Based on the analysis of collective activities of ant colonies, the typicalexample of swarm intelligence, a new approach to construct swarm intelligence basedmulti-agent-system (SMAS) for dynamic real-time scheduling ...Based on the analysis of collective activities of ant colonies, the typicalexample of swarm intelligence, a new approach to construct swarm intelligence basedmulti-agent-system (SMAS) for dynamic real-time scheduling for semiconductor wafer fab is proposed.The relevant algorithm, pheromone-based dynamic real-time scheduling algorithm (PBDR), is given.MIMAC test bed data set mini-fab is used to compare PBDR with FIFO (first in first out),SRPT(shortest remaining processing time) and CR(critical ratio) under three different release rules,i.e. deterministic rule, Poisson rule and CONWIP (constant WIP). It is shown that PBDR is prior toFIFO, SRPT and CR with better performance of cycle time, throughput, and on-time delivery,especially for on-time delivery performance.展开更多
In radar target tracking application, the observation noise is usually non-Gaussian, which is also referred as glint noise. The performances of conventional trackers degra de severely in the presence of glint noise. A...In radar target tracking application, the observation noise is usually non-Gaussian, which is also referred as glint noise. The performances of conventional trackers degra de severely in the presence of glint noise. An improved particle filter, Markov chain Monte Carlo particle filter (MCMC-PF), is applied to cope with radar target tracking when the measurements are perturbed by glint noise. Tracking performance of the filter is demonstrated in the present of glint noise by computer simulation.展开更多
Two procedures are developed here to compute the Peak-to-Average envelope power Ratio (PAR) of the continuous signal with N subcarriers in the Orthogonal Frequency Division Multiplexing (OFDM) and Discrete MultiTone (...Two procedures are developed here to compute the Peak-to-Average envelope power Ratio (PAR) of the continuous signal with N subcarriers in the Orthogonal Frequency Division Multiplexing (OFDM) and Discrete MultiTone (DMT) systems. The first one is an accurate computation method for small N, in which the peak of the Instantaneous Envelope Power Function (IEPF) is obtained by solving the roots of a polynomial, a linear sum of a set of Chebyshev polynomials of the first kind and the second kind. The second procedure, called Stepwise Refinement Algorithm (SRA), is a highly precise and fast computation method for arbitrary N by using Inverse Fast Fourier Transform (IFFT), the Chirp Z-Transform (CZT) and a newly introduced relationship between the IEPF peak and its most adjacent oversampled sample.展开更多
The PMD-induced pulse broadening may cause the degradation ofreceiver sensitivity and has negative effects on the power spectrumof received signals. The expression s of PMO-induced pulse broadeningeffects on receiver ...The PMD-induced pulse broadening may cause the degradation ofreceiver sensitivity and has negative effects on the power spectrumof received signals. The expression s of PMO-induced pulse broadeningeffects on receiver sensitivity are derived based on the concept ofman square pulse width. The effects of PMD on the spectrum ofreceived power are analyzed in detail. Finally, the scheme isdiscussed with which the poser of a certain frequency component isextracted as a feedback control signal in a PMD compensation system.展开更多
The transmission delay of photogenerated carriers in a CMOS-process-compatible double photodiode (DPD) is analyzed by using device simulation.The DPD small signal equivalent circuit model which includes transmission d...The transmission delay of photogenerated carriers in a CMOS-process-compatible double photodiode (DPD) is analyzed by using device simulation.The DPD small signal equivalent circuit model which includes transmission delay of photogenerated carriers is given.From analysis on the frequency domain of the circuit model the device has two poles.One has the relationship with junction capacitance and the DPD’s load,the other with the depth and the doping concentration of the N-well in the DPD.Different depth of the N-well and different area of the DPDs with bandwidth were compared.The analysis results are important to design the high speed DPDs.展开更多
The characteristic of EDFA in WDM system is analyzed. The simulation system based on the architecture of the China Information Network (CAINONET) is introduced, and the influence of noise figure, gain unflatness and o...The characteristic of EDFA in WDM system is analyzed. The simulation system based on the architecture of the China Information Network (CAINONET) is introduced, and the influence of noise figure, gain unflatness and output power of EDFA on the BER performance and scale of network is investigated. Moreover, the influence of noise figure is studied with different crosstalk . Meanwhile, it is indicated that it is important to apply the "node isolation principle" in the optical network. The research results can provide the valuable reference for the practical construction of all optical network .展开更多
A novel multiresolution pyramidal edge detector, based on adaptive weighted fuzzy mean(AWFM)filtering and fuzzy linking model, is presented in this paper. The algorithm first constructs a pyramidal structure by repeti...A novel multiresolution pyramidal edge detector, based on adaptive weighted fuzzy mean(AWFM)filtering and fuzzy linking model, is presented in this paper. The algorithm first constructs a pyramidal structure by repetitive AWFM filtering and subsampling of original image. Then it utilizes multiple heuristic linking criteria between the edge nodes of two adjacent levels and considers the linkage as a fuzzy model, which is trained offline. Through this fuzzy linking model, the boundaries detected at coarse resolution are propagated and refined to the bottom level from the coarse-to fine edge detection. The validation experiment results demonstrate that the proposed approach has superior performance compared with standard fixed resolution detector andprevious multiresolution approach, especially in impulse noise environment.展开更多
Two novel poly[(3-alkylthiophene-2,5-diyl)-(benzylidenequinomethane-2,5-diyl)s] derivatives, poly[ (3-butylthiophene-2,5-diyl)-( p-N,N-dimethylamino) benzylidenequinomethane-2,5-diyl) ] ( PBTDMABQ) and poly [( 3-octyl...Two novel poly[(3-alkylthiophene-2,5-diyl)-(benzylidenequinomethane-2,5-diyl)s] derivatives, poly[ (3-butylthiophene-2,5-diyl)-( p-N,N-dimethylamino) benzylidenequinomethane-2,5-diyl) ] ( PBTDMABQ) and poly [( 3-octylthiophene2,5-diyl) -(p-N, N-dimethylamino ) benzylidenequinomethane-2, 5-diyl)] (POTDMABQ), were synthesized.The band gaps of the two polymers are calculated as 1. 75 eV for PBTDMABQ and 1. 69 eV for POTDMABQ,respectively. The homogenous films of the two polymers were prepared and their third-ordernonlinear optical properties were studied by the backward degenerate four-wave mixing at 532 nm. Byusing the relative measurement technique, the third-order nonlinear optical susceptibilities ofPBTDMABQ and POTDMABQ are calculated as 5. 62 X 10^(-9) and 1. 22 X 10^(-8) ESU, respectively. It isfound that substituted alky groups have strong effects on the band gap and nonlinear opticalproperties of the two polymers. The relatively big third-order nonlinear optical susceptibilitiesand small band gap of POTDMABQ resulted mainly from the longer alkyl with strong electron-donatingability can enhance the delocation degree of conjugated π electronics.展开更多
Threshold current characteristics of intracavity-contacted oxide-confinedvertical-cavity surface-emitting laser had been investigated in detail. Threshold currentcharacteristics not only were depended on the size of o...Threshold current characteristics of intracavity-contacted oxide-confinedvertical-cavity surface-emitting laser had been investigated in detail. Threshold currentcharacteristics not only were depended on the size of oxide-aperture, but also were also stronglyaffected by the mismatch of its lasing mode and gain peak. For the same degree detuning of the gainpeak and lasing mode at room temperature, the threshold current was approximately proportional tothe square of the oxide-aperture diameter of above 5 μm. For the same oxide-aperture device, thelarger the detuning degree of the lasing mode shifted to the shorter wavelength of the gain peak atroom temperature was, the lower the minimum threshold current was. The wavelengths of the lasingmode and gain peak were ± N X 10 nm detuning at 300 K, The temperature of the minimum thresholdcurrent was changed to be about ± N X 40 K(N real number). The calculated results were consistentwith the experimental ones.展开更多
According to the Wide Area Network model, we formulate Internet flow control as a constrained convex programming problem, where the objective is to maximize the total utility of all sources over their transmission rat...According to the Wide Area Network model, we formulate Internet flow control as a constrained convex programming problem, where the objective is to maximize the total utility of all sources over their transmission rates. Based on this formulation, flow control can be converted to a normal unconstrained optimization problem through the barrier function method, so that it can be solved by means of a gradient projection algorithm with properly rate iterations. We prove that the algorithm converges to the global optimal point, which is also a stable proportional fair rate allocation point, provided that the step size is properly chosen. The main difficulty facing the realization of iteration algorithm is the distributed computation of congestion measure. Fortunately, Explicit Congestion Notification (ECN) is likely to be used to improve the performance of TCP in the near future. By using ECN, it is possible to realize the iteration algorithm in IP networks. Our algorithm is divided into two parts, algorithms in the router and in the source. The router marks the ECN bit with a probability that varies as its buffer occupancy varies, so that the congestion measure of links can be communicated to the source when the marked ECN bits are reflected back from its destination. Source rates are then updated by all sessions according to the received congestion measure. The main advantage of our scheme is its fast convergence ability and robustness; it can also provide the network with zero packet loss by properly choosing the queue threshold and provide differentiated service to users by applying different utility functions.展开更多
A kind of novel binary phase code named sidelobe suppression code is proposed in this paper. It is defined to be the code whose corresponding optimal sidelobe suppression filter outputs the minimum sidelobes. It is sh...A kind of novel binary phase code named sidelobe suppression code is proposed in this paper. It is defined to be the code whose corresponding optimal sidelobe suppression filter outputs the minimum sidelobes. It is shown that there do exist sidelobe suppression codes better than the conventional optimal codes-Barker codes. For example, the sidelobe suppression code of length 11 with filter of length 39 has better sidelobe level up to 17dB than that of Barker code with the same code length and filter length.展开更多
For the efficient dynamic dispersion compensation, it is essential to monitor the dispersion accurately. The existing main dispersion monitoring techniques in high bit-rate optical communication systems are presented ...For the efficient dynamic dispersion compensation, it is essential to monitor the dispersion accurately. The existing main dispersion monitoring techniques in high bit-rate optical communication systems are presented as well as their operating principles and research progress. The advantages and disadvantages of these methods are analyzed and discussed.展开更多
A kind of fiber Bragg grating pressure sensor based on corrugated diaphragm is proposed. The relationship between the central wavelength of reflective wave of FBG and pressure is given, and the expression of the press...A kind of fiber Bragg grating pressure sensor based on corrugated diaphragm is proposed. The relationship between the central wavelength of reflective wave of FBG and pressure is given, and the expression of the pressure sensitivity coefficient is also given. Within the range from 0 MPa to 0.3 MPa, the experimental pressure sensitivity is 7.83 nm/MPa, which is 2 610 times than that of the bare fiber grating. The experimental results agree with the theoretical analysis. It is indicated that the expected pressure sensitivity of the sensor can be obtained by optimizing the size and mechanical parameters of the corrugated diaphragm.展开更多
A 2-cm long Bragg grating with reflectivity of～99.95% in B/Ge codoped optical fiber without hydrogen loading was created by phase-mask method with a pulsed KrF excimer laser at 248 nm. DC and AC components of refract...A 2-cm long Bragg grating with reflectivity of～99.95% in B/Ge codoped optical fiber without hydrogen loading was created by phase-mask method with a pulsed KrF excimer laser at 248 nm. DC and AC components of refractive index change were analyzed by monitoring transmission spectrum evolution during the writing process of fiber Bragg grating. The relations of the evolution of center wavelength and reflectivity with number of pulses were respectively investigated.展开更多
Two alkyl substituted polythiophene derivatives: poly(3-hexylthiophene)(P3HT) and poly(3-decylthiophene)(P3DT), have synthesized by oxidation coupling polymerization of 3-alkylthiophene using iron(III) chloride as cat...Two alkyl substituted polythiophene derivatives: poly(3-hexylthiophene)(P3HT) and poly(3-decylthiophene)(P3DT), have synthesized by oxidation coupling polymerization of 3-alkylthiophene using iron(III) chloride as catalyst in chloroform. While both polymers in pure chloroform solution have maximum absorption at approximately same wavelength of 440nm, they behave differently with respect to changes observed on their UV-visible and photoluminescence spectra when the quality of the poor solvent is changed in good solvent (chloroform) / poor solvent (methanol) mixtures. With increasing volume fraction of methanol in mixtures, the absorption spectra of P3HT and P3DT red-shift, peaking at maximum wavelength of 495nm (P3HT) and 510nm(P3DT). Furthermore, the absorption spectra of the two polymers in chloroform blue-shift as the temperature rises. P3HT shows 4.73nm blue-shifts at 50℃ in contrast to the case at 20℃, while P3DT blue-shifts about 5.04nm. The photoluminescence spectra of the two polymers in mixed solution are also investigated, which show that the luminescence spectra shift to longer wavelength with an accompanying drop in the PL intensity as methanol is increased. The absorption and emission spectra of the two polymers in a poor solvent and a thin film are similar, which indicate that a similar longer conjugation length in the two cases. It could conclude that the polymers exist almost the same conformations and aggregations in both a poor solvent and a thin film. P3DT exhibits more sensitive spectra properties (big red-shifts in both absorption and luminescence spectra in poor solvents and large blue-shifts at high temperature) with contrast to P3HT, which imply that long side alkyl may improve the chromic properties of the polymer.展开更多
In order to improve the nonlinear optical property and stability of azo-dye chromophore, the nonlinear optical polyimide (NLOPI) attached with azo chromophore side chain is synthesized by diazo coupling reaction of 4-...In order to improve the nonlinear optical property and stability of azo-dye chromophore, the nonlinear optical polyimide (NLOPI) attached with azo chromophore side chain is synthesized by diazo coupling reaction of 4-nitrobenzenediazonium tetrafloroborate. The designed chemical structure of production can be proved in the infrared spectrum and ultraviolet-visible absorption spectrum. The NLOPI exhibited UV-Vis absorption of the azobenzene chromophore in the vicinity of the wavelengths of 330 and 490 nm. The broad amorphous peak proved that the NLOPI was amorphous with a little periodical structure along the side chain. According to transmission electron microscope, the NLOPI film was homogeneous. NLOPI only displayed a decrease in mass of about 5% at the temperature of 400 ℃ through thermogravimetric analysis.展开更多
To efficiently retrieve relevant document from the rapid proliferation of large information collections, a novel immune algorithm for document query optimization is proposed. The essential ideal of the immune algorith...To efficiently retrieve relevant document from the rapid proliferation of large information collections, a novel immune algorithm for document query optimization is proposed. The essential ideal of the immune algorithm is that the crossover and mutation of operator are constructed according to its own characteristics of information retrieval. Immune operator is adopted to avoid degeneracy. Relevant documents retrieved are merged to a single document list according to rank formula. Experimental results show that the novel immune algorithm can lead to substantial improvements of relevant document retrieval effectiveness.展开更多
This paper proposes a TSK fuzzy approach to channel estimation for Orthogonal Frequency Division Multiplexing （OFDM） systems. The information of dispersive fading channel is described by using TSK fuzzy model, which...This paper proposes a TSK fuzzy approach to channel estimation for Orthogonal Frequency Division Multiplexing （OFDM） systems. The information of dispersive fading channel is described by using TSK fuzzy model, which is updated by the pilot symbols. The proposed approach can trace the variation of channel and it is computationally simple. Its performance is tested via simulations. Results show that it is comparable to that of ideal Minimum Mean-Square-Error （MMSE） method, especially at the low Signal to Noise Ratio （SNR）.展开更多
基金This project is supported by National 973 Project of China (No.2002-CB312202) National Natural Science Foundation of China (No.60374005, No.60104004) Chinese Postdoctoral Fellowship Foundation.
文摘Based on the analysis of collective activities of ant colonies, the typicalexample of swarm intelligence, a new approach to construct swarm intelligence basedmulti-agent-system (SMAS) for dynamic real-time scheduling for semiconductor wafer fab is proposed.The relevant algorithm, pheromone-based dynamic real-time scheduling algorithm (PBDR), is given.MIMAC test bed data set mini-fab is used to compare PBDR with FIFO (first in first out),SRPT(shortest remaining processing time) and CR(critical ratio) under three different release rules,i.e. deterministic rule, Poisson rule and CONWIP (constant WIP). It is shown that PBDR is prior toFIFO, SRPT and CR with better performance of cycle time, throughput, and on-time delivery,especially for on-time delivery performance.
文摘In radar target tracking application, the observation noise is usually non-Gaussian, which is also referred as glint noise. The performances of conventional trackers degra de severely in the presence of glint noise. An improved particle filter, Markov chain Monte Carlo particle filter (MCMC-PF), is applied to cope with radar target tracking when the measurements are perturbed by glint noise. Tracking performance of the filter is demonstrated in the present of glint noise by computer simulation.
文摘Two procedures are developed here to compute the Peak-to-Average envelope power Ratio (PAR) of the continuous signal with N subcarriers in the Orthogonal Frequency Division Multiplexing (OFDM) and Discrete MultiTone (DMT) systems. The first one is an accurate computation method for small N, in which the peak of the Instantaneous Envelope Power Function (IEPF) is obtained by solving the roots of a polynomial, a linear sum of a set of Chebyshev polynomials of the first kind and the second kind. The second procedure, called Stepwise Refinement Algorithm (SRA), is a highly precise and fast computation method for arbitrary N by using Inverse Fast Fourier Transform (IFFT), the Chirp Z-Transform (CZT) and a newly introduced relationship between the IEPF peak and its most adjacent oversampled sample.
文摘The PMD-induced pulse broadening may cause the degradation ofreceiver sensitivity and has negative effects on the power spectrumof received signals. The expression s of PMO-induced pulse broadeningeffects on receiver sensitivity are derived based on the concept ofman square pulse width. The effects of PMD on the spectrum ofreceived power are analyzed in detail. Finally, the scheme isdiscussed with which the poser of a certain frequency component isextracted as a feedback control signal in a PMD compensation system.
文摘The transmission delay of photogenerated carriers in a CMOS-process-compatible double photodiode (DPD) is analyzed by using device simulation.The DPD small signal equivalent circuit model which includes transmission delay of photogenerated carriers is given.From analysis on the frequency domain of the circuit model the device has two poles.One has the relationship with junction capacitance and the DPD’s load,the other with the depth and the doping concentration of the N-well in the DPD.Different depth of the N-well and different area of the DPDs with bandwidth were compared.The analysis results are important to design the high speed DPDs.
文摘The characteristic of EDFA in WDM system is analyzed. The simulation system based on the architecture of the China Information Network (CAINONET) is introduced, and the influence of noise figure, gain unflatness and output power of EDFA on the BER performance and scale of network is investigated. Moreover, the influence of noise figure is studied with different crosstalk . Meanwhile, it is indicated that it is important to apply the "node isolation principle" in the optical network. The research results can provide the valuable reference for the practical construction of all optical network .
文摘A novel multiresolution pyramidal edge detector, based on adaptive weighted fuzzy mean(AWFM)filtering and fuzzy linking model, is presented in this paper. The algorithm first constructs a pyramidal structure by repetitive AWFM filtering and subsampling of original image. Then it utilizes multiple heuristic linking criteria between the edge nodes of two adjacent levels and considers the linkage as a fuzzy model, which is trained offline. Through this fuzzy linking model, the boundaries detected at coarse resolution are propagated and refined to the bottom level from the coarse-to fine edge detection. The validation experiment results demonstrate that the proposed approach has superior performance compared with standard fixed resolution detector andprevious multiresolution approach, especially in impulse noise environment.
基金National Natural Science Foundation of China (60277002)
文摘Two novel poly[(3-alkylthiophene-2,5-diyl)-(benzylidenequinomethane-2,5-diyl)s] derivatives, poly[ (3-butylthiophene-2,5-diyl)-( p-N,N-dimethylamino) benzylidenequinomethane-2,5-diyl) ] ( PBTDMABQ) and poly [( 3-octylthiophene2,5-diyl) -(p-N, N-dimethylamino ) benzylidenequinomethane-2, 5-diyl)] (POTDMABQ), were synthesized.The band gaps of the two polymers are calculated as 1. 75 eV for PBTDMABQ and 1. 69 eV for POTDMABQ,respectively. The homogenous films of the two polymers were prepared and their third-ordernonlinear optical properties were studied by the backward degenerate four-wave mixing at 532 nm. Byusing the relative measurement technique, the third-order nonlinear optical susceptibilities ofPBTDMABQ and POTDMABQ are calculated as 5. 62 X 10^(-9) and 1. 22 X 10^(-8) ESU, respectively. It isfound that substituted alky groups have strong effects on the band gap and nonlinear opticalproperties of the two polymers. The relatively big third-order nonlinear optical susceptibilitiesand small band gap of POTDMABQ resulted mainly from the longer alkyl with strong electron-donatingability can enhance the delocation degree of conjugated π electronics.
基金National Natural Science Foundation of China ( 60276033 ) National High Technology Research and Development Program of china(2002AA312070)+1 种基金 National Key Basic Research Plan of china(G20000683-02) Beijing Natural Science Foundation of China
文摘Threshold current characteristics of intracavity-contacted oxide-confinedvertical-cavity surface-emitting laser had been investigated in detail. Threshold currentcharacteristics not only were depended on the size of oxide-aperture, but also were also stronglyaffected by the mismatch of its lasing mode and gain peak. For the same degree detuning of the gainpeak and lasing mode at room temperature, the threshold current was approximately proportional tothe square of the oxide-aperture diameter of above 5 μm. For the same oxide-aperture device, thelarger the detuning degree of the lasing mode shifted to the shorter wavelength of the gain peak atroom temperature was, the lower the minimum threshold current was. The wavelengths of the lasingmode and gain peak were ± N X 10 nm detuning at 300 K, The temperature of the minimum thresholdcurrent was changed to be about ± N X 40 K(N real number). The calculated results were consistentwith the experimental ones.
文摘According to the Wide Area Network model, we formulate Internet flow control as a constrained convex programming problem, where the objective is to maximize the total utility of all sources over their transmission rates. Based on this formulation, flow control can be converted to a normal unconstrained optimization problem through the barrier function method, so that it can be solved by means of a gradient projection algorithm with properly rate iterations. We prove that the algorithm converges to the global optimal point, which is also a stable proportional fair rate allocation point, provided that the step size is properly chosen. The main difficulty facing the realization of iteration algorithm is the distributed computation of congestion measure. Fortunately, Explicit Congestion Notification (ECN) is likely to be used to improve the performance of TCP in the near future. By using ECN, it is possible to realize the iteration algorithm in IP networks. Our algorithm is divided into two parts, algorithms in the router and in the source. The router marks the ECN bit with a probability that varies as its buffer occupancy varies, so that the congestion measure of links can be communicated to the source when the marked ECN bits are reflected back from its destination. Source rates are then updated by all sessions according to the received congestion measure. The main advantage of our scheme is its fast convergence ability and robustness; it can also provide the network with zero packet loss by properly choosing the queue threshold and provide differentiated service to users by applying different utility functions.
基金Supported by 10th 5-year National Defense Pre-research Project(No.106010303)
文摘A kind of novel binary phase code named sidelobe suppression code is proposed in this paper. It is defined to be the code whose corresponding optimal sidelobe suppression filter outputs the minimum sidelobes. It is shown that there do exist sidelobe suppression codes better than the conventional optimal codes-Barker codes. For example, the sidelobe suppression code of length 11 with filter of length 39 has better sidelobe level up to 17dB than that of Barker code with the same code length and filter length.
文摘For the efficient dynamic dispersion compensation, it is essential to monitor the dispersion accurately. The existing main dispersion monitoring techniques in high bit-rate optical communication systems are presented as well as their operating principles and research progress. The advantages and disadvantages of these methods are analyzed and discussed.
文摘A kind of fiber Bragg grating pressure sensor based on corrugated diaphragm is proposed. The relationship between the central wavelength of reflective wave of FBG and pressure is given, and the expression of the pressure sensitivity coefficient is also given. Within the range from 0 MPa to 0.3 MPa, the experimental pressure sensitivity is 7.83 nm/MPa, which is 2 610 times than that of the bare fiber grating. The experimental results agree with the theoretical analysis. It is indicated that the expected pressure sensitivity of the sensor can be obtained by optimizing the size and mechanical parameters of the corrugated diaphragm.
基金National Basic Research Program of China (2003CB314906)
文摘A 2-cm long Bragg grating with reflectivity of～99.95% in B/Ge codoped optical fiber without hydrogen loading was created by phase-mask method with a pulsed KrF excimer laser at 248 nm. DC and AC components of refractive index change were analyzed by monitoring transmission spectrum evolution during the writing process of fiber Bragg grating. The relations of the evolution of center wavelength and reflectivity with number of pulses were respectively investigated.
基金National Natural Science Foundation of China (60277002)
文摘Two alkyl substituted polythiophene derivatives: poly(3-hexylthiophene)(P3HT) and poly(3-decylthiophene)(P3DT), have synthesized by oxidation coupling polymerization of 3-alkylthiophene using iron(III) chloride as catalyst in chloroform. While both polymers in pure chloroform solution have maximum absorption at approximately same wavelength of 440nm, they behave differently with respect to changes observed on their UV-visible and photoluminescence spectra when the quality of the poor solvent is changed in good solvent (chloroform) / poor solvent (methanol) mixtures. With increasing volume fraction of methanol in mixtures, the absorption spectra of P3HT and P3DT red-shift, peaking at maximum wavelength of 495nm (P3HT) and 510nm(P3DT). Furthermore, the absorption spectra of the two polymers in chloroform blue-shift as the temperature rises. P3HT shows 4.73nm blue-shifts at 50℃ in contrast to the case at 20℃, while P3DT blue-shifts about 5.04nm. The photoluminescence spectra of the two polymers in mixed solution are also investigated, which show that the luminescence spectra shift to longer wavelength with an accompanying drop in the PL intensity as methanol is increased. The absorption and emission spectra of the two polymers in a poor solvent and a thin film are similar, which indicate that a similar longer conjugation length in the two cases. It could conclude that the polymers exist almost the same conformations and aggregations in both a poor solvent and a thin film. P3DT exhibits more sensitive spectra properties (big red-shifts in both absorption and luminescence spectra in poor solvents and large blue-shifts at high temperature) with contrast to P3HT, which imply that long side alkyl may improve the chromic properties of the polymer.
文摘In order to improve the nonlinear optical property and stability of azo-dye chromophore, the nonlinear optical polyimide (NLOPI) attached with azo chromophore side chain is synthesized by diazo coupling reaction of 4-nitrobenzenediazonium tetrafloroborate. The designed chemical structure of production can be proved in the infrared spectrum and ultraviolet-visible absorption spectrum. The NLOPI exhibited UV-Vis absorption of the azobenzene chromophore in the vicinity of the wavelengths of 330 and 490 nm. The broad amorphous peak proved that the NLOPI was amorphous with a little periodical structure along the side chain. According to transmission electron microscope, the NLOPI film was homogeneous. NLOPI only displayed a decrease in mass of about 5% at the temperature of 400 ℃ through thermogravimetric analysis.
基金TheNationalHigh TechDevelopment 863ProgramofChina (No .2 0 0 3AA1Z2 610 )
文摘To efficiently retrieve relevant document from the rapid proliferation of large information collections, a novel immune algorithm for document query optimization is proposed. The essential ideal of the immune algorithm is that the crossover and mutation of operator are constructed according to its own characteristics of information retrieval. Immune operator is adopted to avoid degeneracy. Relevant documents retrieved are merged to a single document list according to rank formula. Experimental results show that the novel immune algorithm can lead to substantial improvements of relevant document retrieval effectiveness.
文摘This paper proposes a TSK fuzzy approach to channel estimation for Orthogonal Frequency Division Multiplexing （OFDM） systems. The information of dispersive fading channel is described by using TSK fuzzy model, which is updated by the pilot symbols. The proposed approach can trace the variation of channel and it is computationally simple. Its performance is tested via simulations. Results show that it is comparable to that of ideal Minimum Mean-Square-Error （MMSE） method, especially at the low Signal to Noise Ratio （SNR）.
