By electrical resistance tomography (ERT) the cross sectional profiles of gas hold-up in a φ56mm bubble column are obtained with four designs of gas sparger. The effect of sparger geometry on the bubble distribution ...By electrical resistance tomography (ERT) the cross sectional profiles of gas hold-up in a φ56mm bubble column are obtained with four designs of gas sparger. The effect of sparger geometry on the bubble distribution is re-vealed by applying a sensitivity conjugated gradients reconstruction method (SCG). Experimental results show that over-all hold-up obtained by ERT is generally in good agreement with those measured with the pressure transducer and the ERT system produces informative evidence that the radial profiles of hold-up is very similar to the sparger design in the lower section of bubble column. Meanwhile, the rise velocity of bubble swarm and the Sauter mean bubble size are evaluated using ERT based on dynamic gas disengagement theory. The experimental results are in good agreement with correlations and conventional estimation obtained using pressure transmitter methods.展开更多
Wear properties of two different crushers used for grinding raw materials of cement industry are compared using pin-on-disk wear test.The wear test was carried out with different loads on a pin.Abrasive wear behavior ...Wear properties of two different crushers used for grinding raw materials of cement industry are compared using pin-on-disk wear test.The wear test was carried out with different loads on a pin.Abrasive wear behavior of two alloys was evaluated by comparing mass loss,wear resistance,microhardness and friction coefficient.The microstructure of the specimens was detected using optical microscope.The results showed that abrasive wear of high chromium cast iron is lower than that of Hadfield steel.Due to the presence of M7C3 carbides on the high chromium cast iron matrix,impact crushers exhibited higher friction coefficient展开更多
Mineral sulphide （MS）-lime （CaO） ion exchange reactions （MS ＋ CaO = MO ＋ CaS） and the effect of CaO/C mole ratio during carbothermic reduction （MS ＋ CaO ＋ C = M ＋ CaS ＋ CO（g）） were investigated for com...Mineral sulphide （MS）-lime （CaO） ion exchange reactions （MS ＋ CaO = MO ＋ CaS） and the effect of CaO/C mole ratio during carbothermic reduction （MS ＋ CaO ＋ C = M ＋ CaS ＋ CO（g）） were investigated for complex froth flotation mineral sulphide concentrates. Phases in the partially and fully reacted samples were characterised by X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The primary phases during mineral sulphide-lime ion exchange reactions are Fe304, CaSO4 Cu2S, and CaS. A complex liquid phase of Ca2CuFeO3S forms during mineral sulphide-lime exchange reactions above 1173 K. The formation mechanisms of Ca2CuFeO3S liquid phase are determined by characterising the partially reacted samples. The reduction rate and extent of mineral sulphides in the presence of CaO and C increase with the increase in CaO/C ratio. The metallic phases are surrounded by the CaS rich phase at CaO/C 〉 1, but the metallic phases and CaS are found as separate phases at CaO/C 〈 1. Experimental results show that the stoichiometric ratio of carbon should be slightly higher than that of CaO. The reactions between CaO and gangue minerals （SiO2 and A1203） are only observed at CaO/C 〉 1 and the reacted samples are excessively sintered.展开更多
3D visualisations of the microstructure of flocculated particulates and sediments using optical confocal laser mi- croscopy and high resolution X-ray microtomography (XMT) methods are described. Data obtained from in-...3D visualisations of the microstructure of flocculated particulates and sediments using optical confocal laser mi- croscopy and high resolution X-ray microtomography (XMT) methods are described. Data obtained from in-situ measurements should enable direct computation of the properties of solids assembly (shape, size, contact area) and their permeability to fluids. A specific application relating to the formation of silica aggregates is described from which the behaviour of sediments containing these materials can be predicted on the basis of a bench-top test and the use of a Lattice Boltzman simulation. It is proposed that the method can potentially be used to predict trends such as the filtration behaviour of porous structures under different states of compression. This offers a significant benefit in assisting the formulation design of flocculated materials pertinent to a number of industrial sectors wishing to design optimal filtration or relevant operations.展开更多
Using natural mineral wollastonite, talc and quartz sands as raw materials, rare earth oxides (La2O3, Nd2O3 and Y2O3) as additives, the bio-soluble alkaline earth silicate fibers were prepared by melting and blowing p...Using natural mineral wollastonite, talc and quartz sands as raw materials, rare earth oxides (La2O3, Nd2O3 and Y2O3) as additives, the bio-soluble alkaline earth silicate fibers were prepared by melting and blowing process. The viscosity of the molten ma-terials, bio-solubility and crystallization behavior of the fiber were investigated. The results indicated that the fiber drawing tempera-ture range could be broadened since the slope of the temperature-viscosity curve decreased with adding rare earth oxide. The addition of rare earth oxide was beneficial to the increase of crystallization temperature by strengthening the network structure of the fiber. The existence of rare earth oxide in the fibers would reduce the solubility of the fibers, which still belonged to bio-soluble fibers.展开更多
The standard Gibbs free energy of formation of magnesium ferrite was determined by means of two types of solid state electrochemical cells： one using MgZr4（PO4）6 （MZP） as the solid electrolyte and the other using...The standard Gibbs free energy of formation of magnesium ferrite was determined by means of two types of solid state electrochemical cells： one using MgZr4（PO4）6 （MZP） as the solid electrolyte and the other using CaF2 as the solid electrolyte. The first cell was operated in the range of 950 to 1100 K. The second cell was operated in the range of 1125 to 1200 K. The reversibility of the cell EMFs was confirmed by microcoulometric titration. The Gibbs energy changes of magnesium ferrite relative to component oxides were calculated based on EMF measurements and are given by following expressions, respectively： AG1 = -3579-15 T （J/mol） and AGⅡ =6258-24.3 T （J/mol）. The results obtained from two different cells are consistent with each other. The results also are in agreement with Rao＇ s and Tretjakov＇s data in the measured temperature range. When the Gibbs free energies of formation of MgO and Fe203 were substituted in the reaction, the Gibbs free energies of formation of MgFe204 was obtained in two temperature ranges and the for mations are shown as follows： AG 1Formation =-1427394＋360.5 T （J/mol） and AGⅡ Formition =-1417557＋351.2 T （J/mol）.展开更多
Work has been ongoing in building a thermodynamic database for the prediction of phase equilibria in Pt-based superalloys. The alloys are being developed for high texture applications in aggressive environments. The d...Work has been ongoing in building a thermodynamic database for the prediction of phase equilibria in Pt-based superalloys. The alloys are being developed for high texture applications in aggressive environments. The database will aid the design of alloys by enabling the calculation of the composition and proportions of phases present in alloys of different compositions. In order to extend this database, a preliminary assessment of the Cr-Pt-Ru system has been undertaken, using a combination of Pandat and MTDATA software. As a first step, it was necessary to provide thermodynamic models for the three associated binary systems. Owing to a lack of thermodynamic information for these systems, the binary assessments were based on phase diagrams available in the literature. Using recent experimental phase equilibria data for the ternary system, a preliminary assessment of the Cr-Pt-Ru system has been produced. In this preliminary assessment, simplified models were employed for the L12 and sigma phases with a view to extending the descriptions as new experimental information becomes available.展开更多
This paper presents initial development of polymer application. PNC materials containing a polyamide （PA） and nano to improve the mechanical properties. Commercial polyamide 6 nanocomposites （PNC） material for rap...This paper presents initial development of polymer application. PNC materials containing a polyamide （PA） and nano to improve the mechanical properties. Commercial polyamide 6 nanocomposites （PNC） material for rapid manufacturing （RM） particles （5 wt%） were produced by solution blending with the aim （PA6） was dissolved in formic acid （HCO2H） together with two different types of nano particle materials： yttrium stabilised zirconia （YSZ） and Hectorite clay （Benton 166） and spray-dried to create powder, creating powder with particle sizes in the range of 10-40 μm. The materials were processed on a CO2 selective laser sintering （SLS） experimental machine. Mechanical properties of the PNCs were evaluated and the results were compared with the unfilled base polymer. Good dispersion of additives was achieved by solution blending, however the PA6 was degraded during the material preparation and spray drying process which resulted in the formation of porous structure and low strength. However the addition of 5 （wt%） nano particles in the PA6 has shown to increase strength by an average of 50-60%. Further work on powder preparation is required in order to fully realize these performance benefits.展开更多
Near infrared spectroscopy （NIR） is now probably the most popular process analytical technology （PAT） for pharmaceutical and some other industries. However, unlike mid-IR, NIR is known to have difficulties in moni...Near infrared spectroscopy （NIR） is now probably the most popular process analytical technology （PAT） for pharmaceutical and some other industries. However, unlike mid-IR, NIR is known to have difficulties in monitoring crystallization or precipitation processes because the existence of solids could cause distortion of the spectra. This phenomenon, seen as unfavorable previously, is however an indication that NIR spectra contain rich information about both solids and liquids, giving the possibility of using the same instrument for multiple property characterization. In this study, transflectance NIR calibration data was obtained using solutions and slurries of varied solution concentration, particle size, solid concentration and temperature. The data was used to build calibration models for prediction of the multiple properties of both phases. Predictive models were developed for this challenging application using an approach that combines genetic algorithm （GA） and support vector machine （SVM）. GA is used for wavelength selection and SVM for mode building. The new GA-SVM approach is shown to outperform other methods including GA-PLS （partial least squares） and traditional SVM. NIR is thus successfully applied to monitoring seeded and unseeded cooling crystallization processes of L-glutamic acid.展开更多
Rising energy costs and growing environmental awareness motivate a critical revision of the design of distillation units. Systematic design techniques, such as the rectification body, column profile map, and temperatu...Rising energy costs and growing environmental awareness motivate a critical revision of the design of distillation units. Systematic design techniques, such as the rectification body, column profile map, and temperature collocation methods, require exact knowledge of all pinch points in a particular system, because these stationary points delineate the possible composition trajectories realizable in separation columns. This paper demonstrates novel methods for rigorously determining all pinch points for the constant relative volatility, ideal and non-ideal systems. Constant relative volatility and ideal solution systems are transformed into one-dimensional polynomial and nonlinear functions, regardless of the number of the components. A deflation method is proposed to locate all zeros in ideal and non-ideal zeotropic problems. For more challenging non-ideal problems, a novel hybrid sequential niche algorithm is used to solve hard azeotropic problems successfully. Finally, the design implications of these pinch point locations are investigated to show how new separation configurations can be devised. Methodically the paper points out the use of rigorous pinch point computations in conjunction with continuous composition profiles for robust distillation design.展开更多
We present an Euler-Lagrange method for the simulation of wood gasification in a bubbling fluidized bed. The gas phase is modeled as a continuum using the 2D Navier-Stokes equations and the solid phase is modeled by a...We present an Euler-Lagrange method for the simulation of wood gasification in a bubbling fluidized bed. The gas phase is modeled as a continuum using the 2D Navier-Stokes equations and the solid phase is modeled by a Discrete Element Method （DEM） using a soft-sphere approach for the particle collision dynamic. Turbulence is included via a Large-Eddy approach using the Smagorinsky sub-grid model. The model takes into account detailed gas phase chemistry, zero-dimensional modeling of the pyrolysis and gasification of each individual particle, particle shrinkage, and heat and mass transfer between the gas phase and the particulate phase. We investigate the influence of wood feeding rate and compare exhaust gas compositions and temperature results obtained with the model against experimental data of a laboratory scale bubbling fiuidized bed reactor.展开更多
Recent research has demonstrated that on-line video imaging is a very promising technique for monitoring crystallization processes. The bottleneck in applying the technique for real-time closed-loop control is conside...Recent research has demonstrated that on-line video imaging is a very promising technique for monitoring crystallization processes. The bottleneck in applying the technique for real-time closed-loop control is considered as image analysis that needs to be robust, fast and able to handle varied image qualities due to temporal variations of operating conditions such as mixing and solid concentrations. Image analysis at highsolid concentrations turns out to be extremely challenging because crystals tend to overlap or attach to each other and the boundaries between the crystals are usually ambiguous. This paper presents an image segmentation algorithm that can effectively deal with images taken at high-solid concentrations. The method segments crystals attached to each other along the mostly related concave points on the contours of crystal blocks. The detailed procedure is introduced with application to crystallization of L-glutamic acid in a hot-stage reactor.展开更多
The flame-holding mechanism in hypersonic propulsion technology is the most important factor in prolonging the duration time of hypersonic vehicles.The two-dimensional coupled implicit Reynolds-averaged Navier-Stokes ...The flame-holding mechanism in hypersonic propulsion technology is the most important factor in prolonging the duration time of hypersonic vehicles.The two-dimensional coupled implicit Reynolds-averaged Navier-Stokes equations,the shear-stress transport k-ω turbulence model and the finite-rate/eddy-dissipation reaction models were used to simulate the combustion flow field of a typical strut-based scramjet combustor.We investigated the effects of the hydrogen-air reaction mechanism and fuel injection temperature and pressure on the parametric distributions in the combustor.The numerical results show qualitative agreement with the experimental data.The hydrogen-air reaction mechanism makes only a slight difference in parametric distributions along the walls of the combustor,and the expansion waves and shock waves exist in the combustor simultaneously.Furthermore,the expansion wave is formed ahead of the shock wave.A transition occurs from the shock wave to the normal shock wave when the injection pressure or temperature increases,and the reaction zone becomes broader.When the injection pressure and temperature both increase,the waves are pushed out of the combustor with subsonic flows.When the waves are generated ahead of the strut,the separation zone is formed in double near the walls of the combustor because of the interaction of the shock wave and the boundary layer.The separation zone becomes smaller and disappears with the disappearance of the shock wave.Because of the horizontal fuel injection,the vorticity is generated near the base face of the strut,and this region is the main origin for turbulent combustion.展开更多
The study presented here was carried out to obtain the actual solids flow rate by the combination of electrical resistance tomography and electromagnetic flow meter. A new in-situ measurement method based on measureme...The study presented here was carried out to obtain the actual solids flow rate by the combination of electrical resistance tomography and electromagnetic flow meter. A new in-situ measurement method based on measurements of the Electromagnetic Flow Meters （EFM） and Electrical Resistance Tomography （ERT） to study the flow rates of individual phases in a vertical flow was proposed. The study was based on laboratory experiments that were carded out with a 50 mm vertical flow rig for a number of sand concentrations and different mixture velocities. A range of sand slurries with median particle size from 212 μm to 355 μm was tested. The solid concentration by volume covered was 5% and 15%, and the corresponding density of 5% was 1078 kg/m^3 and of 15% was 1238 kg/m^3. The flow velocity was between 1.5 m/s and 3.0 m/s. A total of 6 experimental tests were conducted. The equivalent liquid model was adopted to validate in-situ volumetric solids fraction and calculate the slip velocity. The results show that the ERT technique can be used in conjunction with an electromagnetic flow meter as a way of measurement of slurry flow rate in a vertical pipe flow. However it should be emphasized that the EFM results must be treated with reservation when the flow pattern at the EFM mounting position is a non-homogenous flow. The flow rate obtained by the EFM should be corrected considering the slip velocity and the flow pattern.展开更多
The use of X-ray microtomographic （XMT） methods in analysing particulate systems has expanded rapidly in recent years with the availability of affordable desk-top apparatus. This review presents a summary of the maj...The use of X-ray microtomographic （XMT） methods in analysing particulate systems has expanded rapidly in recent years with the availability of affordable desk-top apparatus. This review presents a summary of the major applications in which computer simulations are explicitly coupled with XMT in the area of granular and porous materials. We envisage two main ways of establishing the coupling between both techniques, based on the transference or exchange of information by using physical or geometrical parameters （i.e. a parametric link through fitting to a process model） or through the direct use of3D XMT digital images （i.e. comparing image pixels and features directly）. Examples of coupled applications are shown for the study of transport properties of rocks, particle packing, mechanical loading and sintering. Often, the link between XMT and computer simulations is based on visual comparisons and we conclude that the use of quantitative parameters such as the number of interparticle contacts, force networks or granule shape to link both techniques is still underrepresented in the literature. Strategies to provide a more robust and quantitative approach to optimise the information obtained from such tomography analyses are proposed. 2010 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.展开更多
Magnetic polymer particles have found applications in diverse areas such as biomedical treatments, diagnosis and separation technology. These applications require the particles to have controlled sizes and narrow size...Magnetic polymer particles have found applications in diverse areas such as biomedical treatments, diagnosis and separation technology. These applications require the particles to have controlled sizes and narrow size distributions to gain better control and reproducibility in use. This paper reviews recent developments in the preparation of magnetic polymer particles at nano- and micro-scales by encapsulating magnetic components with dissolved or in situ formed polymers. Particle manufacture using emulsification and embedment methods produces magnetic polymer particles at micro-scale dimensions. However, the production of particles in this range using conventional emulsification methods affords very limited control over particle sizes and polydispersity. We report on alternative routes using membrane and microfluidics emulsification techniques, which have a capability to produce monodisperse emulsions and polymer microspheres （with coefficients of variation of less than 10%） in the range from submicrometer to a few 100 μm. The performance of these manufacturing methods is assessed with a view to future applications.展开更多
文摘By electrical resistance tomography (ERT) the cross sectional profiles of gas hold-up in a φ56mm bubble column are obtained with four designs of gas sparger. The effect of sparger geometry on the bubble distribution is re-vealed by applying a sensitivity conjugated gradients reconstruction method (SCG). Experimental results show that over-all hold-up obtained by ERT is generally in good agreement with those measured with the pressure transducer and the ERT system produces informative evidence that the radial profiles of hold-up is very similar to the sparger design in the lower section of bubble column. Meanwhile, the rise velocity of bubble swarm and the Sauter mean bubble size are evaluated using ERT based on dynamic gas disengagement theory. The experimental results are in good agreement with correlations and conventional estimation obtained using pressure transmitter methods.
文摘Wear properties of two different crushers used for grinding raw materials of cement industry are compared using pin-on-disk wear test.The wear test was carried out with different loads on a pin.Abrasive wear behavior of two alloys was evaluated by comparing mass loss,wear resistance,microhardness and friction coefficient.The microstructure of the specimens was detected using optical microscope.The results showed that abrasive wear of high chromium cast iron is lower than that of Hadfield steel.Due to the presence of M7C3 carbides on the high chromium cast iron matrix,impact crushers exhibited higher friction coefficient
基金the financial support by the Copperbelt University in Zambia and the Institute of Materials,Minerals and Mining(IOM~3)
文摘Mineral sulphide （MS）-lime （CaO） ion exchange reactions （MS ＋ CaO = MO ＋ CaS） and the effect of CaO/C mole ratio during carbothermic reduction （MS ＋ CaO ＋ C = M ＋ CaS ＋ CO（g）） were investigated for complex froth flotation mineral sulphide concentrates. Phases in the partially and fully reacted samples were characterised by X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The primary phases during mineral sulphide-lime ion exchange reactions are Fe304, CaSO4 Cu2S, and CaS. A complex liquid phase of Ca2CuFeO3S forms during mineral sulphide-lime exchange reactions above 1173 K. The formation mechanisms of Ca2CuFeO3S liquid phase are determined by characterising the partially reacted samples. The reduction rate and extent of mineral sulphides in the presence of CaO and C increase with the increase in CaO/C ratio. The metallic phases are surrounded by the CaS rich phase at CaO/C 〉 1, but the metallic phases and CaS are found as separate phases at CaO/C 〈 1. Experimental results show that the stoichiometric ratio of carbon should be slightly higher than that of CaO. The reactions between CaO and gangue minerals （SiO2 and A1203） are only observed at CaO/C 〉 1 and the reacted samples are excessively sintered.
文摘3D visualisations of the microstructure of flocculated particulates and sediments using optical confocal laser mi- croscopy and high resolution X-ray microtomography (XMT) methods are described. Data obtained from in-situ measurements should enable direct computation of the properties of solids assembly (shape, size, contact area) and their permeability to fluids. A specific application relating to the formation of silica aggregates is described from which the behaviour of sediments containing these materials can be predicted on the basis of a bench-top test and the use of a Lattice Boltzman simulation. It is proposed that the method can potentially be used to predict trends such as the filtration behaviour of porous structures under different states of compression. This offers a significant benefit in assisting the formulation design of flocculated materials pertinent to a number of industrial sectors wishing to design optimal filtration or relevant operations.
基金supported by the National Basic Research Program of China(973 Program)(2014CB660802)the National Natural Science Foundation of China(51474166)Natural Science Foundation of Hubei Province(2012FFA102)
文摘Using natural mineral wollastonite, talc and quartz sands as raw materials, rare earth oxides (La2O3, Nd2O3 and Y2O3) as additives, the bio-soluble alkaline earth silicate fibers were prepared by melting and blowing process. The viscosity of the molten ma-terials, bio-solubility and crystallization behavior of the fiber were investigated. The results indicated that the fiber drawing tempera-ture range could be broadened since the slope of the temperature-viscosity curve decreased with adding rare earth oxide. The addition of rare earth oxide was beneficial to the increase of crystallization temperature by strengthening the network structure of the fiber. The existence of rare earth oxide in the fibers would reduce the solubility of the fibers, which still belonged to bio-soluble fibers.
基金the National Natural Science Foundation of China (No.50572024) the Education Ministry Foundation for Returning Overseas Scholar of China.
文摘The standard Gibbs free energy of formation of magnesium ferrite was determined by means of two types of solid state electrochemical cells： one using MgZr4（PO4）6 （MZP） as the solid electrolyte and the other using CaF2 as the solid electrolyte. The first cell was operated in the range of 950 to 1100 K. The second cell was operated in the range of 1125 to 1200 K. The reversibility of the cell EMFs was confirmed by microcoulometric titration. The Gibbs energy changes of magnesium ferrite relative to component oxides were calculated based on EMF measurements and are given by following expressions, respectively： AG1 = -3579-15 T （J/mol） and AGⅡ =6258-24.3 T （J/mol）. The results obtained from two different cells are consistent with each other. The results also are in agreement with Rao＇ s and Tretjakov＇s data in the measured temperature range. When the Gibbs free energies of formation of MgO and Fe203 were substituted in the reaction, the Gibbs free energies of formation of MgFe204 was obtained in two temperature ranges and the for mations are shown as follows： AG 1Formation =-1427394＋360.5 T （J/mol） and AGⅡ Formition =-1417557＋351.2 T （J/mol）.
基金The work was financially supported by EPSRC platform grant GR/R95798, "The Platinum Development Initiative", and the Department of Science and Technology, South Africa
文摘Work has been ongoing in building a thermodynamic database for the prediction of phase equilibria in Pt-based superalloys. The alloys are being developed for high texture applications in aggressive environments. The database will aid the design of alloys by enabling the calculation of the composition and proportions of phases present in alloys of different compositions. In order to extend this database, a preliminary assessment of the Cr-Pt-Ru system has been undertaken, using a combination of Pandat and MTDATA software. As a first step, it was necessary to provide thermodynamic models for the three associated binary systems. Owing to a lack of thermodynamic information for these systems, the binary assessments were based on phase diagrams available in the literature. Using recent experimental phase equilibria data for the ternary system, a preliminary assessment of the Cr-Pt-Ru system has been produced. In this preliminary assessment, simplified models were employed for the L12 and sigma phases with a view to extending the descriptions as new experimental information becomes available.
文摘This paper presents initial development of polymer application. PNC materials containing a polyamide （PA） and nano to improve the mechanical properties. Commercial polyamide 6 nanocomposites （PNC） material for rapid manufacturing （RM） particles （5 wt%） were produced by solution blending with the aim （PA6） was dissolved in formic acid （HCO2H） together with two different types of nano particle materials： yttrium stabilised zirconia （YSZ） and Hectorite clay （Benton 166） and spray-dried to create powder, creating powder with particle sizes in the range of 10-40 μm. The materials were processed on a CO2 selective laser sintering （SLS） experimental machine. Mechanical properties of the PNCs were evaluated and the results were compared with the unfilled base polymer. Good dispersion of additives was achieved by solution blending, however the PA6 was degraded during the material preparation and spray drying process which resulted in the formation of porous structure and low strength. However the addition of 5 （wt%） nano particles in the PA6 has shown to increase strength by an average of 50-60%. Further work on powder preparation is required in order to fully realize these performance benefits.
基金UK Engineering and Physical Sciences Research Council for funding the research (EPSRCGrant Reference: EP/C001788/1)
文摘Near infrared spectroscopy （NIR） is now probably the most popular process analytical technology （PAT） for pharmaceutical and some other industries. However, unlike mid-IR, NIR is known to have difficulties in monitoring crystallization or precipitation processes because the existence of solids could cause distortion of the spectra. This phenomenon, seen as unfavorable previously, is however an indication that NIR spectra contain rich information about both solids and liquids, giving the possibility of using the same instrument for multiple property characterization. In this study, transflectance NIR calibration data was obtained using solutions and slurries of varied solution concentration, particle size, solid concentration and temperature. The data was used to build calibration models for prediction of the multiple properties of both phases. Predictive models were developed for this challenging application using an approach that combines genetic algorithm （GA） and support vector machine （SVM）. GA is used for wavelength selection and SVM for mode building. The new GA-SVM approach is shown to outperform other methods including GA-PLS （partial least squares） and traditional SVM. NIR is thus successfully applied to monitoring seeded and unseeded cooling crystallization processes of L-glutamic acid.
文摘Rising energy costs and growing environmental awareness motivate a critical revision of the design of distillation units. Systematic design techniques, such as the rectification body, column profile map, and temperature collocation methods, require exact knowledge of all pinch points in a particular system, because these stationary points delineate the possible composition trajectories realizable in separation columns. This paper demonstrates novel methods for rigorously determining all pinch points for the constant relative volatility, ideal and non-ideal systems. Constant relative volatility and ideal solution systems are transformed into one-dimensional polynomial and nonlinear functions, regardless of the number of the components. A deflation method is proposed to locate all zeros in ideal and non-ideal zeotropic problems. For more challenging non-ideal problems, a novel hybrid sequential niche algorithm is used to solve hard azeotropic problems successfully. Finally, the design implications of these pinch point locations are investigated to show how new separation configurations can be devised. Methodically the paper points out the use of rigorous pinch point computations in conjunction with continuous composition profiles for robust distillation design.
文摘We present an Euler-Lagrange method for the simulation of wood gasification in a bubbling fluidized bed. The gas phase is modeled as a continuum using the 2D Navier-Stokes equations and the solid phase is modeled by a Discrete Element Method （DEM） using a soft-sphere approach for the particle collision dynamic. Turbulence is included via a Large-Eddy approach using the Smagorinsky sub-grid model. The model takes into account detailed gas phase chemistry, zero-dimensional modeling of the pyrolysis and gasification of each individual particle, particle shrinkage, and heat and mass transfer between the gas phase and the particulate phase. We investigate the influence of wood feeding rate and compare exhaust gas compositions and temperature results obtained with the model against experimental data of a laboratory scale bubbling fiuidized bed reactor.
文摘Recent research has demonstrated that on-line video imaging is a very promising technique for monitoring crystallization processes. The bottleneck in applying the technique for real-time closed-loop control is considered as image analysis that needs to be robust, fast and able to handle varied image qualities due to temporal variations of operating conditions such as mixing and solid concentrations. Image analysis at highsolid concentrations turns out to be extremely challenging because crystals tend to overlap or attach to each other and the boundaries between the crystals are usually ambiguous. This paper presents an image segmentation algorithm that can effectively deal with images taken at high-solid concentrations. The method segments crystals attached to each other along the mostly related concave points on the contours of crystal blocks. The detailed procedure is introduced with application to crystallization of L-glutamic acid in a hot-stage reactor.
基金supported by the National Natural Science Foundation of China (90816027 and 61004094)the Excellent Graduate Student Innovative Project of the National University of Defense Technology (B070101)+1 种基金the Hunan Provincial Innovation Foundation for Post graduate (3206)the Chinese Scholarship Council (2009611036)
文摘The flame-holding mechanism in hypersonic propulsion technology is the most important factor in prolonging the duration time of hypersonic vehicles.The two-dimensional coupled implicit Reynolds-averaged Navier-Stokes equations,the shear-stress transport k-ω turbulence model and the finite-rate/eddy-dissipation reaction models were used to simulate the combustion flow field of a typical strut-based scramjet combustor.We investigated the effects of the hydrogen-air reaction mechanism and fuel injection temperature and pressure on the parametric distributions in the combustor.The numerical results show qualitative agreement with the experimental data.The hydrogen-air reaction mechanism makes only a slight difference in parametric distributions along the walls of the combustor,and the expansion waves and shock waves exist in the combustor simultaneously.Furthermore,the expansion wave is formed ahead of the shock wave.A transition occurs from the shock wave to the normal shock wave when the injection pressure or temperature increases,and the reaction zone becomes broader.When the injection pressure and temperature both increase,the waves are pushed out of the combustor with subsonic flows.When the waves are generated ahead of the strut,the separation zone is formed in double near the walls of the combustor because of the interaction of the shock wave and the boundary layer.The separation zone becomes smaller and disappears with the disappearance of the shock wave.Because of the horizontal fuel injection,the vorticity is generated near the base face of the strut,and this region is the main origin for turbulent combustion.
基金supported by the China-UK joint project of a study of multi-phase flow meter on EIT and CTA Techniques: Royal Society (Grant No. 15933)
文摘The study presented here was carried out to obtain the actual solids flow rate by the combination of electrical resistance tomography and electromagnetic flow meter. A new in-situ measurement method based on measurements of the Electromagnetic Flow Meters （EFM） and Electrical Resistance Tomography （ERT） to study the flow rates of individual phases in a vertical flow was proposed. The study was based on laboratory experiments that were carded out with a 50 mm vertical flow rig for a number of sand concentrations and different mixture velocities. A range of sand slurries with median particle size from 212 μm to 355 μm was tested. The solid concentration by volume covered was 5% and 15%, and the corresponding density of 5% was 1078 kg/m^3 and of 15% was 1238 kg/m^3. The flow velocity was between 1.5 m/s and 3.0 m/s. A total of 6 experimental tests were conducted. The equivalent liquid model was adopted to validate in-situ volumetric solids fraction and calculate the slip velocity. The results show that the ERT technique can be used in conjunction with an electromagnetic flow meter as a way of measurement of slurry flow rate in a vertical pipe flow. However it should be emphasized that the EFM results must be treated with reservation when the flow pattern at the EFM mounting position is a non-homogenous flow. The flow rate obtained by the EFM should be corrected considering the slip velocity and the flow pattern.
基金support of this work (Grant EP/D031257/1)and the contribution of illustrations from Prof. U. Tuzun (University of Surrey), Prof. C. Lin(University of Utah) and Dr C. Selomulya (Monash University)
文摘The use of X-ray microtomographic （XMT） methods in analysing particulate systems has expanded rapidly in recent years with the availability of affordable desk-top apparatus. This review presents a summary of the major applications in which computer simulations are explicitly coupled with XMT in the area of granular and porous materials. We envisage two main ways of establishing the coupling between both techniques, based on the transference or exchange of information by using physical or geometrical parameters （i.e. a parametric link through fitting to a process model） or through the direct use of3D XMT digital images （i.e. comparing image pixels and features directly）. Examples of coupled applications are shown for the study of transport properties of rocks, particle packing, mechanical loading and sintering. Often, the link between XMT and computer simulations is based on visual comparisons and we conclude that the use of quantitative parameters such as the number of interparticle contacts, force networks or granule shape to link both techniques is still underrepresented in the literature. Strategies to provide a more robust and quantitative approach to optimise the information obtained from such tomography analyses are proposed. 2010 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
文摘Magnetic polymer particles have found applications in diverse areas such as biomedical treatments, diagnosis and separation technology. These applications require the particles to have controlled sizes and narrow size distributions to gain better control and reproducibility in use. This paper reviews recent developments in the preparation of magnetic polymer particles at nano- and micro-scales by encapsulating magnetic components with dissolved or in situ formed polymers. Particle manufacture using emulsification and embedment methods produces magnetic polymer particles at micro-scale dimensions. However, the production of particles in this range using conventional emulsification methods affords very limited control over particle sizes and polydispersity. We report on alternative routes using membrane and microfluidics emulsification techniques, which have a capability to produce monodisperse emulsions and polymer microspheres （with coefficients of variation of less than 10%） in the range from submicrometer to a few 100 μm. The performance of these manufacturing methods is assessed with a view to future applications.
