The PMD-induced pulse broadening may cause the degradation ofreceiver sensitivity and has negative effects on the power spectrumof received signals. The expression s of PMO-induced pulse broadeningeffects on receiver ...The PMD-induced pulse broadening may cause the degradation ofreceiver sensitivity and has negative effects on the power spectrumof received signals. The expression s of PMO-induced pulse broadeningeffects on receiver sensitivity are derived based on the concept ofman square pulse width. The effects of PMD on the spectrum ofreceived power are analyzed in detail. Finally, the scheme isdiscussed with which the poser of a certain frequency component isextracted as a feedback control signal in a PMD compensation system.展开更多
A kind of fiber Bragg grating pressure sensor based on corrugated diaphragm is proposed. The relationship between the central wavelength of reflective wave of FBG and pressure is given, and the expression of the press...A kind of fiber Bragg grating pressure sensor based on corrugated diaphragm is proposed. The relationship between the central wavelength of reflective wave of FBG and pressure is given, and the expression of the pressure sensitivity coefficient is also given. Within the range from 0 MPa to 0.3 MPa, the experimental pressure sensitivity is 7.83 nm/MPa, which is 2 610 times than that of the bare fiber grating. The experimental results agree with the theoretical analysis. It is indicated that the expected pressure sensitivity of the sensor can be obtained by optimizing the size and mechanical parameters of the corrugated diaphragm.展开更多
Two alkyl substituted polythiophene derivatives: poly(3-hexylthiophene)(P3HT) and poly(3-decylthiophene)(P3DT), have synthesized by oxidation coupling polymerization of 3-alkylthiophene using iron(III) chloride as cat...Two alkyl substituted polythiophene derivatives: poly(3-hexylthiophene)(P3HT) and poly(3-decylthiophene)(P3DT), have synthesized by oxidation coupling polymerization of 3-alkylthiophene using iron(III) chloride as catalyst in chloroform. While both polymers in pure chloroform solution have maximum absorption at approximately same wavelength of 440nm, they behave differently with respect to changes observed on their UV-visible and photoluminescence spectra when the quality of the poor solvent is changed in good solvent (chloroform) / poor solvent (methanol) mixtures. With increasing volume fraction of methanol in mixtures, the absorption spectra of P3HT and P3DT red-shift, peaking at maximum wavelength of 495nm (P3HT) and 510nm(P3DT). Furthermore, the absorption spectra of the two polymers in chloroform blue-shift as the temperature rises. P3HT shows 4.73nm blue-shifts at 50℃ in contrast to the case at 20℃, while P3DT blue-shifts about 5.04nm. The photoluminescence spectra of the two polymers in mixed solution are also investigated, which show that the luminescence spectra shift to longer wavelength with an accompanying drop in the PL intensity as methanol is increased. The absorption and emission spectra of the two polymers in a poor solvent and a thin film are similar, which indicate that a similar longer conjugation length in the two cases. It could conclude that the polymers exist almost the same conformations and aggregations in both a poor solvent and a thin film. P3DT exhibits more sensitive spectra properties (big red-shifts in both absorption and luminescence spectra in poor solvents and large blue-shifts at high temperature) with contrast to P3HT, which imply that long side alkyl may improve the chromic properties of the polymer.展开更多
In order to improve the nonlinear optical property and stability of azo-dye chromophore, the nonlinear optical polyimide (NLOPI) attached with azo chromophore side chain is synthesized by diazo coupling reaction of 4-...In order to improve the nonlinear optical property and stability of azo-dye chromophore, the nonlinear optical polyimide (NLOPI) attached with azo chromophore side chain is synthesized by diazo coupling reaction of 4-nitrobenzenediazonium tetrafloroborate. The designed chemical structure of production can be proved in the infrared spectrum and ultraviolet-visible absorption spectrum. The NLOPI exhibited UV-Vis absorption of the azobenzene chromophore in the vicinity of the wavelengths of 330 and 490 nm. The broad amorphous peak proved that the NLOPI was amorphous with a little periodical structure along the side chain. According to transmission electron microscope, the NLOPI film was homogeneous. NLOPI only displayed a decrease in mass of about 5% at the temperature of 400 ℃ through thermogravimetric analysis.展开更多
文摘The PMD-induced pulse broadening may cause the degradation ofreceiver sensitivity and has negative effects on the power spectrumof received signals. The expression s of PMO-induced pulse broadeningeffects on receiver sensitivity are derived based on the concept ofman square pulse width. The effects of PMD on the spectrum ofreceived power are analyzed in detail. Finally, the scheme isdiscussed with which the poser of a certain frequency component isextracted as a feedback control signal in a PMD compensation system.
文摘A kind of fiber Bragg grating pressure sensor based on corrugated diaphragm is proposed. The relationship between the central wavelength of reflective wave of FBG and pressure is given, and the expression of the pressure sensitivity coefficient is also given. Within the range from 0 MPa to 0.3 MPa, the experimental pressure sensitivity is 7.83 nm/MPa, which is 2 610 times than that of the bare fiber grating. The experimental results agree with the theoretical analysis. It is indicated that the expected pressure sensitivity of the sensor can be obtained by optimizing the size and mechanical parameters of the corrugated diaphragm.
基金National Natural Science Foundation of China (60277002)
文摘Two alkyl substituted polythiophene derivatives: poly(3-hexylthiophene)(P3HT) and poly(3-decylthiophene)(P3DT), have synthesized by oxidation coupling polymerization of 3-alkylthiophene using iron(III) chloride as catalyst in chloroform. While both polymers in pure chloroform solution have maximum absorption at approximately same wavelength of 440nm, they behave differently with respect to changes observed on their UV-visible and photoluminescence spectra when the quality of the poor solvent is changed in good solvent (chloroform) / poor solvent (methanol) mixtures. With increasing volume fraction of methanol in mixtures, the absorption spectra of P3HT and P3DT red-shift, peaking at maximum wavelength of 495nm (P3HT) and 510nm(P3DT). Furthermore, the absorption spectra of the two polymers in chloroform blue-shift as the temperature rises. P3HT shows 4.73nm blue-shifts at 50℃ in contrast to the case at 20℃, while P3DT blue-shifts about 5.04nm. The photoluminescence spectra of the two polymers in mixed solution are also investigated, which show that the luminescence spectra shift to longer wavelength with an accompanying drop in the PL intensity as methanol is increased. The absorption and emission spectra of the two polymers in a poor solvent and a thin film are similar, which indicate that a similar longer conjugation length in the two cases. It could conclude that the polymers exist almost the same conformations and aggregations in both a poor solvent and a thin film. P3DT exhibits more sensitive spectra properties (big red-shifts in both absorption and luminescence spectra in poor solvents and large blue-shifts at high temperature) with contrast to P3HT, which imply that long side alkyl may improve the chromic properties of the polymer.
文摘In order to improve the nonlinear optical property and stability of azo-dye chromophore, the nonlinear optical polyimide (NLOPI) attached with azo chromophore side chain is synthesized by diazo coupling reaction of 4-nitrobenzenediazonium tetrafloroborate. The designed chemical structure of production can be proved in the infrared spectrum and ultraviolet-visible absorption spectrum. The NLOPI exhibited UV-Vis absorption of the azobenzene chromophore in the vicinity of the wavelengths of 330 and 490 nm. The broad amorphous peak proved that the NLOPI was amorphous with a little periodical structure along the side chain. According to transmission electron microscope, the NLOPI film was homogeneous. NLOPI only displayed a decrease in mass of about 5% at the temperature of 400 ℃ through thermogravimetric analysis.
