Zeolitic imidazole frameworks(ZIFs)are a class of three-dimensional(3D)skeletalmaterials with zeolitic topology composed of metal ions and imidazolium ligands,which combine the advantages of zeolites and metal-organic...Zeolitic imidazole frameworks(ZIFs)are a class of three-dimensional(3D)skeletalmaterials with zeolitic topology composed of metal ions and imidazolium ligands,which combine the advantages of zeolites and metal-organic frameworks.ZIFs are widely used for adsorption of carbon dioxide(CO_(2))from flue gas due to its excellent hydrophobicity,chemical stability,thermal stability and gas adsorption properties.This study focuses on the effects of structures of ZIFs on CO_(2)capture and separation from the viewpoints of topologies,pore channels,ligand functional groups and composite structures.On this basis,the mechanisms of CO_(2)adsorption and selective separation are reviewed,as well as the challenges such as hydrophobicity,thermal and chemical stability faced by ZIFs in practical applications.展开更多
基金supported by the Fundamental Research Program of Shanxi Province(Nos.20210302124003 and 20210302124015)the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(No.2021L032)+2 种基金the National Natural Science Foundation of China(No.52103307)China Postdoctoral Science Foundation(No.2023M742575)the General Program of Shanxi Province(No.202203021211150).
文摘Zeolitic imidazole frameworks(ZIFs)are a class of three-dimensional(3D)skeletalmaterials with zeolitic topology composed of metal ions and imidazolium ligands,which combine the advantages of zeolites and metal-organic frameworks.ZIFs are widely used for adsorption of carbon dioxide(CO_(2))from flue gas due to its excellent hydrophobicity,chemical stability,thermal stability and gas adsorption properties.This study focuses on the effects of structures of ZIFs on CO_(2)capture and separation from the viewpoints of topologies,pore channels,ligand functional groups and composite structures.On this basis,the mechanisms of CO_(2)adsorption and selective separation are reviewed,as well as the challenges such as hydrophobicity,thermal and chemical stability faced by ZIFs in practical applications.
