Aqueous zinc ion batteries are regarded as one of the most promising candidates for large-scale energy stor-age due to their high safety,cost-effectiveness,and environ-mental friendliness.However,uncontrolled zinc den...Aqueous zinc ion batteries are regarded as one of the most promising candidates for large-scale energy stor-age due to their high safety,cost-effectiveness,and environ-mental friendliness.However,uncontrolled zinc dendrite growth and side reactions of the zinc anode decrease the sta-bility of Zn batteries.We report the synthesis of an air-oxid-ized carbon nanotube(O-CNT)film by chemical vapor de-position followed by heat treatment in air which is used as a protective layer on the Zn foil to suppress zinc dendrite growth.The increase in the hydrophilicity of the O-CNT film caused by air oxidation facilitates zinc deposition between the film and the anode instead of deposition on the film surface.The porous structure of the O-CNT film homogenizes the Zn^(2+)ion flux and the electric field on the surface of the Zn foil,leading to the uniform deposition of Zn.As a result,a O-CNT@Zn symmetric cell has a much better cycling stability with a life of more than 3000 h at 1 mA cm^(−2) with a capacity of 1 mAh cm^(−2),and values of more than 2000 h and 1 mAh cm^(−2) at 5 mA cm^(−2).In addition,a O-CNT@Zn||Mn^(2+)inserted hydrated vanadium pentoxide(MnVOH)full cell has a better rate per-formance than a Zn||MnVOH cell,achieving a high discharge capacity of 194 mAh g^(−1) at a high current density of 8 A g^(−1).In a long-term cycling test,the O-CNT@Zn||MnVOH full cell has a capacity retention of 58.8%after 2000 cycles at a current density of 5 A·g^(−1).展开更多
The development of efficient and durable electrocatalysts for oxygen reduction reaction(ORR)holds a pivotal significance in the successful commercialization of proton exchange membrane fuel cells(PEMFCs)but is still c...The development of efficient and durable electrocatalysts for oxygen reduction reaction(ORR)holds a pivotal significance in the successful commercialization of proton exchange membrane fuel cells(PEMFCs)but is still challenging.Herein,we report a worm-liked PtCu nanocrystals dispersed on nitrogen-doped carbon hollow microspheres(Pt_(0.38)Cu_(0.62)/N-HCS).Benefiting from its structural and compositional advantages,the resulting Pt_(0.38)Cu_(0.62)/N-HCS catalyst delivers exceptional electrocatalytic activity for ORR,with a half-wave potential(E_(1/2))of 0.837 V,a mass activity of 0.672 A mgPt^(-1),and a Tafel slope of 50.66 mV dec^(-1),surpassing that of commercial Pt/C.Moreover,the Pt_(0.38)Cu_(0.62)/N-HCS follows the desired four-electron transfer mechanism throughout the ORR process,thereby displaying a high selectivity for direct reduction of O_(2)to H_(2)O.Remarkably,this catalyst also showcases high stability,with only a 25 mV drop in E_(1/2)after 10,000 cycles in an acidic electrolyte.Theoretical calculations elucidate the incorporation of Cu into Pt lattice induces compressive strain,which effectively tailors the d band center of Pt active sites and strengthens the surface chemisorption of O_(2)molecules on PtCu alloys.Consequently,the Pt_(0.38)Cu_(0.62)/N-HCS catalyst exhibits an improved ability to adsorb O_(2)molecules on its surface,accelerating the reaction kinetics of O_(2)conversion to*OOH.Additionally,Cu atoms,not only serving as sacrificial anode,undergo preferential oxidation during PEMFCs operation when compared to Pt,but also the stable Cu species in PtCu alloys contributes significantly to maintaining the strain effect,collectively enhancing both activity and durability.Overall,this research offers an effective and promising approach to enhance the activity and stability of Pt-based ORR electrocatalysts in PEMFCs.展开更多
Magneto-active soft materials,composed of hard-magnetic particles embedded in polymeric matrices,have found widespread applications in soft robotics,active metamaterials,and shape-morphing structures across various le...Magneto-active soft materials,composed of hard-magnetic particles embedded in polymeric matrices,have found widespread applications in soft robotics,active metamaterials,and shape-morphing structures across various length scales due to their ability to undergo reversible,untethered,and rapid deformation in response to magnetic actuation.At small scales,surface effects play a crucial role in the mechanical behavior of these soft materials.In this paper,we theoretically investigate the influence of surface effects on the buckling instability and large deformation of magneto-active soft beams under a uniform magnetic field.The theoretical model is derived according to the principle of minimum potential energy and numerically solved with the finite difference method.By employing the developed theoretical model,parametric studies are performed to explore how surface effects influence the buckling instability and large deformation of magneto-active soft cantilever beams with varying geometric parameters under different uniform magnetic fields.Our results reveal that the influence of surface effects on the mechanical behavior of magneto-active soft beams depends not only on the geometric parameters but also on the magnetic field strength.Specifically,when the magnetic field strength is relatively small,surface effects reduce the deformation of magneto-active soft beams,particularly for beams with smaller thicknesses and larger length-to-thickness ratios.However,when the magnetic field strength is sufficiently large,and the beam's deformation becomes saturated,surface effects have little influence on the deformation.This work uncovers the role of surface effects in the mechanical behavior of magnetoactive soft materials,which could provide guidelines for the design and optimization of small-scale magnetic-active soft material-based applications.展开更多
Shikonin,a naphthoquinone compound derived from the root of Lithospermum erythrorhizon,has been extensively studied for its antibacterial,antioxidant,and anti-inflammatory properties.Increasing evidence highlights its...Shikonin,a naphthoquinone compound derived from the root of Lithospermum erythrorhizon,has been extensively studied for its antibacterial,antioxidant,and anti-inflammatory properties.Increasing evidence highlights its potential in treating inflammation-related diseases.However,its clinical application is hindered by challenges such as poor water solubility,rapid metabolism in vivo,and other limitations.Recent advancements have demonstrated that encapsulating shikonin within nanocarriers can significantly enhance its water solubility and pharmacokinetic profile.Building on this,this perspective paper outlines the current landscape of inflammation treatment,explores the anti-inflammatory mechanisms of shikonin,reviews the latest progress in shikonin-based nanomaterials for anti-inflammatory applications,and discusses the challenges and future directions for the clinical translation of shikonin nanoformulations.展开更多
Based on the Pathfinder sea surface temperature(PFSST),the surface axis and its pattern of the Yellow Sea Warm Current(YSWC) are discussed.A structure of double-warm-tongue is found in February and it varies in differ...Based on the Pathfinder sea surface temperature(PFSST),the surface axis and its pattern of the Yellow Sea Warm Current(YSWC) are discussed.A structure of double-warm-tongue is found in February and it varies in different years.Two indexes are calculated to represent the westward shift(WSI) and northward extension(NEI) of the warm water in the Yellow Sea(YS).Wavelet analysis illustrates that the WSI and NEI have prominent periods of 3-6 years and 3-4 years,respectively.The Empirical Orthogonal Function(EOF) decomposition is applied to the winter wind stress curl and the Kuroshio Current(KC) transport,which are believed to play important roles in forcing the variability of the YSWC surface axis.Statistics shows that the WSI is significantly related with the second EOF mode of the wind stress curl in February,which may force the YSWC surface axis moving westward and maintaining the double warm tongues because of its opposite curl in the YSWC domain.The first EOF mode of wind stress curl in January is propitious for inducing the warm tongue in the YS to advance more northward.Hence,the wind stress curls both in January and in February could force variations of the YSWC surface axis;however,the effect of the January wind stress curl is relatively weaker than that of the February.The relationship between the NEI and the KC transport is remarkable,and it seems that the stronger KC supplies more power to push the YSWC northward against the southward wind.展开更多
The tradeoff between the strength and the fracture elongation in the high-strength Cu-Ni-Si alloy became a hot research topic recently.Cu-Ni-Si-(Ti) alloys were fabricated in a vacuum induction melting furnace to stud...The tradeoff between the strength and the fracture elongation in the high-strength Cu-Ni-Si alloy became a hot research topic recently.Cu-Ni-Si-(Ti) alloys were fabricated in a vacuum induction melting furnace to study the effects of titanium on the microstructure and mechanical properties of Cu-Ni-Si alloys with different thermo-mechanical treatments.After homogenization at 900℃ for 4 h,hot-rolled by 80%,solution treatment at 970℃ for 2 h,cold-rolled by 50%,and finally aged at 450℃ for 180 min,the studied Cu-10 Ni-Si-2 Ti alloy achieved the hardness of HV 252.4,electrical conductivity of 23.6% IACS,tensile strength of 764.4 MPa,yield strength of 622.26 MPa,fracture elongation of 10.4%,and strength-elongation product of 7.95 GPa%,which are less than those of the studied Cu-10 Ni-2 Si alloy.The addition of Ti contributed to refining the microstructure,suppressing the decreasing trend in mechanical properties after peak hardening,and arousing a primary substructure strengthening mechanism rather than the precipitation strengthening in Cu-Ni-Si alloys.These findings provide essential understandings of the effects of the Ti on Cu-Ni-Si system alloys,and the designed Cu-Ni-Si alloys with highstrength and fracture elongation could fulfill some requirements of the electronic and electrical industry.展开更多
In this paper, we propose a compound algorithm for the image restoration. The algorithm is a convex combination of the ROF model and the LLT model with a parameter function 0. The numerical experiments demonstrate tha...In this paper, we propose a compound algorithm for the image restoration. The algorithm is a convex combination of the ROF model and the LLT model with a parameter function 0. The numerical experiments demonstrate that our compound algorithm is efficient and preserves the main advantages of the two models. In particular, the errors of the compound algorithm in L2 norm between the exact images and corresponding restored images are the smallest among the three models. For images with strong noises, the restored images of the compound algorithm are the best in the corresponding restored images. The proposed algorithm combines the fixed point method, an improved AMG method and the Krylov acceleration. It is found that the combination of these methods is efficient and robust in the image restoration.展开更多
Lithium(Li)is a promising candidate for nextgeneration battery anode due to its high theoretical specific capacity and low reduction potential.However,safety issues derived from the uncontrolled growth of Li dendrite ...Lithium(Li)is a promising candidate for nextgeneration battery anode due to its high theoretical specific capacity and low reduction potential.However,safety issues derived from the uncontrolled growth of Li dendrite and huge volume change of Li hinder its practical application.C onstructing dendrite-free composite Li anodes can significantly alleviate the above problems.Copper(Cu)-based materials have bee n widely used as substrates of the composite electrodes due to their chemical stability,excellent conductivity,and good mechanical strength.Copper/lithium(Cu/Li)composite anodes significantly regulate the local current density and decrease Li nucleation overp otential,realizing the uniform and dendrite-free Li deposition.In this review,Cu/Li composite methods including electrodeposition,melting infusion,and mechanical rolling are systematically summarized and discussed.Additionally,design strategies of Cu-based current collectors for high performance Cu/Li composite anodes are illustrated.General challenges and future development for Cu/Li composite anodes are presented and postulated.We hope that this review can provide a comprehensive understanding of Cu/Li composite methods of the latest development of Li metal anode and stimulate more research in the future.展开更多
Objective To evaluate the efficacy of cis-2-dodecenoic acid(BDSF) in the treatment and prevention of vaginal candidiasis in vivo. Methods The activities of different concentrations of BDSF against the virulence factor...Objective To evaluate the efficacy of cis-2-dodecenoic acid(BDSF) in the treatment and prevention of vaginal candidiasis in vivo. Methods The activities of different concentrations of BDSF against the virulence factors of Candida albicans(C. albicans) were determined in vitro. An experimental mouse model of Candida vaginitis was treated with 250 μmol/L BDSF. Treatment efficiency was evaluated in accordance with vaginal fungal burden and inflammation symptoms. Results In vitro experiments indicated that BDSF attenuated the adhesion and damage of C. albicans to epithelial cells by decreasing phospholipase secretion and blocking filament formation. Treatment with 30 μmol/L BDSF reduced the adhesion and damage of C. albicans to epithelial cells by 36.9% and 42.3%, respectively. Treatment with 200 μmol/L BDSF completely inhibited phospholipase activity. In vivo mouse experiments demonstrated that BDSF could effectively eliminate vaginal infection and relieve inflammatory symptoms. Four days of treatment with 250 μmol/L BDSF reduced vaginal fungal loads by 6-fold and depressed inflammation. Moreover, BDSF treatment decreased the expression levels of the inflammatory chemokine-associated genes MCP-1 and IGFBP3 by 2.5-and 2-fold, respectively. Conclusion BDSF is a novel alternative drug that can efficiently control vaginal candidiasis by inhibiting the virulence factors of C. albicans.展开更多
Monolayer group VI transition metal dichalcogenides(TMDs)have recently emerged as promising candidates for photonic and opto-valleytronic applications.The optoelectronic properties of these atomically-thin semiconduct...Monolayer group VI transition metal dichalcogenides(TMDs)have recently emerged as promising candidates for photonic and opto-valleytronic applications.The optoelectronic properties of these atomically-thin semiconducting crystals are strongly governed by the tightly bound electron-hole pairs such as excitons and trions(charged excitons).The anomalous spin and valley configurations at the conduction band edges in monolayer WS_(2)give rise to even more fascinating valley many-body complexes.Here we find that the indirect Q valley in the first Brillouin zone of monolayer WS_(2)plays a critical role in the formation of a new excitonic state,which has not been well studied.By employing a high-quality h-BN encapsulated WS_(2)field-effect transistor,we are able to switch the electron concentration within K-Q valleys at conduction band edges.Consequently,a distinct emission feature could be excited at the high electron doping region.Such feature has a competing population with the K valley trion,and experiences nonlinear power-law response and lifetime dynamics under doping.Our findings open up a new avenue for the study of valley many-body physics and quantum optics in semiconducting 2D materials,as well as provide a promising way of valley manipulation for next-generation entangled photonic devices.展开更多
An applied field is used to perform Ga^(+)ion irradiation on a CoFe/PtMn bilayer.Effects of the applied field and energy transfer between Ga^(+)ions and antiferromagnetic(AFM)atoms on the exchange bias field Hex are i...An applied field is used to perform Ga^(+)ion irradiation on a CoFe/PtMn bilayer.Effects of the applied field and energy transfer between Ga^(+)ions and antiferromagnetic(AFM)atoms on the exchange bias field Hex are investigated.A partially reversed H_(ex)is found in CoFe/PtMn specimens irradiated at a dose of 1×10^(14)ions/cm^(2)with an applied field anti-parallel to the original exchange bias direction.We believe that the rapid energy transfer and local temperature increase originating from the interaction between Ga^(+)ions and AFM atoms result in spin reversal and the formation of reversed AFM domains when specimens are irradiated with anti-parallel fields.The decrease in H_(ex)when annealing the film in a negative saturation field indicates a thermal decay process.The AFM moments are reversed by thermal activation over an energy barrier distribution,which may change in some way as the temperature increases.展开更多
We study the two-dimensional(2D)Cauchy problem of nonhomogeneous Boussinesq system for magnetohydrodynamics convection without heat diffusion in the whole plane.Based on delicate weighted estimates,we derive the globa...We study the two-dimensional(2D)Cauchy problem of nonhomogeneous Boussinesq system for magnetohydrodynamics convection without heat diffusion in the whole plane.Based on delicate weighted estimates,we derive the global existence and uniqueness of strong solutions.In particular,the initial data can be arbitrarily large and the initial density may contain vacuum states and even have compact support.展开更多
α-MnO_(2) is a potential positive electrode material for aqueous zinc-ion batteries,but its electrochemical performance of zinc storage requires further improvement.In this paper,potassium ion-doped manganese dioxide...α-MnO_(2) is a potential positive electrode material for aqueous zinc-ion batteries,but its electrochemical performance of zinc storage requires further improvement.In this paper,potassium ion-doped manganese dioxide nanoscrolls(K-MnO_(2))with oxygen vacancy were synthesized by a one-step hydrothermal method.It was observed that the electrochemical specific capacity was 250.9 m Ah/g at a current density of 0.2 C,which was better than the existing commercialα-MnO_(2).At a high current of 1 C,these batteries demonstrate improved cycle stability.Synchrotron radiation and other experiments as well as DFT theoretical calculations provided additional evidence that K doping was efficient in regulating the metal bond type and the mean charge regulation of covalent bonds with oxygen atoms in MnO_(2).When Mn-O and Mn-K bonds are present,K-MnO_(2) showed outstanding adsorption of Zn~(2+)and further enhanced the Zn^(2+)embedding process.Simultaneously,oxygen defects caused by doping boosted the development of the nanoscroll structure,leading to an increase in active sites available for electrochemical reactions and subsequently enhancing the electrical conductivity ofα-MnO_(2).This study exhibits the potential of optimizing materials based on manganese with the introduction of a potassium doping strategy,resulting in improved performance for aquatic zinc-ion batteries,and presents novel perspectives for related research.展开更多
Aqueous zinc-ion batteries encounter impediments on their trajectory towards commercialization,primarily due to challenges such as dendritic growth,hydrogen evolution reaction.Throughout recent decades of investigatio...Aqueous zinc-ion batteries encounter impediments on their trajectory towards commercialization,primarily due to challenges such as dendritic growth,hydrogen evolution reaction.Throughout recent decades of investigation,electrolyte modulation by using function additives is widely considered as a facile and efficient way to prolong the Zn anode lifespan.Herein,N-(2-hydroxypropyl)ethylenediamine is employed as an additive to attach onto the Zn surface with a substantial adsorption energy with(002)facet.The as-formed in-situ solid-electrolyte interphase layer effectively mitigates hydrogen evolution reaction by constructing a lean-water internal Helmholtz layer.Additionally,N-(2-hydroxypropyl)ethylenediamine establishes a coordination complex with Zn^(2+),thereby modulating the solvation structure and enhancing the mobility of Zn^(2+).As expected,the Zn-symmetrical cell with N-(2-hydroxypropyl)ethylenediamine additive demonstrated successful cycling exceeding 1500 h under 1 mA cm^(-2) for0.5 mAh cm^(-2).Furthermore,the Zn//δ-MnO_(2) battery maintains a capacity of approximately 130 mAh g^(-1) after 800 cycles at 1 A g^(-1),with a Coulombic efficiency surpassing 98%.This work presents a streamlined approach for realizing aqueous zinc-ion batteries with extended service life.展开更多
Cardiovascular disease(CVD)represents the foremost cause of mortality globally,imposing a substantial economic burden.In 2021,approximately 19.4 million deaths were attributed to cardiovascular conditions,constituting...Cardiovascular disease(CVD)represents the foremost cause of mortality globally,imposing a substantial economic burden.In 2021,approximately 19.4 million deaths were attributed to cardiovascular conditions,constituting 32%of global mortality[1].Over three-quarters of these fatalities occurred in low and middle-income nations.Notably,ischemic heart disease and stroke were responsible for 84%of CVD-related deaths.Among them,the number of cases of ischemic cardiomyopathy increased by 68%in 2021 compared to 1990(Figure 1A).展开更多
Developing fast-charging lithium-ion batteries(LIBs)that feature high energy density is critical for the scalable application of electric vehicles.Iron vanadate(FVO)holds great potential as anode material in fast-char...Developing fast-charging lithium-ion batteries(LIBs)that feature high energy density is critical for the scalable application of electric vehicles.Iron vanadate(FVO)holds great potential as anode material in fast-charging LIBs because of its high theoretical specific capacity and the high natural abundance of its constituents.However,the capacity of FVO rapidly decays due to its low electrical conductivity.Herein,uniform FVO nanoparticles are grown in situ on ordered mesoporous carbon(CMK-3)support,forming a highly electrically conductive porous network,FVO/CMK-3.The structure of CMK-3 helps prevent agglomeration of FVO particles.The electrically conductive nature of CMK-3 can further enhance the electrical conductivity of FVO/CMK-3 and buffer the volume expansion of FVO particles during cycling processes.As a result,the FVO/CMK-3 displays excellent fast-charging performance of 364.6 mAh·g^(-1)capacity for 2500 cycles at 10 A·g^(-1)(with an ultralow average capacity loss per cycle of 0.003%)through a pseudocapacitive-dominant process.Moreover,the LiCoO_(2)//FVO/CMK-3 full cell achieves a high capacity of 100.2 mAh·g^(-1)and a high capacity retention(96.2%)after 200 cycles.The superior electrochemical performance demonstrates that FVO/CMK-3 is an ideal anode material candidate for fast-charging,stable LIBs with high energy density.展开更多
Pulsed electrolysis for CO_(2)reduction reaction has emerged as an effective method to enhance catalyst efficiency and optimize product selectivity.However,challenges remain in understanding the mechanisms of surface ...Pulsed electrolysis for CO_(2)reduction reaction has emerged as an effective method to enhance catalyst efficiency and optimize product selectivity.However,challenges remain in understanding the mechanisms of surface transformation under pulsed conditions.In this study,using in-situ time-resolved surface-enhanced Raman spectroscopy and differential electrochemical mass spectroscopy,we found local pH at the surface and Cu–O–C species that was generated during the anodic pulse played a key role in pulsed electrolysis.During the pulsed oxidation,an oxidation layer first formed,depleting OH–and lowering the local pH.When the pH was below 8.4,HCO_(3)–transformed the oxidation layer to a nanometer-thick Cu–O–C species,which is a highly reactive catalyst.In the reduction pulse,about 7.4%of the surface Cu–O–C was transformed into CO and CuOx species,enhancing CO_(2)reduction activity.Even in Ar-saturated 0.1 M KHCO_(3),through a Cu–O–C intermediate,a Faradaic efficiency of 0.17%for bicarbonate reduction to CO was observed.Our findings highlight the crucial role of the anodic pulse process in improving CO_(2)reduction activity.展开更多
The Sustainable Development Goals(SDGs)are crucial in tackling the sustainability challenges and emerging issues faced by humanity,with government attention being a significant factor in promoting their successful ach...The Sustainable Development Goals(SDGs)are crucial in tackling the sustainability challenges and emerging issues faced by humanity,with government attention being a significant factor in promoting their successful achievement.However,there is limited quantitative research systematically examining the impacts of government attention on SDGs progress.This study employs text analysis and a panel regression model to analyze the impacts of government attention intensity,text similarity,and tone on the achievement of SDGs,utilizing data extracted from China’s Government Work Reports spanning the decade from 2010 to 2020.The findings reveal that the Chinese government attention to the SDGs has generally increased over time.The heightened focus has notably bolstered the achievement of the SDGs,with the most significant impact observed post-2015.Government attention intensity was identified as the most impactful factor.Moreover,government attention intensity,text similarity,and tone have positively influenced the coupling coordination relationship between 17 SDGs,as measured by the coupling coordination degree,leading to a more harmonious and balanced achievement of socioeconomic and environmental goals in China.Financial investment served as a moderating factor,enhancing the positive impacts of attention intensity,text similarity and tone on the promotion of SDGs attainment.The effects of government attention on SDGs progress were notably positive in the eastern region,exhibiting greater significance in areas with stronger governance capacity compared to those with weaker governance capacity.This study provides insightful information for enhancing the modernization and efficiency of China’s national governance system,promoting SDGs at local and global scales,and fostering sustainable transformation.展开更多
Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extrac...Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extracting sustainable and clean energy fromthe salinity gradient energy.However,the scarcity of research investigating the intricate multi-factor coupling effects on the energy conversion performance,especially the trade-offs between ion selectivity and mass transfer in nanochannels,of NRED poses a great challenge to achieving breakthroughs in energy conversion processes.This numerical study innovatively investigates the multi-factor coupling effect of three critical operational factors,including the nanochannel configuration,the temperature field,and the concentration difference,on the energy conversion processes of NRED.In this work,a dimensionless amplitude parameter s is introduced to emulate the randomly varied wall configuration of nanochannels that inherently occur in practical applications,thereby enhancing the realism and applicability of our analysis.Numerical results reveal that the application of a temperature gradient,which is oriented in opposition to the concentration gradient,enhances the ion transportation and selectivity simultaneously,leading to an enhancement in both output power and energy conversion efficiency.Additionally,the increased fluctuation of the nanochannel wall from s=0 to s=0.08 improves ion selectivity yet raises ion transport resistance,resulting in an enhancement in output power and energy conversion efficiency but a slight reduction in current.Furthermore,with increasing the concentration ratio cH/cL from 10 to 1000,either within a fixed temperature field or at a constant dimensionless amplitude,the maximumpower consistently attains its optimal value at a concentration ratio of 100 but the cation transfer number experiences amonotonic decrease across this entire range of concentration ratios.Finally,uponmodifying the operational parameters fromthe baseline condition of s=0,c_(H)/c_(L)=10,andΔT=0 K to the targetedconditionof s=0.08,c_(H)/c_(L)=50,andΔT=25 K,there is a concerted improvement observed in the open-circuit potential,short-circuit current,andmaximumpower,with respective increments of 8.86%,204.97%,and 232.01%,but a reduction in cation transfer number with a notable decrease of 15.37%.展开更多
基金supported by the National Natural Science Foundation of China(22179093 and21905202)。
文摘Aqueous zinc ion batteries are regarded as one of the most promising candidates for large-scale energy stor-age due to their high safety,cost-effectiveness,and environ-mental friendliness.However,uncontrolled zinc dendrite growth and side reactions of the zinc anode decrease the sta-bility of Zn batteries.We report the synthesis of an air-oxid-ized carbon nanotube(O-CNT)film by chemical vapor de-position followed by heat treatment in air which is used as a protective layer on the Zn foil to suppress zinc dendrite growth.The increase in the hydrophilicity of the O-CNT film caused by air oxidation facilitates zinc deposition between the film and the anode instead of deposition on the film surface.The porous structure of the O-CNT film homogenizes the Zn^(2+)ion flux and the electric field on the surface of the Zn foil,leading to the uniform deposition of Zn.As a result,a O-CNT@Zn symmetric cell has a much better cycling stability with a life of more than 3000 h at 1 mA cm^(−2) with a capacity of 1 mAh cm^(−2),and values of more than 2000 h and 1 mAh cm^(−2) at 5 mA cm^(−2).In addition,a O-CNT@Zn||Mn^(2+)inserted hydrated vanadium pentoxide(MnVOH)full cell has a better rate per-formance than a Zn||MnVOH cell,achieving a high discharge capacity of 194 mAh g^(−1) at a high current density of 8 A g^(−1).In a long-term cycling test,the O-CNT@Zn||MnVOH full cell has a capacity retention of 58.8%after 2000 cycles at a current density of 5 A·g^(−1).
基金the Young Elite Scientists Sponsorship Program by CAST(2021QNRC001)Natural Science Foundation of Chongqing(CSTB2022NSCQ-MSX0557,cstb2023nscq-msx0979)+3 种基金Talent Introduction of Chongqing University of Science and Technology(ckrc2021050,ckrc20230401,ckrc2021053)the Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202201532,KJQN202301542)the National Natural Science Foundation of China(22109016)Open Research Fund of CNMGE Platform&NSCC-TJ(CNMGE2023016).
文摘The development of efficient and durable electrocatalysts for oxygen reduction reaction(ORR)holds a pivotal significance in the successful commercialization of proton exchange membrane fuel cells(PEMFCs)but is still challenging.Herein,we report a worm-liked PtCu nanocrystals dispersed on nitrogen-doped carbon hollow microspheres(Pt_(0.38)Cu_(0.62)/N-HCS).Benefiting from its structural and compositional advantages,the resulting Pt_(0.38)Cu_(0.62)/N-HCS catalyst delivers exceptional electrocatalytic activity for ORR,with a half-wave potential(E_(1/2))of 0.837 V,a mass activity of 0.672 A mgPt^(-1),and a Tafel slope of 50.66 mV dec^(-1),surpassing that of commercial Pt/C.Moreover,the Pt_(0.38)Cu_(0.62)/N-HCS follows the desired four-electron transfer mechanism throughout the ORR process,thereby displaying a high selectivity for direct reduction of O_(2)to H_(2)O.Remarkably,this catalyst also showcases high stability,with only a 25 mV drop in E_(1/2)after 10,000 cycles in an acidic electrolyte.Theoretical calculations elucidate the incorporation of Cu into Pt lattice induces compressive strain,which effectively tailors the d band center of Pt active sites and strengthens the surface chemisorption of O_(2)molecules on PtCu alloys.Consequently,the Pt_(0.38)Cu_(0.62)/N-HCS catalyst exhibits an improved ability to adsorb O_(2)molecules on its surface,accelerating the reaction kinetics of O_(2)conversion to*OOH.Additionally,Cu atoms,not only serving as sacrificial anode,undergo preferential oxidation during PEMFCs operation when compared to Pt,but also the stable Cu species in PtCu alloys contributes significantly to maintaining the strain effect,collectively enhancing both activity and durability.Overall,this research offers an effective and promising approach to enhance the activity and stability of Pt-based ORR electrocatalysts in PEMFCs.
基金Project supported by the National Natural Science Foundation of China(Nos.12202009 and12002004)。
文摘Magneto-active soft materials,composed of hard-magnetic particles embedded in polymeric matrices,have found widespread applications in soft robotics,active metamaterials,and shape-morphing structures across various length scales due to their ability to undergo reversible,untethered,and rapid deformation in response to magnetic actuation.At small scales,surface effects play a crucial role in the mechanical behavior of these soft materials.In this paper,we theoretically investigate the influence of surface effects on the buckling instability and large deformation of magneto-active soft beams under a uniform magnetic field.The theoretical model is derived according to the principle of minimum potential energy and numerically solved with the finite difference method.By employing the developed theoretical model,parametric studies are performed to explore how surface effects influence the buckling instability and large deformation of magneto-active soft cantilever beams with varying geometric parameters under different uniform magnetic fields.Our results reveal that the influence of surface effects on the mechanical behavior of magneto-active soft beams depends not only on the geometric parameters but also on the magnetic field strength.Specifically,when the magnetic field strength is relatively small,surface effects reduce the deformation of magneto-active soft beams,particularly for beams with smaller thicknesses and larger length-to-thickness ratios.However,when the magnetic field strength is sufficiently large,and the beam's deformation becomes saturated,surface effects have little influence on the deformation.This work uncovers the role of surface effects in the mechanical behavior of magnetoactive soft materials,which could provide guidelines for the design and optimization of small-scale magnetic-active soft material-based applications.
基金supported by the National Natural Science Foundation of China(82373393),Xinjiang Uygur Autonomous Region“Tianchi Yingcai”Project(2023TCYCQNBS02)Xinjiang Uygur Autonomous Region Colleges and Universities Basic Research Operating Expenses Scientific Research Project(XJEDU2022P106).
文摘Shikonin,a naphthoquinone compound derived from the root of Lithospermum erythrorhizon,has been extensively studied for its antibacterial,antioxidant,and anti-inflammatory properties.Increasing evidence highlights its potential in treating inflammation-related diseases.However,its clinical application is hindered by challenges such as poor water solubility,rapid metabolism in vivo,and other limitations.Recent advancements have demonstrated that encapsulating shikonin within nanocarriers can significantly enhance its water solubility and pharmacokinetic profile.Building on this,this perspective paper outlines the current landscape of inflammation treatment,explores the anti-inflammatory mechanisms of shikonin,reviews the latest progress in shikonin-based nanomaterials for anti-inflammatory applications,and discusses the challenges and future directions for the clinical translation of shikonin nanoformulations.
基金Supported by the National Basic Research Program of China (973 Program) (No 2005C B422308)the National High-tech Research and Development Program (863 Program) (No 2006AA09Z149)the China International Science and Technology Cooperation Program (No2006DFB21250)
文摘Based on the Pathfinder sea surface temperature(PFSST),the surface axis and its pattern of the Yellow Sea Warm Current(YSWC) are discussed.A structure of double-warm-tongue is found in February and it varies in different years.Two indexes are calculated to represent the westward shift(WSI) and northward extension(NEI) of the warm water in the Yellow Sea(YS).Wavelet analysis illustrates that the WSI and NEI have prominent periods of 3-6 years and 3-4 years,respectively.The Empirical Orthogonal Function(EOF) decomposition is applied to the winter wind stress curl and the Kuroshio Current(KC) transport,which are believed to play important roles in forcing the variability of the YSWC surface axis.Statistics shows that the WSI is significantly related with the second EOF mode of the wind stress curl in February,which may force the YSWC surface axis moving westward and maintaining the double warm tongues because of its opposite curl in the YSWC domain.The first EOF mode of wind stress curl in January is propitious for inducing the warm tongue in the YS to advance more northward.Hence,the wind stress curls both in January and in February could force variations of the YSWC surface axis;however,the effect of the January wind stress curl is relatively weaker than that of the February.The relationship between the NEI and the KC transport is remarkable,and it seems that the stronger KC supplies more power to push the YSWC northward against the southward wind.
基金financially supported by the National MCF Energy R&D Program of China(No.2018YFE0306100)the National Natural Science Foundation of China(No.51901250)+2 种基金the Natural Science Foundation of Hunan Province(No.2019JJ50765)Ningbo“Science and Technology Innovation 2025”Major Project(No.2019B10087)the Open sharing Fund of the Large-scale Instruments and Equipment of Central South University(No.CSUZC202010)。
文摘The tradeoff between the strength and the fracture elongation in the high-strength Cu-Ni-Si alloy became a hot research topic recently.Cu-Ni-Si-(Ti) alloys were fabricated in a vacuum induction melting furnace to study the effects of titanium on the microstructure and mechanical properties of Cu-Ni-Si alloys with different thermo-mechanical treatments.After homogenization at 900℃ for 4 h,hot-rolled by 80%,solution treatment at 970℃ for 2 h,cold-rolled by 50%,and finally aged at 450℃ for 180 min,the studied Cu-10 Ni-Si-2 Ti alloy achieved the hardness of HV 252.4,electrical conductivity of 23.6% IACS,tensile strength of 764.4 MPa,yield strength of 622.26 MPa,fracture elongation of 10.4%,and strength-elongation product of 7.95 GPa%,which are less than those of the studied Cu-10 Ni-2 Si alloy.The addition of Ti contributed to refining the microstructure,suppressing the decreasing trend in mechanical properties after peak hardening,and arousing a primary substructure strengthening mechanism rather than the precipitation strengthening in Cu-Ni-Si alloys.These findings provide essential understandings of the effects of the Ti on Cu-Ni-Si system alloys,and the designed Cu-Ni-Si alloys with highstrength and fracture elongation could fulfill some requirements of the electronic and electrical industry.
基金suppprt from NSFC of China,Singapore NTU project SUG 20/07,MOE Grant T207B2202NRF2007IDMIDM002-010
文摘In this paper, we propose a compound algorithm for the image restoration. The algorithm is a convex combination of the ROF model and the LLT model with a parameter function 0. The numerical experiments demonstrate that our compound algorithm is efficient and preserves the main advantages of the two models. In particular, the errors of the compound algorithm in L2 norm between the exact images and corresponding restored images are the smallest among the three models. For images with strong noises, the restored images of the compound algorithm are the best in the corresponding restored images. The proposed algorithm combines the fixed point method, an improved AMG method and the Krylov acceleration. It is found that the combination of these methods is efficient and robust in the image restoration.
基金supported by the National Key Research and Development Program of China(No.2021YFB2500200)the National Natural Science Foundation of China(No.52302243)China Postdoctoral Science Foundation(Nos.2022M721029 and 2022M721030)。
文摘Lithium(Li)is a promising candidate for nextgeneration battery anode due to its high theoretical specific capacity and low reduction potential.However,safety issues derived from the uncontrolled growth of Li dendrite and huge volume change of Li hinder its practical application.C onstructing dendrite-free composite Li anodes can significantly alleviate the above problems.Copper(Cu)-based materials have bee n widely used as substrates of the composite electrodes due to their chemical stability,excellent conductivity,and good mechanical strength.Copper/lithium(Cu/Li)composite anodes significantly regulate the local current density and decrease Li nucleation overp otential,realizing the uniform and dendrite-free Li deposition.In this review,Cu/Li composite methods including electrodeposition,melting infusion,and mechanical rolling are systematically summarized and discussed.Additionally,design strategies of Cu-based current collectors for high performance Cu/Li composite anodes are illustrated.General challenges and future development for Cu/Li composite anodes are presented and postulated.We hope that this review can provide a comprehensive understanding of Cu/Li composite methods of the latest development of Li metal anode and stimulate more research in the future.
基金financially supported by the National Natural Science Foundation of China [81273409]the Program for Changjiang Scholars and Innovative Research Team in University [IRT_15R37]the Ministry of Science and Technology of China [2017YFA0205301]
文摘Objective To evaluate the efficacy of cis-2-dodecenoic acid(BDSF) in the treatment and prevention of vaginal candidiasis in vivo. Methods The activities of different concentrations of BDSF against the virulence factors of Candida albicans(C. albicans) were determined in vitro. An experimental mouse model of Candida vaginitis was treated with 250 μmol/L BDSF. Treatment efficiency was evaluated in accordance with vaginal fungal burden and inflammation symptoms. Results In vitro experiments indicated that BDSF attenuated the adhesion and damage of C. albicans to epithelial cells by decreasing phospholipase secretion and blocking filament formation. Treatment with 30 μmol/L BDSF reduced the adhesion and damage of C. albicans to epithelial cells by 36.9% and 42.3%, respectively. Treatment with 200 μmol/L BDSF completely inhibited phospholipase activity. In vivo mouse experiments demonstrated that BDSF could effectively eliminate vaginal infection and relieve inflammatory symptoms. Four days of treatment with 250 μmol/L BDSF reduced vaginal fungal loads by 6-fold and depressed inflammation. Moreover, BDSF treatment decreased the expression levels of the inflammatory chemokine-associated genes MCP-1 and IGFBP3 by 2.5-and 2-fold, respectively. Conclusion BDSF is a novel alternative drug that can efficiently control vaginal candidiasis by inhibiting the virulence factors of C. albicans.
基金the strong support from Singapore Ministry of Education via AcRF Tier 3 Programme “Geometrical Quantum Materials” (MOE2018-T3-1-002)AcRF Tier 2 grants (MOE2017-T2-1040)+7 种基金the National Natural Science Foundation of China (Grant No. 61435010)the National Natural Science Foundation of China (Grant No. 61905156)the National Natural Science Foundation of China (Grant No. 61575010)the China Postdoctoral Science Foundation (Grant No. 2017M622764)the Natural Science Foundation of Fujian Province (Grant No. 2022J01555)the Beijing Municipal Natural Science Foundation (Grant No. 4162016)the financial support of the Presidential Postdoctoral Fellowship program of the Nanyang Technological Universitysupport from the Elemental Strategy Initiative conducted by the MEXT, Japan and the CREST (JPMJCR15F3), JST
文摘Monolayer group VI transition metal dichalcogenides(TMDs)have recently emerged as promising candidates for photonic and opto-valleytronic applications.The optoelectronic properties of these atomically-thin semiconducting crystals are strongly governed by the tightly bound electron-hole pairs such as excitons and trions(charged excitons).The anomalous spin and valley configurations at the conduction band edges in monolayer WS_(2)give rise to even more fascinating valley many-body complexes.Here we find that the indirect Q valley in the first Brillouin zone of monolayer WS_(2)plays a critical role in the formation of a new excitonic state,which has not been well studied.By employing a high-quality h-BN encapsulated WS_(2)field-effect transistor,we are able to switch the electron concentration within K-Q valleys at conduction band edges.Consequently,a distinct emission feature could be excited at the high electron doping region.Such feature has a competing population with the K valley trion,and experiences nonlinear power-law response and lifetime dynamics under doping.Our findings open up a new avenue for the study of valley many-body physics and quantum optics in semiconducting 2D materials,as well as provide a promising way of valley manipulation for next-generation entangled photonic devices.
基金Supported by the College Natural Science Foundation of Jiangsu Province under Grant No 09KJB43001。
文摘An applied field is used to perform Ga^(+)ion irradiation on a CoFe/PtMn bilayer.Effects of the applied field and energy transfer between Ga^(+)ions and antiferromagnetic(AFM)atoms on the exchange bias field Hex are investigated.A partially reversed H_(ex)is found in CoFe/PtMn specimens irradiated at a dose of 1×10^(14)ions/cm^(2)with an applied field anti-parallel to the original exchange bias direction.We believe that the rapid energy transfer and local temperature increase originating from the interaction between Ga^(+)ions and AFM atoms result in spin reversal and the formation of reversed AFM domains when specimens are irradiated with anti-parallel fields.The decrease in H_(ex)when annealing the film in a negative saturation field indicates a thermal decay process.The AFM moments are reversed by thermal activation over an energy barrier distribution,which may change in some way as the temperature increases.
文摘We study the two-dimensional(2D)Cauchy problem of nonhomogeneous Boussinesq system for magnetohydrodynamics convection without heat diffusion in the whole plane.Based on delicate weighted estimates,we derive the global existence and uniqueness of strong solutions.In particular,the initial data can be arbitrarily large and the initial density may contain vacuum states and even have compact support.
基金supported by Beijing Synchrotron Radiation 4B9A and 1W2A Work Station in China,National Natural Science Foundation of China(No.52250710161)。
文摘α-MnO_(2) is a potential positive electrode material for aqueous zinc-ion batteries,but its electrochemical performance of zinc storage requires further improvement.In this paper,potassium ion-doped manganese dioxide nanoscrolls(K-MnO_(2))with oxygen vacancy were synthesized by a one-step hydrothermal method.It was observed that the electrochemical specific capacity was 250.9 m Ah/g at a current density of 0.2 C,which was better than the existing commercialα-MnO_(2).At a high current of 1 C,these batteries demonstrate improved cycle stability.Synchrotron radiation and other experiments as well as DFT theoretical calculations provided additional evidence that K doping was efficient in regulating the metal bond type and the mean charge regulation of covalent bonds with oxygen atoms in MnO_(2).When Mn-O and Mn-K bonds are present,K-MnO_(2) showed outstanding adsorption of Zn~(2+)and further enhanced the Zn^(2+)embedding process.Simultaneously,oxygen defects caused by doping boosted the development of the nanoscroll structure,leading to an increase in active sites available for electrochemical reactions and subsequently enhancing the electrical conductivity ofα-MnO_(2).This study exhibits the potential of optimizing materials based on manganese with the introduction of a potassium doping strategy,resulting in improved performance for aquatic zinc-ion batteries,and presents novel perspectives for related research.
基金supported by the National Natural Science Foundation of China(52272258 and 52411530056)the Beijing Nova Program(20220484214)+1 种基金Key R&D and Transformation Projects in Qinghai Province(2023-HZ-801)the financial support from the China Scholarship Council(No.202006210070)。
文摘Aqueous zinc-ion batteries encounter impediments on their trajectory towards commercialization,primarily due to challenges such as dendritic growth,hydrogen evolution reaction.Throughout recent decades of investigation,electrolyte modulation by using function additives is widely considered as a facile and efficient way to prolong the Zn anode lifespan.Herein,N-(2-hydroxypropyl)ethylenediamine is employed as an additive to attach onto the Zn surface with a substantial adsorption energy with(002)facet.The as-formed in-situ solid-electrolyte interphase layer effectively mitigates hydrogen evolution reaction by constructing a lean-water internal Helmholtz layer.Additionally,N-(2-hydroxypropyl)ethylenediamine establishes a coordination complex with Zn^(2+),thereby modulating the solvation structure and enhancing the mobility of Zn^(2+).As expected,the Zn-symmetrical cell with N-(2-hydroxypropyl)ethylenediamine additive demonstrated successful cycling exceeding 1500 h under 1 mA cm^(-2) for0.5 mAh cm^(-2).Furthermore,the Zn//δ-MnO_(2) battery maintains a capacity of approximately 130 mAh g^(-1) after 800 cycles at 1 A g^(-1),with a Coulombic efficiency surpassing 98%.This work presents a streamlined approach for realizing aqueous zinc-ion batteries with extended service life.
基金supported by the National Natural Science Foundation of China(No.82270364)Science and Technology Program of Guizhou Province(No.ZK[2023]321)+3 种基金Guizhou Provincial Youth Science and Technology Talents Growth Project(No.KY[2022]214)Excellent Young Talents Plan of Guizhou Medical University(No.[2023]112)Guizhou Medical University Key Laboratory of Cardiovascular Disease Basic and Clinical Research(No.2024001)Start-up Fund of Guizhou Medical University(No.J2021032).
文摘Cardiovascular disease(CVD)represents the foremost cause of mortality globally,imposing a substantial economic burden.In 2021,approximately 19.4 million deaths were attributed to cardiovascular conditions,constituting 32%of global mortality[1].Over three-quarters of these fatalities occurred in low and middle-income nations.Notably,ischemic heart disease and stroke were responsible for 84%of CVD-related deaths.Among them,the number of cases of ischemic cardiomyopathy increased by 68%in 2021 compared to 1990(Figure 1A).
基金supported by the National Natural Science Foundation of China(No.52002170)the Central Guidance Fund Project for Local Scientific and Technological Development in Qinghai Province(No.2024ZY013)+1 种基金the Foundation of Key Laboratory of Flexible Electronics of Zhejiang Province(No.2023FE011)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX24_1635).
文摘Developing fast-charging lithium-ion batteries(LIBs)that feature high energy density is critical for the scalable application of electric vehicles.Iron vanadate(FVO)holds great potential as anode material in fast-charging LIBs because of its high theoretical specific capacity and the high natural abundance of its constituents.However,the capacity of FVO rapidly decays due to its low electrical conductivity.Herein,uniform FVO nanoparticles are grown in situ on ordered mesoporous carbon(CMK-3)support,forming a highly electrically conductive porous network,FVO/CMK-3.The structure of CMK-3 helps prevent agglomeration of FVO particles.The electrically conductive nature of CMK-3 can further enhance the electrical conductivity of FVO/CMK-3 and buffer the volume expansion of FVO particles during cycling processes.As a result,the FVO/CMK-3 displays excellent fast-charging performance of 364.6 mAh·g^(-1)capacity for 2500 cycles at 10 A·g^(-1)(with an ultralow average capacity loss per cycle of 0.003%)through a pseudocapacitive-dominant process.Moreover,the LiCoO_(2)//FVO/CMK-3 full cell achieves a high capacity of 100.2 mAh·g^(-1)and a high capacity retention(96.2%)after 200 cycles.The superior electrochemical performance demonstrates that FVO/CMK-3 is an ideal anode material candidate for fast-charging,stable LIBs with high energy density.
基金financially supported by the National Natural Science Foundation of China (52173173, 22403047)Natural Science Foundation of Jiangsu Province (BK20220051)+2 种基金Jiangsu Province Carbon Peak and Neutrality Innovation Program (Industry tackling on prospect and key technology) (BE2022031-4, BE2022002-3)The Natural Foundation of Jiangsu Higher Education Institutions of China (23KJB430021)State Key Laboratory of Materials-Oriented Chemical Engineering (No.SKL-MCE-24A16)
文摘Pulsed electrolysis for CO_(2)reduction reaction has emerged as an effective method to enhance catalyst efficiency and optimize product selectivity.However,challenges remain in understanding the mechanisms of surface transformation under pulsed conditions.In this study,using in-situ time-resolved surface-enhanced Raman spectroscopy and differential electrochemical mass spectroscopy,we found local pH at the surface and Cu–O–C species that was generated during the anodic pulse played a key role in pulsed electrolysis.During the pulsed oxidation,an oxidation layer first formed,depleting OH–and lowering the local pH.When the pH was below 8.4,HCO_(3)–transformed the oxidation layer to a nanometer-thick Cu–O–C species,which is a highly reactive catalyst.In the reduction pulse,about 7.4%of the surface Cu–O–C was transformed into CO and CuOx species,enhancing CO_(2)reduction activity.Even in Ar-saturated 0.1 M KHCO_(3),through a Cu–O–C intermediate,a Faradaic efficiency of 0.17%for bicarbonate reduction to CO was observed.Our findings highlight the crucial role of the anodic pulse process in improving CO_(2)reduction activity.
基金supported by Guizhou Province Major Science and Technology Achievement Transformation Project(QKHCG[2024]ZD016)the Excellent Young Scientists Fund from the National Natural Science Foundation of China(Grant No.42422105)+1 种基金Guizhou Province Natural Science Research Project(Qian Jiao Ji[2023]No.033)Provincial Science and Technology Program of Guizhou Province(Grant No.20201Y288).
文摘The Sustainable Development Goals(SDGs)are crucial in tackling the sustainability challenges and emerging issues faced by humanity,with government attention being a significant factor in promoting their successful achievement.However,there is limited quantitative research systematically examining the impacts of government attention on SDGs progress.This study employs text analysis and a panel regression model to analyze the impacts of government attention intensity,text similarity,and tone on the achievement of SDGs,utilizing data extracted from China’s Government Work Reports spanning the decade from 2010 to 2020.The findings reveal that the Chinese government attention to the SDGs has generally increased over time.The heightened focus has notably bolstered the achievement of the SDGs,with the most significant impact observed post-2015.Government attention intensity was identified as the most impactful factor.Moreover,government attention intensity,text similarity,and tone have positively influenced the coupling coordination relationship between 17 SDGs,as measured by the coupling coordination degree,leading to a more harmonious and balanced achievement of socioeconomic and environmental goals in China.Financial investment served as a moderating factor,enhancing the positive impacts of attention intensity,text similarity and tone on the promotion of SDGs attainment.The effects of government attention on SDGs progress were notably positive in the eastern region,exhibiting greater significance in areas with stronger governance capacity compared to those with weaker governance capacity.This study provides insightful information for enhancing the modernization and efficiency of China’s national governance system,promoting SDGs at local and global scales,and fostering sustainable transformation.
基金funded by the National Natural Science Foundation of China[52106246]the Postgraduate Research&Practice innovation Program of Jiangsu Province[KYCX24_1641].
文摘Based on the rapid advancements in nanomaterials and nanotechnology,the Nanofluidic Reverse Electrodialysis(NRED)has attracted significant attention as an innovative and promising energy conversion strategy for extracting sustainable and clean energy fromthe salinity gradient energy.However,the scarcity of research investigating the intricate multi-factor coupling effects on the energy conversion performance,especially the trade-offs between ion selectivity and mass transfer in nanochannels,of NRED poses a great challenge to achieving breakthroughs in energy conversion processes.This numerical study innovatively investigates the multi-factor coupling effect of three critical operational factors,including the nanochannel configuration,the temperature field,and the concentration difference,on the energy conversion processes of NRED.In this work,a dimensionless amplitude parameter s is introduced to emulate the randomly varied wall configuration of nanochannels that inherently occur in practical applications,thereby enhancing the realism and applicability of our analysis.Numerical results reveal that the application of a temperature gradient,which is oriented in opposition to the concentration gradient,enhances the ion transportation and selectivity simultaneously,leading to an enhancement in both output power and energy conversion efficiency.Additionally,the increased fluctuation of the nanochannel wall from s=0 to s=0.08 improves ion selectivity yet raises ion transport resistance,resulting in an enhancement in output power and energy conversion efficiency but a slight reduction in current.Furthermore,with increasing the concentration ratio cH/cL from 10 to 1000,either within a fixed temperature field or at a constant dimensionless amplitude,the maximumpower consistently attains its optimal value at a concentration ratio of 100 but the cation transfer number experiences amonotonic decrease across this entire range of concentration ratios.Finally,uponmodifying the operational parameters fromthe baseline condition of s=0,c_(H)/c_(L)=10,andΔT=0 K to the targetedconditionof s=0.08,c_(H)/c_(L)=50,andΔT=25 K,there is a concerted improvement observed in the open-circuit potential,short-circuit current,andmaximumpower,with respective increments of 8.86%,204.97%,and 232.01%,but a reduction in cation transfer number with a notable decrease of 15.37%.
