Groundwater,the world’s largest freshwater supply,is facing increasing strain due to various uses such as agriculture,industry,livestock,and household.This study aims to investigate groundwater prospective zonation i...Groundwater,the world’s largest freshwater supply,is facing increasing strain due to various uses such as agriculture,industry,livestock,and household.This study aims to investigate groundwater prospective zonation in the Bandu Sub-watershed in Purulia,West Bengal,using the AHP model and RS&GIS methodologies.To achieve Goal 6 of the UN-initiated 17 SDGs,it is crucial to determine the spatial distribution of groundwater prospective zones village-by-village,with 1/3 of the regions falling under red alert zones for sustainable development.The 16 most crucial elements affecting groundwater prospective zones(GWPZs)were mapped using AHP,and the final prospective map was obtained through Weighted Overlay analysis.The study identified five different classes within the Sub-watershed as excellent,good,moderate,poor,and very poor.The validation results showed that the approach used to derive GWPZ is reliable,and the results can be applied to future sustainable developments to reduce water shortages through suitable management methods.The research aims to increase the effectiveness of sustainable groundwater zone management,ensuring long-term water management and access.展开更多
Understanding the levels,causes,and sources of fluoride in groundwater is critical for public health,effective water resource management,and sustainable utilization.This study employs multivariate statistical methods,...Understanding the levels,causes,and sources of fluoride in groundwater is critical for public health,effective water resource management,and sustainable utilization.This study employs multivariate statistical methods,hazard quotient assessment,and geochemical analyses,such as mineral saturation index,ionic activities,and Gibbs diagrams,to investigate the hydrochemical characteristics,causes,and noncarcinogenic risks of fluoride in Red bed groundwater and geothermal water in the Guang'an area and neighboring regions.Approximately 9%of the Red bed groundwater samples contain fluoride concentrations exceeding 1 mg·L^(-1).The predominant water types identified are Cl-Na and HCO_(3)-Na,primarily influenced by evapotranspiration.Low-fluoride groundwater and high-fluoride geothermal water exhibit distinct hydrochemical types HCO_(3)-Ca and SO_(4)-Ca,respectively,which are mainly related to the weathering of carbonate,sulfate,and fluorite-containing rocks.Correlation analysis reveals that fluoride content in Red bed groundwater is positively associated with Na^(+),Cl^(-),SO_(4)^(2-),and TDS(r^(2)=0.45-0.64,p<0.01),while in geothermal water,it correlates strongly with pH,K^(+),Ca^(2+),and Mg^(2+)(r^(2)=0.52-0.80,p<0.05).Mineral saturation indices and ionic activities indicate that ion exchange processes and the dissolution of minerals such as carbonatite and fluorite are important sources of fluoride in groundwater.The enrichment of fluorine in the Red bed groundwater is linked to evaporation,cation exchange and dissolution of fluorite,caused by the lithologic characteristics of the red bed in this area.However,it exhibits minimal correlation with the geothermal water in the adjacent area.The noncarcinogenic health risk assessment indicates that 7%(n=5)of Red bed groundwater points exceed the fluoride safety limit for adults,while 12%(n=8)exceed the limit for children.These findings underscore the importance of avoiding highly fluoridated red bed groundwater as a direct drinking source and enhancing groundwater monitoring to mitigate health risks associated with elevated fluoride levels.展开更多
Based on such principles as sustainable development and ecological cycle, this paper evaluates the water resources carrying capacity(WCC) of Changchun-Jilin region using a population-economy-water resources correlatio...Based on such principles as sustainable development and ecological cycle, this paper evaluates the water resources carrying capacity(WCC) of Changchun-Jilin region using a population-economy-water resources correlation evaluation model built on the basis of WCC evaluation method as elaborated in the methodology of Functional Zoning of Population Development. Results show that the annual WCC of Changchun-Jilin region is able to support the population there, as a basic balance is struck between population and water resources. The incorporation of WCC into overall urban planning is one of the building blocks for sustainable city development with an advisable size.展开更多
reshwater essential for civilization faces risk from untreated effluents discharged by industries,agriculture,urban areas,and other sources.Increasing demand and abstraction of freshwater deteriorate the pollution sce...reshwater essential for civilization faces risk from untreated effluents discharged by industries,agriculture,urban areas,and other sources.Increasing demand and abstraction of freshwater deteriorate the pollution scenario more.Hence,water quality analysis(WQA)is an important task for researchers and policymakers to maintain sustainability and public health.This study aims to gather and discuss the methods used for WQA by the researchers,focusing on their advantages and limitations.Simultaneously,this study compares different WQA methods,discussing their trends and future directions.Publications from the past decade on WQA are reviewed,and insights are explored to aggregate them in particular categories.Three major approaches,namely—water quality indexing,water quality modeling(WQM)and artificial intelligence-based WQM,are recognized.Different methodologies adopted to execute these three approaches are presented in this study,which leads to formulate a comparative discussion.Using statistical operations and soft computing techniques have been done by researchers to combat the subjectivity error in indexing.To achieve better results,WQMs are being modified to incorporate the physical processes influencing water quality more robustly.The utilization of artificial intelligence was primarily restricted to conventional networks,but in the last 5 years,implications of deep learning have increased rapidly and exhibited good results with the hybridization of feature extracting and time series modeling.Overall,this study is a valuable resource for researchers dedicated to WQA.展开更多
1.Introduction Planning and managing land resources requires the use of land use and land cover(LULC)maps,which provide vital information on the interactions between humans and the environment(Esfandeh et al.,2022;Pra...1.Introduction Planning and managing land resources requires the use of land use and land cover(LULC)maps,which provide vital information on the interactions between humans and the environment(Esfandeh et al.,2022;Pratic`o et al.,2021;Yao et al.,2022).The precision of LULC monitoring has increased due to developments in Earth observation and remote sensing,allowing for well-informed environmental management decision-making(Qian and Zhang,2022;Viana et al.,2019).展开更多
Urchin-like W_(18)O_(49),with a large specific surface area(113.738 m^(2)g^(-1))and abundant oxygen vacancies(OVs),was prepared using an active sites tuning and microstructure engineering method.This material was appl...Urchin-like W_(18)O_(49),with a large specific surface area(113.738 m^(2)g^(-1))and abundant oxygen vacancies(OVs),was prepared using an active sites tuning and microstructure engineering method.This material was applied for U(Ⅵ)adsorption for the first time,demonstrating a high adsorption capacity of 567.55 mg g^(-1),which exceeds that of most inorganic adsorbents.Characterization via active site masking experiments and theoretical calculations,etc.,indicated that the excellent adsorption performance toward U(Ⅵ)was due to strong complexation between UO_(2)^(2+)and W–O bond of W_(18)O_(49),facile oxygen vacancy adsorption,and interface electron transfer from W^(5+)to UO_(2)^(2+),which acted as a reducing agent,partially converting U(Ⅵ)to U(IV).Furthermore,W_(18)O_(49)exhibited practical applicability with a removal rate exceeding 82%after 5 cycles,a 92.79%removal rate for real uranium-containing wastewater,and a high uranium recovery rate of 75.96%.Additionally,the synergistic adsorption-photocatalytic effect significantly enhanced U(Ⅵ)extraction,reaching an extraction capacity of 988.0mg g^(-1).This work provides a promising strategy for developing highly efficient U(Ⅵ)WO_(3)-based adsorbents.展开更多
Graphene Oxide(GO),nanoscale Zero-Valent Iron(nZVI)and GO-modified nZVI(GO-nZVI)composite materials were prepared by the Hummer and polyphenol reduction method,respectively,and Scanning Electron Microscope(SEM)and X-r...Graphene Oxide(GO),nanoscale Zero-Valent Iron(nZVI)and GO-modified nZVI(GO-nZVI)composite materials were prepared by the Hummer and polyphenol reduction method,respectively,and Scanning Electron Microscope(SEM)and X-ray Diffraction(XRD)were used to characterize the morphology and phase composition of these materials.A series of batch experiments were then conducted to inves-tigate the performance and influencing factors of GO-nZVI activating peroxydisulfate(SPS)for the degra-dation of 1,2,3-trichloropropane(TCP).Finally,an in-situ oxidation reaction zone was created by GO-nZVI-activated SPS in a one-dimensional simulated system to study the remediation of TCP contamination under different aquifer conditions.The results showed that the GO-nZVI composite exhibited a porous,fluffy structure,with spherical nZVI particles loaded onto the surface and folds of the GO sheets.Compared with unmodified nZVI particles,the GO-nZVI composite significantly enhanced the removal efficiency of TCP by activated SPS,achieving a removal rate of 67.2%within an hour-78.2%higher than that of the unmodi-fied system.The SPS dosage and the C/Fe ratio in GO-nZVI were found to significantly affect the degradation efficiency of TCP.The removal rate of TCP increased with higher SPS concentration,and a 10%carbon addition,yielded the best activation effect.The one-dimensional simulation results indicated that the removal rate of TCP ranged from 30.1%to 73.3%under different conditions.A larger medium particle size and higher concentrations of reactants(SPS and GO-nZVI)improved pollutant degradation efficiency,increasing TCP removal by 62.1%,23.8%,and 3.7%,respectively.In contrast,a higher groundwater flow velocity was not conducive to the removal of pollutants,with the TCP removal rate decreasing by approxi-mately 41.9%.展开更多
Stable carbon isotopes(δ^(13)C)are extensively utilized to study intrinsic water use efficiency(iWUE)at the leaf-scale in terrestrial ecosystems,serving as a crucial metric for assessing plant adaptation to climate c...Stable carbon isotopes(δ^(13)C)are extensively utilized to study intrinsic water use efficiency(iWUE)at the leaf-scale in terrestrial ecosystems,serving as a crucial metric for assessing plant adaptation to climate change.However,there is currently a lack of consensus regarding the leaf-scale iWUE variation characteristics among different functional types.In this study,we measured theδ^(13)Cleaf and iWUE values of different functional plants(i.e.,life forms,leaf types,and mycorrhizal types)from 120 species across distinct habitat types(i.e.,hillside,nearpeak,and peak)in a subtropical forest on the western slope of Wuyi Mountains,southern China.The results showed that theδ^(13)Cleaf values of plants on the western slope of Wuyi Mountains ranged from-34.63‰to-30.04‰,and iWUE ranged from 5.93μmol mol^(-1)to 57.34μmol mol^(-1).Theδ^(13)Cleaf and iWUE values differed significantly among plant life forms,following the order of herbs>vine plants>shrubs>trees.Theδ^(13)Cleaf and iWUE values of ectomycorrhizal(ECM)species were greater than those of arbuscular mycorrhizal(AM)species despite there being no significant difference between plants with different leaf types(Simple leaves(SL)vs.Compound leaves(CL)).From the hillside to the peak,both at the community level and at the species level,theδ^(13)C values of leaves and iWUE values of plants exhibited an upward trend.The regression analysis revealed that leaf-scale iWUE was significantly negatively correlated with soil water content and significantly positively correlated with leaf phosphorus content.The findings indicated that leaf carbon isotope fractionation and corresponding iWUE can be influenced by life form,mycorrhizal type,and soil water availability.These insights provide a deeper understanding of the coupling mechanisms of carbon,water,and nutrients among different functional plant types in subtropical forests,and offer insights into predicting plant adaptability under climate change.展开更多
Through system design and analysis from the aspects of entity categories, hierarchical design, attribute design, and the final function design and realization of the system, this paper develops a software application ...Through system design and analysis from the aspects of entity categories, hierarchical design, attribute design, and the final function design and realization of the system, this paper develops a software application based on Arc-view platform with a view to solving the deficiencies of conventional groundwater dynamic management in managing the spatial graphics data. Using this application into the supporting automatic monitoring system of groundwater level helps to achieve the automatic analysis of attribute data, and offer a new, visual and efficient automated management tool. Moreover, the computer geospatial modeling can realize the quick query and spatial analysis of geographic information, and thus facilitating dynamic simulation and prediction of the research object. However, a multi-functional, multi-level groundwater level information management system is a complex system engineering, which requires continuous improvement of the structure, development of functions, and supplement of user models.展开更多
Statistical study of analyses of water from 43 samples from geothermal wells, three groundwater wells, and one sample of local rainwater along with rainwater data from the Global Net- work of Isotopes in Precipitation...Statistical study of analyses of water from 43 samples from geothermal wells, three groundwater wells, and one sample of local rainwater along with rainwater data from the Global Net- work of Isotopes in Precipitation has been used to identify the origin and evolution of geothermal water in the Niutuozhen （~f=~jg） geothermal field and estimate the renewability rate of its geothermal re- source. The results show that the geothermal waters of the Jixianian Wumishanian dolomite reservoir and the Ordovician limestone reservoir are of CI-Na type, the geothermal water of the Pliocene Minghuazben （H~/~） Formation sandstone reservoir are CI-Na type and HCO3-Na type and the groundwater of the Quaternary aquifer is HCO3-Na and HCO3-Na.Mg.Ca type. A linear relationship between silica concentration and temperature indicates that higher temperature probably enhances concentration of silica in Jixianian geothermal water. 81SO shift in Wumishanian geothermal water av- eraged 1.57%o, and was less than 1%o in the other geothermal waters. The minimum and maxi-mum 14C ages of Wumishanian geothermal wa- ter are 17 000 and 33 000 years from north to the south of the Niutuozhen geothermal field. Geo- thermal water and Quaternary groundwater belong to different groundwater systems with no hydraulic connections. Although the geothermal field receives some recharge from the Yanshan and Taihang mountains outside the northern and western boundaries of the geothermal field re- spectively, the renewability rate of geothermal water is on the scale of 10 000 years.展开更多
The amount of water withdrawn by wells is one of the quantitative variables that can be applied to estimate groundwater resources and further evaluate the human influence on groundwater systems. The accuracy for the c...The amount of water withdrawn by wells is one of the quantitative variables that can be applied to estimate groundwater resources and further evaluate the human influence on groundwater systems. The accuracy for the calculation of the amount of water withdrawal significantly influences the regional groundwater resource evaluation and management. However, the decentralized groundwater pumping, inefficient management, measurement errors and uncertainties have resulted in considerable errors in the groundwater withdrawal estimation. In this study, to improve the estimation of the groundwater withdrawal, an innovative approach was proposed using an inversion method based on a regional groundwater flow numerical model, and this method was then applied in the North China Plain. The principle of the method was matching the simulated water levels with the observation ones by adjusting the amount of groundwater withdrawal. In addition, uncertainty analysis of hydraulic conductivity and specific yield for the estimation of the groundwater withdrawal was conducted. By using the proposed inversion method, the estimated annual average groundwater withdrawal was approximately 24.92×10^9 m^3 in the North China Plain from 2002 to 2008. The inversion method also significantly improved the simulation results for both hydrograph and the flow field. Results of the uncertainty analysis showed that the hydraulic conductivity was more sensitive to the inversion results than the specific yield.展开更多
Nyemo-Nagqu, Tibet, is rich in high-temperature geothermal resources. The geothermal fields in Yangbajain and Yangyi as well as 11 unexplored geothermal fields along the geothermal belt from Nyemo to Nagqu were system...Nyemo-Nagqu, Tibet, is rich in high-temperature geothermal resources. The geothermal fields in Yangbajain and Yangyi as well as 11 unexplored geothermal fields along the geothermal belt from Nyemo to Nagqu were systematically investigated and the hydrochemistry data were collected from the whole field. Meanwhile, H-O-C-S isotope data were obtained for the new fields, and H-O isotope data for the Yangbajain and Yangyi fields. A comparison of the Nyemo-Nagqu geothermal fields with those in the Yangbajain area shows that the types of high-temperature geothermal water are dominated by Cl-Na and Cl·HCO3-Na, while the types of medium-high-temperature geothermal water are dominated by HCO3-Na. The concentrations of Li, F, SiO2, and HBO2 in the geothermal water are positively correlated with Cl content, indicating possible mixing with magma water. The reservoir temperatures range from 90 to 270°C by geothermometers. Slight drifting of 18O was recorded at the Dongweng and Nyingzhong high-temperature geothermal fields, while more significant drifting was recorded at Gulu. The geothermal water is mainly replenished by atmospheric precipitation. The low tritium contents（〈1 TU） of the geothermal water from Nyingzhong, Gulu, and Luoma indicate that it is mainly replenished by sub-modern（prior to 1952） water, while the high tritium content（8.4 TU） in Yuela implies modern water replenishment. Other geothermal fields are replenished by a mix of sub-modern fresher water. The isotopic data in this study show that the carbon and sulfur in the geothermal water originates mainly from sediment leaching, with some of the carbon and sulfur having a deep origin.展开更多
A groundwater transient flow model was developed to evaluate the applicability and effectiveness of artificial recharge scenarios in the middle-upper part of the Yongding River alluvial fan in Beijing. These scenarios...A groundwater transient flow model was developed to evaluate the applicability and effectiveness of artificial recharge scenarios in the middle-upper part of the Yongding River alluvial fan in Beijing. These scenarios were designed by taking into account different types of recharge facilities and their infiltration rate with the Middle Route Project for South-to-North Water Transfer（MRP） as the recharge water source. The simulation results suggest that：（1） the maximum amount of artificial recharge water, for scenario I, would be 127.42×106 m3 with surface infiltration facilities; and would be243.48×106 m3 for scenario II with surface infiltration and recharge wells under the constraint of the upper limit of groundwater;（2） with preferred pattern of recharge facilities, groundwater levels in both optimized recharge scenarios would not exceed the upper limit within the given recharge period; and（3implementation of the recharge scenarios would efficiently increase the aquifer replenishment and the groundwater budget will change from-54.11×106 to 70.89×104 and 183.36×104 m3, respectively. In addition, under these two scenarios groundwater level would rise up to 30 and 34 m, respectively, without increasing the amount of evaporation. The simulation results indicate that the proposed recharge scenarios are practically feasible, and artificial recharge can also contribute to an efficient recovery of groundwater storage in Beijing.展开更多
The North China Plain（NCP） is one of the global hotspots of groundwater depletion, groundwater is almost the only source of water for agricultural, industrial and drinking water in this region. After long-term＇s ov...The North China Plain（NCP） is one of the global hotspots of groundwater depletion, groundwater is almost the only source of water for agricultural, industrial and drinking water in this region. After long-term＇s over-exploitation of deep groundwater, there appeared several deep groundwater depression cones, such as Cangzhou cone, Dezhou cone, Hengshui cone, Tianjin cone, etc., in which the Cangzhou cone is one of the typical cones for its special geography and hydrogeology conditions. In this study, the authors intended to analyze the evolution characteristics and influence factors of deep groundwater depression cone in Cangzhou region, especially the No. III aquifer depression cone, which is the main exploitation zone in this region. Analysis of the evolution of the groundwater depression cone of the No. III aquifer group in Cangzhou region showed that this process can be divided into four stages, namely, development, stable development, rapid expansion, and gradual recovery. The shape and evolution characteristics of the depression cone at different stages are described by analyzing the evolution of the-30,-40, and-50 contours of the groundwater table, for example the closed area of water table contour of-50 m has been enlarged from 95 km2 in 1985 to 6 528.5 km2 in 2005. The dominant factors that affect the evolution characteristics at different stages are proposed. The results showed that relatively long dry periods with less precipitation, special geological and hydrogeological conditions, and sharply increased water consumption for industrial and agricultural development are the main factors that cause the formation of deep groundwater depression cones. Meanwhile, an environmental response against groundwater exploitation is presented, and rational solutions are suggested to avert water crisis.展开更多
High salinity industrial wastewater is difficult to treat using biological treatment system because of the high concentrations of salt.The potential of a sequencing batch biofilm reactor(SBBR)process in treating synth...High salinity industrial wastewater is difficult to treat using biological treatment system because of the high concentrations of salt.The potential of a sequencing batch biofilm reactor(SBBR)process in treating synthetic high salinity wastewater was evaluated at laboratory scale during a 110-day operation.The reactor was operated in a 12 h cycle,and each cycle consisted of 0.25 h influent addition,8 h aeration,3 h anoxic reaction,0.5 h sedimentation and 0.25 h effluent withdrawal.Gradual increase in salinity gradient was applied during the acclimatization period.The acclimated SBBR system was demonstrated to be an effective process to remove organic compounds and ammonia nitrogen under high salinity conditions with chemical oxygen demand(COD)and ammonia nitrogen(NH3-N)removal efficiencies of 88% and 80%,respectively.The microscopic examination indicated that rather than rotifers or vorticella,the zoogloea,filamentous fungus mingled with a small quantity of swimming infusorians were dominant bacteria in SBBR system.The removal efficiencies close to 80% in COD and 75% in NH3-N were achieved at an organic loading rate(OLR)of 0.96 kg COD/(m3·d),pH of 7.0,salinity of 14 g/L and NH3-N of 30 mg/L.展开更多
Water resources are scarce in arid or semiarid areas,which not only limits economic development,but also threatens the survival of mankind.The local communities around the Hangjinqi gasfield depend on groundwater sour...Water resources are scarce in arid or semiarid areas,which not only limits economic development,but also threatens the survival of mankind.The local communities around the Hangjinqi gasfield depend on groundwater sources for water supply.A clear understanding of the groundwater hydrogeochemical characteristics and the groundwater quality and its seasonal cycle is invaluable and indispensable for groundwater protection and management.In this study,self-organizing maps were used in combination with the quantization and topographic errors and K-means clustering method to investigate groundwater chemistry datasets.The Piper and Gibbs diagrams and saturation index were systematically applied to investigate the hydrogeochemical characteristics of groundwater from both rainy and dry seasons.Further,the entropy-weighted theory was used to characterize groundwater quality and assess its seasonal variability and suitability for drinking purposes.Our hydrochemical groundwater dataset,consisting of 10 parameters measured during both dry and rainy seasons,was classified into 6 clusters,and the Piper diagram revealed three hydrochemical facies:Cl-Na type(clusters 1,2 and 3),mixed type(clusters 4 and 5),and HCO3-Ca type(cluster 6).The Gibbs diagram and saturation index suggested thatweathering of rock-forming mineralswere the primary process controlling groundwater chemical composition and validated the credibility and practicality of the clustering results.Two-thirds of 45 groundwater samples were categorized as excellent-or good-quality and were suitable as drinking water.Cluster changes within the same and different clusters from the dry season to the rainy season were detected in approximately 78%of the collected samples.The main factors affecting the groundwater quality were hydrogeochemical characteristics,and dry season groundwater quality was better than rainy season groundwater quality.Based on this work,such results can be used to investigate the seasonal variation of hydrogeochemical characteristics and assess water quality accurately in the others similar area.展开更多
Isotopic and chemical compositions of pore water(PW) are highly relevant to environmental and forensic study. Five lake water(LW)samples and five sediment samples were collected to investigate the effects of pore size...Isotopic and chemical compositions of pore water(PW) are highly relevant to environmental and forensic study. Five lake water(LW)samples and five sediment samples were collected to investigate the effects of pore sizes of sediments on PW chemistry and stable isotopes and determine mechanisms controlling their variations. Six pore water fractions were extracted from different-sized pores in each sediment sample at six sequential centrifugal speeds for chemical and isotopic analysis. The sediments consisted mainly of quartz, feldspar, and clay minerals. The hydrogen and oxygen isotopic compositions of PW are mainly controlled by the overlying LW, although the lag effect of exchange between overlying LW and PW results in isotopic differences when recharge of LW is quicker than isotopic exchange in PW. Identical isotopic compositions of PW from sediments with different pore sizes indicate that isotopic exchange of water molecules with different pore sizes is a quick process. The ratio of average total dissolved solid(TDS) concentration of PW to TDS concentration of LW shows a strong relationship with adsorption capacity of sediments, demonstrating that remobilization of ions bound to sediments mainly causes a chemical shift from LW to PW.Concentrations of Ca^(2+), Mg^(2+),and Cl^-in PW remain unchanged,while concentrations of Na^+,K^+,and SO_4^(2-) slightly increase with decreasing pore size. Chemical differences of PW from sediments with different pore sizes are governed by ion adsorption properties and surface characteristics of different-si zed particles.展开更多
Delingha is located in the northeast margin of Qaidam Basin.Bayin River alluvial proluvial fan is the main aquifer of Delingha,in which groundwater generally flows from north to south.The hydrochemistry results showed...Delingha is located in the northeast margin of Qaidam Basin.Bayin River alluvial proluvial fan is the main aquifer of Delingha,in which groundwater generally flows from north to south.The hydrochemistry results showed that two different hydrochemical evolution paths formed along southeast and southwest directions,respectively.Cl-Na type groundwater was formed in front of Gahai Lake,and SO_(4)·HCO_(3)-Na·Ca type groundwater was formed in front of Keluke Lake.The results of deuterium(D)and 18O revealed that the groundwater mainly originated from the continuous accumulation of precipitation during geological history under cold and humid climate conditions.In addition,results of^(14)C indicated that the groundwater age was more than 1140 years,implying relatively poor renewal capability of regional groundwater.Moreover,our numerical modeling results showed that the regional groundwater level will continue to rise under the warm and humid climate conditions.展开更多
Water flow from an artesian well stopped on December 17, 2007 but recovered when the Wenchuan Ms 8.0 earthquake occurred on May 12, 2008. This well is located 90 km south of the epicenter in an extensional tectonic se...Water flow from an artesian well stopped on December 17, 2007 but recovered when the Wenchuan Ms 8.0 earthquake occurred on May 12, 2008. This well is located 90 km south of the epicenter in an extensional tectonic setting, where similar changes of water level and resistivity were observed at two other nearby sites. Our investigation suggests that this phenomenon was not caused by environmental disturbances, such as drought or borehole-drilling activity, but might be a precursor to the earthquake.展开更多
Electric current stimulation has been shown to have a positive influence on heterotrophic denitrifying microbial viability and has the potential to improve wastewater denitrification performance. This study investigat...Electric current stimulation has been shown to have a positive influence on heterotrophic denitrifying microbial viability and has the potential to improve wastewater denitrification performance. This study investigated the effects of varying current densities on microbial activity and NO_3^- removal efficiency under heterotrophic conditions.NO_3^-removal rate was highest at an applied current density of 400 mA/m^2. However, the optimum removal efficiency of total inorganic nitrogen(TIN; 99%) was achieved when the current density was fixed at 200 m A/m^2. Accumulation of NH_4^+-N and NO_2^--N byproducts were also minimized at this current density. The activity of heterotrophic denitrifying microorganisms was much higher at both 200 and 400 mA/m^2. Moreover, the average adenosine-5′-triphosphate(ATP)content(an indicator of cell metabolism) at a current density of 1600 mA/m^2 was lower than that under no current, indicating heterotrophic denitrifying microbial activity can be inhibited at high current densities. Hence, direct electrical stimulation on the activity of heterotrophic denitrifying microorganisms in the developed system should be lower than 1600 mA/m^2. This study improves the understanding of electric current influence on heterotrophic denitrifying microorganisms and promotes the intelligent application of direct electrical stimulation on wastewater treatment processes.展开更多
文摘Groundwater,the world’s largest freshwater supply,is facing increasing strain due to various uses such as agriculture,industry,livestock,and household.This study aims to investigate groundwater prospective zonation in the Bandu Sub-watershed in Purulia,West Bengal,using the AHP model and RS&GIS methodologies.To achieve Goal 6 of the UN-initiated 17 SDGs,it is crucial to determine the spatial distribution of groundwater prospective zones village-by-village,with 1/3 of the regions falling under red alert zones for sustainable development.The 16 most crucial elements affecting groundwater prospective zones(GWPZs)were mapped using AHP,and the final prospective map was obtained through Weighted Overlay analysis.The study identified five different classes within the Sub-watershed as excellent,good,moderate,poor,and very poor.The validation results showed that the approach used to derive GWPZ is reliable,and the results can be applied to future sustainable developments to reduce water shortages through suitable management methods.The research aims to increase the effectiveness of sustainable groundwater zone management,ensuring long-term water management and access.
基金supported by the China Geological Survey Project(Nos.DD20220864 and DD20243077).
文摘Understanding the levels,causes,and sources of fluoride in groundwater is critical for public health,effective water resource management,and sustainable utilization.This study employs multivariate statistical methods,hazard quotient assessment,and geochemical analyses,such as mineral saturation index,ionic activities,and Gibbs diagrams,to investigate the hydrochemical characteristics,causes,and noncarcinogenic risks of fluoride in Red bed groundwater and geothermal water in the Guang'an area and neighboring regions.Approximately 9%of the Red bed groundwater samples contain fluoride concentrations exceeding 1 mg·L^(-1).The predominant water types identified are Cl-Na and HCO_(3)-Na,primarily influenced by evapotranspiration.Low-fluoride groundwater and high-fluoride geothermal water exhibit distinct hydrochemical types HCO_(3)-Ca and SO_(4)-Ca,respectively,which are mainly related to the weathering of carbonate,sulfate,and fluorite-containing rocks.Correlation analysis reveals that fluoride content in Red bed groundwater is positively associated with Na^(+),Cl^(-),SO_(4)^(2-),and TDS(r^(2)=0.45-0.64,p<0.01),while in geothermal water,it correlates strongly with pH,K^(+),Ca^(2+),and Mg^(2+)(r^(2)=0.52-0.80,p<0.05).Mineral saturation indices and ionic activities indicate that ion exchange processes and the dissolution of minerals such as carbonatite and fluorite are important sources of fluoride in groundwater.The enrichment of fluorine in the Red bed groundwater is linked to evaporation,cation exchange and dissolution of fluorite,caused by the lithologic characteristics of the red bed in this area.However,it exhibits minimal correlation with the geothermal water in the adjacent area.The noncarcinogenic health risk assessment indicates that 7%(n=5)of Red bed groundwater points exceed the fluoride safety limit for adults,while 12%(n=8)exceed the limit for children.These findings underscore the importance of avoiding highly fluoridated red bed groundwater as a direct drinking source and enhancing groundwater monitoring to mitigate health risks associated with elevated fluoride levels.
基金The research and demonstration of key technologies and methods of eco-planning in urban construction,the 11th Five-year Plan of National Science and Technology Infrastructure Program,MOST,2007-2011(No.2007BAC28B02)
文摘Based on such principles as sustainable development and ecological cycle, this paper evaluates the water resources carrying capacity(WCC) of Changchun-Jilin region using a population-economy-water resources correlation evaluation model built on the basis of WCC evaluation method as elaborated in the methodology of Functional Zoning of Population Development. Results show that the annual WCC of Changchun-Jilin region is able to support the population there, as a basic balance is struck between population and water resources. The incorporation of WCC into overall urban planning is one of the building blocks for sustainable city development with an advisable size.
基金State University Research Excellence(SURE),SERB,GOI,Grant/Award Number:SUR/2022/001557。
文摘reshwater essential for civilization faces risk from untreated effluents discharged by industries,agriculture,urban areas,and other sources.Increasing demand and abstraction of freshwater deteriorate the pollution scenario more.Hence,water quality analysis(WQA)is an important task for researchers and policymakers to maintain sustainability and public health.This study aims to gather and discuss the methods used for WQA by the researchers,focusing on their advantages and limitations.Simultaneously,this study compares different WQA methods,discussing their trends and future directions.Publications from the past decade on WQA are reviewed,and insights are explored to aggregate them in particular categories.Three major approaches,namely—water quality indexing,water quality modeling(WQM)and artificial intelligence-based WQM,are recognized.Different methodologies adopted to execute these three approaches are presented in this study,which leads to formulate a comparative discussion.Using statistical operations and soft computing techniques have been done by researchers to combat the subjectivity error in indexing.To achieve better results,WQMs are being modified to incorporate the physical processes influencing water quality more robustly.The utilization of artificial intelligence was primarily restricted to conventional networks,but in the last 5 years,implications of deep learning have increased rapidly and exhibited good results with the hybridization of feature extracting and time series modeling.Overall,this study is a valuable resource for researchers dedicated to WQA.
文摘1.Introduction Planning and managing land resources requires the use of land use and land cover(LULC)maps,which provide vital information on the interactions between humans and the environment(Esfandeh et al.,2022;Pratic`o et al.,2021;Yao et al.,2022).The precision of LULC monitoring has increased due to developments in Earth observation and remote sensing,allowing for well-informed environmental management decision-making(Qian and Zhang,2022;Viana et al.,2019).
基金financially supported by the National Natural Science Foundation of China(Nos.22366004 and 42302293)the National Key Laboratory of Uranium Resources Exploration-Mining and Nuclear Remote Sensing Independent Project(No.2024QZ-TD-19)+2 种基金the Key R&D Plan of Jiangxi Province(No.20212BBG71011)China Uranium Corporation Limited-East China University of Technology State Key Laboratory of Nuclear Resources and Environment Joint Innovation Fund(No.2023NRE-LH-19)the Innovation Special Fund Project of Graduate Student in East China University of Technology(No.DHYC-202414)
文摘Urchin-like W_(18)O_(49),with a large specific surface area(113.738 m^(2)g^(-1))and abundant oxygen vacancies(OVs),was prepared using an active sites tuning and microstructure engineering method.This material was applied for U(Ⅵ)adsorption for the first time,demonstrating a high adsorption capacity of 567.55 mg g^(-1),which exceeds that of most inorganic adsorbents.Characterization via active site masking experiments and theoretical calculations,etc.,indicated that the excellent adsorption performance toward U(Ⅵ)was due to strong complexation between UO_(2)^(2+)and W–O bond of W_(18)O_(49),facile oxygen vacancy adsorption,and interface electron transfer from W^(5+)to UO_(2)^(2+),which acted as a reducing agent,partially converting U(Ⅵ)to U(IV).Furthermore,W_(18)O_(49)exhibited practical applicability with a removal rate exceeding 82%after 5 cycles,a 92.79%removal rate for real uranium-containing wastewater,and a high uranium recovery rate of 75.96%.Additionally,the synergistic adsorption-photocatalytic effect significantly enhanced U(Ⅵ)extraction,reaching an extraction capacity of 988.0mg g^(-1).This work provides a promising strategy for developing highly efficient U(Ⅵ)WO_(3)-based adsorbents.
基金financially supported by the Basal Research Fund of Chinese Academy of Geological Sciences(NO.SK202318)the Natural Science Foundation of Xiamen,China(No.3502Z20227309)the Natural Science Foundation of Fujian Province of China(NO.2023J01227).
文摘Graphene Oxide(GO),nanoscale Zero-Valent Iron(nZVI)and GO-modified nZVI(GO-nZVI)composite materials were prepared by the Hummer and polyphenol reduction method,respectively,and Scanning Electron Microscope(SEM)and X-ray Diffraction(XRD)were used to characterize the morphology and phase composition of these materials.A series of batch experiments were then conducted to inves-tigate the performance and influencing factors of GO-nZVI activating peroxydisulfate(SPS)for the degra-dation of 1,2,3-trichloropropane(TCP).Finally,an in-situ oxidation reaction zone was created by GO-nZVI-activated SPS in a one-dimensional simulated system to study the remediation of TCP contamination under different aquifer conditions.The results showed that the GO-nZVI composite exhibited a porous,fluffy structure,with spherical nZVI particles loaded onto the surface and folds of the GO sheets.Compared with unmodified nZVI particles,the GO-nZVI composite significantly enhanced the removal efficiency of TCP by activated SPS,achieving a removal rate of 67.2%within an hour-78.2%higher than that of the unmodi-fied system.The SPS dosage and the C/Fe ratio in GO-nZVI were found to significantly affect the degradation efficiency of TCP.The removal rate of TCP increased with higher SPS concentration,and a 10%carbon addition,yielded the best activation effect.The one-dimensional simulation results indicated that the removal rate of TCP ranged from 30.1%to 73.3%under different conditions.A larger medium particle size and higher concentrations of reactants(SPS and GO-nZVI)improved pollutant degradation efficiency,increasing TCP removal by 62.1%,23.8%,and 3.7%,respectively.In contrast,a higher groundwater flow velocity was not conducive to the removal of pollutants,with the TCP removal rate decreasing by approxi-mately 41.9%.
基金supported by the Open Research Fund of Jiangxi Provincial Academy of Water Resources Sciences(2022SKTR05&2022SKTR03)the National Natural Science Foundation of China(42067049&42367049),the Jiangxi Provincial Natural Science Foundation(20242BAB25350)+5 种基金the Research Project of the Jiangxi Provincial Department of Forestry(CXZX(2025)14 and JXTG(2023)15)the Ganpo Juncai Plan(QN2023018)the Ganpo Yingcai Plan(gpyc20240038)the Double Thousand Plan of Jiangxi Province(jxsq2023102213 and jxsq2023102214)the Jiangxi Province“Science and Technology+Water Resources”Joint Plan Project(2023KSG01001)the Major Discipline Academic and Technical Leaders Training Program of Jiangxi Province(20243BCE51025).
文摘Stable carbon isotopes(δ^(13)C)are extensively utilized to study intrinsic water use efficiency(iWUE)at the leaf-scale in terrestrial ecosystems,serving as a crucial metric for assessing plant adaptation to climate change.However,there is currently a lack of consensus regarding the leaf-scale iWUE variation characteristics among different functional types.In this study,we measured theδ^(13)Cleaf and iWUE values of different functional plants(i.e.,life forms,leaf types,and mycorrhizal types)from 120 species across distinct habitat types(i.e.,hillside,nearpeak,and peak)in a subtropical forest on the western slope of Wuyi Mountains,southern China.The results showed that theδ^(13)Cleaf values of plants on the western slope of Wuyi Mountains ranged from-34.63‰to-30.04‰,and iWUE ranged from 5.93μmol mol^(-1)to 57.34μmol mol^(-1).Theδ^(13)Cleaf and iWUE values differed significantly among plant life forms,following the order of herbs>vine plants>shrubs>trees.Theδ^(13)Cleaf and iWUE values of ectomycorrhizal(ECM)species were greater than those of arbuscular mycorrhizal(AM)species despite there being no significant difference between plants with different leaf types(Simple leaves(SL)vs.Compound leaves(CL)).From the hillside to the peak,both at the community level and at the species level,theδ^(13)C values of leaves and iWUE values of plants exhibited an upward trend.The regression analysis revealed that leaf-scale iWUE was significantly negatively correlated with soil water content and significantly positively correlated with leaf phosphorus content.The findings indicated that leaf carbon isotope fractionation and corresponding iWUE can be influenced by life form,mycorrhizal type,and soil water availability.These insights provide a deeper understanding of the coupling mechanisms of carbon,water,and nutrients among different functional plant types in subtropical forests,and offer insights into predicting plant adaptability under climate change.
基金supported by Hebei Province Universities Research Project (ZD2014023)Hebei Province Science and Technology Department Research Project (15273630)Hebei Province Graduate Student Innovation Fund Project(CXZZSS2017129)
文摘Through system design and analysis from the aspects of entity categories, hierarchical design, attribute design, and the final function design and realization of the system, this paper develops a software application based on Arc-view platform with a view to solving the deficiencies of conventional groundwater dynamic management in managing the spatial graphics data. Using this application into the supporting automatic monitoring system of groundwater level helps to achieve the automatic analysis of attribute data, and offer a new, visual and efficient automated management tool. Moreover, the computer geospatial modeling can realize the quick query and spatial analysis of geographic information, and thus facilitating dynamic simulation and prediction of the research object. However, a multi-functional, multi-level groundwater level information management system is a complex system engineering, which requires continuous improvement of the structure, development of functions, and supplement of user models.
基金supported by the National Basic Research Program of China(No.2010CB428806)Beijing Municipal Science and Technology Project(No.D07050601510000)
文摘Statistical study of analyses of water from 43 samples from geothermal wells, three groundwater wells, and one sample of local rainwater along with rainwater data from the Global Net- work of Isotopes in Precipitation has been used to identify the origin and evolution of geothermal water in the Niutuozhen （~f=~jg） geothermal field and estimate the renewability rate of its geothermal re- source. The results show that the geothermal waters of the Jixianian Wumishanian dolomite reservoir and the Ordovician limestone reservoir are of CI-Na type, the geothermal water of the Pliocene Minghuazben （H~/~） Formation sandstone reservoir are CI-Na type and HCO3-Na type and the groundwater of the Quaternary aquifer is HCO3-Na and HCO3-Na.Mg.Ca type. A linear relationship between silica concentration and temperature indicates that higher temperature probably enhances concentration of silica in Jixianian geothermal water. 81SO shift in Wumishanian geothermal water av- eraged 1.57%o, and was less than 1%o in the other geothermal waters. The minimum and maxi-mum 14C ages of Wumishanian geothermal wa- ter are 17 000 and 33 000 years from north to the south of the Niutuozhen geothermal field. Geo- thermal water and Quaternary groundwater belong to different groundwater systems with no hydraulic connections. Although the geothermal field receives some recharge from the Yanshan and Taihang mountains outside the northern and western boundaries of the geothermal field re- spectively, the renewability rate of geothermal water is on the scale of 10 000 years.
基金supported by the National Basic Research Program of China (No. 2010CB428804)the Public Welfare Industry Special Funds for Scientific Research from Ministry of Land and Resources of China (No. 201211079-4).
文摘The amount of water withdrawn by wells is one of the quantitative variables that can be applied to estimate groundwater resources and further evaluate the human influence on groundwater systems. The accuracy for the calculation of the amount of water withdrawal significantly influences the regional groundwater resource evaluation and management. However, the decentralized groundwater pumping, inefficient management, measurement errors and uncertainties have resulted in considerable errors in the groundwater withdrawal estimation. In this study, to improve the estimation of the groundwater withdrawal, an innovative approach was proposed using an inversion method based on a regional groundwater flow numerical model, and this method was then applied in the North China Plain. The principle of the method was matching the simulated water levels with the observation ones by adjusting the amount of groundwater withdrawal. In addition, uncertainty analysis of hydraulic conductivity and specific yield for the estimation of the groundwater withdrawal was conducted. By using the proposed inversion method, the estimated annual average groundwater withdrawal was approximately 24.92×10^9 m^3 in the North China Plain from 2002 to 2008. The inversion method also significantly improved the simulation results for both hydrograph and the flow field. Results of the uncertainty analysis showed that the hydraulic conductivity was more sensitive to the inversion results than the specific yield.
基金funded by the Natural Science Foundation of China(Grant Nos.41502220)the Chinese Academy of Geological Sciences Fund(No.YK201611)
文摘Nyemo-Nagqu, Tibet, is rich in high-temperature geothermal resources. The geothermal fields in Yangbajain and Yangyi as well as 11 unexplored geothermal fields along the geothermal belt from Nyemo to Nagqu were systematically investigated and the hydrochemistry data were collected from the whole field. Meanwhile, H-O-C-S isotope data were obtained for the new fields, and H-O isotope data for the Yangbajain and Yangyi fields. A comparison of the Nyemo-Nagqu geothermal fields with those in the Yangbajain area shows that the types of high-temperature geothermal water are dominated by Cl-Na and Cl·HCO3-Na, while the types of medium-high-temperature geothermal water are dominated by HCO3-Na. The concentrations of Li, F, SiO2, and HBO2 in the geothermal water are positively correlated with Cl content, indicating possible mixing with magma water. The reservoir temperatures range from 90 to 270°C by geothermometers. Slight drifting of 18O was recorded at the Dongweng and Nyingzhong high-temperature geothermal fields, while more significant drifting was recorded at Gulu. The geothermal water is mainly replenished by atmospheric precipitation. The low tritium contents（〈1 TU） of the geothermal water from Nyingzhong, Gulu, and Luoma indicate that it is mainly replenished by sub-modern（prior to 1952） water, while the high tritium content（8.4 TU） in Yuela implies modern water replenishment. Other geothermal fields are replenished by a mix of sub-modern fresher water. The isotopic data in this study show that the carbon and sulfur in the geothermal water originates mainly from sediment leaching, with some of the carbon and sulfur having a deep origin.
基金supported by the National Basic Research Program of China (No. 2010CB428804) the Public Welfare Industry Special Funds for Scientific Research from Ministry of Land and Resources of P. R. China (No. 201211079-4)
文摘A groundwater transient flow model was developed to evaluate the applicability and effectiveness of artificial recharge scenarios in the middle-upper part of the Yongding River alluvial fan in Beijing. These scenarios were designed by taking into account different types of recharge facilities and their infiltration rate with the Middle Route Project for South-to-North Water Transfer（MRP） as the recharge water source. The simulation results suggest that：（1） the maximum amount of artificial recharge water, for scenario I, would be 127.42×106 m3 with surface infiltration facilities; and would be243.48×106 m3 for scenario II with surface infiltration and recharge wells under the constraint of the upper limit of groundwater;（2） with preferred pattern of recharge facilities, groundwater levels in both optimized recharge scenarios would not exceed the upper limit within the given recharge period; and（3implementation of the recharge scenarios would efficiently increase the aquifer replenishment and the groundwater budget will change from-54.11×106 to 70.89×104 and 183.36×104 m3, respectively. In addition, under these two scenarios groundwater level would rise up to 30 and 34 m, respectively, without increasing the amount of evaporation. The simulation results indicate that the proposed recharge scenarios are practically feasible, and artificial recharge can also contribute to an efficient recovery of groundwater storage in Beijing.
基金supported by the National Basic Research Program (973) of China (No. 2010CB428803)the National Natural Science Foundation of China (No. 41402235)
文摘The North China Plain（NCP） is one of the global hotspots of groundwater depletion, groundwater is almost the only source of water for agricultural, industrial and drinking water in this region. After long-term＇s over-exploitation of deep groundwater, there appeared several deep groundwater depression cones, such as Cangzhou cone, Dezhou cone, Hengshui cone, Tianjin cone, etc., in which the Cangzhou cone is one of the typical cones for its special geography and hydrogeology conditions. In this study, the authors intended to analyze the evolution characteristics and influence factors of deep groundwater depression cone in Cangzhou region, especially the No. III aquifer depression cone, which is the main exploitation zone in this region. Analysis of the evolution of the groundwater depression cone of the No. III aquifer group in Cangzhou region showed that this process can be divided into four stages, namely, development, stable development, rapid expansion, and gradual recovery. The shape and evolution characteristics of the depression cone at different stages are described by analyzing the evolution of the-30,-40, and-50 contours of the groundwater table, for example the closed area of water table contour of-50 m has been enlarged from 95 km2 in 1985 to 6 528.5 km2 in 2005. The dominant factors that affect the evolution characteristics at different stages are proposed. The results showed that relatively long dry periods with less precipitation, special geological and hydrogeological conditions, and sharply increased water consumption for industrial and agricultural development are the main factors that cause the formation of deep groundwater depression cones. Meanwhile, an environmental response against groundwater exploitation is presented, and rational solutions are suggested to avert water crisis.
基金Projects(ZR2013BL010,ZR2012DL05)supported by the Natural Science Foundation of Shandong Province,ChinaProject(4041412016)supported by the Research Excellence Award of Shandong University of Technology,ChinaProjects(2013GG03116,2011GG02115)supported by the Science and Technology Development Planning Project of Zibo,China
文摘High salinity industrial wastewater is difficult to treat using biological treatment system because of the high concentrations of salt.The potential of a sequencing batch biofilm reactor(SBBR)process in treating synthetic high salinity wastewater was evaluated at laboratory scale during a 110-day operation.The reactor was operated in a 12 h cycle,and each cycle consisted of 0.25 h influent addition,8 h aeration,3 h anoxic reaction,0.5 h sedimentation and 0.25 h effluent withdrawal.Gradual increase in salinity gradient was applied during the acclimatization period.The acclimated SBBR system was demonstrated to be an effective process to remove organic compounds and ammonia nitrogen under high salinity conditions with chemical oxygen demand(COD)and ammonia nitrogen(NH3-N)removal efficiencies of 88% and 80%,respectively.The microscopic examination indicated that rather than rotifers or vorticella,the zoogloea,filamentous fungus mingled with a small quantity of swimming infusorians were dominant bacteria in SBBR system.The removal efficiencies close to 80% in COD and 75% in NH3-N were achieved at an organic loading rate(OLR)of 0.96 kg COD/(m3·d),pH of 7.0,salinity of 14 g/L and NH3-N of 30 mg/L.
基金the National Natural Science Foundation of China(Nos.41972259 and 41572227)the National Key Research and Development Program of China(No.2018YFC0406404).
文摘Water resources are scarce in arid or semiarid areas,which not only limits economic development,but also threatens the survival of mankind.The local communities around the Hangjinqi gasfield depend on groundwater sources for water supply.A clear understanding of the groundwater hydrogeochemical characteristics and the groundwater quality and its seasonal cycle is invaluable and indispensable for groundwater protection and management.In this study,self-organizing maps were used in combination with the quantization and topographic errors and K-means clustering method to investigate groundwater chemistry datasets.The Piper and Gibbs diagrams and saturation index were systematically applied to investigate the hydrogeochemical characteristics of groundwater from both rainy and dry seasons.Further,the entropy-weighted theory was used to characterize groundwater quality and assess its seasonal variability and suitability for drinking purposes.Our hydrochemical groundwater dataset,consisting of 10 parameters measured during both dry and rainy seasons,was classified into 6 clusters,and the Piper diagram revealed three hydrochemical facies:Cl-Na type(clusters 1,2 and 3),mixed type(clusters 4 and 5),and HCO3-Ca type(cluster 6).The Gibbs diagram and saturation index suggested thatweathering of rock-forming mineralswere the primary process controlling groundwater chemical composition and validated the credibility and practicality of the clustering results.Two-thirds of 45 groundwater samples were categorized as excellent-or good-quality and were suitable as drinking water.Cluster changes within the same and different clusters from the dry season to the rainy season were detected in approximately 78%of the collected samples.The main factors affecting the groundwater quality were hydrogeochemical characteristics,and dry season groundwater quality was better than rainy season groundwater quality.Based on this work,such results can be used to investigate the seasonal variation of hydrogeochemical characteristics and assess water quality accurately in the others similar area.
基金supported by the National Natural Science Foundation of China(Grants No.41672225 and 41222020)the Program of the China Geology Survey(Grant No.12120113103700)the Fundamental Research Funds for the Central Universities(Grant No.2652013028)
文摘Isotopic and chemical compositions of pore water(PW) are highly relevant to environmental and forensic study. Five lake water(LW)samples and five sediment samples were collected to investigate the effects of pore sizes of sediments on PW chemistry and stable isotopes and determine mechanisms controlling their variations. Six pore water fractions were extracted from different-sized pores in each sediment sample at six sequential centrifugal speeds for chemical and isotopic analysis. The sediments consisted mainly of quartz, feldspar, and clay minerals. The hydrogen and oxygen isotopic compositions of PW are mainly controlled by the overlying LW, although the lag effect of exchange between overlying LW and PW results in isotopic differences when recharge of LW is quicker than isotopic exchange in PW. Identical isotopic compositions of PW from sediments with different pore sizes indicate that isotopic exchange of water molecules with different pore sizes is a quick process. The ratio of average total dissolved solid(TDS) concentration of PW to TDS concentration of LW shows a strong relationship with adsorption capacity of sediments, demonstrating that remobilization of ions bound to sediments mainly causes a chemical shift from LW to PW.Concentrations of Ca^(2+), Mg^(2+),and Cl^-in PW remain unchanged,while concentrations of Na^+,K^+,and SO_4^(2-) slightly increase with decreasing pore size. Chemical differences of PW from sediments with different pore sizes are governed by ion adsorption properties and surface characteristics of different-si zed particles.
基金This work was supported by the National Natural Science Foundation of China(41672243)the China Geological Survey Program(DD20160291,DD20189270).
文摘Delingha is located in the northeast margin of Qaidam Basin.Bayin River alluvial proluvial fan is the main aquifer of Delingha,in which groundwater generally flows from north to south.The hydrochemistry results showed that two different hydrochemical evolution paths formed along southeast and southwest directions,respectively.Cl-Na type groundwater was formed in front of Gahai Lake,and SO_(4)·HCO_(3)-Na·Ca type groundwater was formed in front of Keluke Lake.The results of deuterium(D)and 18O revealed that the groundwater mainly originated from the continuous accumulation of precipitation during geological history under cold and humid climate conditions.In addition,results of^(14)C indicated that the groundwater age was more than 1140 years,implying relatively poor renewal capability of regional groundwater.Moreover,our numerical modeling results showed that the regional groundwater level will continue to rise under the warm and humid climate conditions.
基金supported by the National Natural Science Foundation ofChina(40930637)Basic Science Research Special Item of the Instituteof Geology,China Earthquake Administration(DF-IGCEA-0608210)Special Research Program of China Earthquake Administration(200808079)
文摘Water flow from an artesian well stopped on December 17, 2007 but recovered when the Wenchuan Ms 8.0 earthquake occurred on May 12, 2008. This well is located 90 km south of the epicenter in an extensional tectonic setting, where similar changes of water level and resistivity were observed at two other nearby sites. Our investigation suggests that this phenomenon was not caused by environmental disturbances, such as drought or borehole-drilling activity, but might be a precursor to the earthquake.
基金supported by the National Key Research and Development Program of China(No.2016YFD0501405)the National Natural Science Foundation of China(No.51578519)+1 种基金the China Postdoctoral Science Foundation(No.2018M630245)the Beijing Postdoctoral Research Foundation(No.2017-ZZ-137)
文摘Electric current stimulation has been shown to have a positive influence on heterotrophic denitrifying microbial viability and has the potential to improve wastewater denitrification performance. This study investigated the effects of varying current densities on microbial activity and NO_3^- removal efficiency under heterotrophic conditions.NO_3^-removal rate was highest at an applied current density of 400 mA/m^2. However, the optimum removal efficiency of total inorganic nitrogen(TIN; 99%) was achieved when the current density was fixed at 200 m A/m^2. Accumulation of NH_4^+-N and NO_2^--N byproducts were also minimized at this current density. The activity of heterotrophic denitrifying microorganisms was much higher at both 200 and 400 mA/m^2. Moreover, the average adenosine-5′-triphosphate(ATP)content(an indicator of cell metabolism) at a current density of 1600 mA/m^2 was lower than that under no current, indicating heterotrophic denitrifying microbial activity can be inhibited at high current densities. Hence, direct electrical stimulation on the activity of heterotrophic denitrifying microorganisms in the developed system should be lower than 1600 mA/m^2. This study improves the understanding of electric current influence on heterotrophic denitrifying microorganisms and promotes the intelligent application of direct electrical stimulation on wastewater treatment processes.
