This study investigates the hydrodynamic process of a cylinder ejected from the water’s surface through high-speed camera experiments.Using digital image processing methods,the images obtained through experiments are...This study investigates the hydrodynamic process of a cylinder ejected from the water’s surface through high-speed camera experiments.Using digital image processing methods,the images obtained through experiments are processed and analyzed.Although the dynamics of rising buoyant cylinders have been thoroughly investigated,the pop-up height of the cylinders has not been extensively explored.Statistical analysis of the kinematic and dynamic data of cylinders is conducted.Research has shown that after the cylinder rises,it pops out of the water’s surface.Within the experimental range,the pop-up height of the cylinder is related to the release depth.Furthermore,the pop-up height and release depth of the cylinder vary linearly under vertical release conditions.Under horizontal release conditions,the relationship between pop-up height and release depth shows irregular changes mainly because of the unstable shedding of the wake vortex.展开更多
Oceanic dissolved oxygen(DO)in the ocean has an indispensable role on supporting biological respiration,maintaining ecological balance and promoting nutrient cycling.According to existing research,the total DO has dec...Oceanic dissolved oxygen(DO)in the ocean has an indispensable role on supporting biological respiration,maintaining ecological balance and promoting nutrient cycling.According to existing research,the total DO has declined by 2%of the total over the past 50 a,and the tropical Pacific Ocean occupied the largest oxygen minimum zone(OMZ)areas.However,the sparse observation data is limited to understanding the dynamic variation and trend of ocean using traditional interpolation methods.In this study,we applied different machine learning algorithms to fit regression models between measured DO,ocean reanalysis physical variables,and spatiotemporal variables.We demonstrate that extreme gradient boosting(XGBoost)model has the best performance,hereby reconstructing a four-dimensional DO dataset of the tropical Pacific Ocean from 1920 to 2023.The results reveal that XGBoost significantly improves the reconstruction performance in the tropical Pacific Ocean,with a 35.3%reduction in root mean-squared error and a 39.5%decrease in mean absolute error.Additionally,we compare the results with three Coupled Model Intercomparison Project Phase 6(CMIP6)models data to confirm the high accuracy of the 4-dimensional reconstruction.Overall,the OMZ mainly dominates the eastern tropical Pacific Ocean,with a slow expansion.This study used XGBoost to efficiently reconstructing 4-dimensional DO enhancing the understanding of the hypoxic expansion in the tropical Pacific Ocean and we foresee that this approach would be extended to reconstruct more ocean elements.展开更多
Understanding the seasonal variations of the zooplankton community’s structure in the Western Pacific Warm Pool(WPWP)-the most stable open marine environment in the Pacific Ocean-is crucial to predict the impacts of ...Understanding the seasonal variations of the zooplankton community’s structure in the Western Pacific Warm Pool(WPWP)-the most stable open marine environment in the Pacific Ocean-is crucial to predict the impacts of climate change on the ecosystem.However,knowledge on these variations in this region down to the mesopelagic zone is insufficient.In this study,the environmental DNA(eDNA)metabarcoding method was used to investigate the zooplankton community during summer,autumn,and winter,from the surface to a depth of 1000 m spanning the epipelagic to mesopelagic zones.The zooplankton community structure exhibited seasonal fluctuations at multiple depths except for 200 and 1000 m.In addition,a stronger zooplankton seasonality was particularly recorded in the epipelagic zone than in the mesopelagic zone,which is consistent with the environmental changes.The studied zooplanktons are dominated by medusae and copepods that showed distinct seasonality.At all depths,medusae exhibited greater seasonal variations than the overall zooplankton community,whereas the copepods did not exhibit significant seasonality.The environmental features and the seasons exerted greater influences on the structure of the zooplankton communities than did the spatial factors.The results of this study indicate that eDNA metabarcoding can provide novel insights into zooplankton assemblages due to its ability to capture a rich variety of medusae,which are often underestimated by net collection.展开更多
A three-dimensional coupled sea ice-ice shelf-ocean numerical model is developed for the Prydz Bay,Antarctica,using the Regional Ocean Modeling System with a grid resolution of approximately 2 km.The influence of the ...A three-dimensional coupled sea ice-ice shelf-ocean numerical model is developed for the Prydz Bay,Antarctica,using the Regional Ocean Modeling System with a grid resolution of approximately 2 km.The influence of the grounding giant iceberg D15 on the distribution of sea ice and polynyas in the Prydz Bay is analyzed through two numerical experiments.Iceberg D15,grounded off the western edge of the West Ice Shelf(WIS),obstructs the southwestward transport of sea ice along the east coast of Prydz Bay,causing sea ice to accumulate to the east of the iceberg and form multi-year fast ice.Grounding of Iceberg D15 also decreases sea ice coverage off its south edge and creates ice-free openings in spring near Davis Station and Zhongshan Station,facilitating the accessibility of vessels to the research stations.These simulated sea ice patterns closely match current satellite observations.When Iceberg D15 is removed,the previously blocked sea ice north of the iceberg,which moved westward,shifts southwesterly along the coastline,leading to a reduction in sea ice thickness during winter and spring,as well as lower sea ice concentrations in spring across large areas north and west of the iceberg.In contrast,the sea ice thickness increases considerably southwest of the WIS,extending to the front of the Amery Ice Shelf during seasons covered by sea ice.The increase in sea ice concentration can also extend to as far as 75°E in spring.Without Iceberg D15,which previously contributed to the ice barrier of Barrier Polynya(BP),the shape of BP changes,the area of BP and Davis Polynya(DP)decreases,and the polynya off the northwest edge of the WIS near 83°E expands.These polynya patterns are much similar to the satellite remote sensing observations before Iceberg D15 was grounded.From April to October,the total area of BP and DP decreases by 2.83×10^(4)km^(2)(60%)and 2.20×10^(3)km^(2)(20%),respectively,while the total sea ice production decreases by 4.11×10^(10)m^(3)(66%)and 1.52×10^(10)m^(3)(52%)compared to the experiment with iceberg.These results indicate the substantial effects of grounding giant icebergs on the spatio-temporal distribution of sea ice,the area of polynyas,and sea ice production.High-resolution Antarctic coastal numerical models,typically with grid scales of kilometers,are sufficient to represent large icebergs,and adding the grounding giant icebergs is crucial for producing realistic simulations of sea ice and polynyas.展开更多
Temperate glaciers are highly sensitive to variations in climate and environmental conditions.Investigating the chemical composition of dissolved organic matter(DOM)in glacier snow is essential for understanding its c...Temperate glaciers are highly sensitive to variations in climate and environmental conditions.Investigating the chemical composition of dissolved organic matter(DOM)in glacier snow is essential for understanding its characteristics,sources,and transformation processes within glacial systems.This study aims to elucidate the chemical composition and transformation of DOM in snow environment by analyzing samples collected from snowpits,surface snow,and snow meltwater at Baishui Glacier No.1 on Mt.Yulong during May and June.The average concentrations of dissolved organic carbon(DOC)in snow meltwater collected in May(1.63±0.63 mg L^(-1))and June(1.54±0.35 mg L^(-1))were both significantly higher than those measured in snowpit samples from May(0.74±0.10 mg L^(-1))and June(0.54±0.10 mg L^(-1)),as well as in surface snow samples from May(0.65±0.31 mg L^(-1))and June(0.69±0.30 mg L^(-1)).However,the concentrations of DOC in samples from the same category did not show significant variation between May and June.Using excitation-emission matrix(EEM)fluorescence spectroscopy coupled with parallel factor(PARAFAC)analysis,three protein-like components(C_(1),C_(2),and C_(3))and one humic-like component(C_(4))were identified.The protein-like components accounted for more than 75%of the total DOM in all snow samples,indicating that the fluorescent DOM originated from biological or microbial sources.Significant differences in the relative proportions of the four fluorescent components were observed between snowpit samples from May and June,whereas no significant variations were noted in the other sample types.Furthermore,a clear transformation from protein-like to humic-like components was observed during the transition from snowpits to snow meltwater.Further analysis using Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS)revealed that DOM in these snow samples was predominantly composed of aliphatic and peptide-like compounds(30.9%-50.9%),suggesting a substantial microbial contribution.FT-ICR MS data also demonstrated compositional shifts in DOM among snowpit,surface snow,and meltwater samples.Specifically,aliphatic and peptide-like compounds were progressively transformed into unsaturated compounds with high oxygen content,polyphenolic species,and condensed aromatic compounds during their transition from snowpit to meltwater.Therefore,the relative contribution of terrestrial-derived DOM increased during the transition from snowpit to snowmelt.Furthermore,an increase in heteroatom content in the DOM of meltwater samples indicated continuous chemical transformations likely driven by biological activity and/or photochemical processes during snowmelt and leaching.展开更多
Organic amine pesticides(OAPs)are widely used in modern agriculture and these compounds can contaminate drinking water sources in different ways.However,there is a lack of data on the occurrence of OAPs in drinking wa...Organic amine pesticides(OAPs)are widely used in modern agriculture and these compounds can contaminate drinking water sources in different ways.However,there is a lack of data on the occurrence of OAPs in drinking water and their potential human health risks.In this study,tapwater(TW)and bottledwater(BW)sampleswere collected from eight cities in the Yangtze River Delta urban agglomeration in China,and their OAP levelswere analyzed using high-throughput organic analysis testing coupled with high-volume solid-phase extraction(Hi-throat/Hi-volume SPE techniques).This study is the first to systematically characterize the trace levels of OAPs in drinking water in China.Our findings indicated that the total concentration of OAPs(OAPs)in TW(average 11.06±4.99 ng/L)was 29.4%higher than in BW(average 8.55±3.98 ng/L)and fewer kinds(7)of OAPs were detected in BW.Furthermore,the long-term intake of TW in some areas was linked to carcinogenic risks even at an acceptable OAP range,particularly in males,with molinate being the major contributor(61.3%)to OAP exposure.Further analysis revealed that the occurrence and health risks of OAPs in drinking water were mainly influenced by the quality of water sources and the technologies adopted in drinking water treatment plants(DWTPs).Furthermore,our findings demonstrated that advanced treatment technologies such as nanofiltration could more effectively remove OAPs in raw water(up to 87.5%).Therefore,our findings highlighted the importance of selecting appropriate advanced treatment technologies in DWTPs.展开更多
Friendship paradox states that individuals are likely to have fewer friends than their friends do,on average.Despite of its wide existence and appealing applications in real social networks,the mathematical understand...Friendship paradox states that individuals are likely to have fewer friends than their friends do,on average.Despite of its wide existence and appealing applications in real social networks,the mathematical understanding of friendship paradox is very limited.Only few works provide theoretical evidence of single-step and multi-step friendship paradoxes,given that the neighbors of interest are onehop and multi-hop away from the target node.However,they consider non-evolving networks,as opposed to the topology of real social networks that are constantly growing over time.We are thus motivated to present a first look into friendship paradox in evolving networks,where newly added nodes preferentially attach themselves to those with higher degrees.Our analytical verification of both single-step and multistep friendship paradoxes in evolving networks,along with comparison to the non-evolving counterparts,discloses that“friendship paradox is even more paradoxical in evolving networks”,primarily from three aspects:1)we demonstrate a strengthened effect of single-step friendship paradox in evolving networks,with a larger probability(more than 0.8)of a random node’s neighbors having higher average degree than the random node itself;2)we unravel higher effectiveness of multi-step friendship paradox in seeking for influential nodes in evolving networks,as the rate of reaching the max degree node can be improved by a factor of at least Θ(t^(2/3))with t being the network size;3)we empirically verify our findings through both synthetic and real datasets,which suggest high agreements of results and consolidate the reasonability of evolving model for real social networks.展开更多
Dissolved organic matter(DOM)is very important in aquatic environments,yet it is challenging to characterize DOM as a highly complex mixture of thousands of molecules,and the knowledge of the effects of different degr...Dissolved organic matter(DOM)is very important in aquatic environments,yet it is challenging to characterize DOM as a highly complex mixture of thousands of molecules,and the knowledge of the effects of different degradation processes on different molecules remains limited.This study examined the distribution and degradation of DOM in a large subtropical river using optical techniques and Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR-MS).At the molecular level,DOM was mainly composed of CHO and lignin-like compounds,which was related to the dominance of forestland in the watershed and resulted in a low biological lability index(MLBL).The modified aromaticity index(AI_(mod)),unsaturation degree(DBE),and humic content(HIX)decreased while MLBL,H/C,absorption spectral slope(S_(275–295)),and biological index(BIX)increased in the estuarine zone due to the increasing autochthonous contribution.Photo-and microbial degradation resulted in a similar decrease in the bulk dissolved organic carbon,while they showed opposite effects on the DOM composition.Photo-degradation removed all fluorescent components and decreased molecular weight,HIX,AI_(mod),DBE,%CHO,%lignin-like,%tannin-like,and%condensed aromatic-like compounds.In contrast,bio-degradation preferentially consumed lipid-like,protein-like,and carbohydrate-like compounds,with increases in%ligninlike,%tannin-like,%condensed aromatic-like compounds,and humic-like fluorescent components.Overall,the application of ultra-high resolutionmass spectrometry provided valuable insights into the composition and behavior of DOM at themolecular level and revealed the contrasting effects of photo-and microbial degradation on different compounds.These results have implications for better understanding the composition and transformation of aquatic DOM.展开更多
Antarctic ice-free areas(<0.4%of the continent)represent Antarctic biodiversity oases,where microbial communities sustain terrestrial ecosystem functions.These habitats-encompassing mineral,ornithogenic soils,biolo...Antarctic ice-free areas(<0.4%of the continent)represent Antarctic biodiversity oases,where microbial communities sustain terrestrial ecosystem functions.These habitats-encompassing mineral,ornithogenic soils,biological soil crusts,and hypolithic/endolithic niches-are shaped by environmental factors such as pH,organic C/N ratios,moisture,elevation,and trace element availability.The diversity of prokaryotes,eukaryotes,and viruses is lower than in other regions,yet the communities exhibit strong endemism,with site-specific uncultivated lineages.Microorganisms persist through cold and stress adaptations,performing organic carbon decomposition,phototrophy,and oxidation of trace gases to drive carbon and nitrogen cycling in various Antarctic soil habitats.Climate change and anthropogenic disturbances are shifting communities toward copiotrophic generalists,altering elementary cycling and feeding back to climate change.Culturation and genomic-based techniques reveal novel microbial taxa with broad biotechnological potentials on bioactive compounds and cryotolerant enzymes.In summary,this review offers a foundation for exploring Antarctic microbial biodiversity,ecosystem resilience,and the development of novel biotechnologies,while also highlighting the urgent need for effective monitoring and preservation strategies to mitigate the impacts of ongoing environmental changes on Antarctic soil ecosystems.展开更多
The inter-model difference in the tropical Pacific SST warming pattern is a big stumbling block for reliable projections of global climate change. Here by conducting an inter-model Empirical Orthogonal Function(EOF) a...The inter-model difference in the tropical Pacific SST warming pattern is a big stumbling block for reliable projections of global climate change. Here by conducting an inter-model Empirical Orthogonal Function(EOF) analysis as well as an ocean mixed-layer heat budget, we find that the first two modes of inter-model difference in the SST warming pattern projected by 30 CMIP6 models, explaining more than three-quarters of the total inter-model variance, are both tied to different cloud–radiation feedbacks. The EOF1 mode that captures the different magnitudes of El Ni?o-like warming as well as the largest inter-model variance in the far eastern equatorial Pacific, is likely driven by highly diverse cloud–radiation feedbacks in the east and, to a lesser extent, by differing changes in the oceanic vertical temperature gradient. The EOF2 mode that mainly represents the different magnitudes of SST warming in the western equatorial Pacific, is associated with differing levels of negative cloud–radiation feedback over the central equatorial Pacific through a dynamic air–sea coupled process involving both the Bjerknes feedback and the wind–evaporation–SST feedback.Considering in isolation the robust common model bias of a weak negative cloud–radiation feedback over the central equatorial Pacific, the projected SST warming in the western equatorial Pacific is likely to be smaller than the multi-model ensemble mean, thereby presenting a more weakeened zonal SST gradient than expected, implying the potential for more severe climate extremes under global warming.展开更多
American horseshoe crabs Limulus polyphemus were tracked using acoustic telemetry and traditional tagging in a semi-enclosed bay on Cape Cod （Pleasant Bay）, Massachusetts, USA, to determine seasonal movement pattern...American horseshoe crabs Limulus polyphemus were tracked using acoustic telemetry and traditional tagging in a semi-enclosed bay on Cape Cod （Pleasant Bay）, Massachusetts, USA, to determine seasonal movement patterns. Fifty-five actively spawning females were fitted with transmitters in 2008 and 2009 and were tracked using acoustic telemetry from May 2008 through July 2010. Fil^een crabs with transmitters also had archive depth-temperature tags attached. In addition, over 2000 spawning crabs （males and females） were tagged with US Fish and Wildlife CIdSFWS） button tags over the same period. Ninety-one percent of the crabs with transmitters were detected during this study. In the spring, crabs were primarily located in the northern section of the bay near spawning beaches, whereas in the fall crabs moved towards the deeper portions of the bay, and some may have overwIntered in the bay. There was evidence that a majority （58%-71%） of the females with transmitters spawned in two sequential seasons. One archive tag was recovered resulting in a year-long continuous record of depth and tem- perature data that, when integrated with telemetry data, indicated that the crab overwintered in the bay. The live recapture rate of crabs with USFWS button tags was 11%, with all re-sighted crabs except one observed inside Pleasant Bay. Eighty-three percent of recaptures were found within 2.5kin of the tagging location, and 51% were observed at the same beach where they were tagged. This study provides further evidence that horseshoe crabs in Pleasant Bay may be philopatric to this embayment展开更多
A thorough understanding of the biogeochemical cycling of trace metals in the ocean is crucial because of the important role these elements play in regulating metabolism in marine biotas and thus,the climate.However,a...A thorough understanding of the biogeochemical cycling of trace metals in the ocean is crucial because of the important role these elements play in regulating metabolism in marine biotas and thus,the climate.However,a precise and accurate analysis of trace metals in seawater is difficult because they are present at extremely low concentrations in a high salt matrix.In this study,we report an analytical method for the preconcentration and separation of six trace metals,Fe,Ni,Cu,Zn,Cd and Pb,in seawater using a sea FAST automatic solid-phase extraction device,analysis by a triple quadrupole collision/reaction technique with inductively coupled plasma mass spectrometry(ICP-MS),and quantification by the isotope dilution technique.A small volume(10 m L)of seawater sample was mixed with a multi-element isotope spike and subjected to sea FAST procedures.The preconcentrate solution was then analyzed using the optimized collision/reaction cell mode of ICP-MS,with NH_(3)gas for Fe and Cd with a flow rate of 0.22 m L/min and He for Ni,Cu,Zn and Pb with a flow rate of 4.0 m L/min.The procedure blanks were 130 pmol/L,3.0 pmol/L,6.8 pmol/L,37 pmol/L,0.29 pmol/L and 0.42 pmol/L,for Fe,Ni,Cu,Zn,Cd and Pb,respectively.The method was validated using five reference materials(SLRs-6,SLEW-3,CASS-6,NASS-7 and GEOTRACE-GSC),and our results were consistent with the consensus values.The method was further validated by measuring full-water-column seawater samples from the subtropical Northwest Pacific Ocean,and our results demonstrated good oceanic consistency.展开更多
The growth, metabolism and physiological response of the sea cucumber, Apostichopus japonicus, were investigated during periods of inactivity. The body weight, oxygen consumption rate (OCR), activities of acidic phosp...The growth, metabolism and physiological response of the sea cucumber, Apostichopus japonicus, were investigated during periods of inactivity. The body weight, oxygen consumption rate (OCR), activities of acidic phosphatase (ACP), alkaline phosphatase (AKP), catalase (CAT) and superoxide dismutase (SOD), and content of heat shock protein 70 (Hsp70) in the body wall and coelomic fluid of A. japonicus were measured during starvation, experimental aestivation and aestivation. The results showed that the body weight of sea cucumber in the three treatments decreased significantly during the experimental period (P < 0.05). The OCR of sea cucumber reduced in starvation and experimental aestivation treatments, but increased gradually in natural aestivation treatment. The activities of ACP and AKP of sea cucumber decreased gradually in all treatments, whereas those of SOD and CAT as well as Hsp70 content decreased in the starvation and experimental aestivation treatments and increased in natural aestivation treatment. The sea cucumber entered a state of aestivation at 24℃. To some extent, the animals in experimental aestivation were different from those in natural aestivation in metabolism and physiological response. These findings suggested that the aestivation mechanism of A. japonicus is complex and may not be attributed to the elevated temperature only.展开更多
So far, large uncertainties of the Indonesian throughflow(ITF) reside in the eastern Indonesian seas, such as the Maluku Sea and the Halmahera Sea. In this study, the water sources of the Maluku Sea and the Halmahera ...So far, large uncertainties of the Indonesian throughflow(ITF) reside in the eastern Indonesian seas, such as the Maluku Sea and the Halmahera Sea. In this study, the water sources of the Maluku Sea and the Halmahera Sea are diagnosed at seasonal and interannual timescales and at different vertical layers, using the state-of-the-art simulations of the Ocean General Circulation Model(OGCM) for Earth Simulator(OFES). Asian monsoon leaves clear seasonal footprints on the eastern Indonesian seas. Consequently, the subsurface waters(around 24.5σ_θ and at ～150 m) in both the Maluku Sea and the Halmahera Sea stem from the South Pacific(SP) during winter monsoon, but during summer monsoon the Maluku Sea is from the North Pacific(NP), and the Halmahera Sea is a mixture of waters originating from the NP and the SP. The monsoon impact decreases with depth, so that in the Maluku Sea, the intermediate water(around 26.8σ_θ and at ～480 m) is always from the northern Banda Sea and the Halmahera Sea water is mainly from the SP in winter and the Banda Sea in summer. The deep waters(around27.2σ_θ and at ～1 040 m) in both seas are from the SP, with weak seasonal variability. At the interannual timescale,the subsurface water in the Maluku Sea originates from the NP/SP during El Ni?o/La Ni?a, while the subsurface water in the Halmahera Sea always originates from the SP. Similar to the seasonal variability, the intermediate water in Maluku Sea mainly comes from the Banda Sea and the Halmahera Sea always originates from the SP. The deep waters in both seas are from the SP. Our findings are helpful for drawing a comprehensive picture of the water properties in the Indonesian seas and will contribute to a better understanding of the ocean-atmosphere interaction over the maritime continent.展开更多
In this study, we construct one 2-dimensional tidal simulation, using an unstructured Finite Volume Coastal Ocean Model （FVCOM）. In the 2-D model, we simulated the tidal turbines through adding additional bottom dra...In this study, we construct one 2-dimensional tidal simulation, using an unstructured Finite Volume Coastal Ocean Model （FVCOM）. In the 2-D model, we simulated the tidal turbines through adding additional bottom drag in the element where the tidal turbines reside. The additional bottom drag was calculated from the relationship of the bottom friction dissipation and the rated rotor efficiency of the tidal energy turbine. This study analyzed the effect of the tidal energy turbine to the hydrodynamic environment, and calculated the amount of the extractable tidal energy resource at the Guishan Hangmen Channel, considering the rotor wake effect.展开更多
As an interoceanic arc,the Kyushu-Palau Ridge(KPR)is an exceptional place to study the subduction process and related magmatism through its interior velocity structure.However,the crustal structure and its nature of t...As an interoceanic arc,the Kyushu-Palau Ridge(KPR)is an exceptional place to study the subduction process and related magmatism through its interior velocity structure.However,the crustal structure and its nature of the KPR,especially the southern part with limited seismic data,are still in mystery.In order to unveil the crustal structure of the southern part of the KPR,this study uses deep reflection/refraction seismic data recorded by 24 ocean bottom seismometers to reconstruct a detailed P-wave velocity model along the ridge.Results show strong alongridge variations either on the crustal velocity or the thickness of the KPR.P-wave velocity model is featured with(1)a crustal thickness between 6–12 km,with velocity increases from 4.0 km/s to 7.0 km/s from top to bottom;(2)high gradient(~1 s^(-1))in the upper crust but low one(<0.2 s^(-1))in the lower crust;(3)a slow mantle velocity between 7.2 km/s and 7.6 km/s in the uppermost mantle;and(4)inhomogenous velocity anomalies in the lower crust beneath seamounts.By comparing with the mature arc in the Izu-Bonin-Mariana arc in the east,this study suggests the southern part of KPR is a thicken oceanic crust rather than a typical arc crust.The origin of low velocities in the lower crust and upper mantle may be related with crustal differentiation,which implies advanced crustal evolution from normal oceanic crust to partly thicken oceanic crust.High velocities in the lower crust are related to the difference in magmatism.展开更多
Fractional crystallization of basaltic magma at variable depths influences strongly the geochemical compositions of mid-ocean ridge basalts(MORBs),especially at slow-spreading mid-ocean ridges.The Carlsberg Ridge is a...Fractional crystallization of basaltic magma at variable depths influences strongly the geochemical compositions of mid-ocean ridge basalts(MORBs),especially at slow-spreading mid-ocean ridges.The Carlsberg Ridge is a typical slow-spreading ridge located in the northwestern Indian Ocean.In this study,we conducted petrological,geochemical and modelling studies of MORBs collected along the Carlsberg Ridge from 57°-65°E to understand the fractional crystallization processes of magma and the controls on variations in MORB geochemistry.Our results show that the mantle sources beneath the Carlsberg Ridge are heterogeneous even on the local scale of a segment;such heterogeneity may be ubiquitous beneath the Carlsberg Ridge.Mantle heterogeneity may be caused by the enriched components resulting in the"DUPAL"anomaly,whereas the effect of pyroxenite on mantle heterogeneity is negligible.The parental melts experienced crystallization of olivine,plagioclase and clinopyroxene prior to eruption,which played a significant role in the major and trace element variations in MORBs from the Carlsberg Ridge.The liquid lines of descent(LLDs),deduced from the forward modelling of three parental magma compositions using the Petrolog3 program at pressures between 1 atm and 10 kbar,demonstrate that clinopyroxene joined the olivine and plagioclase cotectic.The over-enrichment in highly incompatible elements relative to LLDs may be caused by the processes of replenishment-tapping-crystallization in magma chambers.The calculated crystallization pressures suggest that parental magmas beneath the Carlsberg Ridge experienced moderateto high-pressure crystallization and that crystallization beneath the slow-spreading Carlsberg Ridge may start at upper mantle depths.展开更多
Many seamounts are covered with cobalt-rich ferromanganese crusts,and are increasingly attracting interest for the potential extraction of valuable mineral resources from deep seabed environments.However,the impacts o...Many seamounts are covered with cobalt-rich ferromanganese crusts,and are increasingly attracting interest for the potential extraction of valuable mineral resources from deep seabed environments.However,the impacts of potential mining activities on the vulnerable seamount ecosystem remain unclear.To enhance the understanding of connectivity in benthic invertebrate populations in the Northwest Pacific,several seamounts were surveyed and biological samples collected.In the present study,the ophiuroid species Ophioplinthaca defensor is reported for the first time from four deep seamounts in the Northwest Pacific,and described,providing more detailed morphological diagnosis characters.To assess the population structure of the species between and within seamounts,two mitochondrial markers(COI and 16 S)were sequenced.In total,20 haplotypes from 32 COI sequences and 8 haplotypes from 3716 S sequences were recovered.The star-shaped TCS networks and nonsignificant pairwise population differences reveal the absence of distinct population structures between and within seamounts.In addition,the O.defensor population seemed to have undergone a demographic expansion in history.This is the first study on the genetic population structure of a benthic invertebrate from seamounts in the Northwest Pacific,and this results suggest a potentially high,long distance dispersal capacity in O.defensor between seamounts,which could inform the development of the Regional Environmental Management Plans for the cobalt-rich crust seamounts in the area.展开更多
Using the mesoscale eddy trajectory atlas product derived from satellite altimeter data from 1993 to 2016,this study analyzes statistical characteristics and seasonal variability of mesoscale eddies in the Banda Sea o...Using the mesoscale eddy trajectory atlas product derived from satellite altimeter data from 1993 to 2016,this study analyzes statistical characteristics and seasonal variability of mesoscale eddies in the Banda Sea of the Indonesian seas.The results show that there were 147 mesoscale eddies that occurred in the Banda Sea,of which 137 eddies were locally generated and 10 originated from outside.The total numbers of cyclonic eddies(CEs,clockwise)and anticyclonic eddies(AEs,anticlockwise)are 76 and 71,respectively.Seasonally,the number of CEs(AEs)is twice larger than the number of AEs(CEs)in winter(summer).In winter,CEs are distributed in the southern and AEs in the northern basins,respectively,but the opposite thing occurs in summer,i.e.,the polarities of mesoscale eddies observed at the same location reverse seasonally.The mechanisms of polarity distribution reversal(PDR)of mesoscale eddies are examined with reanalysis data of ocean currents and winds.The results indicate that the basin-scale vorticity,wind stress curl,and the meridional shear of zonal current reverse seasonally,which are favorable to the PDR of mesoscale eddies.The possible generation mechanisms of mesoscale eddies include direct wind forcing,barotropic and baroclinic instabilities,of which the direct wind forcing should play the dominant role.展开更多
The continental slope in the northern South China Sea(SCS) is rich in mesoscale eddies which play an important role in transport and retention of nutrients and biota. In this study, we investigate the statistical prop...The continental slope in the northern South China Sea(SCS) is rich in mesoscale eddies which play an important role in transport and retention of nutrients and biota. In this study, we investigate the statistical properties of eddy distributions and propagation in a period of 24 years between 1993 and 2016 by using the altimeter data. A total of 147 eddies are found in the continental slope region(CSR), including 70 cyclonic eddies(CEs) and 77 anticyclonic eddies(ACEs). For those eddies that appear in the CSR, the surrounding areas of Dongsha Islands(DS) and southwest of Taiwan(SWT) are considered as the primary sources, where eddies generated contribute more than 60% of the total. According to the spatial distribution of eddy relative vorticity, eddies are weakening as propagating westward. Although both CEs and ACEs roughly propagate along the slope isobaths, there are discrepancies between CEs and ACEs. The ACEs move slightly faster in the zonal direction, while the CEs tend to cross the isobaths with large bottom depth change. The ACEs generally move further into the basin areas after leaving the CSR while CEs remain around the CSR. The eddy propagation on the continental slope is likely to be associated with mean flow at a certain degree because the eddy trajectories have notable seasonal signals that are consistent with the seasonal cycle of geostrophic current. The results indicate that the eddy translation speed is statistically consistent with geostrophic velocity in both magnitude and direction.展开更多
基金supported in part by the National Natural Science Foundation of China under Grant No.41706108the Science and Technology Commission of Shanghai Municipality Project 20dz1206600+2 种基金the Natural Science Foundation of Shanghai under Grant No.20ZR1424800the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University under Grant No.SL2022ZD106the Natural Science Foundation of Chongqing under Grant No.cstc2021jcyj-msxmX0650.
文摘This study investigates the hydrodynamic process of a cylinder ejected from the water’s surface through high-speed camera experiments.Using digital image processing methods,the images obtained through experiments are processed and analyzed.Although the dynamics of rising buoyant cylinders have been thoroughly investigated,the pop-up height of the cylinders has not been extensively explored.Statistical analysis of the kinematic and dynamic data of cylinders is conducted.Research has shown that after the cylinder rises,it pops out of the water’s surface.Within the experimental range,the pop-up height of the cylinder is related to the release depth.Furthermore,the pop-up height and release depth of the cylinder vary linearly under vertical release conditions.Under horizontal release conditions,the relationship between pop-up height and release depth shows irregular changes mainly because of the unstable shedding of the wake vortex.
基金The National Natural Science Foundation of China under contract Nos T2421002, 623B2071,and 42125601the National Key R&D Program of China under contract No. 2023YFF0805300
文摘Oceanic dissolved oxygen(DO)in the ocean has an indispensable role on supporting biological respiration,maintaining ecological balance and promoting nutrient cycling.According to existing research,the total DO has declined by 2%of the total over the past 50 a,and the tropical Pacific Ocean occupied the largest oxygen minimum zone(OMZ)areas.However,the sparse observation data is limited to understanding the dynamic variation and trend of ocean using traditional interpolation methods.In this study,we applied different machine learning algorithms to fit regression models between measured DO,ocean reanalysis physical variables,and spatiotemporal variables.We demonstrate that extreme gradient boosting(XGBoost)model has the best performance,hereby reconstructing a four-dimensional DO dataset of the tropical Pacific Ocean from 1920 to 2023.The results reveal that XGBoost significantly improves the reconstruction performance in the tropical Pacific Ocean,with a 35.3%reduction in root mean-squared error and a 39.5%decrease in mean absolute error.Additionally,we compare the results with three Coupled Model Intercomparison Project Phase 6(CMIP6)models data to confirm the high accuracy of the 4-dimensional reconstruction.Overall,the OMZ mainly dominates the eastern tropical Pacific Ocean,with a slow expansion.This study used XGBoost to efficiently reconstructing 4-dimensional DO enhancing the understanding of the hypoxic expansion in the tropical Pacific Ocean and we foresee that this approach would be extended to reconstruct more ocean elements.
基金Supported by the National Key Research and Development Program of China(No.2022YFC2806805)the National Natural Science Foundation of China(Nos.42076122,42306130)the Digital Deep-sea Typical Habitats Program of China Deep Ocean Affairs Administration(No.DYXZ-02)。
文摘Understanding the seasonal variations of the zooplankton community’s structure in the Western Pacific Warm Pool(WPWP)-the most stable open marine environment in the Pacific Ocean-is crucial to predict the impacts of climate change on the ecosystem.However,knowledge on these variations in this region down to the mesopelagic zone is insufficient.In this study,the environmental DNA(eDNA)metabarcoding method was used to investigate the zooplankton community during summer,autumn,and winter,from the surface to a depth of 1000 m spanning the epipelagic to mesopelagic zones.The zooplankton community structure exhibited seasonal fluctuations at multiple depths except for 200 and 1000 m.In addition,a stronger zooplankton seasonality was particularly recorded in the epipelagic zone than in the mesopelagic zone,which is consistent with the environmental changes.The studied zooplanktons are dominated by medusae and copepods that showed distinct seasonality.At all depths,medusae exhibited greater seasonal variations than the overall zooplankton community,whereas the copepods did not exhibit significant seasonality.The environmental features and the seasons exerted greater influences on the structure of the zooplankton communities than did the spatial factors.The results of this study indicate that eDNA metabarcoding can provide novel insights into zooplankton assemblages due to its ability to capture a rich variety of medusae,which are often underestimated by net collection.
基金The National Natural Science Foundation of China under contract Nos 41976217 and 42306249the National Key Research and Development Program of China under contract No.2018YFA0605701.
文摘A three-dimensional coupled sea ice-ice shelf-ocean numerical model is developed for the Prydz Bay,Antarctica,using the Regional Ocean Modeling System with a grid resolution of approximately 2 km.The influence of the grounding giant iceberg D15 on the distribution of sea ice and polynyas in the Prydz Bay is analyzed through two numerical experiments.Iceberg D15,grounded off the western edge of the West Ice Shelf(WIS),obstructs the southwestward transport of sea ice along the east coast of Prydz Bay,causing sea ice to accumulate to the east of the iceberg and form multi-year fast ice.Grounding of Iceberg D15 also decreases sea ice coverage off its south edge and creates ice-free openings in spring near Davis Station and Zhongshan Station,facilitating the accessibility of vessels to the research stations.These simulated sea ice patterns closely match current satellite observations.When Iceberg D15 is removed,the previously blocked sea ice north of the iceberg,which moved westward,shifts southwesterly along the coastline,leading to a reduction in sea ice thickness during winter and spring,as well as lower sea ice concentrations in spring across large areas north and west of the iceberg.In contrast,the sea ice thickness increases considerably southwest of the WIS,extending to the front of the Amery Ice Shelf during seasons covered by sea ice.The increase in sea ice concentration can also extend to as far as 75°E in spring.Without Iceberg D15,which previously contributed to the ice barrier of Barrier Polynya(BP),the shape of BP changes,the area of BP and Davis Polynya(DP)decreases,and the polynya off the northwest edge of the WIS near 83°E expands.These polynya patterns are much similar to the satellite remote sensing observations before Iceberg D15 was grounded.From April to October,the total area of BP and DP decreases by 2.83×10^(4)km^(2)(60%)and 2.20×10^(3)km^(2)(20%),respectively,while the total sea ice production decreases by 4.11×10^(10)m^(3)(66%)and 1.52×10^(10)m^(3)(52%)compared to the experiment with iceberg.These results indicate the substantial effects of grounding giant icebergs on the spatio-temporal distribution of sea ice,the area of polynyas,and sea ice production.High-resolution Antarctic coastal numerical models,typically with grid scales of kilometers,are sufficient to represent large icebergs,and adding the grounding giant icebergs is crucial for producing realistic simulations of sea ice and polynyas.
基金supported by grants from the Sichuan Natural Science Foundation Project(2024NSFSC0793)Dagu Glacier Research Institute(Center)project of Aba Normal College(AS-DTPT 2023072)the support of Youth Innovation Promotion Association CAS(2021429)。
文摘Temperate glaciers are highly sensitive to variations in climate and environmental conditions.Investigating the chemical composition of dissolved organic matter(DOM)in glacier snow is essential for understanding its characteristics,sources,and transformation processes within glacial systems.This study aims to elucidate the chemical composition and transformation of DOM in snow environment by analyzing samples collected from snowpits,surface snow,and snow meltwater at Baishui Glacier No.1 on Mt.Yulong during May and June.The average concentrations of dissolved organic carbon(DOC)in snow meltwater collected in May(1.63±0.63 mg L^(-1))and June(1.54±0.35 mg L^(-1))were both significantly higher than those measured in snowpit samples from May(0.74±0.10 mg L^(-1))and June(0.54±0.10 mg L^(-1)),as well as in surface snow samples from May(0.65±0.31 mg L^(-1))and June(0.69±0.30 mg L^(-1)).However,the concentrations of DOC in samples from the same category did not show significant variation between May and June.Using excitation-emission matrix(EEM)fluorescence spectroscopy coupled with parallel factor(PARAFAC)analysis,three protein-like components(C_(1),C_(2),and C_(3))and one humic-like component(C_(4))were identified.The protein-like components accounted for more than 75%of the total DOM in all snow samples,indicating that the fluorescent DOM originated from biological or microbial sources.Significant differences in the relative proportions of the four fluorescent components were observed between snowpit samples from May and June,whereas no significant variations were noted in the other sample types.Furthermore,a clear transformation from protein-like to humic-like components was observed during the transition from snowpits to snow meltwater.Further analysis using Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR MS)revealed that DOM in these snow samples was predominantly composed of aliphatic and peptide-like compounds(30.9%-50.9%),suggesting a substantial microbial contribution.FT-ICR MS data also demonstrated compositional shifts in DOM among snowpit,surface snow,and meltwater samples.Specifically,aliphatic and peptide-like compounds were progressively transformed into unsaturated compounds with high oxygen content,polyphenolic species,and condensed aromatic compounds during their transition from snowpit to meltwater.Therefore,the relative contribution of terrestrial-derived DOM increased during the transition from snowpit to snowmelt.Furthermore,an increase in heteroatom content in the DOM of meltwater samples indicated continuous chemical transformations likely driven by biological activity and/or photochemical processes during snowmelt and leaching.
基金supported by the National Key Research and Development Program of China(No.2019YFD1100203).
文摘Organic amine pesticides(OAPs)are widely used in modern agriculture and these compounds can contaminate drinking water sources in different ways.However,there is a lack of data on the occurrence of OAPs in drinking water and their potential human health risks.In this study,tapwater(TW)and bottledwater(BW)sampleswere collected from eight cities in the Yangtze River Delta urban agglomeration in China,and their OAP levelswere analyzed using high-throughput organic analysis testing coupled with high-volume solid-phase extraction(Hi-throat/Hi-volume SPE techniques).This study is the first to systematically characterize the trace levels of OAPs in drinking water in China.Our findings indicated that the total concentration of OAPs(OAPs)in TW(average 11.06±4.99 ng/L)was 29.4%higher than in BW(average 8.55±3.98 ng/L)and fewer kinds(7)of OAPs were detected in BW.Furthermore,the long-term intake of TW in some areas was linked to carcinogenic risks even at an acceptable OAP range,particularly in males,with molinate being the major contributor(61.3%)to OAP exposure.Further analysis revealed that the occurrence and health risks of OAPs in drinking water were mainly influenced by the quality of water sources and the technologies adopted in drinking water treatment plants(DWTPs).Furthermore,our findings demonstrated that advanced treatment technologies such as nanofiltration could more effectively remove OAPs in raw water(up to 87.5%).Therefore,our findings highlighted the importance of selecting appropriate advanced treatment technologies in DWTPs.
基金supported by NSF China(No.61960206002,62020106005,42050105,62061146002)Shanghai Pilot Program for Basic Research–Shanghai Jiao Tong University.
文摘Friendship paradox states that individuals are likely to have fewer friends than their friends do,on average.Despite of its wide existence and appealing applications in real social networks,the mathematical understanding of friendship paradox is very limited.Only few works provide theoretical evidence of single-step and multi-step friendship paradoxes,given that the neighbors of interest are onehop and multi-hop away from the target node.However,they consider non-evolving networks,as opposed to the topology of real social networks that are constantly growing over time.We are thus motivated to present a first look into friendship paradox in evolving networks,where newly added nodes preferentially attach themselves to those with higher degrees.Our analytical verification of both single-step and multistep friendship paradoxes in evolving networks,along with comparison to the non-evolving counterparts,discloses that“friendship paradox is even more paradoxical in evolving networks”,primarily from three aspects:1)we demonstrate a strengthened effect of single-step friendship paradox in evolving networks,with a larger probability(more than 0.8)of a random node’s neighbors having higher average degree than the random node itself;2)we unravel higher effectiveness of multi-step friendship paradox in seeking for influential nodes in evolving networks,as the rate of reaching the max degree node can be improved by a factor of at least Θ(t^(2/3))with t being the network size;3)we empirically verify our findings through both synthetic and real datasets,which suggest high agreements of results and consolidate the reasonability of evolving model for real social networks.
基金supported by Fujian Provincial Natural Science Foundation of China(Nos.2023J01456 and 2021J01626)the National Natural Science Foundation of China(No.41976042)the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University(Nos.SL2022ZD207 and SL2023MS019).
文摘Dissolved organic matter(DOM)is very important in aquatic environments,yet it is challenging to characterize DOM as a highly complex mixture of thousands of molecules,and the knowledge of the effects of different degradation processes on different molecules remains limited.This study examined the distribution and degradation of DOM in a large subtropical river using optical techniques and Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR-MS).At the molecular level,DOM was mainly composed of CHO and lignin-like compounds,which was related to the dominance of forestland in the watershed and resulted in a low biological lability index(MLBL).The modified aromaticity index(AI_(mod)),unsaturation degree(DBE),and humic content(HIX)decreased while MLBL,H/C,absorption spectral slope(S_(275–295)),and biological index(BIX)increased in the estuarine zone due to the increasing autochthonous contribution.Photo-and microbial degradation resulted in a similar decrease in the bulk dissolved organic carbon,while they showed opposite effects on the DOM composition.Photo-degradation removed all fluorescent components and decreased molecular weight,HIX,AI_(mod),DBE,%CHO,%lignin-like,%tannin-like,and%condensed aromatic-like compounds.In contrast,bio-degradation preferentially consumed lipid-like,protein-like,and carbohydrate-like compounds,with increases in%ligninlike,%tannin-like,%condensed aromatic-like compounds,and humic-like fluorescent components.Overall,the application of ultra-high resolutionmass spectrometry provided valuable insights into the composition and behavior of DOM at themolecular level and revealed the contrasting effects of photo-and microbial degradation on different compounds.These results have implications for better understanding the composition and transformation of aquatic DOM.
基金supported by the Shanghai Frontiers Science Center of Polar Science(Grant no.SOO2024-04)the National Natural Science Foundation of China(Grant no.42476264)Lanzhou University(Grant no.lzuibky-2024-oy01).
文摘Antarctic ice-free areas(<0.4%of the continent)represent Antarctic biodiversity oases,where microbial communities sustain terrestrial ecosystem functions.These habitats-encompassing mineral,ornithogenic soils,biological soil crusts,and hypolithic/endolithic niches-are shaped by environmental factors such as pH,organic C/N ratios,moisture,elevation,and trace element availability.The diversity of prokaryotes,eukaryotes,and viruses is lower than in other regions,yet the communities exhibit strong endemism,with site-specific uncultivated lineages.Microorganisms persist through cold and stress adaptations,performing organic carbon decomposition,phototrophy,and oxidation of trace gases to drive carbon and nitrogen cycling in various Antarctic soil habitats.Climate change and anthropogenic disturbances are shifting communities toward copiotrophic generalists,altering elementary cycling and feeding back to climate change.Culturation and genomic-based techniques reveal novel microbial taxa with broad biotechnological potentials on bioactive compounds and cryotolerant enzymes.In summary,this review offers a foundation for exploring Antarctic microbial biodiversity,ecosystem resilience,and the development of novel biotechnologies,while also highlighting the urgent need for effective monitoring and preservation strategies to mitigate the impacts of ongoing environmental changes on Antarctic soil ecosystems.
基金supported by the National Natural Science Foundation of China (Grant Nos.42227901, 42476020)the Scientific Research Fund of the Second Institute of Oceanography, Ministry of Natural Resources (Grant No.QNYC2001)+4 种基金the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University (Project No.SL2023MS020)the Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) (No.311024001)supported by the Natural Environment Research Council grant NE/W005239/1supported by the open fund of the State Key Laboratory of Satellite Ocean Environment Dynamics, Second Institute of Oceanography, MNR (No.QNHX2328)supported by the National Natural Science Foundation of China (Grant No.42222502)。
文摘The inter-model difference in the tropical Pacific SST warming pattern is a big stumbling block for reliable projections of global climate change. Here by conducting an inter-model Empirical Orthogonal Function(EOF) analysis as well as an ocean mixed-layer heat budget, we find that the first two modes of inter-model difference in the SST warming pattern projected by 30 CMIP6 models, explaining more than three-quarters of the total inter-model variance, are both tied to different cloud–radiation feedbacks. The EOF1 mode that captures the different magnitudes of El Ni?o-like warming as well as the largest inter-model variance in the far eastern equatorial Pacific, is likely driven by highly diverse cloud–radiation feedbacks in the east and, to a lesser extent, by differing changes in the oceanic vertical temperature gradient. The EOF2 mode that mainly represents the different magnitudes of SST warming in the western equatorial Pacific, is associated with differing levels of negative cloud–radiation feedback over the central equatorial Pacific through a dynamic air–sea coupled process involving both the Bjerknes feedback and the wind–evaporation–SST feedback.Considering in isolation the robust common model bias of a weak negative cloud–radiation feedback over the central equatorial Pacific, the projected SST warming in the western equatorial Pacific is likely to be smaller than the multi-model ensemble mean, thereby presenting a more weakeened zonal SST gradient than expected, implying the potential for more severe climate extremes under global warming.
基金supported by the National Park Service under Cooperative Agreement Number CA452099007 with the University of Rhode Island
文摘American horseshoe crabs Limulus polyphemus were tracked using acoustic telemetry and traditional tagging in a semi-enclosed bay on Cape Cod （Pleasant Bay）, Massachusetts, USA, to determine seasonal movement patterns. Fifty-five actively spawning females were fitted with transmitters in 2008 and 2009 and were tracked using acoustic telemetry from May 2008 through July 2010. Fil^een crabs with transmitters also had archive depth-temperature tags attached. In addition, over 2000 spawning crabs （males and females） were tagged with US Fish and Wildlife CIdSFWS） button tags over the same period. Ninety-one percent of the crabs with transmitters were detected during this study. In the spring, crabs were primarily located in the northern section of the bay near spawning beaches, whereas in the fall crabs moved towards the deeper portions of the bay, and some may have overwIntered in the bay. There was evidence that a majority （58%-71%） of the females with transmitters spawned in two sequential seasons. One archive tag was recovered resulting in a year-long continuous record of depth and tem- perature data that, when integrated with telemetry data, indicated that the crab overwintered in the bay. The live recapture rate of crabs with USFWS button tags was 11%, with all re-sighted crabs except one observed inside Pleasant Bay. Eighty-three percent of recaptures were found within 2.5kin of the tagging location, and 51% were observed at the same beach where they were tagged. This study provides further evidence that horseshoe crabs in Pleasant Bay may be philopatric to this embayment
基金The National Natural Science Foundation of China under contract Nos 41921006,41890801 and 42076227the Impact and Response of Antarctic Seas to Climate Change,Grant 583 under contract No.IRASCC 1-02-01B。
文摘A thorough understanding of the biogeochemical cycling of trace metals in the ocean is crucial because of the important role these elements play in regulating metabolism in marine biotas and thus,the climate.However,a precise and accurate analysis of trace metals in seawater is difficult because they are present at extremely low concentrations in a high salt matrix.In this study,we report an analytical method for the preconcentration and separation of six trace metals,Fe,Ni,Cu,Zn,Cd and Pb,in seawater using a sea FAST automatic solid-phase extraction device,analysis by a triple quadrupole collision/reaction technique with inductively coupled plasma mass spectrometry(ICP-MS),and quantification by the isotope dilution technique.A small volume(10 m L)of seawater sample was mixed with a multi-element isotope spike and subjected to sea FAST procedures.The preconcentrate solution was then analyzed using the optimized collision/reaction cell mode of ICP-MS,with NH_(3)gas for Fe and Cd with a flow rate of 0.22 m L/min and He for Ni,Cu,Zn and Pb with a flow rate of 4.0 m L/min.The procedure blanks were 130 pmol/L,3.0 pmol/L,6.8 pmol/L,37 pmol/L,0.29 pmol/L and 0.42 pmol/L,for Fe,Ni,Cu,Zn,Cd and Pb,respectively.The method was validated using five reference materials(SLRs-6,SLEW-3,CASS-6,NASS-7 and GEOTRACE-GSC),and our results were consistent with the consensus values.The method was further validated by measuring full-water-column seawater samples from the subtropical Northwest Pacific Ocean,and our results demonstrated good oceanic consistency.
基金supported by the Natural Science Funds for Distinguished Young Scientists of Shandong Province (No.JQ201009)the National Great Project of Scientific and Technical Supporting Programs (No.2011-BAD13B03)+2 种基金the National Natural Science Foundation of China (No.30771661)the Public Science and Technology Research Funds Projects of Ocean, State Oceanic Administration of China (No.200905020)the 111 Project of China Ministry of Education (No.B08049)
文摘The growth, metabolism and physiological response of the sea cucumber, Apostichopus japonicus, were investigated during periods of inactivity. The body weight, oxygen consumption rate (OCR), activities of acidic phosphatase (ACP), alkaline phosphatase (AKP), catalase (CAT) and superoxide dismutase (SOD), and content of heat shock protein 70 (Hsp70) in the body wall and coelomic fluid of A. japonicus were measured during starvation, experimental aestivation and aestivation. The results showed that the body weight of sea cucumber in the three treatments decreased significantly during the experimental period (P < 0.05). The OCR of sea cucumber reduced in starvation and experimental aestivation treatments, but increased gradually in natural aestivation treatment. The activities of ACP and AKP of sea cucumber decreased gradually in all treatments, whereas those of SOD and CAT as well as Hsp70 content decreased in the starvation and experimental aestivation treatments and increased in natural aestivation treatment. The sea cucumber entered a state of aestivation at 24℃. To some extent, the animals in experimental aestivation were different from those in natural aestivation in metabolism and physiological response. These findings suggested that the aestivation mechanism of A. japonicus is complex and may not be attributed to the elevated temperature only.
基金The GASI Project under contract Nos GASI-IPOVAI-01-02 and GASI-02-SCS-YGST2-02the National Natural Science Foundation of China under contract Nos 41776034 and 41706025the Foundation of Guangdong Province for Outstanding Young Teachers in University under contract No.YQ201588
文摘So far, large uncertainties of the Indonesian throughflow(ITF) reside in the eastern Indonesian seas, such as the Maluku Sea and the Halmahera Sea. In this study, the water sources of the Maluku Sea and the Halmahera Sea are diagnosed at seasonal and interannual timescales and at different vertical layers, using the state-of-the-art simulations of the Ocean General Circulation Model(OGCM) for Earth Simulator(OFES). Asian monsoon leaves clear seasonal footprints on the eastern Indonesian seas. Consequently, the subsurface waters(around 24.5σ_θ and at ～150 m) in both the Maluku Sea and the Halmahera Sea stem from the South Pacific(SP) during winter monsoon, but during summer monsoon the Maluku Sea is from the North Pacific(NP), and the Halmahera Sea is a mixture of waters originating from the NP and the SP. The monsoon impact decreases with depth, so that in the Maluku Sea, the intermediate water(around 26.8σ_θ and at ～480 m) is always from the northern Banda Sea and the Halmahera Sea water is mainly from the SP in winter and the Banda Sea in summer. The deep waters(around27.2σ_θ and at ～1 040 m) in both seas are from the SP, with weak seasonal variability. At the interannual timescale,the subsurface water in the Maluku Sea originates from the NP/SP during El Ni?o/La Ni?a, while the subsurface water in the Halmahera Sea always originates from the SP. Similar to the seasonal variability, the intermediate water in Maluku Sea mainly comes from the Banda Sea and the Halmahera Sea always originates from the SP. The deep waters in both seas are from the SP. Our findings are helpful for drawing a comprehensive picture of the water properties in the Indonesian seas and will contribute to a better understanding of the ocean-atmosphere interaction over the maritime continent.
基金The Public Science and Technology Research Funds Projects of Ocean under contract No.201305031
文摘In this study, we construct one 2-dimensional tidal simulation, using an unstructured Finite Volume Coastal Ocean Model （FVCOM）. In the 2-D model, we simulated the tidal turbines through adding additional bottom drag in the element where the tidal turbines reside. The additional bottom drag was calculated from the relationship of the bottom friction dissipation and the rated rotor efficiency of the tidal energy turbine. This study analyzed the effect of the tidal energy turbine to the hydrodynamic environment, and calculated the amount of the extractable tidal energy resource at the Guishan Hangmen Channel, considering the rotor wake effect.
基金The Scientific Research Fund of the Second Institute of OceanographyMNR under contract No.QNYC1801+3 种基金the National Natural Science Foundation of China under contract Nos 91858214,41776053,42025601,42076047,41890811 and 42006072the National Program on Global Change and Air-Sea InteractionMinistry of Natural Resources under contract No.GASI-02-PACDWZP02the Innovation Group Project of Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)under contract No.311020018。
文摘As an interoceanic arc,the Kyushu-Palau Ridge(KPR)is an exceptional place to study the subduction process and related magmatism through its interior velocity structure.However,the crustal structure and its nature of the KPR,especially the southern part with limited seismic data,are still in mystery.In order to unveil the crustal structure of the southern part of the KPR,this study uses deep reflection/refraction seismic data recorded by 24 ocean bottom seismometers to reconstruct a detailed P-wave velocity model along the ridge.Results show strong alongridge variations either on the crustal velocity or the thickness of the KPR.P-wave velocity model is featured with(1)a crustal thickness between 6–12 km,with velocity increases from 4.0 km/s to 7.0 km/s from top to bottom;(2)high gradient(~1 s^(-1))in the upper crust but low one(<0.2 s^(-1))in the lower crust;(3)a slow mantle velocity between 7.2 km/s and 7.6 km/s in the uppermost mantle;and(4)inhomogenous velocity anomalies in the lower crust beneath seamounts.By comparing with the mature arc in the Izu-Bonin-Mariana arc in the east,this study suggests the southern part of KPR is a thicken oceanic crust rather than a typical arc crust.The origin of low velocities in the lower crust and upper mantle may be related with crustal differentiation,which implies advanced crustal evolution from normal oceanic crust to partly thicken oceanic crust.High velocities in the lower crust are related to the difference in magmatism.
基金Supported by the National Key R&D Program of China(No.2018YFC0309903)the China Ocean Mineral Resources R&D Association Project(No.DY135-S2-1-2,5&7)+1 种基金the National Natural Science Foundation of China(Nos.91228101,41872242)the Scientific Research Fund of the Second Institute of Oceanography,Ministry of Natural Resources,China(Nos.JG1410,JG1405,QNYC1701,JZ1901)
文摘Fractional crystallization of basaltic magma at variable depths influences strongly the geochemical compositions of mid-ocean ridge basalts(MORBs),especially at slow-spreading mid-ocean ridges.The Carlsberg Ridge is a typical slow-spreading ridge located in the northwestern Indian Ocean.In this study,we conducted petrological,geochemical and modelling studies of MORBs collected along the Carlsberg Ridge from 57°-65°E to understand the fractional crystallization processes of magma and the controls on variations in MORB geochemistry.Our results show that the mantle sources beneath the Carlsberg Ridge are heterogeneous even on the local scale of a segment;such heterogeneity may be ubiquitous beneath the Carlsberg Ridge.Mantle heterogeneity may be caused by the enriched components resulting in the"DUPAL"anomaly,whereas the effect of pyroxenite on mantle heterogeneity is negligible.The parental melts experienced crystallization of olivine,plagioclase and clinopyroxene prior to eruption,which played a significant role in the major and trace element variations in MORBs from the Carlsberg Ridge.The liquid lines of descent(LLDs),deduced from the forward modelling of three parental magma compositions using the Petrolog3 program at pressures between 1 atm and 10 kbar,demonstrate that clinopyroxene joined the olivine and plagioclase cotectic.The over-enrichment in highly incompatible elements relative to LLDs may be caused by the processes of replenishment-tapping-crystallization in magma chambers.The calculated crystallization pressures suggest that parental magmas beneath the Carlsberg Ridge experienced moderateto high-pressure crystallization and that crystallization beneath the slow-spreading Carlsberg Ridge may start at upper mantle depths.
基金The National Natural Science Foundation of China under contract No.42076135the Foundation of China Ocean Mineral Resources R&D Association under contract Nos DY135-E2-2-06 and DY135-E2-2-03+1 种基金the Project of State Key Laboratory of Satellite Ocean Environment Dynamics,Second Institute of Oceanography,Ministry of Natural Resources,under contract No.SOEDZZ2002the Scientific Research Fund of the Second Institute of Oceanography,Ministry of Natural Resources,under contract No.JG1528
文摘Many seamounts are covered with cobalt-rich ferromanganese crusts,and are increasingly attracting interest for the potential extraction of valuable mineral resources from deep seabed environments.However,the impacts of potential mining activities on the vulnerable seamount ecosystem remain unclear.To enhance the understanding of connectivity in benthic invertebrate populations in the Northwest Pacific,several seamounts were surveyed and biological samples collected.In the present study,the ophiuroid species Ophioplinthaca defensor is reported for the first time from four deep seamounts in the Northwest Pacific,and described,providing more detailed morphological diagnosis characters.To assess the population structure of the species between and within seamounts,two mitochondrial markers(COI and 16 S)were sequenced.In total,20 haplotypes from 32 COI sequences and 8 haplotypes from 3716 S sequences were recovered.The star-shaped TCS networks and nonsignificant pairwise population differences reveal the absence of distinct population structures between and within seamounts.In addition,the O.defensor population seemed to have undergone a demographic expansion in history.This is the first study on the genetic population structure of a benthic invertebrate from seamounts in the Northwest Pacific,and this results suggest a potentially high,long distance dispersal capacity in O.defensor between seamounts,which could inform the development of the Regional Environmental Management Plans for the cobalt-rich crust seamounts in the area.
基金The National Natural Science Foundation of China under contract No.41776034the Special Project of Global Change and Air and Sea Interaction under contract Nos GASI-IPOVAI-01-02 and GASI-02-SCS-YGST2-02the Guangdong Province First-Class Discipline Plan under contract Nos CYL231419012 and 231819002
文摘Using the mesoscale eddy trajectory atlas product derived from satellite altimeter data from 1993 to 2016,this study analyzes statistical characteristics and seasonal variability of mesoscale eddies in the Banda Sea of the Indonesian seas.The results show that there were 147 mesoscale eddies that occurred in the Banda Sea,of which 137 eddies were locally generated and 10 originated from outside.The total numbers of cyclonic eddies(CEs,clockwise)and anticyclonic eddies(AEs,anticlockwise)are 76 and 71,respectively.Seasonally,the number of CEs(AEs)is twice larger than the number of AEs(CEs)in winter(summer).In winter,CEs are distributed in the southern and AEs in the northern basins,respectively,but the opposite thing occurs in summer,i.e.,the polarities of mesoscale eddies observed at the same location reverse seasonally.The mechanisms of polarity distribution reversal(PDR)of mesoscale eddies are examined with reanalysis data of ocean currents and winds.The results indicate that the basin-scale vorticity,wind stress curl,and the meridional shear of zonal current reverse seasonally,which are favorable to the PDR of mesoscale eddies.The possible generation mechanisms of mesoscale eddies include direct wind forcing,barotropic and baroclinic instabilities,of which the direct wind forcing should play the dominant role.
基金The National Basic Research Program of China under contract Nos 2014CB441500 and 2014CB441506the National Natural Science Fundation of China under contract No. 41706014the Shanghai Jiao Tong University Fund under contract No. 2019 SJTU-HKUST.
文摘The continental slope in the northern South China Sea(SCS) is rich in mesoscale eddies which play an important role in transport and retention of nutrients and biota. In this study, we investigate the statistical properties of eddy distributions and propagation in a period of 24 years between 1993 and 2016 by using the altimeter data. A total of 147 eddies are found in the continental slope region(CSR), including 70 cyclonic eddies(CEs) and 77 anticyclonic eddies(ACEs). For those eddies that appear in the CSR, the surrounding areas of Dongsha Islands(DS) and southwest of Taiwan(SWT) are considered as the primary sources, where eddies generated contribute more than 60% of the total. According to the spatial distribution of eddy relative vorticity, eddies are weakening as propagating westward. Although both CEs and ACEs roughly propagate along the slope isobaths, there are discrepancies between CEs and ACEs. The ACEs move slightly faster in the zonal direction, while the CEs tend to cross the isobaths with large bottom depth change. The ACEs generally move further into the basin areas after leaving the CSR while CEs remain around the CSR. The eddy propagation on the continental slope is likely to be associated with mean flow at a certain degree because the eddy trajectories have notable seasonal signals that are consistent with the seasonal cycle of geostrophic current. The results indicate that the eddy translation speed is statistically consistent with geostrophic velocity in both magnitude and direction.
