)the National Natural Science Foundation of China (Grant Nos 60708003,60578050 and 10434060)
文摘Taking the intrinsic decoherence effect into account, this paper investigates the entanglement of a two-qubit anisotropic Heisenberg XYZ model in the presence of nonuniform external magnetic fields by employing the concurrence as entanglement measure. It is found that both the intrinsic decoherence and the anisotropy of the system give a significant suppression to the entanglement. Moreover it finds that the initial state of the system plays an important role in the time evolution of the entanglement, which means that the entanglement of the system is independent of the nonuniformity and uniformity of the magnetic field when the system is in the initial state ｜ψ （0）） = ｜00） and [ψ′ （0）） = m ｜01） ＋ n ｜10）, respectively.
基金The project supported by National Natural Science Foundation of China under Grant Nos. 60578050 and 10434060 We would like to thank Dr. Yong-Jian Han and Dr. Zheng-Wei Zhou for their helpful suggestions on the topic of classical communication cost.
文摘We propose a scheme to remotely prepare a general two-particle entangled state by using a bipartite entangled state and a tripartite entangled W state as the quantum channel. Our scheme consists of one sender and two remote receivers. The sender can help either one of the receivers to remotely reconstruct the original state with the assistance of the other receiver＇s single-partlcle orthogona/measurement. We obtain the total success probability and discuss the classical communication cost in our remote state preparation scheme.
基金Project supported by the National Natural Science Foundation of China （Grant Nos. 10674047, 10804031, 10904037, 10974055, 11034002, and 11274114）, the National Basic Research Program of China （Grant Nos. 2006CB921604 and 2011 CB921602）, the Basic Key Program of Shanghai Municipality of China （Grant No. 07JCI4017）, and the Leading Academic Discipline Project of Shanghai Municipality of China （Grant No. 8408）.
文摘We propose a simple scheme for trapping cold polar molecules in low-field seeking states on the surface of a chip by using a grounded metal plate and two finite-length charged wires that half embanked in an insulating substrate, calculate the electric field distributions generated by our charged-wire layout in free space and the corresponding Stark potentials for ND3 molecules, and analyze the dependence of the trapping center position on the geometric parameters. Moreover, the loading and trapping processes of cold ND3 molecules are studied by using the Monte Carlo method. Our study shows that the loading efficiency of the trap scheme can reach 11.5%, and the corresponding temperature of the trapped cold molecules is about 26.4 mK.
基金supported by the National Basic Research Program of China (Grant Nos. 2012CB821302 and 2010CB922903)the National Natural Science Foundation of China (Grant Nos. 11134003 and 10774044)the Shanghai Excellent Academic Leaders Program of China (Grant No. 12XD1402400)
文摘An optical atomic clock with 171yb atoms is devised and tested. By using a two-stage Doppler cooling technique, the 171Yb atoms are cooled down to a temperature of 6 ± 3 μK, which is close to the Doppler limit. Then, the cold 171Yb atoms are loaded into a one-dimensional optical lattice with a wavelength of 759 nm in the Lamb-Dicke regime. Furthermore, these cold 171yb atoms are excited from the ground-state 1S0 to the excited-state 3P0 by a clock laser with a wavelength of 578 nm. Finally, the 1S0-3P0 clock-transition spectrum of these 171yb atoms is obtained by measuring the dependence of the population of the ground-state 1 S0 upon the clock-laser detuning.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11174081,11034002,11104075,60708003,and 11134003the National Basic Research Program of China under Grant Nos.2011CB921602 and 2012CB821302
文摘By means of the reduced-density linear entropy, we investigate the properties of dynamical entanglement of vibrations in integrable dimer and realistic small molecules which are initially in the two-mode squeezed vacuum state. It is found that the entropy of the integrable dimer is periodic for weak coupling strength cl and small squeezing parameter r, and there exists a beat phenomenon for strong el and large r. Moreover, the entropy of the small molecules is quasi-periodic for small r, ＆nd the begt phenomenon occurs in the entropy evolution of the two molecules C2D2 and S02 for large r. Our results might be used for molecular quantum computing based on vibrational states.
基金Project supported by the National Natural Science Foundation of China (Grant Nos 60708003, 60578050 and 10434060)the National Basic Research Program of China (Grant No 2006CB921604)+1 种基金the Shanghai Science and Technology Committee (GrantNo 07JC14017)by the Director Fund of State Key Laboratory of Precision Spectroscopy
文摘Quantum teleportation via the entangled channel composed of a two-qubit Heisenberg XYZ model with Dzyaloshinski-Moriya （DM） interaction in the presence of intrinsic decoherence has been investigated. We find that the initial state of the channel plays an important role in the teleported state and the average fidelity of teleportation. When the initial channel is in the state ｜ψ1 （0）〉 = a｜00〉 ＋ b｜11〉, the average fidelity is equal to 1/3 constantly, which is independent of the DM interaction and the intrinsic decoherence effect. But when the channel is initially in the state ｜ψ2（0）〉 = a｜01〉 ＋ b｜10〉, the average fidelity is always larger than 2/3. Moreover, under a certain condition, the average fidelity can be enhanced by adjusting the DM interaction, and the intrinsic decoherence leads to a suppression of the fluctuation of the average fidelity.
