A novel vapor-liquid-solid circulating fluidized bed evaporator, meaning for enhancing heat transfer and preventing fouling, is applied to wheat straw black liquor, which is the primary pollutant in China’s papermaki...A novel vapor-liquid-solid circulating fluidized bed evaporator, meaning for enhancing heat transfer and preventing fouling, is applied to wheat straw black liquor, which is the primary pollutant in China’s papermaking industry. It is treated by alkali recovery, in which evaporation is a key process. The experimental results show that the vapor-liquid-solid three-phase boiling heat transfer coefficient is enhanced by 20%～40% than that of vapor-liquid two-phase boiling flow, also, the novel evaporator exhibits an excellent function of fouling prevention.展开更多
The gas-liquid-liquid reactive extraction system for preparing hydrogen peroxide via anthraquinone was investigated. The oxidation reaction of hydrogenated working solution was combined with the extraction of hydrogen...The gas-liquid-liquid reactive extraction system for preparing hydrogen peroxide via anthraquinone was investigated. The oxidation reaction of hydrogenated working solution was combined with the extraction of hydrogen peroxide from working solution in a sieve plate column. The reaction of 2-ethylanthrahydroquionone with oxygen and the liquid-liquid extraction of hydrogen peroxide take place simultaneously. The oxygen was introduced with hydrogenated working solution through a nozzle in the bottom of the column, which worked as agitated air as well as oxidation reagent. The results showed the oxidation and extraction do not hamper each other, on the contrary, the presence of oxidation gas in the column can promote the transfer of hydrogen peroxide from organic phase to aqueous phase, thus the reaction efficiency and extraction efficiency increased with increasing gas superficial velocity. Furthermore, the oxidation efficiency is almost 100% and the extraction efficiency is higher than 90% in this process.展开更多
文摘A novel vapor-liquid-solid circulating fluidized bed evaporator, meaning for enhancing heat transfer and preventing fouling, is applied to wheat straw black liquor, which is the primary pollutant in China’s papermaking industry. It is treated by alkali recovery, in which evaporation is a key process. The experimental results show that the vapor-liquid-solid three-phase boiling heat transfer coefficient is enhanced by 20%～40% than that of vapor-liquid two-phase boiling flow, also, the novel evaporator exhibits an excellent function of fouling prevention.
文摘The gas-liquid-liquid reactive extraction system for preparing hydrogen peroxide via anthraquinone was investigated. The oxidation reaction of hydrogenated working solution was combined with the extraction of hydrogen peroxide from working solution in a sieve plate column. The reaction of 2-ethylanthrahydroquionone with oxygen and the liquid-liquid extraction of hydrogen peroxide take place simultaneously. The oxygen was introduced with hydrogenated working solution through a nozzle in the bottom of the column, which worked as agitated air as well as oxidation reagent. The results showed the oxidation and extraction do not hamper each other, on the contrary, the presence of oxidation gas in the column can promote the transfer of hydrogen peroxide from organic phase to aqueous phase, thus the reaction efficiency and extraction efficiency increased with increasing gas superficial velocity. Furthermore, the oxidation efficiency is almost 100% and the extraction efficiency is higher than 90% in this process.
